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1. 发明申请

WO2015161203A1 FUNCTIONALIZED NANOSTRUCTURES AND DEVICES INCLUDING PHOTOVOLTAIC DEVICES 审中-公开
标题翻译：功能化的纳米结构和包括光伏器件的器件
公开(公告)号：WO2015161203A1
公开(公告)日：2015-10-22
申请号：PCT/US2015/026379
申请日：2015-04-17
申请人： MASSACHUSETTS INSTITUTE OF TECHNOLOGY , ENI S.P.A.
发明人： SWAGER, Timothy, M. , BULOVIC, Vladimir , HAN, Ggoch, Ddeul , MAURANO, Andrea , PO, Riccardo , PELLEGRINO, Andrea
IPC分类号： H01B1/04 , H01B1/12
CPC分类号： H01L51/0047 , C01B32/152 , H01B1/04 , H01B1/12 , H01L51/0035 , H01L51/0036 , H01L51/0037 , H01L51/0043 , H01L51/0049 , H01L51/4253 , H01L51/441 , Y02E10/549
摘要： Embodiments described herein provide functionalized carbon nanostructures for use in various devices, including photovoltaic devices (e.g., solar cells). In some cases, the carbon nanostructures are fullerenes substituted with one or more isobenzofulvene species and/or indane species. Devices including such materials may exhibit increased efficiency, increased open circuit potential, high electron/hole mobility, and/or low electrical resistance.
摘要翻译：本文所述的实施方案提供用于各种装置的官能化碳纳米结构，包括光伏器件（例如，太阳能电池）。在一些情况下，碳纳米结构是被一种或多种异苯并富烯和/或茚满物质取代的富勒烯。包括这种材料的器件可以表现出提高的效率，增加的开路电位，高电子/空穴迁移率和/或低电阻。

2. 发明申请

WO2013001519A1 PHOTOACTIVE CONJUGATED POLYMER COMPRISING DIBENZOTHIENYLPYRROLE UNITS 审中-公开
标题翻译：包含二苯并噻吩单体的光聚合聚合物
公开(公告)号：WO2013001519A1
公开(公告)日：2013-01-03
申请号：PCT/IB2012/053741
申请日：2012-07-23
申请人： ENI S.P.A. , PELLEGRINO, Andrea , SCHIMPERNA, Giuliana
发明人： PELLEGRINO, Andrea , SCHIMPERNA, Giuliana
IPC分类号： C08L61/12 , C08G73/00 , H01B1/00 , H01L51/00 , C09K11/00
CPC分类号： C08L61/12 , C08G61/123 , C08G61/124 , C08G61/126 , C08G73/00 , C08G73/0672 , C08G2261/124 , C08G2261/1412 , C08G2261/3223 , C08G2261/3241 , C08G2261/3243 , C08G2261/3246 , C08G2261/411 , C08G2261/91 , C09K11/00 , H01B1/00 , H01L51/00 , H01L51/0036 , H01L51/4253 , Y02E10/549
摘要： A photoactive conjugated polymer comprising dibenzothienylpyrrole units having general formula (I) wherein: - A and B, equal to or different from each other, represent a 1,2-vinylene group; or they can be selected from divalent cyclic or polycyclic groups containing one or more aromatic or heteroaromatic rings, said aromatic or heteroaromatic rings being optionally substituted; - R represents a linear or branched C 1 -C 32 , preferably C 4 -C 24 , alkyl group; an aryl group optionally substituted; - n is an integer ranging from 10 to 300, preferably ranging from 25 to 250. Said photoactive conjugated polymer comprising dibenzothienylpyrrole units can be advantageously used in the construction of photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both rigid and flexible supports.
摘要翻译：包含具有通式（I）的二苯并噻吩基吡咯单元的光活性共轭聚合物，其中：-A和B彼此相同或不同，表示1,2-亚乙烯基; 或它们可以选自含有一个或多个芳族或杂芳环的二价环状或多环基团，所述芳族或杂芳环任选被取代; -R表示直链或支链C 1 -C 32，优选C 4 -C 24烷基; 任选取代的芳基; - n为10-300，优选为25-250的整数。所述包含二苯并噻吩基吡咯单元的光敏共轭聚合物可有利地用于构建光电器件，例如光伏电池，光伏组件，太阳能电池，太阳能组件，刚性和柔性支撑。

