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1. 发明申请

WO1996011985A1 THERMOPLASTIC RESIN COMPOSITION, INJECTION MOLDING METHOD THEREOF AND INJECTION MOLDED ARTICLE 审中-公开
标题翻译：热塑性树脂组合物，注射成型方法及注塑成型
公开(公告)号：WO1996011985A1
公开(公告)日：1996-04-25
申请号：PCT/JP1995002133
申请日：1995-10-18
申请人： POLYPLASTICS CO., LTD. , MIYAZAKI, Hirotaka , AKETA, Tomoyuki , MURAKAMI, Haruji , ISHIKAWA, Takayuki , KOBAYASHI, Kazuhito , MIGITA, Ayako
发明人： POLYPLASTICS CO., LTD.
IPC分类号： C08L101/00
CPC分类号： C08L55/02 , B29C45/0001 , B29C45/2708 , B29K2105/0079 , C08G2261/312 , C08L23/10 , C08L25/06 , C08L33/06 , C08L59/00 , C08L65/02 , C08L67/00 , C08L67/02 , C08L67/03 , C08L67/04 , C08L69/00 , C08L77/00 , C08L81/02 , C08L101/00 , C08L2205/12 , Y10T428/1352 , Y10T428/1397 , Y10T428/24994 , Y10T428/269 , C08L2666/18 , C08L2666/14 , C08L2666/02
摘要： This invention provides a thermoplastic resin composition comprising a thermoplastic resin (A) not forming an anisotropic melt phase and a liquid crystal polymer (B) capable of forming the anisotropic melt phase, an injection molding method thereof and an injection molded article capable of providing a thin molded article having excellent mechanical strength. A thermoplastic resin composition (C) comprises 99 to 50 wt.% of the thermoplastic resin (A) and 1 to 50 wt.% of the liquid crystal polymer (B). The liquid crystal polymer (B) is microscopically dispersed in an island form in the matrix phase of the thermoplastic resin (A) so that when the composition (C) is heat-treated at a temperature not higher than the melting point of the liquid crystal polymer (B) under a non-load state and is then cooled, the liquid crystal polymer (B) falls within the range of the weight average particle diameter of 10 to 40 mu m and at least 80 wt.% thereof falls within the range of the particle diameter of 0.5 to 60 mu m. The injection molding method comprises carrying out injection molding of the thermoplastic resin composition (C) at a resin temperature not lower than the fluidization start temperature of the liquid crystal polymer (B) and at a gate passage rate of the molten resin of at least 500 m/min, and an injection molded article characterized in that the liquid crystal polymer (B) is dispersed in a fibrous form in the matrix phase of the thermoplastic resin (A) at a mean aspect ratio of at least 6.
摘要翻译：本发明提供一种热塑性树脂组合物，其包含不形成各向异性熔融相的热塑性树脂（A）和能够形成各向异性熔融相的液晶聚合物（B），其注射成型方法和能够提供薄模制品具有优异的机械强度。热塑性树脂组合物（C）含有99〜50重量％的热塑性树脂（A）和1〜50重量％的液晶聚合物（B）。液晶聚合物（B）在热塑性树脂（A）的基体相中以岛状显微分散，使得当组合物（C）在不高于液晶的熔点的温度下进行热处理时聚合物（B），然后冷却，液晶聚合物（B）落入重量平均粒径为10〜40μm的范围内，其中至少80wt％落在范围内的粒径为0.5〜60μm。注射成型方法包括在不低于液晶聚合物（B）的流化开始温度的树脂温度下进行热塑性树脂组合物（C）的注射成型，并且熔融树脂的浇口通道速率为至少500 m / min，注射成型制品的特征在于，液晶聚合物（B）以热塑性树脂（A）的基质相以纤维状分散，平均纵横比为6以上。

