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1. 发明申请

WO2011129519A3 BLOCK AND GRAFT COPOLYMERS OF POLY (ALKYLENE CARBONATE) AND VARIOUS POLYMERS 审中-公开
标题翻译：聚碳酸亚乙酯和各种聚合物的嵌段共聚物及接枝共聚物
公开(公告)号：WO2011129519A3
公开(公告)日：2011-12-29
申请号：PCT/KR2011000504
申请日：2011-01-25
申请人： SK INNOVATION CO LTD , JEONG JI SU , NA SUNG JAE , SUDEVAN SUJITH , OK MYUNG AHN , HAN YONG GYU , CHUNG KWANG JIN , LEE BUN YEOUL , CYRIAC ANISH , LEE SANG HWAN
发明人： JEONG JI SU , NA SUNG JAE , SUDEVAN SUJITH , OK MYUNG AHN , HAN YONG GYU , CHUNG KWANG JIN , LEE BUN YEOUL , CYRIAC ANISH , LEE SANG HWAN
IPC分类号： C08G64/32 , C08F290/06 , C08F290/14
CPC分类号： C08G81/027 , C08G63/64 , C08G64/18 , C08G64/183 , C08G64/186 , C08G64/34
摘要： Provided is preparation of poly(alkylene carbonate) by alternating copolymerization of carbon dioxide and epoxide. To be specific, provided are a method for preparing block or graft copolymers of the polymer compound and poly(alkylene carbonate) by alternating-copolymerization of an epoxide compound and carbon dioxide by using a metal (?) compound prepared from salen-type ligand with a quaternary ammonium salt as a catalyst in the presence of a polymer compound having a functional group of hydroxyl or carboxylic acid, and block or graft copolymers prepared by the method.
摘要翻译：提供了通过二氧化碳和环氧化物的交替共聚制备聚（亚烷基碳酸酯）。具体而言，提供了通过使用由salen型配体制备的金属（α）化合物与环氧化合物和二氧化碳交替共聚而制备聚合物化合物和聚（亚烷基碳酸酯）的嵌段或接枝共聚物的方法，在具有羟基或羧酸官能团的聚合物化合物存在下作为催化剂的季铵盐，以及通过该方法制备的嵌段或接枝共聚物。

2. 发明申请

WO2011105846A3 CATALYTIC SYSTEM OF NITRATE ANIONS FOR CARBON DIOXIDE/EPOXIDE COPOLYMERIZATION 审中-公开
标题翻译：二氧化碳/环氧化物共聚硝酸盐阴离子催化体系
公开(公告)号：WO2011105846A3
公开(公告)日：2012-02-02
申请号：PCT/KR2011001324
申请日：2011-02-25
申请人： SK ENERGY CO LTD , JEONG JI SU , SUDEVAN SUJITH , OK MYUNG AHN , NA SUNG JAE , HAN YONG GYU , CHUNG KWANG JIN , LEE BUN YEOUL , KODIYAN VERGHESE JOB
发明人： JEONG JI SU , SUDEVAN SUJITH , OK MYUNG AHN , NA SUNG JAE , HAN YONG GYU , CHUNG KWANG JIN , LEE BUN YEOUL , KODIYAN VERGHESE JOB
IPC分类号： C07F15/06 , B01J31/18 , C08G64/20 , C08G64/32
CPC分类号： C07C251/24 , C07C2601/14 , C07F15/065 , C08G65/2603 , C08G65/266
摘要： This invention relates to a Salen type ligand including three or more quaternary ammonium salts of nitrate anions, to a trivalent metal complex compound prepared from this ligand and a method of preparing the same, to a method of preparing polycarbonate by copolymerizing an epoxide compound and carbon dioxide using the complex compound as a catalyst, and to a method of separating and collecting the catalyst from the copolymer after copolymerization. This catalyst used to copolymerize an epoxide compound and carbon dioxide can be more simply prepared, and has lower catalyst preparation and recovery costs, and higher activity, compared to conventional catalysts.
摘要翻译：本发明涉及包含三种或更多种硝酸根阴离子的季铵盐的Salen型配体，由该配体制备的三价金属配位化合物及其制备方法，涉及通过使环氧化合物和碳共聚制备聚碳酸酯的方法使用配位化合物作为催化剂的二氧化碳，以及共聚后从共聚物中分离和收集催化剂的方法。与常规催化剂相比，用于共聚环氧化合物和二氧化碳的催化剂可以更简单地制备，并且具有较低的催化剂制备和回收成本，以及更高的活性。