3. 发明申请

WO2013140328A1 PROCESS FOR THE PREPARATION OF TETRACARBOXYNAPHTHALENEDIIMIDE COMPOUNDS DISUBSTITUTED WITH HETEROARYL GROUPS 审中-公开
标题翻译：制备与异构体组分离的四羧基苯乙烯二胺化合物的方法
公开(公告)号：WO2013140328A1
公开(公告)日：2013-09-26
申请号：PCT/IB2013/052153
申请日：2013-03-18
申请人： ENI S.P.A.
发明人： SCHIMPERNA, Giuliana , PELLEGRINO, Andrea , CHIABERGE, Stefano , BIANCHI, Gabriele
IPC分类号： C07D471/06
CPC分类号： C07D471/06 , C09B57/08
摘要： A process for the preparation of a tetracarboxynaphthalenediimide compound disubstituted with heteroaryl groups having general formula (I), comprising the reaction of at least one disubstituted N,N I- dialkyl-1,4,5,8-tetracarboxynaphthalenediimide with at least one heteroaryl compound. Said tetracarboxynaphthalenediimide compound disubstituted with heteroaryl groups can be advantageously used as monomer in the synthesis of semiconductor polymers which can be advantageously used in the construction of organic field effect transistors (OFET) or of organic thin film transistors (OTFT).
摘要翻译：一种制备用通式（I）的杂芳基二取代的四羧基萘二酰亚胺化合物的方法，其包括至少一种二取代的N，N-二烷基-1,4,5,8-四羧基萘二亚胺与至少一种杂芳基化合物的反应。用杂芳基二取代的所述四羧基萘二酰亚胺化合物可有利地用作合成半导体聚合物中的单体，其可有利地用于构建有机场效应晶体管（OFET）或有机薄膜晶体管（OTFT）。

4. 发明申请

WO2011072876A1 COPOLYMERS FOR SOLAR CELLS BASED ON ACRIDONIC UNITS 审中-公开
标题翻译：基于ACRIDONIC单位的太阳能电池共聚物
公开(公告)号：WO2011072876A1
公开(公告)日：2011-06-23
申请号：PCT/EP2010/007771
申请日：2010-12-15
申请人： ENI S.P.A. , CALDARARO, Maria , PELLEGRINO, Andrea , SCHIMPERNA, Giuliana , PO', Riccardo
发明人： CALDARARO, Maria , PELLEGRINO, Andrea , SCHIMPERNA, Giuliana , PO', Riccardo
IPC分类号： C08G73/06 , C07D409/14 , C08G61/12 , C09D11/10 , H01L51/00
CPC分类号： C07D409/14 , C08G61/122 , C08G61/123 , C08G61/126 , C08G2261/3241 , C08G2261/3246 , C08G2261/411 , C08G2261/91 , H01L51/0036 , H01L51/0043 , H01L51/4253 , Y02E10/549
摘要： The present invention relates to copolymers for solar cells based on acridonic units comprising: a monomeric unit (A) having general formula (I) wherein X is S or Se, Y is 0, S or NR' and R, R', the same or different, are C 4 -C 24 alkyl groups, aryl groups optionally substituted with other functional groups, acyl groups or thioacyl groups; at least one monomer unit (B) having general formula (II) wherein Z is 0, S, Se or N-R", wherein R" is a C 4 -C 24 alkyl group, an aryl group optionally substituted with other functional groups, an acyl group or thioacyl group, said monomeric unit (B) being connected to any position available of a hetero-aromatic side ring of the unit (A) through one of the two positions indicated by the dashed lines in general formula (II). Photovoltaic devices comprising said alternating π-conjugated polymers are also described.
摘要翻译：本发明涉及基于吖啶单体的太阳能电池用共聚物，包括：具有通式（I）的单体单元（A），其中X为S或Se，Y为0，S或NR'，R，R'为相同或不同的是C 4 -C 24烷基，任选被其它官能团取代的芳基，酰基或硫代酰基; 至少一种具有通式（II）的单体单元（B），其中Z为0，S，Se或NR“，其中R”为C 4 -C 24烷基，任选被其它官能团取代的芳基，酰基或硫代酰基，所述单体单元（B）通过通式（II）中虚线所示的两个位置之一连接到单元（A）的异芳族侧环的任何位置上。还描述了包含所述交替的p共轭聚合物的光伏器件。

