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1. 发明申请

WO2012053826A1 THICK LAYER POLYIMIDE METAL CLAD LAMINATE 审中-公开
标题翻译：厚层聚酰亚胺金属层压板
公开(公告)号：WO2012053826A1
公开(公告)日：2012-04-26
申请号：PCT/KR2011/007799
申请日：2011-10-19
申请人： SK INNOVATION CO.,LTD. , KIM, Ho Sub , KIM, Dae Nyoun , JUNG, Seung Hoon , JO, Byoung Wook , KIM, Young Do , CHOI, Weon Jung
发明人： KIM, Ho Sub , KIM, Dae Nyoun , JUNG, Seung Hoon , JO, Byoung Wook , KIM, Young Do , CHOI, Weon Jung
IPC分类号： B32B15/08 , B32B37/00
CPC分类号： B32B37/10 , B32B7/02 , B32B15/08 , B32B15/088 , B32B27/281 , B32B2250/03 , B32B2250/40 , B32B2307/206 , B32B2309/02 , B32B2309/12 , B32B2311/00 , B32B2379/08 , B32B2457/00
摘要： Provided is a thick layer polyimide metal clad laminate, and more particularly, a thick layer polyimide metal clad laminate for producing a product with excellent process stability and superior dimensional stability. Specifically, the present invention is directed to providing a thick layer polyimide metal clad laminate, in which a polyimide laminate and a metal foil, which is on one side or both sides of the polyimide laminate, are attached by a lamination process, wherein the polyimide laminate includes a polyimide film and a thermoplastic polyimide layer formed on one side or both sides of the polyimide film, the polyimide film having an elongation of 30% or less, and a tensile modulus of 3GPa or more, which is measured by IPC-TM-650 (2.4.19) method, and a coefficient of thermal linear expansion (CTE) of 5 to 30ppm/℃, which is calculated from 100 to 250℃.
摘要翻译：提供了一种厚层聚酰亚胺金属包覆层压体，更具体地，涉及一种制造具有优异的工艺稳定性和优异的尺寸稳定性的产品的厚层聚酰亚胺金属包覆层压板。具体地说，本发明涉及提供一层叠层聚酰亚胺金属包覆层压板，其中聚酰亚胺层叠体的一面或两面上的聚酰亚胺层叠体和金属箔通过层压方法附着，其中聚酰亚胺层压体包括聚酰亚胺膜和形成在聚酰亚胺膜的一侧或两侧的热塑性聚酰亚胺层，聚酰亚胺膜的伸长率为30％以下，拉伸弹性模量为3GPa以上，通过IPC-TM -650（2.4.19），热线膨胀系数（CTE）为5〜30ppm /□，由100〜250？计算。

2. 发明申请

WO2014098495A1 MULTI-LAYER FLEXIBLE METAL-CLAD LAMINATE AND MANUFACTURING METHOD THEREOF 审中-公开
标题翻译：多层柔性金属层压板及其制造方法
公开(公告)号：WO2014098495A1
公开(公告)日：2014-06-26
申请号：PCT/KR2013/011871
申请日：2013-12-19
申请人： SK INNOVATION CO., LTD.
发明人： KIM, Ho Sub , JO, Byoung Wook , KIM, Young Do , CHOI, Weon Jung , KIM, Dae Nyoun , KOOK, Seung Jeong
IPC分类号： B32B15/08 , B32B27/34 , C08G73/10 , H05K1/03
CPC分类号： H05K1/036 , B32B15/08 , B32B15/20 , B32B27/08 , B32B27/281 , B32B2250/40 , B32B2307/538 , B32B2457/08 , C09D179/08 , H05K3/022 , H05K2201/0108 , H05K2201/0154 , H05K2201/0195 , Y10T156/10 , Y10T428/24355
摘要： Provided are a multi-layer flexible metal-clad laminate, and a manufacturing method thereof, and more particularly, a multi-layer flexible metal-clad laminate in which at the time of manufacturing a multi-layer polyimide film on a surface of a metal foil having a predetermined surface roughness value (Rz and Ra) and having roughening particles having a predetermined size or less attached thereon, a multi-coating method is used to form each polyimide mixed layer, such that a light reflection on a surface of the polyimide film and a light reflection generated at an interlayer interface of the polyimide in the multi-layer polyimide film are decreased to have an improved light transmittance of a polyimide film after the metal foil is removed, and a manufacturing method thereof.
摘要翻译：本发明提供一种多层柔性覆金属层压板及其制造方法，更具体地，涉及在金属表面上制造多层聚酰亚胺膜时的多层柔性金属包覆层压板具有预定表面粗糙度值（Rz和Ra）并具有预定尺寸或更小的粗糙颗粒的箔，使用多次涂覆法形成每个聚酰亚胺混合层，使得在聚酰亚胺表面上的光反射在多层聚酰亚胺膜中的聚酰亚胺的层间界面处产生的膜和光反射减少，从而在去除金属箔之后聚酰亚胺膜的透光率提高，及其制造方法。

3. 发明申请

WO2009054577A1 METHOD FOR PREPARATION OF CROSS-CONDENSED COMPOUND BETWEEN AMINO ACIDS AND AMINOALKYLSILANE HAVING ALKOXY GROUPS USING MICROWAVE 审中-公开
标题翻译：使用微波制备氨基酸与氨基酸组合的氨基酸组合物之间的交联化合物的方法
公开(公告)号：WO2009054577A1
公开(公告)日：2009-04-30
申请号：PCT/KR2008/001058
申请日：2008-02-22
申请人： INHA-INDUSTRY PARTNERSHIP INSTITUTE , LEE, Ik Mo , LEE, Dong Hwan , KIM, Ho Sub , PARK, Sang Eon
发明人： LEE, Ik Mo , LEE, Dong Hwan , KIM, Ho Sub , PARK, Sang Eon
IPC分类号： C07F7/18
CPC分类号： C07F7/1892
摘要： The present invention provides a method of preparing a cross -condensed compound of an amino-acid derivative and (aminoalkyl) trialkoxysilane using microwave, including: irradiating and heating an amino-acid derivative and (aminoalkyl) trialkoxysilane in a microwave reactor to obtain a reaction product (step 1); and refining the reaction product obtained in the step 1 by removing an unreacted solid material from the reaction product and then leaving the reaction product at room temperature under vacuum to remove excess (aminoalkyl) trialkoxysilane therefrom (step 2). According to the method, since a cross -condensation reaction is performed using microwave, unlike a conventional condensation reaction, economic efficiency is increased due to no catalyst, short reaction time and no solvent. Further, the yield and selectivity of products is increased, and the condensation reaction can be environment -friendly performed because a solvent which can badly influence the environment may not be used.
摘要翻译：本发明提供了使用微波制备氨基酸衍生物和（氨基烷基）三烷氧基硅烷的交联缩合化合物的方法，包括：在微波反应器中照射和加热氨基酸衍生物和（氨基烷基）三烷氧基硅烷以获得反应产品（步骤1）; 并通过从反应产物中除去未反应的固体物质，然后在真空下将反应产物在室温下离心以从其中除去过量的（氨基烷基）三烷氧基硅烷，从而精制步骤1中获得的反应产物（步骤2）。根据该方法，由于使用微波进行交联缩合反应，与常规的缩合反应不同，由于没有催化剂，反应时间短，无溶剂，经济效率提高。此外，产物的收率和选择性增加，并且缩合反应可以是环境友好的，因为可能不能使用可能严重影响环境的溶剂。

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