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    • 5. 发明申请
    • THERMOPLASTIC ELASTOMERS
    • 热塑弹性体
    • WO1993007194A1
    • 1993-04-15
    • PCT/US1992008508
    • 1992-10-06
    • LANDEC CORPORATION
    • LANDEC CORPORATIONBITLER, Steven, P.STEWART, Ray, F.KAMP, David, A.FREELIN, Robert, G.YOON, Valentine, Y.
    • C08G18/48
    • C08G81/02A61K47/34C05G3/0029C05G3/0047C06B45/10C06B45/18C08F283/006C08F293/00C08G18/10C08G18/4854C08G18/4858C08G81/00C08G2170/40C08G2250/00C08G2390/00C08L2666/04C09J171/02C08G18/48
    • A novel thermoplastic elastomer (TPE) which comprises (i) polymeric A blocks in which there are side chains comprising crystallizable moieties having a melting point Tq, and (ii) at least one amorphous polymeric B block having a glass transition point, Tgs, which is less than (Tq - 10) DEG C. The relative proportions and molecular weights of the A and B blocks can be adjusted so as to produce desired physical properties with comparatively little change in Tq, which depends chiefly upon the nature of the crystallizable moieties, which may be for example n-alkyl groups containing 12 to 50 carbon atoms. The novel TPE's show a sharply reduced viscosity in the region of Tq, and can be melt-processed at temperatures close to Tq. The novel TPE's are useful in the form of compositions, shaped articles and assemblies which comprise one of the novel TPE's and a second component which is mixed with, or surrounded by, or surrounds or otherwise provides a substrate for, the TPE. Preferred second components are explosives and other energetic materials, pharmaceuticals, seeds, perfumes, deodorizers, pest control agents, herbicides, insecticides, fungicides, biologically active materials, agrichemicals, and disinfectants. Second components can be released from such a composition or shaped article by a natural increase in the ambient temperature or by heating the composition or article to a temperature at least equal to Tq by means of heat which is (i) generated artificially or (ii) generated by a mammalian body and/or (iii) is conveyed artificially to the composition, article or assembly.
    • 一种新型热塑性弹性体(TPE),其包含(i)聚合物A嵌段,其中存在包含具有熔点Tq的可结晶部分的侧链,和(ii)至少一个具有玻璃化转变点的无定形聚合物B​​嵌段,其Tg 小于(Tq-10)℃。可以调节A和B嵌段的相对比例和分子量,以便产生所需的物理性质,其中Tq的变化相对较小,这主要取决于可结晶部分的性质 ,其可以是例如含有12至50个碳原子的n-烷基。 新型TPE在Tq区域显示出显着降低的粘度,并可在接近Tq的温度进行熔融加工。 新型TPE可用于组合物,成型制品和组件的形式,其包含新型TPE之一和与TPE混合或围绕或围绕或以其它方式提供底物的第二组分。 优选的第二组分是爆炸物和其它高能材料,药物,种子,香料,除臭剂,害虫控制剂,除草剂,杀虫剂,杀真菌剂,生物活性物质,农药和消毒剂。 可以通过环境温度的自然增加或通过加热组合物或制品至组合物或制品至少等于Tq的温度,通过以下方式产生第二组分或成型制品:(i)人造或(ii) 由哺乳动物身体产生和/或(iii)被人工地输送到组合物,制品或组装体上。