2. 发明申请

WO1998023430A1 INJECTION-MOLDED OBJECT 审中-公开
标题翻译：注射成型对象
公开(公告)号：WO1998023430A1
公开(公告)日：1998-06-04
申请号：PCT/JP1997004318
申请日：1997-11-26
申请人： POLYPLASTICS CO., LTD. , MURAKAMI, Haruji , ISHIKAWA, Takayuki , KOBAYASHI, Kazuhito
发明人： POLYPLASTICS CO., LTD.
IPC分类号： B29C45/00
CPC分类号： C08L67/00 , B29C45/0001 , B29K2105/0079 , C08K3/24 , C08K5/5425 , C08K5/5455 , C08K5/548 , C08K2201/016 , C08L67/03 , C08L69/00 , C08L2205/12 , Y10T428/1095 , C08L2666/18
摘要： A resin composition comprising a blend of a thermoplastic resin with a liquid-crystalline polymer is injection-molded while form the liquid-crystalline polymer into fibers during the molding to thereby give an injection-molded object excellent in mechanical strength etc. A thermoplastic resin composition comprising 100 parts by weight of a resin ingredient consisting of 99 to 50 parts by weight of a thermoplastic resin (A) forming no anisotropic molten phase and 1 to 50 parts by weight of a liquid-crystalline polymer (B) capable of forming an anisotropic molten phase and 0,01 to 1.0 part by weight of at least one compound (C) selected among phosphoric acid, phosphorous acid, and metal salts thereof is injection-molded to give a molding in which the polymer (B) is present in the form of fibers having an average aspect ratio of 6 or higher in the matrix of the resin (A).
摘要翻译：将包含热塑性树脂与液晶聚合物的共混物的树脂组合物注射成型，同时在成型期间将液晶聚合物形成纤维，从而得到机械强度等优异的注塑成型体。热塑性树脂组合物包含100重量份的由99〜50重量份不形成各向异性熔融相的热塑性树脂（A）和1〜50重量份能够形成各向异性的液晶聚合物（B）的树脂成分熔融相和0.01-1.0重量份的至少一种选自磷酸，亚磷酸及其金属盐的化合物（C）进行注射成型，得到聚合物（B）存在于在树脂（A）的基体中具有6或更高的平均纵横比的纤维的形式。

3. 发明申请

WO1997024404A1 LIQUID CRYSTALLINE POLYMER COMPOSITION AND MOLDINGS 审中-公开
标题翻译：液晶聚合物组合物和模具
公开(公告)号：WO1997024404A1
公开(公告)日：1997-07-10
申请号：PCT/JP1996003880
申请日：1996-12-27
申请人： POLYPLASTICS CO., LTD. , MURAKAMI, Haruji , KOBAYASHI, Kazuhito
发明人： POLYPLASTICS CO., LTD.
IPC分类号： C08L101/12
CPC分类号： C08L101/00 , C08K7/04 , C08K2201/016 , C08L77/12 , C08L101/12 , C08L2205/12
摘要： A plurality of fibrous fillers or a fibrous filler and a particulate filler are incorporated in a particular proportion into a liquid crystalline polymer to provide a liquid crystalline polymer composition possessing a low coefficient of linear expansion without significantly deteriorating the mechanical properties.
摘要翻译：将多种纤维填料或纤维填料和颗粒填料以特定比例掺入液晶聚合物中，以提供具有低线性膨胀系数而不显着劣化机械性能的液晶聚合物组合物。

4. 发明申请

WO1995005279A1 APPARATUS, METHOD AND COVERING DIE FOR PRODUCING A LONG FIBER-REINFORCED THERMOPLASTIC COMPOSITION 审中-公开
标题翻译：用于生产长纤维增强热塑性组合物的装置，方法和覆盖层
公开(公告)号：WO1995005279A1
公开(公告)日：1995-02-23
申请号：PCT/JP1994001363
申请日：1994-08-17
申请人： POLYPLASTICS CO., LTD. , SHIRAI, Yoshimitsu , HIRAGOHRI, Motohito , AMAIKE, Takeshi , MURAKAMI, Haruji
发明人： POLYPLASTICS CO., LTD.
IPC分类号： B29C70/50
CPC分类号： B29C47/0816 , B29B15/122 , B29C47/0021 , B29C47/02 , B29C47/025 , B29C47/16 , B29C70/50 , B29K2101/12
摘要： An apparatus, a method and a covering die for producing a long fiber-reinforced thermoplastic composition for reducing unevenness in extrusion in a web width direction when covering a bundle of continuous fibers which are opened in a web form with fused thermoplastic resin extruded from a slit, wherein fused thermoplastic resin is extruded from a slit set so as to have a width substantially equal to that of the web and a gap changing in the web width direction to thereby cover at least one side of the moving bundle of continuous fibers which are opened in a web form.
摘要翻译：一种用于制造长纤维增强热塑性组合物的装置，方法和覆盖模具，用于当覆盖一束由网状形式的连续纤维形成时，从卷边宽度方向挤出的熔融热塑性树脂其特征在于，熔融热塑性树脂从狭缝组挤压成具有与所述纤维网的宽度大致相同的宽度，以及在所述幅材宽度方向上变化的间隙，从而覆盖所述连续纤维的开放的至少一侧，以网络形式。

