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1. 发明申请

WO1994025417A1 SKELETAL ISOMERIZATION OF N-PENTENES 审中-公开
标题翻译： N-PENTENES的骨骼异构化
公开(公告)号：WO1994025417A1
公开(公告)日：1994-11-10
申请号：PCT/US1994004112
申请日：1994-04-14
申请人： MOBIL OIL CORPORATION
发明人： MOBIL OIL CORPORATION , BEECH, James, Harding, Jr. , SAEGER, Roland, Bernard , WARE, Robert, Adams
IPC分类号： C07C05/22
CPC分类号： C07C5/2775 , C07C11/02
摘要： A process for converting linear C5 olefins in the presence of contaminant C5 diolefins to corresponding iso-olefins of the same carbon number comprises contacting a linear C5 olefin-containing organic feedstock in the presence of hydrogen with a catalyst comprising material having the structure of ZSM-35 under conditions including a temperature of 100 and 750 DEG C, a weight hourly space velocity (WHSV) based on linear C5 olefins in said feedstock between 0.1 and 500 WHSV, and C5 linear olefin partial pressure of 2 to 2000 kPa.
摘要翻译：在存在污染物C5二烯烃的情况下将线性C5烯烃转化为相同碳数的相应异烯烃的方法包括在氢气存在下使含有直链C 5烯烃的有机原料与含有ZSM- 35，在100至750℃的温度条件下，基于所述原料中的线性C 5烯烃在0.1至500 WHSV之间的重时空速（WHSV）和2至2000kPa的C5线性烯烃分压。

2. 发明申请

WO1995016740A1 HYDROGEN FLUORIDE COMPOSITION 审中-公开
标题翻译：氢氟化合物
公开(公告)号：WO1995016740A1
公开(公告)日：1995-06-22
申请号：PCT/US1994008157
申请日：1994-07-20
申请人： MOBIL OIL CORPORATION
发明人： MOBIL OIL CORPORATION , DEL ROSSI, Kenneth, J. , HUSS, Albin, Jr. , LANDIS, Michael, E. , SAEGER, Roland, Bernard , TREWELLA, Jeffrey, C.
IPC分类号： C08K05/45
CPC分类号： B01J31/068 , B01J2231/323 , C01B7/191 , C07C2/62 , C07C2527/1206 , C07C2531/06 , C08K3/16
摘要： A composition comprising HF and a viscoelastic polymer having an average molecular weight of at least about 100,000 is useful in isoparaffin/olefin alkylation as a substitute for concentrated HF catalyst.
摘要翻译：包含HF和平均分子量为至少约100,000的粘弹性聚合物的组合物可用于异链烷烃/烯烃烷基化，作为浓缩HF催化剂的替代物。

3. 发明申请

WO1995006024A1 PRODUCTION OF ALKYL TERTIARY ALKYL ETHERS 审中-公开
标题翻译：生产碱金属碱金属盐
公开(公告)号：WO1995006024A1
公开(公告)日：1995-03-02
申请号：PCT/US1994008399
申请日：1994-07-26
申请人： MOBIL OIL CORPORATION
发明人： MOBIL OIL CORPORATION , CHIN, Arthur, Achhing , STOOS, James, Arthur , SAEGER, Roland, Bernard , WARE, Robert, Adams
IPC分类号： C07C41/05
CPC分类号： C07C41/06 , C07C41/42 , Y02P20/127 , C07C43/046
摘要： A process is disclosed for producing alkyl tertiary alkyl ether such as TAME from alkanol and hydrocarbon feedstock containing linear olefins, iso-olefins, linear alkanes and iso-alkanes such as C5 streams from FCC. The process selectively etherifies iso-olefins in a plural stage etherification zone whose linear olefin-containing effluent is treated by distillation to remove iso-alkanes, and alkanol before passing to a skeletal isomerization zone using constrained intermediate pore size zeolite catalyst such as ZSM-22, ZSM-23, or ZSM-35, which converts linear olefins to iso-olefins which are recycled for etherification. The use of distillation to remove iso-alkanes and alkanol reduces mass flow to the etherification process and minimizes skeletal isomerization catalyst poisoning by alkanol, without resort to water extraction processes which require subsequent treatment of the isomerization zone feed to remove water.
摘要翻译：公开了一种从链烷醇生产烷基叔烷基醚如TAME的方法，以及含有直链烯烃，异烯烃，直链烷烃和异烷烃如FCC的C5流的烃原料。该方法选择性地醚化多级醚化区中的异烯烃，其直链烯烃流出物通过蒸馏处理以除去异烷烃，和链烷醇在使用约束的中等孔径沸石催化剂如ZSM-22进入骨架异构化区，ZSM-23或ZSM-35，其将线性烯烃转化为异烯烃，其被再循环用于醚化。使用蒸馏来除去异烷烃和链烷醇减少了醚化过程的质量流动，并且使骨架异构化催化剂由链烷醇中毒最小化，而不用采用需要随后处理异构化区域进料以除去水的水提取方法。

