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    • 3. 发明申请
    • WATER IN OIL EXPLOSIVE EMULSIONS
    • 油爆炸乳液中的水
    • WO0155058A3
    • 2002-03-07
    • PCT/US0102181
    • 2001-01-23
    • LUBRIZOL CORPPOLLACK ROBERT AMULLAY JOHN JFILIPPINI BRIAN B
    • POLLACK ROBERT AMULLAY JOHN JFILIPPINI BRIAN B
    • C06B31/28C06B47/00C06B47/14
    • C06B31/285C06B47/00C06B47/145
    • Water-in-oil emulsion explosive compositions comprising a) an aqueous oxidizer phase comprising at least one oxygen supplying component wherein said oxygen supplying component comprises at least 50% by weight of prilled agricultural grade ammonium nitrate, b) an organic phase, comprising at least one organic fuel and c) an emulsifying amount of an aliphatic hydrocarbyl group substituted succinic emulsifier composition, said succinic emulsifier composition having at least one of succinic ester groups, succinic amide groups, succinic imine groups, succinic ester-amide and succinimide groups, and mixtures thereof, wherein each of said groups is substituted with an aminoalkyl group, wherein the aliphatic hydrocarbon based group contains from about 18 up to about 500 carbon atoms.
    • 油包水乳剂炸药组合物,其包含a)包含至少一种供氧组分的含水氧化剂相,其中所述供氧组分包含至少50重量%的颗粒状农业级硝酸铵,b)有机相,至少包含 一种有机燃料和c)乳化量的脂族烃基取代的琥珀酸乳化剂组合物,所述琥珀酸乳化剂组合物具有琥珀酸酯基,琥珀酰胺基,琥珀酰亚胺基,琥珀酸酯 - 酰胺和琥珀酰亚胺基中的至少一种,以及混合物 其中所述基团各自被氨基烷基取代,其中脂族烃基基团含有约18至约500个碳原子。
    • 4. 发明申请
    • PARTIALLY DEHYDRATED REACTION PRODUCT, PROCESS FOR MAKING SAME, AND EMULSION CONTAINING SAME
    • 部分脱水反应产物,其制备方法和含有其的乳液
    • WO0152976A9
    • 2002-10-24
    • PCT/US0101939
    • 2001-01-22
    • LUBRIZOL CORP
    • FILIPPINI BRIAN BLANGE RICHARD MGRISSO BRYAN AHIRD BRYN
    • B01F17/52B01F17/00C05G3/00C05G5/00C06B47/00C06B47/14C10L1/32C10M129/74C10M129/76C10M129/95C10M133/04C10M133/16C10M133/56C10M159/12C10M173/00C10N30/04C10N40/08C10N40/20C10N40/22A01N25/04A01N25/30C05G3/06C06B23/00E21B43/27
    • C10L1/328B01F17/0021B01F17/0028B01F17/0042B01F17/005C06B47/145
    • The disclosed invention relates to a composition comprising a partially dehydrated product made by: (I) reacting (A) a hydrocarbyl substituted succinic acid or anhydride with (B) a polyol, a polyamine, a hydroxyamine, or a mixture of two or more thereof, to form a first intermediate product comprising: an ester, partial ester or mixture thereof when (B) is a polyol; an amide, imide, salt, amide/salt, partial amide or mixture of two or more thereof when (B) is a polyamine; or an ester, partial ester, amide, partial amide, amide/salt, imide, ester/salt, salt or a mixture of two or more thereof when (B) is a hydroxyamine, a mixture of a polyol and a polyamine, a mixture of a polyol and a hydroxyamine, or a mixture of a polyamine and a hydroxyamine, or a mixture of a polyol, a polyamine and a hydroxyamine; the hydrocarbyl substituent of said acid or anhydride having an average of about 8 to about 200 carbon atoms; and (II) heating said first intermediate product at an effective temperature to form a second intermediate product with water of reaction being formed, and separating a portion of said water of reaction from said second intermediate product, when (A) is said succinic anhydride the amount of water of reaction that is separated is from about 0.2 to about 0.9 equivalents of said water of reaction per equivalent of said succinic anhydride, when (A) is said succinic acid the amount of water of reaction that is separated is from about 1.2 to about 1.9 moles of said water of reaction per equivalent of said succinic acid, said partially dehydrated product having a total acid number in the range of about 20 to about 100 mg of KOH/g.
    • 所公开的发明涉及包含部分脱水产物的组合物,其通过以下步骤制备:(I)使(A)烃基取代的琥珀酸或酸酐与(B)多元醇,多胺,羟胺或其两种或更多种的混合物 形成第一中间产物,其包含:(B)为多元醇时的酯,偏酯或其混合物; 当(B)是多胺时,酰胺,酰亚胺,盐,酰胺/盐,部分酰胺或其两种或更多种的混合物; 或(B)为羟基胺,多元醇和多胺的混合物,混合物或其混合物时,可以使用酯,酯,酯,酰胺,部分酰胺,酰胺/盐,酰亚胺,酯/盐,盐或其两种或多种的混合物 的多元醇和羟胺,或多胺和羟胺的混合物,或多元醇,多胺和羟胺的混合物; 所述酸或酸酐的烃基取代基具有约8至约200个碳原子的平均值; 和(II)在有效温度下加热所述第一中间产物以形成具有反应水的第二中间产物,并且当(A)是所述琥珀酸酐时,将所述反应水的一部分与所述第二中间产物分离 当(A)是所述琥珀酸时,分离的反应水的量为约0.2至约0.9当量的所述反应水反应当量的所述琥珀酸酐时,分离的反应水的量为约1.2至 每当量所述琥珀酸约1.9摩尔所述反应水,所述部分脱水产物的总酸值在约20至约100mg KOH / g的范围内。