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    • 3. 发明申请
    • CROSSLINKED POLYSULFIDE-CONTAINING CYCLOALIPHATIC COMPOUND
    • 含交联聚氨酯的环状化合物
    • WO2010051398A1
    • 2010-05-06
    • PCT/US2009/062668
    • 2009-10-30
    • MOMENTIVE PERFORMANCE MATERIALS INC.CRUSE, Richard, W.YORK, William, MichaelRECKER, CarlaKRAMER, ThomasHERZOG, Katharina
    • CRUSE, Richard, W.YORK, William, MichaelRECKER, CarlaKRAMER, ThomasHERZOG, Katharina
    • C08G75/00
    • C08G75/14Y10T428/139
    • A crosslinked polysulfide-containing cycloaliphatic compound, useful as a crosslinker for filled sulfur-vulcanizable elastomer compositions, is represented by the general formula: [(C a H 2a -) m G 1 (-C b H 2b S x -) n-m and C c H 2c -G 2 - C d H 2d S y - ] p [R]q wherein G 1 is a saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen or a saturated monocyclic silicone [RSiO-] n [R 2 SiO-] r group of valence n; G 2 is a saturated, divalent cyclic aliphatic group of valence 2 containing from S to 12 carbon atoms and optionally containing at least one halogen or a saturated monocyclic silicone [RSiO-] n [R 2 SiO-] r group of valence n;; each R independently is a selected from the group consisting of a hydrogen atom, monovalent hydrocarbon of up to 20 carbon atoms and a halogen atom; each occurrence of subscripts a, b, c, d, m, n, o, p, q, x and y independently is an integer wherein a is 2 to 6; b is 2 to 6; c is 1 to 6; d is 1 to 6; m is 1 or 2; n is 3 to 5; o is a positive integer, p is 0 or a positive integer; q is a positive integer; r is an integer of from 0 to 3; x is 1 to 10 and y is 1 to 10, with the provisos that, (i) at least one x is 2 to 10; (ii) the ratio of p to o is less than 1 to 5; and q is equal to the sum of unfilled valences of the (C a H 2a -) m G 1 (-C b H 2b S x -) n-m and C c H 2c -G 2 - C d H 2d S y - groups.
    • 可用作填充的硫可硫化弹性体组合物的交联剂的交联的含多硫化物的脂环族化合物由以下通式表示:[(CaH2a)mG1(-CbH2bSx-)nm和CcH2c-G2- CdH2dSy-] p [R 其中G1是含有5至12个碳原子并且任选地含有至少一个卤素或饱和单环硅氧烷[RSiO - ] n [R 2 SiO] - 基的n价的饱和单环脂族基团n; G2是含有S至12个碳原子并且任选地含有至少一个卤素或饱和单环硅氧烷[RSiO - ] n [R 2 SiO] - 基团的饱和二价环状脂族基团2。 每个R独立地选自氢原子,至多20个碳原子的一价烃和卤素原子; 每个出现的下标a,b,c,d,m,n,o,p,q,x和y独立地是其中a是2至6的整数; b为2〜6; c为1〜6; d为1〜6; m为1或2; n为3〜5; o是正整数,p是0或正整数; q是正整数; r为0〜3的整数; x为1至10且y为1至10,条件是(i)至少一个x为2至10; (ii)p与o之比小于1至5; 且q等于(CaH2a)mG1(-CbH2bSx-)n-m和CcH2c-G2-CdH2dSy-基团的未饱和化合价的总和。