5. 发明申请

WO2010046114A2 π-CONJUGATED LOW-BAND-GAP COPOLYMERS CONTAINING BENZOTRIAZOLE UNITS 审中-公开
标题翻译：含有苯并噻唑单体的p型共轭低级共聚物
公开(公告)号：WO2010046114A2
公开(公告)日：2010-04-29
申请号：PCT/EP2009/007581
申请日：2009-10-16
申请人： ENI S.P.A. , PO', Riccardo , PELLEGRINO, Andrea , SCHIMPERNA, Giuliana , CALDARARO, Maria
发明人： PO', Riccardo , PELLEGRINO, Andrea , SCHIMPERNA, Giuliana , CALDARARO, Maria
CPC分类号： C08G73/08 , C08G61/123 , C08G61/126 , C08G73/0672 , C08G2261/3142 , C08G2261/3223 , C08G2261/3241 , H01L51/0035 , H01L51/0036 , H01L51/0043 , H01L51/42 , Y02E10/549
摘要： The present invention relates to an alternating or statistical conjugated copolymer comprising: at least one benzotriazole unit B having general formula (Ia) or (Ib) : wherein the group R is selected from alkyl, aryl, acyl or thioacyl groups, possibly substituted; at least one conjugated structural unit A, wherein each unit B is connected with at least one unit A in any of the positions 4, 5, 6 or 7, preferably in positions 4 or 7.
摘要翻译：本发明涉及一种交替或统计共轭共聚物，其包含：至少一种具有通式（Ia）或（Ib）的苯并三唑单元B：其中基团R选自可能被取代的烷基，芳基，酰基或硫代酰基; 至少一个共轭结构单元A，其中每个单元B与位置4,5,6或7中的任何位置中的至少一个单元A相连，优选位置4或7。

6. 发明申请

WO2018007991A1 NON-AQUEOUS REDOX FLOW BATTERIES 审中-公开
标题翻译：非水性氧化还原液流电池
公开(公告)号：WO2018007991A1
公开(公告)日：2018-01-11
申请号：PCT/IB2017/054106
申请日：2017-07-07
申请人： ENI S.P.A.
发明人： TACCA, Alessandra , PELLEGRINO, Andrea
IPC分类号： H01M8/18 , H01M10/056 , H01M10/36 , H01M10/627
摘要： Non-aqueous redox flow battery (RFB) comprising: a positive compartment in which a positive electrode is positioned and in which a positive non-aqueous liquid electrolyte is caused to flow; a negative compartment in which a negative electrode is positioned and in which a negative non-aqueous liquid electrolyte is caused to flow; an ion-exchange membrane positioned between the positive compartment and the negative compartment in which: said positive non-aqueous liquid electrolyte comprises a solution of copper triflate or tetrafluoroborate complexes [Cu(l) or Cu(ll)] in at least one organic solvent; said negative non-aqueous liquid electrolyte comprises a solution of at least one benzothiadiazole or a derivative thereof in at least one organic solvent. Said non-aqueous redox flow battery (RFB) may advantageously be used in devices which require a moderate to large power output (e.g., about 100 kW - 100 MW) for a number of hours (i.e. > 1 hour) such as, for example, devices for storing energy derived from industrial plants or from alternative energy sources (such as, solar or wind energy) for subsequent use (for example, for domestic use) or for sale.
摘要翻译：非水性氧化还原液流电池（RFB）包括：正极室，其中正极定位在正极室中，并且正极非水电解液流入其中; 负极室，在负极室中放置负极，并使负极非水电解液流过; 位于所述正隔室和所述负隔室之间的离子交换膜，其中：所述正非水液体电解质包含三氟甲磺酸铜或四氟硼酸铜络合物[Cu（I）或Cu（II）]在至少一种有机溶剂中的溶液 ; 所述负型非水液体电解质包含至少一种苯并噻二唑或其衍生物在至少一种有机溶剂中的溶液。所述非水性氧化还原液流电池（RFB）可有利地用于需要中等至大功率输出（例如，大约100kW至100MW）若干小时（即> 1小时）的装置中，例如用于例如，用于存储来自工业工厂或来自替代能源（例如太阳能或风能）的能量用于随后使用（例如，用于家用）或用于销售的设备。