5. 发明申请

WO1996005956A1 METHOD FOR PRODUCING LONG FIBER-REINFORCED THERMOPLASTIC RESIN COMPOSITION 审中-公开
标题翻译：生产长纤维增强热塑性树脂组合物的方法
公开(公告)号：WO1996005956A1
公开(公告)日：1996-02-29
申请号：PCT/JP1994001370
申请日：1994-08-19
申请人： POLYPLASTICS CO., LTD. , MURAKAMI, Haruji
发明人： POLYPLASTICS CO., LTD.
IPC分类号： B29C70/50
CPC分类号： B29B15/122
摘要： A method for producing long fiber-reinforced thermoplastic resin composition for promoting the impregnation of fused thermoplastic resin discharged against a bundle of fibers which are opened in a web form so as to cover the same into and between the web-form fibers without damaging the fibers and mixing of deteriorated resin in an impregnated product comprising the steps of allowing a bundle of continuous fibers which are opened in a web form to pass through a covering die having a resin discharge port, covering at least one of upper and lower sides of the web-form bundle of continuous fibers with fused thermoplastic resin discharged from the resin discharge port, and, in an impregnation process comprising a plurality of bars set vertically in such a manner that the portions which are in contact with the web-form bundle of continuous fibers are substantially horizontal and that their longitudinal direction is perpendicular to the axial direction of the fibers, pulling in the web-form bundle of continuous fibers which is so covered substantially horizontally from the rear so as to bring it into contact with the bars at the top and bottom sides thereof, to thereby impregnate the bundle with fused thermoplastic resin.
摘要翻译：一种生产长纤维增强热塑性树脂组合物的方法，其用于促进对以纤维网形式打开的纤维束排出的熔融热塑性树脂的浸渍，以便将其覆盖在纤维网形纤维之间和之间而不损伤纤维以及在浸渍产品中混合劣化树脂，包括以下步骤：允许以网状形式打开的一束连续纤维通过具有树脂排出口的覆盖模具，该覆盖模具覆盖幅材的上下两个中的至少一个形成从树脂排出口排出的熔融热塑性树脂的连续纤维束，并且在浸渍工艺中，包括垂直设置的多个条，使得与连续纤维的网状束接触的部分基本上是水平的，并且它们的纵向方向垂直于纤维的轴向方向，拉动网状一束连续纤维从后面基本上水平地覆盖，以使其在其顶侧和底侧与杆接触，从而用熔化的热塑性树脂浸渍束。

6. 发明申请

WO1995005280A1 APPARATUS, METHOD AND COVERING DIE FOR PRODUCING A LONG FIBER-REINFORCED THERMOPLASTIC COMPOSITION 审中-公开
标题翻译：用于生产长纤维增强热塑性组合物的装置，方法和覆盖层
公开(公告)号：WO1995005280A1
公开(公告)日：1995-02-23
申请号：PCT/JP1994001364
申请日：1994-08-17
申请人： POLYPLASTICS CO., LTD. , SHIRAI, Yoshimitsu , NITOH, Toshikatsu , AMAIKE, Takeshi , MURAKAMI, Haruji
发明人： POLYPLASTICS CO., LTD.
IPC分类号： B29C70/50
CPC分类号： B29C70/523 , B29B15/122 , B29K2101/12 , Y10S366/03
摘要： An apparatus, a method and a covering die for producing a long fiber-reinforced thermoplastic composition for reducing unevenness in extrusion in a web width direction when covering a bundle of continuous fibers which are opened in a web form with fused thermoplastic resin extruded from a slit, wherein fused thermoplastic resin is extruded from a slit set so as to have a width substantially equal to that of the web and having a plurality of resin supply lines up to the slit branched on the same plane to thereby cover at least one side of the moving bundle of continuous fibers which are opened in a web form.
摘要翻译：一种用于制造长纤维增强热塑性组合物的装置，方法和覆盖模具，用于当覆盖一束由网状形式的连续纤维形成时，从卷边宽度方向挤出的熔融热塑性树脂其中熔融热塑性树脂从狭缝组中挤出，使其宽度基本上等于纤维网的宽度，并且具有多条树脂供应线，直到在同一平面上分支的狭缝，从而覆盖了至少一面以网状打开的连续纤维的移动束。