3. 发明申请

WO2011028056A2 CONTINUOUS PROCESS FOR MANUFACTURING ALIPHATIC POLYCARBONATE FROM CARBON DIOXIDE AND EPOXIDE COMPOUNDS 审中-公开
标题翻译：从二氧化碳和环氧化合物制造二氧化碳的连续工艺
公开(公告)号：WO2011028056A2
公开(公告)日：2011-03-10
申请号：PCT/KR2010005996
申请日：2010-09-03
申请人： SK INNOVATION CO LTD , CHANG BYOUNG MU , MOON GWANG BIN , OK MYUNG AHN , JEONG JI SU , YOO JI EUN , CHOI SUN , KIM HONG DAE , SUJITH SUDEVAN , SHIN DAE HO , LEE JAE HO , LEE SEONG JUN , KIM GYUNG ROK , PARK MIN GYOO , LEE JANG JAE
发明人： CHANG BYOUNG MU , MOON GWANG BIN , OK MYUNG AHN , JEONG JI SU , YOO JI EUN , CHOI SUN , KIM HONG DAE , SUJITH SUDEVAN , SHIN DAE HO , LEE JAE HO , LEE SEONG JUN , KIM GYUNG ROK , PARK MIN GYOO , LEE JANG JAE
IPC分类号： C08G64/34 , C08G64/20 , C08G64/32 , C08G64/40
CPC分类号： C08G64/34
摘要： Disclosed is a continuous process for manufacturing aliphatic polycarbonate by polymerizing carbon dioxide and one or more epoxide compound in the presence of catalyst, in which carbon dioxide, one or more epoxide compound, and the catalyst are continuously supplied to polymerization reactor to produce aliphatic polycarbonate, separate unreacted carbon dioxide and epoxide compound and recycle them as raw materials.
摘要翻译：公开了一种在催化剂存在下使二氧化碳和一种或多种环氧化合物聚合制造脂肪族聚碳酸酯的连续方法，其中将二氧化碳，一种或多种环氧化合物和催化剂连续地供给到聚合反应器中以制备脂族聚碳酸酯，分离未反应的二氧化碳和环氧化合物，并将其回收为原料。

4. 发明申请

WO2012033375A3 PREPARATION OF POLY(ALKYLENE CARBONATE) CONTAINING CROSS-LINKED HIGH MOLECULAR WEIGHT CHAINS 审中-公开
标题翻译：含有交联高分子量链的聚碳酸亚乙酯的制备
公开(公告)号：WO2012033375A3
公开(公告)日：2012-06-21
申请号：PCT/KR2011006684
申请日：2011-09-08
申请人： SK INNOVATION CO LTD
发明人： JEONG JI SU , NA SUNG JAE , SUJITH SUDEVAN , OK MYUNG AHN , HAN YONG GYU , CHUNG KWANG JIN , LEE BUN YEOUL , ANISH CYRIAC
IPC分类号： C08G64/34 , B01J31/34 , C08G64/14
CPC分类号： C08G64/34 , C08G64/0216
摘要： Provided is preparation of poly(alkylene carbonate) through alternating copolymerization of carbon dioxide and epoxide. According to the disclosure, by introducing a diepoxide compound to alternating copolymerization of carbon dioxide and epoxide compound using a metal(III) prepared with salen-type ligands containing quaternary ammonium salt as a catalyst, some of the polymer chains may be cross-linked to thus increase an average molecular weight of the copolymer and extend a distribution of molecular weight. A resin prepared according to this method may have high mechanical strength and rheological advantages.
摘要翻译：通过二氧化碳和环氧化物的交替共聚制备聚（亚烷基碳酸酯）。根据本发明，通过将二环氧化物化合物引入二氧化碳与环氧化物化合物的交替共聚合中，使用以含季铵盐的salen型配体作为催化剂制备的金属（III），一些聚合物链可交联成从而增加共聚物的平均分子量并延长分子量的分布。根据该方法制备的树脂可具有高机械强度和流变学优点。

5. 发明申请

WO2012121508A3 METHOD FOR PREPARING CARBON DIOXIDE/EPOXIDE COPOLYMERS CONTAINING ETHER LINKAGES 审中-公开
标题翻译：制备含二氧化碳/环氧化合物共聚物的方法
公开(公告)号：WO2012121508A3
公开(公告)日：2012-10-26
申请号：PCT/KR2012001528
申请日：2012-02-29
申请人： SK INNOVATION CO LTD , SK GLOBAL CHEMICAL CO LTD
发明人： JEONG JI SU , NA SUNG JAE , SUDEVAN SUJITH , OK MYUNG AHN , HAN YONG GYU , CHUNG KWANG JIN , LEE BUN YEOUL , JOBI KODIYAN VARGHESE
IPC分类号： C08G64/20 , B01J31/18 , B01J31/22 , C08G64/34 , C08L69/00
CPC分类号： C08G64/34 , C08G65/2603 , C08G65/2663
摘要： Provided is a method for preparing poly(alkylene carbonate) containing ether linkages, by the copolymerization of an epoxy compound and carbon dioxide, with a trivalent metal complex prepared from a salen type ligand containing a quaternary ammonium salt, and a double metal cyanide (DMC) catalyst together. The amount of ether linkages can be controlled by regulating the weight ratio of two catalysts and the carbon dioxide pressure.
摘要翻译：提供了通过环氧化合物和二氧化碳的共聚合制备由含有季铵盐的salen型配体和双金属氰化物（DMC）制备的三价金属络合物制备含有醚键的聚（碳酸亚烷基酯）的方法）催化剂。醚键的量可以通过调节两种催化剂的重量比和二氧化碳压力来控制。