7. 发明申请

WO2017081623A1 PHOTOACTIVE FLUORINATED CONJUGATED COPOLYMER 审中-公开
标题翻译：光活性氟化共轭聚合物
公开(公告)号：WO2017081623A1
公开(公告)日：2017-05-18
申请号：PCT/IB2016/056743
申请日：2016-11-09
申请人： ENI S.P.A.
发明人： PELLEGRINO, Andrea , SIMONE, Fiorenza
IPC分类号： H01L51/00 , H01L51/46
CPC分类号： H01L51/0043 , H01L51/0036 , H01L51/4253 , Y02E10/549
摘要： A photoactive fluorinated conjugated copolymer comprising units having general formula (I): -(D-BTD)- and units having general formula (la): -(D-BTZ)- in which: D represents a donor group having the following general formulae (II), (III), (IV): in which: R 1 , R 2 , R 3 and R 4 , the same or different, represent a hydrogen atom; or they are selected from linear or branched, saturated or unsaturated C 1 -C 20 alkyl groups, preferably C 2 -C 10 , optionally containing heteroatoms; n is 1 or 2; BTD represents a benzothiadiazole group having general formula (V): in which X 1 and X 2 , mutually identical, represent a hydrogen atom; or a fluorine atom; or they are selected from linear or branched, saturated or unsaturated C 1 - C 20 alkyl groups, preferably C 2 -C 10 , optionally containing heteroatoms, linear or branched, saturated or unsaturated C 1 -C 20 alkoxy groups, preferably C 2 -C 10 ; BTZ represents a benzotriazole group having general formula (VI): in which: R 5 is selected from linear or branched, saturated or unsaturated C 1 -C 20 alkyl groups, preferably C 8 -C 18 , optionally containing heteroatoms; X 1 and X 2 , mutually identical, represent a hydrogen atom; or a fluorine atom; or they are selected from linear or branched, saturated or unsaturated C 1 -C 20 alkyl groups, preferably C 2 -C 10 , optionally containing heteroatoms, linear or branched, saturated or unsaturated C 1 -C 20 alkyl groups, preferably C 2 -C 10 ; provided that in at least one from the benzothiadiazole group having general formula (V) and the benzotriazole group having general formula (VI), X 1 and X 2 , mutually identical, represent a fluorine atom. Said photoactive fluorinated conjugated copolymer may be advantageously used in the manufacture of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on rigid support, or on flexible support.
摘要翻译：包含具有通式（I）的单元的光活性氟化共轭共聚物： - （D-BTD） - 和具有通式（Ia）的单元： - （D-BTZ） - 其中：D表示具有以下通式（II），（III），（IV）的供体基团：其中：R 1，R 2，R 3， R 4和R 4相同或不同，代表氢原子; 或者它们选自直链或支链，饱和或不饱和的C 1 -C 20烷基，优选C 2 -C 10 任选含有杂原子; n是1或2; BTD代表具有通式（V）的苯并噻二唑基团：其中X 1和X 2彼此相同，代表氢原子; 或氟原子; 或者它们选自直链或支链，饱和或不饱和的C 1 -C 20烷基，优选C 2 -C 10 任选含有杂原子，直链或支链，饱和或不饱和的C 1 -C 20烷氧基，优选C 2 -C <子> 10 ; BTZ表示具有通式（VI）的苯并三唑基团：其中：R5选自直链或支链，饱和或不饱和的C 1 -C 20烷基，优选C8-C18烷基，任选地含有杂原子; X 1和X 2彼此相同，代表氢原子; 或氟原子; 或者它们选自直链或支链，饱和或不饱和的C 1 -C 20烷基，优选C 2 -C 10 任选含有杂原子，直链或支链，饱和或不饱和的C 1 -C 20烷基，优选C 2 -C 3 - <子> 10 ; 条件是在具有通式（V）的苯并噻二唑基团和具有通式（VI）的苯并三唑基团中的至少一个中，X 1和X 2彼此相同，代表氟原子。所述光敏氟化共轭共聚物可以有利地用于制造光伏设备（或太阳能设备），例如光伏电池（或太阳能电池），光伏模块（或太阳能模块），或者在刚性支撑上，或者在柔性支持。