7. 发明申请

WO1997015631A1 SYNTHETIC RESIN COMPOSITION AND MOLDED ARTICLE THEREOF 审中-公开
标题翻译：合成树脂组合物及其成型品
公开(公告)号：WO1997015631A1
公开(公告)日：1997-05-01
申请号：PCT/JP1996003063
申请日：1996-10-22
申请人： POLYPLASTICS CO., LTD. , SAITO, Tatsuya , ISHIKAWA, Takayuki
发明人： POLYPLASTICS CO., LTD.
IPC分类号： C08L101/00
CPC分类号： C08L67/02 , C08K5/54 , C08L69/00 , C08L101/00 , C08L67/00 , C08L59/02 , C08L77/12 , C08L67/04 , C08L2666/14 , C08L2666/18
摘要： A resin composition comprising a thermoplastic resin (such as polyester resin) which does not exhibit anisotropy in melting and a liquid-crystal polyester resin which causes little delamination and is excellent in mechanical properties can be prepared by blending 100 parts by weight of a resin component comprising (a) 99 to 50 parts by weight of a thermoplastic resin which does not exhibit anisotropy in melting and (b) 1 to 50 parts by weight of a liquid-crystal polyester resin forming an anisotropic molten phase with (c) 0.01 to 3.0 parts by weight of at least one silane compound selected from among vinylalkoxysilanes, aminoalkoxysilanes and mercaptoalkoxysilanes.
摘要翻译：包含不具有熔融各向异性的热塑性树脂（例如聚酯树脂）和几乎不产生分层并且机械性能优异的液晶聚酯树脂的树脂组合物可以通过将100重量份的树脂组分其包含（a）99〜50重量份不具有熔融各向异性的热塑性树脂，（b）1〜50重量份形成各向异性熔融相的液晶聚酯树脂，（c）为0.01〜3.0 重量份的至少一种选自乙烯基烷氧基硅烷，氨基烷氧基硅烷和巯基烷氧基硅烷的硅烷化合物。

8. 发明申请

WO1997015628A1 SYNTHETIC RESIN COMPOSITION 审中-公开
标题翻译：合成树脂组合物
公开(公告)号：WO1997015628A1
公开(公告)日：1997-05-01
申请号：PCT/JP1996003064
申请日：1996-10-22
申请人： POLYPLASTICS CO., LTD. , SAITO, Tatsuya , ISHIKAWA, Takayuki
发明人： POLYPLASTICS CO., LTD.
IPC分类号： C08L67/02
CPC分类号： C08L67/00 , C08K5/54 , C08L67/02 , C08L2666/14
摘要： A synthetic resin composition which comprises a thermoplastic resin not exhibiting anisotropy in a molten state (such as polyester resin) and a liquid-crystal polyester resin and which little causes delamination and is excellent in mechanical properties can be prepared by blending 100 parts by weight of a resin component comprising (a) a thermoplastic resin not exhibiting anisotropy in a molten state in an amount of one part by weight or above but below 50 parts by weight and (b) a liquid-crystal polyester resin forming an anisotropic molten phase in an amount of more than 50 parts by weight up to 99 parts by weight with 0.01 to 3.0 parts by weight of (c) at least one silane compound selected from the group consisting of vinylalkoxysilanes, aminoalkoxysilanes and mercaptoalkoxysilanes.
摘要翻译：包含不具有熔融状态的各向异性的热塑性树脂（例如聚酯树脂）和液晶聚酯树脂并且很少引起分层并且机械性能优异的合成树脂组合物可以通过将100重量份的树脂组分，其包含（a）在熔融状态下不显示各向异性的热塑性树脂，其量为1重量份以上但低于50重量份，和（b）形成各向异性熔融相的液晶聚酯树脂数量大于50重量份，最多99重量份，0.01至3.0重量份的（c）至少一种选自乙烯基烷氧基硅烷，氨基烷氧基硅烷和巯基烷氧基硅烷的硅烷化合物。

