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1. 发明申请

WO2007090884A2 FLUID CATALYTIC CRACKING PROCESS 审中-公开
标题翻译：流体催化裂化工艺
公开(公告)号：WO2007090884A2
公开(公告)日：2007-08-16
申请号：PCT/EP2007/051262
申请日：2007-02-09
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DIERICKX, Jan Lodewijk Maria , HADJIGEORGE, Georghios Agamemnonons , SCHAVERIEN, Colin John
发明人： DIERICKX, Jan Lodewijk Maria , HADJIGEORGE, Georghios Agamemnonons , SCHAVERIEN, Colin John
IPC分类号： C10G3/00 , C10G11/05 , C10G11/18
CPC分类号： C10G3/48 , C10G3/49 , C10G3/62 , C10G11/05 , C10G11/18 , C10G2300/1014 , C10G2300/1022 , C10G2400/02 , Y02P30/20
摘要： A fluid catalytic cracking process for the preparation of cracked products by contacting in a reactor a hydrocarbon feedstock with a cracking catalyst, wherein the hydrocarbon feedstock comprises a paraffinic feedstock and triglycerides.
摘要翻译：通过在反应器中使烃原料与裂化催化剂接触来制备裂化产物的流化催化裂化方法，其中所述烃原料包含链烷烃原料和甘油三酯。

2. 发明申请

WO2005003067A3 PROCESS TO PREPARE BASE OILS FROM A FISHER-TROPSCH SYNTHESIS PRODUCT 审中-公开
公开(公告)号：WO2005003067A3
公开(公告)日：2005-01-13
申请号：PCT/EP2004/051349
申请日：2004-07-02
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , ADAMS, Nicholas james , CRAMWINCKEL, Michiel , DIERICKX, Jan Lodewijk Maria
发明人： ADAMS, Nicholas james , CRAMWINCKEL, Michiel , DIERICKX, Jan Lodewijk Maria
IPC分类号： C10G9/00
摘要： Process to prepare base oils from a Fischer-Tropsch synthesis product by (a) separating the Fischer-Tropsch synthesis product into a fraction (I) boiling in the middle distillate range and below, a heavy ends fraction (iii) and an intermediate base oil precursor fraction (ii) boiling between fraction (I) and fraction (iii), (b) subjecting the base oil precursor fraction (ii) to a catalytic hydroisomerisation and catalytic dewaxing process to yield one or more base oil grades, (c) subjecting the heavy ends fraction (iii) to a conversion step to yield a fraction (iv) boiling below the heavy ends fraction (iii9 and (d) subjecting the high boiling fraction (v) of fraction (iv) to a catalytic hydroisomerisation and catalytic dewaxing process to yield one or more base oil grades.

3. 发明申请

WO2007113178A1 PROCESS FOR THE PREPARATION OF PROPYLENE AND ETHYLENE FROM A FISCHER-TROPSCH SYNTHESIS PRODUCT 审中-公开
标题翻译：由FISCHER-TROPSCH合成产品制备丙烯和乙烯的方法
公开(公告)号：WO2007113178A1
公开(公告)日：2007-10-11
申请号：PCT/EP2007/052948
申请日：2007-03-28
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DIERICKX, Jan Lodewijk Maria
发明人： DIERICKX, Jan Lodewijk Maria
IPC分类号： C10G9/14 , C07C4/02 , C10G9/16
CPC分类号： C07C4/02 , C10G2400/20 , C07C11/04 , C07C11/06
摘要： Process for the preparation of propylene and ethylene, comprising subjecting a gaseous mixture of a dilution gas and a paraffinic feedstock boiling in the gas oil range and having an iso paraffin to normal paraffin ratio of between 2 and 5 to a thermal conversion step.
摘要翻译：制备丙烯和乙烯的方法，包括将稀释气体和在粗柴油中沸腾的具有异构链烷烃的石蜡原料的气体混合物与正常石蜡比率在2至5之间经受热转化步骤。

