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    • 3. 发明申请
    • SHRINK FILMS
    • 收缩膜
    • WO2017013509A1
    • 2017-01-26
    • PCT/IB2016/053949
    • 2016-06-30
    • NOVA CHEMICALS (INTERNATIONAL) S.A.
    • WANG, XiaochuanCHECKNITA, DouglasBAYLEY, John
    • C08J5/18B32B27/32B32B27/08
    • C08J5/18B32B27/08B32B27/32B32B2270/00B32B2307/736B32B2439/00C08F210/16C08J2323/06C08J2323/08C08J2423/06C08J2423/08
    • Films suitable for shrink film applications are disclosed comprising at least one heterogeneous ethylene interpolymer having a short chain branching distribution profile index, DPI SCB , that satisfies the formula: -1 ≤ DPI SCB ≤ 1. The at least one heterogeneous ethylene interpolymer has a density from about 0.911 g/cm 3 to about 0.942 g/cm 3 , a melt index from about 0.2 dg/min to about 3.5 dg/min and is produced using an in-line Ziegler-Natta catalyst. Additional embodiments include shrink films prepared from blends of at least one heterogeneous ethylene interpolymer and at least one high pressure ethylene polymer. The disclosed shrink films have improved puncture strength and machine direction shrink tunnel shrink force relative to control shrink films of the same composition but the control heterogeneous ethylene interpolymer, produced with a batch Ziegler-Natta catalyst, has a DPI SCB greater than 1.0.
    • 公开了适用于收缩膜应用的膜,其包含具有短链支化分布分布指数的至少一种异质乙烯互聚物,DPISCB,其满足以下公式:-1≤DPISCB≤1。所述至少一种异相乙烯互聚物具有约 0.911g / cm 3至约0.942g / cm 3,熔体指数为约0.2dg / min至约3.5dg / min,并使用在线齐格勒 - 纳塔催化剂制备。 另外的实施方案包括由至少一种异质乙烯互聚物和至少一种高压乙烯聚合物的共混物制备的收缩膜。 所公开的收缩膜具有相对于控制相同成分的收缩膜的相对于控制异种乙烯互聚物的批次齐格勒 - 纳塔催化剂的具有改进的穿刺强度和机械方向的收缩隧道收缩力,其DPISCB大于1.0。