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1. 发明申请

WO2008006520A2 METHOD FOR GENERATING SUPRAMOLECULAR ROTARY DEVICES AND SUPRAMOLECULAR ROTARY SWITCH 审中-公开
标题翻译：用于产生分子旋转装置和分子旋转开关的方法
公开(公告)号：WO2008006520A2
公开(公告)日：2008-01-17
申请号：PCT/EP2007/006008
申请日：2007-07-06
申请人： PAUL SCHERRER INSTITUT , BONIFAZI, Davide , CHENG, Fuyong , DIEDERICH, François , JUNG, Thomas , KIEBELE, Andreas , SPILLMANN, Hannes , WINTJES, Nikolai
发明人： BONIFAZI, Davide , CHENG, Fuyong , DIEDERICH, François , JUNG, Thomas , KIEBELE, Andreas , SPILLMANN, Hannes , WINTJES, Nikolai
CPC分类号： B82B3/00 , B82Y10/00 , B82Y30/00 , B82Y40/00 , G11B9/14 , G11B9/149 , G11C13/0014 , G11C2213/14 , Y10T428/249953 , Y10T428/249978
摘要： A method for generating a porous network of supramolecular devices is disclosed, comprising the steps of : a) providing self-organizing molecules comprising connecting bonds and side-groups; b) generating a two-dimensional layer of said molecules on an unstructured surface, wherein self-organizing leads to an at least partially regular network of cells, each cell comprising a number of said self-organizing molecules and each cell offering a functional center; and c) further depositing a predefined amount of said self-organizing molecules and/or of other functional molecules on said two-dimensional layer, wherein these further deposited molecules accommodating in said functional centers of said cells, one or more of said further deposited molecules per cell, wherein said further deposited molecule comprises a multi-stable architecture together with the cell hosting the further deposited molecule. This method provides a rotary switch that offers on a large scale a bottom-up self assembly of the self-organizing molecules that result in a nanoporous network comprising single supramolecular switches that can be addressed individually and switched by changing its orientation. Such rotary switch is at low cost a very flexible and powerful nanodevice that can be largely used in molecurlar electronic applications, such as for the purpose of storing information.
摘要翻译：公开了一种用于产生超分子器件的多孔网络的方法，包括以下步骤：a）提供包括连接键和侧基的自组织分子; b）在非结构化表面上产生所述分子的二维层，其中自组织导致至少部分规则的细胞网络，每个细胞包含多个所述自组织分子，每个细胞提供功能中心; 以及c）在所述二维层上进一步沉积预定量的所述自组织分子和/或其它功能分子，其中这些进一步沉积的分子容纳在所述细胞的所述功能中心中，一个或多个所述另外沉积的分子其中所述另外沉积的分子包含与承载另外沉积的分子的细胞一起的多稳定结构。该方法提供了一种大规模提供自组织分子的自底向上自组装的旋转开关，其导致包含单个超分子开关的纳米多孔网络，其可以通过改变其取向而单独寻址和切换。这种旋转开关是低成本的，非常灵活和强大的纳米器件，其可以主要用于电子应用中，例如用于存储信息的目的。

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