6. 发明申请

WO2012134166A3 POLYMER ELECTROLYTE COMPOSITION AND DYE-SENSITIZED SOLAR CELL CONTAINING THE SAME 审中-公开
标题翻译：聚合物电解质组合物和含有它的透明的太阳能电池
公开(公告)号：WO2012134166A3
公开(公告)日：2013-01-03
申请号：PCT/KR2012002274
申请日：2012-03-28
申请人： SK INNOVATION CO LTD , SK GLOBAL CHEMICAL CO LTD
发明人： HAN YONG GYU , SUDEVAN SUJITH , OK MYUNG AHN , JEONG JI SU , NA SUNG JAE , CHUNG KWANG JIN , KIM DONG WON , CHOI YEON JEONG
IPC分类号： C08L69/00 , C08G64/02 , C08K3/20 , H01L31/042
CPC分类号： H01B1/124 , C08K3/16 , C08K3/20 , C08K3/22 , C08K3/36 , H01G9/2009 , Y02E10/542 , C08L69/00
摘要： Provided are a polymer electrolyte composition, a gel-type polymer electrolyte obtained by mixing the same at normal temperature, and a dye-sensitized solar cell containing the electrolyte. Since the poly(alkylene carbonate)-based polymer is included, a crosslinking process by radiation of heat or UV is not required when the polymer electrolyte is manufactured, such that a manufacturing process is simple. Accordingly, the polymer electrolyte is useful for mass production of a solar cell and maintained in a uniform state without a phase separation between two components due to excellent affinity between the polymer and the organic solvent included in the electrolyte, and has excellent electrode-electrolyte interface property in the solar cell due to an adhesive property of the gelled polymer electrolyte. A dye-sensitized solar cell containing the same as an electrolyte is capable of being used over a long period of time and maintaining stable conversion efficiency at a predetermined level or more.
摘要翻译：提供了一种聚合物电解质组合物，通常在常温下将其混合而获得的凝胶型聚合物电解质和含有电解质的染料敏化太阳能电池。由于包含聚（碳酸亚烷基碳酸酯）基聚合物，所以当制造聚合物电解质时，不需要通过辐射热或UV的交联过程，使得制造过程简单。因此，由于聚合物与包含在电解质中的有机溶剂之间的亲和性优异，聚合物电解质可用于大量生产太阳能电池并保持在均匀状态，而不会由于两种组分之间的相分离，并且具有优异的电极 - 电解质界面由于胶凝聚合物电解质的粘合性，在太阳能电池中的性能。包含与电解质相同的染料敏化太阳能电池能够长时间使用并且将预定水平或更高的转换效率保持在稳定状态。

7. 发明申请

WO2012108696A3 FLAME-RETARDING CARBON DIOXIDE/EPOXIDE COPOLYMER AND METHOD FOR PREPARING THE SAME 审中-公开
标题翻译：阻燃二氧化碳/环氧化合物共聚物及其制备方法
公开(公告)号：WO2012108696A3
公开(公告)日：2012-12-13
申请号：PCT/KR2012000951
申请日：2012-02-09
申请人： SK INNOVATION CO LTD
发明人： JEONG JI SU , NA SUNG JAE , SUDEVAN SUJITH , OK MYUNG AHN , HAN YONG GYU , CHUNG KWANG JIN , LEE BUNYEOUL , CYRIAC ANISH , LEE SANG HWAN
IPC分类号： C08G64/34 , B01J31/18 , C08L69/00 , C09K21/14
CPC分类号： C08G64/34 , C08G64/0208 , C08G64/0258 , C08G64/403 , C08G64/406 , C08G65/2603
摘要： There is provided a method for preparing a low-molecular weight poly(alkylene carbonate) of which the molecular weight and chain shape are precisely controlled, by introducing a phosphorous compound having a hydroxyl group as a chain transfer agent in order to regulate the molecular weight, in alternating copolymerizing an epoxide compound and carbon dioxide by using trivalent metal complex prepared from a Salen type ligand containing a quaternary ammonium salt, and a polymer prepared by the method. Since poly(alkylene carbonate) prepared according to the present invention includes a phosphate or phosphonate group in the polymer chain, it has flame-retarding property.
摘要翻译：提供了通过引入具有羟基的磷化合物作为链转移剂来制备其分子量和链形状被精确控制的低分子量聚（碳酸亚烷基酯）的方法，以调节分子量通过使用由含有季铵盐的Salen型配体制备的三价金属络合物和通过该方法制备的聚合物来交替共聚环氧化合物和二氧化碳。由于根据本发明制备的聚（碳酸亚烷基酯）在聚合物链中包含磷酸酯或膦酸酯基，因此具有阻燃性。

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