4. 发明申请

WO2006067174A1 PROCESS TO PREPARE TWO ISO PARAFFINIC PRODUCTS FROM A FISHER-TROPSCH DERIVED FEED 审中-公开
标题翻译：从渔船出货的饲料中制备两种ISO辅助产品的方法
公开(公告)号：WO2006067174A1
公开(公告)日：2006-06-29
申请号：PCT/EP2005/057012
申请日：2005-12-21
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , CRAMWINCKEL, Michiel , DIERICKX, Jan Lodewijk Maria , HOEK, Arend
发明人： CRAMWINCKEL, Michiel , DIERICKX, Jan Lodewijk Maria , HOEK, Arend
IPC分类号： C10G65/14
CPC分类号： C10G65/14
摘要： Process to prepare an iso-paraffinic product having a carbon range of Cx to Cy and a iso-paraffinic product having a carbon range of Cn to Cm from a Fischer-Tropsch derived feed by performing the following steps, (a) obtaining from the Fischer-Tropsch derived feed at least two different compositions (i) and (ii), which composition (i) has a greater fraction of compounds in the carbon range of C2n to C2m than composition (ii) and composition (ii) has a greater content of C2x to C2y than composition (i); (b) performing separately a hydroconversion/ hydroisomerisation step on feed compositions (i) and (ii) and isolating from the thus obtained effluents the iso-paraffinic product having a carbon range of Cx to Cy and the iso-paraffinic product having a carbon range of Cn to Cm.
摘要翻译：通过进行以下步骤从费 - 托衍生的原料制备碳范围为Cx至Cy的碳范围为Cn至Cm的异链烷烃产物的方法，（a）从Fischer 至少两种不同的组合物（ⅰ）和（ⅱ）组合物（ⅰ）在C2n至C2m的碳范围内比化合物（ⅱ）和组合物（ⅱ）具有更大的化合物比例，具有更大的含量比组成（i）的C2x至C2y; （b）分别在进料组合物（i）和（ii）上分别进行加氢转化/加氢异构化步骤，并从由此获得的流出物中分离出具有碳范围为Cx至Cy的异链烷烃产物和具有碳范围的异链烷烃产物的Cn到Cm。

5. 发明申请

WO2008068305A2 PROCESS FOR PRODUCING A PURIFIED SYNTHESIS GAS STREAM 审中-公开
标题翻译：生产纯化合成气流的方法
公开(公告)号：WO2008068305A2
公开(公告)日：2008-06-12
申请号：PCT/EP2007/063413
申请日：2007-12-06
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DIERICKX, Jan Lodewijk Maria , HESSELINK, Maarten , SMIT, Cornelis Jacobus
发明人： DIERICKX, Jan Lodewijk Maria , HESSELINK, Maarten , SMIT, Cornelis Jacobus
IPC分类号： B01D53/86 , B01D53/14 , B01D53/04 , C01B3/50
CPC分类号： B01D53/04 , B01D53/14 , B01D53/864 , B01D2253/102 , B01D2253/112 , B01D2256/16 , B01D2257/304 , B01D2257/308 , B01D2257/406 , B01D2257/408 , B01D2257/504 , B01D2257/60 , C01B3/12 , C01B3/52 , C01B3/56 , C01B2203/0415 , C01B2203/0465 , C01B2203/0475 , C01B2203/0485 , C10J3/00 , C10J2300/1656 , C10K1/002 , C10K1/003 , C10K1/004 , C10K1/005 , C10K1/006 , C10K1/007 , C10K1/02 , C10K1/16 , C10K1/165 , C10K1/20 , C10K1/32 , C10K3/04 , Y02C10/06 , Y02C10/08 , Y02P20/152 , Y02P20/52
摘要： A process for producing a purified synthesis gas stream from a feed synthesis gas stream comprising hydrogen sulphide, carbonyl sulphide, carbon dioxide, hydrogen cyanide and ammonia besides the main constituents carbon monoxide and hydrogen, the process comprising the steps of : (a) contacting one part of the feed synthesis gas stream with methanol at low temperature and at elevated pressure to remove hydrogen sulphide, carbonyl sulphide, carbon dioxide, hydrogen cyanide and ammonia, thereby obtaining methanol enriched in these compounds and a synthesis gas stream depleted in these compounds; (b) contacting another part of the feed synthesis gas stream with a water gas shift catalyst in the presence of water to react at least part of the carbon monoxide with water, thereby obtaining a shifted synthesis gas stream enriched in hydrogen and in carbon dioxide; (c) contacting the shifted synthesis gas stream with methanol at low temperature and at elevated pressure to remove carbon dioxide, hydrogen sulphide, carbonyl sulphide and ammonia, thereby obtaining solvent enriched in these compounds and a gas stream mainly comprising hydrogen and depleted in carbon dioxide; (d) contacting the synthesis gas stream obtained in step (a) and optionally the gas stream obtained in step (c) with a first solid adsorbent comprising sulphur-impregnated activated carbon and/or activated carbon to remove metals and/or metal carbonyl compounds to obtain a synthesis gas stream depleted in metals and/or metal carbonyl compounds; (e) contacting the synthesis gas stream depleted in metals and/or metal carbonyl compounds in the presence of water with a second solid adsorbent comprising one or more metals or oxides of the metals or combinations thereof, wherein the metals are selected from the group of Ag, Sn, Mo, Fe and Zn at elevated temperature to obtain the purified synthesis gas stream
摘要翻译：一种从包含硫化氢，硫化氢，二氧化碳，氰化氢和氨的原料合成气流中生产纯化的合成气流的方法，除了主要成分一氧化碳和氢之外，该方法包括以下步骤：（a）使一种一部分原料合成气流与甲醇在低温和升高的压力下，以除去硫化氢，羰基硫化物，二氧化碳，氰化氢和氨，从而获得富含这些化合物的甲醇和这些化合物中的合成气流; （b）在水存在下使进料合成气流的另一部分与水煤气变换催化剂接触，使至少部分一氧化碳与水反应，从而获得富含氢气和二氧化碳的经转换的合成气流; （c）在低温和升高的压力下使转移的合成气流与甲醇接触以除去二氧化碳，硫化氢，硫化羰和氨，从而获得富含这些化合物的溶剂和主要包含氢气和二氧化碳的气流 ; （d）将步骤（a）中获得的合成气流和任选的步骤（c）中获得的气流与包含浸硫活性炭和/或活性炭的第一固体吸附剂接触以除去金属和/或金属羰基化合物以获得贫化金属和/或金属羰基化合物的合成气流; （e）在水存在下将贫的金属和/或金属羰基化合物的合成气流与包含一种或多种金属或金属的氧化物或其组合的第二固体吸附剂接触，其中金属选自 Ag，Sn，Mo，Fe和Zn，以获得纯化的合成气流