9. 发明申请

WO1998029510A1 POLYACETAL RESIN COMPOSITION AND MOLDINGS 审中-公开
标题翻译：聚乙烯树脂组合物和模具
公开(公告)号：WO1998029510A1
公开(公告)日：1998-07-09
申请号：PCT/JP1997004758
申请日：1997-12-22
申请人： POLYPLASTICS CO., LTD. , HARASHINA, Hatsuhiko , KURITA, Hayato , YAMADA, Tatsuya
发明人： POLYPLASTICS CO., LTD.
IPC分类号： C08L59/00
CPC分类号： C08K5/3445 , C08L59/00
摘要： A polyacetal resin composition prepared by adding about 0.01 to 10 parts by weight of a glyoxydiureide compound to 100 parts by weight of a polyacetal resin. The glyoxydiureide compounds usable herein include glyoxydiureide itself and derivatives thereof (such as metal salts thereof). About 0.01 to 10 parts by weight of a basic nitrogen compound may be further added thereto. The nitrogen compounds usable herein include melamine, melamine resins, and polyamide resins. In addition, an antioxidant may be added to the composition. The compositions serve to improve the stability, particularly the thermal stability, of the polyacetal resin, and prevents the evolution of formaldehyde.
摘要翻译：通过向100重量份聚缩醛树脂中加入约0.01至10重量份的乙醛酸二乙酯化合物制备的聚缩醛树脂组合物。可用于本发明的乙醛酸二酰酯化合物包括乙二醛二酰亚胺本身及其衍生物（如其金属盐）。可以进一步加入约0.01〜10重量份的碱式氮化合物。可用的氮化合物包括三聚氰胺，三聚氰胺树脂和聚酰胺树脂。此外，可以将抗氧化剂加入到组合物中。该组合物用于提高聚缩醛树脂的稳定性，特别是热稳定性，并防止甲醛的逸出。

10. 发明申请

WO1997048767A1 POLYACETAL RESIN COMPOSITION 审中-公开
标题翻译：聚酯树脂组合物
公开(公告)号：WO1997048767A1
公开(公告)日：1997-12-24
申请号：PCT/JP1997002094
申请日：1997-06-18
申请人： POLYPLASTICS CO., LTD.
发明人： POLYPLASTICS CO., LTD. , FUKASAWA, Yoshihito , ANADA, Sachio
IPC分类号： C08L59/04
CPC分类号： C08L59/00 , C08K3/38 , C08K5/005 , C08K5/1345 , C08K5/34922 , C08L33/26 , C08L61/28 , C08L77/00 , C08L2666/04 , C08L61/20
摘要： A polyacetal resin composition which is excellent in non-corrosiveness to metal and is suppressed in the adverse effects particularly on magnetic tapes, thus being favorably usable for the constituent parts of magnetic tape cassettes, such as reel hubs or tape guides. This composition comprises (A) 100 parts by weight of a polyacetal resin, (B) 0.05 to 5 parts by weight of an antioxidant, (C) 0.001 to 5 parts by weight of a specific nitrogen compound, and (D) 0.001 to 3 parts by weight of a boron compound.
摘要翻译：一种聚合缩醛树脂组合物，其对金属的非腐蚀性优异，特别是对磁带的不利影响被抑制，因此有利地用于诸如卷轴轮毂或带导轨的磁带盒的组成部分。该组合物包含（A）100重量份的聚缩醛树脂，（B）0.05〜5重量份的抗氧化剂，（C）0.001〜5重量份的特定氮化合物，（D）0.001〜3 重量份的硼化合物。

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