8. 发明申请

WO2013160201A1 ORGANIC DYE FOR A DYE-SENSITIZED SOLAR CELL 审中-公开
标题翻译：有机染料用于敏感的敏感细胞
公开(公告)号：WO2013160201A1
公开(公告)日：2013-10-31
申请号：PCT/EP2013/058159
申请日：2013-04-19
申请人： ENI S.P.A. , CNRS (CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE)
发明人： BIAGINI, Paolo , DEMETER, Dora , LERICHE, Philippe , PELLEGRINO, Andrea , RONCALI, Jean , SCHIMPERNA, Giuliana
IPC分类号： C09B57/00 , H01G9/20 , H01L31/042
CPC分类号： H01G9/2059 , C07D333/08 , C09B57/00 , H01G9/2031 , H01L51/0067 , H01L51/0068 , Y02E10/542 , Y02E10/549
摘要： Organic dye for a dye-sensitized solar cell (DSSC) comprising at least one electron-acceptor unit and at least one π-conjugated unit. Said organic dye is particularly useful in a dye-sensitized photoelectric transformation element which, in its turn, can be used in a dye-sensitized solar cell (DSSC).
摘要翻译：用于染料敏化太阳能电池（DSSC）的有机染料包含至少一个电子受体单元和至少一个π-共轭单元。所述有机染料特别可用于染料敏化的光电转换元件，其可以用于染料敏化太阳能电池（DSSC）中。

9. 发明申请

WO2011138655A1 AROMATIC MONOMERS DERIVING FROM GLYCEROL UNITS, PROCESS FOR THEIR PREPARATION AND USE THEREOF FOR THE PREPARATION OF WATER-SOLUBLE CONJUGATED POLYMERS 审中-公开
标题翻译：从甘油单位获得的芳族单体，其制备和使用它们制备水溶性聚合物的方法
公开(公告)号：WO2011138655A1
公开(公告)日：2011-11-10
申请号：PCT/IB2011/000941
申请日：2011-04-29
申请人： ENI S.P.A. , SCHIMPERNA, Giuliana , PO', Riccardo , PELLEGRINO, Andrea , CALDARARO, Maria
发明人： SCHIMPERNA, Giuliana , PO', Riccardo , PELLEGRINO, Andrea , CALDARARO, Maria
IPC分类号： C07D317/22 , C07D405/12 , C07D409/12 , C08G61/12 , H01L51/00
CPC分类号： C07D405/12 , C07D317/22 , C07D409/12 , C08G61/123 , C08G61/124 , C08G61/126 , C08G75/06 , C08G2261/124 , C08G2261/1422 , C08G2261/1424 , C08G2261/3142 , C08G2261/3223 , C08G2261/3241 , C08G2261/3246 , C08G2261/411 , C08G2261/91 , H01L51/0036 , H01L51/0039 , H01L51/0043 , H01L51/0068 , H01L51/0072 , H01L51/42
摘要： Monomers having formula (I) and process for their synthesis which comprises the etherification reaction of a halogen-derivative (Z = C1, Br, I) having formula (III) with the hydroxyl group of the glycerol derivative (IV), according to the following scheme:(Formula III, IV & I) (III) (IV) (I)
摘要翻译：具有式（I）的单体及其合成方法，其包括具有式（III）的卤素衍生物（Z = C1，Br，I）与甘油衍生物（IV）的羟基的醚化反应，根据（式III，IV＆I）（III）（IV）（I）

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