6. 发明申请

WO2005118747A1 PROCESS TO PRODUCE A GAS OIL BY CATALYTIC CRACKING OF A FISHER-TROPSCH PRODUCT 审中-公开
标题翻译：通过渔具运输产品的催化裂化生产气体油的方法
公开(公告)号：WO2005118747A1
公开(公告)日：2005-12-15
申请号：PCT/EP2005/052391
申请日：2005-05-25
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DIERICKX, Jan Lodewijk Maria
发明人： DIERICKX, Jan Lodewijk Maria
IPC分类号： C10G2/00
CPC分类号： C10G2/332 , C10G11/00 , C10G11/05 , C10G11/18 , C10G2300/1022 , C10G2300/1059 , C10G2300/4006 , C10G2400/06
摘要： Process to prepare a gas oil, by (a) isolating from a Fischer-Tropsch synthesis product a first gas oil fraction and a fraction boiling above the gas oil fraction, (b) contacting the heavier fraction with a catalyst system comprising a catalyst, which catalyst comprises an acidic matrix and a large pore molecular sieve in a riser reactor at a temperature of between 450 and 650 °C at a contact time of between 1 and 10 seconds and at a catalyst to oil ratio of between 2 and 20 kg/kg, (c) isolating from the product of step (b) a second gas oil fraction; (d) combining the first gas oil fraction with the second gas oil.
摘要翻译：通过（a）从费 - 托合成产物中分离出第一瓦斯油馏分和在粗柴油馏分上方沸腾的馏分，（b）使较重馏分与包含催化剂的催化剂体系接触，从而制备瓦斯油的方法，该催化剂体系催化剂在提升管反应器中的温度为450至650℃之间的接触时间为1至10秒之间，催化剂油比为2至20kg / kg之间包含酸性基质和大孔分子筛，（c）从步骤（b）的产物中分离第二瓦斯油馏分; （d）将第一瓦斯油馏分与第二瓦斯油组合。