4. 发明申请

WO1998029369A1 METHOD FOR RECOVERING GAS FROM HYDRATES 审中-公开
标题翻译：从水合物中回收气体的方法
公开(公告)号：WO1998029369A1
公开(公告)日：1998-07-09
申请号：PCT/US1997024202
申请日：1997-12-19
申请人： MOBIL OIL CORPORATION
发明人： MOBIL OIL CORPORATION , HEINEMANN, Robert, Frederick , HUANG, David, Da-Teh , LONG, Jingping , SAEGER, Roland, Bernard
IPC分类号： C07C09/00
CPC分类号： E21B43/24 , C10L3/06 , E21B36/00 , E21B43/2401 , E21B2043/0115
摘要： Gas is recovered from a clathrate hydrate (100) by providing the clathrate hydrate (100) within an occupying zone (102), positioning a source of electromagnetic radiation (200) within the clathrate hydrate occupying zone (102), and applying electromagnetic radiation from the electromagnetic radiation source (200) to the clathrate hydrate (100) at a frequency within the range of from direct current to visible light at an energy density sufficient to dissociate the clathrate hydrate (100) and to envolve its constituent gas (402).
摘要翻译：通过在占据区域（102）内提供笼形水合物（100），将电磁辐射源（200）定位在笼形水合物占据区域（102）内，并施加电磁辐射从笼形水合物（100）中回收气体电离辐射源（200）以一定的频率从直流到可见光的频率处于笼状水合物（100），能量密度足以使笼形水合物（100）解离并使其组分气体（402）包合。

5. 发明申请

WO1998027033A1 PROCESS FOR MAKING GAS HYDRATES 审中-公开
标题翻译：制造气体水化物的工艺
公开(公告)号：WO1998027033A1
公开(公告)日：1998-06-25
申请号：PCT/US1997022692
申请日：1997-12-16
申请人： MOBIL OIL CORPORATION
发明人： MOBIL OIL CORPORATION , HEINEMANN, Robert, Frederick , HUANG, David, Da-Teh , LONG, Jinping , SAEGER, Roland, Bernard
IPC分类号： C07C07/20
CPC分类号： F17C11/00 , C10L3/08 , C10L3/108 , Y10S585/95 , Y10T137/0329 , Y10T137/0391
摘要： The present disclosure provides a process for continuously producing clathrate hydrate. This process includes the step of: (a) pressurizing a hydrate-forming gas to an elevated pressure and cooling the hydrate-forming gas below the gas-water-hydrate equilibrium point at the elevated pressure; (b) cooling liquid water below the gas-water-hydrate equilibrium temperature for the elevated pressure; (c) charging hydrate-forming gas at the elevated pressure into a reaction zone which contains a movable surface; (d) atomizing water in the reaction zone in contact with the hydrate-forming gas to form gas hydrate in the reaction; (e) depositing the gas hydrates on the movable surface; and (f) collecting the gas hydrates from the movable surface.
摘要翻译：本公开提供了连续生产笼形水合物的方法。该方法包括以下步骤：（a）将形成水合物的气体加压至升高的压力，并在升高的压力下将形成水合物的气体冷却至气水合水合物平衡点以下; （b）将液态水冷却至低于天然气水合物平衡温度以升高压力; （c）在升高的压力下将形成水合物的气体装入包含活动表面的反应区; （d）使反应区内的水与形成水合物的气体接触，在反应中形成气体水合物; （e）将气体水合物沉积在活动表面上; 和（f）从可移动表面收集气体水合物。

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