7. 发明申请

WO2006069990A1 PROCESS TO PREPARE A BASE OIL FROM A FISCHER-TROPSCH SYNTHESIS PRODUCT 审中-公开
标题翻译：从FISCHER-TROPSCH合成产品制备基础油的方法
公开(公告)号：WO2006069990A1
公开(公告)日：2006-07-06
申请号：PCT/EP2005/057172
申请日：2005-12-27
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DIERICKX, Jan Lodewijk Maria
发明人： DIERICKX, Jan Lodewijk Maria
IPC分类号： C10G65/14
CPC分类号： C10G65/14
摘要： Process to prepare base oils from a Fischer-Tropsch synthesis product by (a) separating the Fischer-Tropsch synthesis product into a fraction (i) boiling in the middle distillate range and below, a heavy ends fraction (iii) and an intermediate base oil precursor fraction (ii) boiling between fraction (i) and fraction (iii) , (b) subjecting the base oil precursor fraction (ii) to a catalytic hydroisomerisation step in the presence of a catalyst comprising a binder, zeolite Beta and a Group VIII metal and a catalytic dewaxing step in the presence of a catalyst comprising a binder, a medium pore size zeolite having and a Group VIII hydrogenation component to yield one or more base oil grades, (c) subjecting the heavy ends fraction (iii) to a conversion step to yield a fraction (iv) boiling below the heavy ends fraction (iii) and (d) subjecting the high boiling fraction (v) of fraction (iv) to a catalytic hydroisomerisation and catalytic dewaxing process to yield one or more base oil grades .
摘要翻译：通过（a）将费 - 托合成产物分离成在中间馏分和沸点范围内沸腾的馏分（i），重馏分（ⅲ）和中间基础油前体馏分（ⅱ）馏分（ⅰ）和馏分（ⅲ）之间的沸腾，（b）在催化剂存在下使基油前体馏分（ⅱ）进行催化加氢异构化步骤，该催化剂包括粘合剂，β沸石和VIII族金属和催化脱蜡步骤，在催化剂存在下，包含粘合剂，具有和VIII族氢化组分的中等孔径的沸石以产生一种或多种基础油级，（c）将重馏分（iii）转化步骤以产生沸点低于重馏分馏分（ⅲ）的馏分（ⅳ）和（d）将馏分（ⅳ）的高沸点馏分（v）进行催化加氢异构化和催化脱蜡过程，得到一种或多种基础油年级 s。

8. 发明申请

WO2006053894A1 PROCESS TO PREPARE A GAS OIL 审中-公开
标题翻译：制备气油的方法
公开(公告)号：WO2006053894A1
公开(公告)日：2006-05-26
申请号：PCT/EP2005/056054
申请日：2005-11-18
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DIERICKX, Jan Lodewijk Maria , HOEK, Arend , KUEH, Lip Piang
发明人： DIERICKX, Jan Lodewijk Maria , HOEK, Arend , KUEH, Lip Piang
IPC分类号： C10G65/16
CPC分类号： C10G65/16
摘要： Process to optimize the yield of gas oils from a Fischer-Tropsch derived feed by performing the following steps: (a) performing a hydroconversion/hydroisomerisation step on part of the Fischer-Tropsch derived feed; (b) performing a hydroconversion/hydroisomerisation step on another part of the Fischer-Tropsch feed at a conversion greater than the conversion in step (a); and (c) isolating by means of distillation a gas oil fraction from the two reaction products obtained in steps (a) and (b).
摘要翻译：通过执行以下步骤从费 - 托衍生的进料优化瓦斯油的产率的方法：（a）对费 - 托衍生的进料的一部分进行加氢转化/加氢异构化步骤; （b）以大于步骤（a）中的转化率的转化率对费 - 托进料的另一部分进行加氢转化/加氢异构化步骤; 和（c）通过蒸馏分离来自步骤（a）和（b）中获得的两种反应产物的粗柴油馏分。

9. 发明申请

WO2009034045A1 A PROCESS FOR HYDROCRACKING AND HYDRO-ISOMERISATION OF A PARAFFINIC FEEDSTOCK 审中-公开
标题翻译：一种分离饲料的水解和水解同位素的方法
公开(公告)号：WO2009034045A1
公开(公告)日：2009-03-19
申请号：PCT/EP2008/061837
申请日：2008-09-08
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BIJLSMA, Focco Cornelis , DIERICKX, Jan Lodewijk Maria , HOEK, Arend
发明人： BIJLSMA, Focco Cornelis , DIERICKX, Jan Lodewijk Maria , HOEK, Arend
IPC分类号： C10G65/12 , C10G45/62 , C10G47/14 , B01J20/16
CPC分类号： C10G45/62 , C10G2300/1022 , C10G2300/301 , C10G2400/06 , C10G2400/10 , Y10S208/95
摘要： A process for hydrocracking and hydro-isomerisation of a paraffinic feedstock obtained by Fischer-Tropsch hydrocarbon synthesis comprising at least 50 wt% of components boiling above 370 C to obtain a hydro- isomerised feedstock, the process comprising contacting the feedstock, in the presence of hydrogen, at elevated temperature and pressure with a catalyst comprising a hydrogenating compound supported on a carrier comprising amorphous silica-alumina, the carrier having a pore volume of at least 0.8 ml/g, wherein at most 40% of the pore volume comes from pores having a pore diameter above 35 nm and wherein at most 20% of the pore volume comes from pores having a pore diameter below 50 A and above 37 A, the carrier having a median pore diameter of at least 85 A, wherein the product of (surface area per pore volume) and (median pore diameter as measured by mercury intrusion porosimetry) of the carrier is at least 34,000 A.m 2 /ml.
摘要翻译：通过费 - 托烃合成获得的石蜡原料的加氢裂化和加氢异构化的方法，其包含至少50重量％沸点高于370℃的组分以获得加氢异构化的原料，该方法包括使原料在氢气，在升高的温度和压力下用包含负载在包含无定形二氧化硅 - 氧化铝的载体上的氢化化合物的催化剂，载体具有至少0.8ml / g的孔体积，其中至多40％的孔体积来自孔具有高于35nm的孔径，并且其中至多20％的孔体积来自孔径低于50A且高于37的孔，所述载体的中值孔径至少为85A，其中（载体的孔隙体积的表面积）和（通过水银侵入孔隙率测定的中值孔径）为至少34,000A·m 2 / ml。

10. 发明申请

WO2005118751A1 ALIPHATIC GASOLINE COMPONENT AND PROCESS TO PREPARE SAID GASOLINE COMPONENT 审中-公开
标题翻译：汽油汽油组分和制备汽油组分的方法
公开(公告)号：WO2005118751A1
公开(公告)日：2005-12-15
申请号：PCT/EP2005/052392
申请日：2005-05-25
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DIERICKX, Jan Lodewijk Maria
发明人： DIERICKX, Jan Lodewijk Maria
IPC分类号： C10L1/08
CPC分类号： C10G57/005 , C10G2/332 , C10G11/02 , C10G55/06 , C10G63/04 , C10G2300/1022 , C10G2300/202 , C10G2300/305 , C10G2300/4006 , C10G2300/80 , C10G2400/02 , C10L1/06 , Y10S208/95
摘要： An aliphatic gasoline component comprising more than 90wt% of a mixture of trimethyl substituted compounds and monomethyl substituted compounds in a weight ratio of trimethyl to monomethyl compounds of at least 0.03 and wherein the compounds may be paraffins and olefins. The invention is also directed to a process to prepare an aliphatic gasoline component by (a) contacting a Fischer-Tropsch synthesis product with a catalyst system comprising a catalyst, which catalyst comprises an acidic matrix and a large pore molecular sieve in a riser reactor at a temperature of between 450 and 650 °C at a contact time of between 1 and 10 seconds and at a catalyst to oil ratio of between 2 and 20 k.g/kg, (b) isolating from the product of step (a) a gasoline fraction and a fraction comprising iso-butane and isobutylene; (c) subjecting the iso-butane and the iso-butylene obtained in step (b) to an alkylation step to prepare a trimethyl substituted pentane, and (d) combining the gasoline fraction obtained in step (b) with the product rich in trimethyl substituted pentane as obtained in step (c).
摘要翻译：一种脂族汽油组分，其包含超过90重量％的三甲基取代的化合物和单甲基取代的化合物，三甲基对单甲基化合物的重量比为至少0.03，其中所述化合物可以是链烷烃和烯烃。本发明还涉及通过以下方法制备脂肪族汽油组分的方法：（a）将费 - 托合成产物与包含催化剂的催化剂体系接触，催化剂在催化剂中包含酸性基质和大孔分子筛接触时间为1至10秒，催化剂油比为2至20 kg / kg之间的温度为450至650℃，（b）从步骤（a）的产物中分离汽油馏分和包含异丁烷和异丁烯的馏分; （c）将步骤（b）中获得的异丁烷和异丁烯经烷基化步骤制备三甲基取代戊烷，和（d）将步骤（b）中获得的汽油馏分与富含三甲基在步骤（c）中获得的取代戊烷。

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