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1. 发明申请

WO2009138886A2 WATER-SENSITIVE FILM CONTAINING AN OLEFINIC ELASTOMER 审中-公开
标题翻译：含有烯烃弹性体的水敏膜
公开(公告)号：WO2009138886A2
公开(公告)日：2009-11-19
申请号：PCT/IB2009/051331
申请日：2009-03-30
申请人： KIMBERLY-CLARK WORLDWIDE, INC. , SHI, Bo , WANG, James, H. , WIDEMAN, Gregory, J.
发明人： SHI, Bo , WANG, James, H. , WIDEMAN, Gregory, J.
IPC分类号： C08J5/18 , C08L29/04 , C08L23/00 , B29D7/01 , A61F13/15
CPC分类号： C08J5/18 , C08J2329/04 , C08K5/0016 , C08K5/053 , C08L1/284 , C08L23/08 , C08L23/0815 , C08L29/04 , C08L53/02 , C08L67/02 , C08L2666/24 , C08L2666/04
摘要： A film that is both elastic and water-sensitive (e.g., water-soluble, water-dispersible, etc.) in that it loses its integrity over time in the presence of water is provided. To achieve these dual attributes, the film contains an olefinic elastomer and a water-soluble polymer. Although these polymers are normally chemically incompatible due to their different polarities, the present inventors have discovered that phase separation may be minimized by selectively controlling certain aspects of the film, such as the nature of the polyolefin, water-soluble polymer, and other film components, the relative amount of the film components, and so forth. For example, certain water-soluble polymers may be selected that have a low molecular weight and viscosity to enhance their melt compatibility with nonpolar polyolefins. This, in turn, may result in a film that is generally free of separate phases, which would otherwise limit the ability of the water-soluble polymer to contact water and disperse.
摘要翻译：提供了具有弹性和水敏性（例如水溶性，水分散性等）的膜，因为它在水的存在下随时间失去其完整性。为了实现这些双重属性，膜含有烯烃弹性体和水溶性聚合物。虽然这些聚合物由于其极性不同而通常是化学上不相容的，但是本发明人已经发现，通过选择性地控制膜的某些方面，例如聚烯烃，水溶性聚合物和其它膜组分的性质，可以使相分离最小化，膜成分的相对量等。例如，可以选择某些具有低分子量和粘度的水溶性聚合物，以提高它们与非极性聚烯烃的熔融相容性。这又可能导致通常没有分离相的膜，否则这将限制水溶性聚合物与水接触并分散的能力。

2. 发明申请

WO2010070470A2 INJECTION MOLDING MATERIAL CONTAINING STARCH AND PLANT PROTEIN 审中-公开
标题翻译：含淀粉和植物蛋白的注射成型材料
公开(公告)号：WO2010070470A2
公开(公告)日：2010-06-24
申请号：PCT/IB2009/054733
申请日：2009-10-26
申请人： KIMBERLY-CLARK WORLDWIDE, INC. , WANG, James, H. , WIDEMAN, Gregory, J. , SHI, Bo , FUNK, Sara, A.
发明人： WANG, James, H. , WIDEMAN, Gregory, J. , SHI, Bo , FUNK, Sara, A.
IPC分类号： C08L3/02 , C08L89/00 , C08L101/00 , B29C45/00
CPC分类号： C08L23/06 , B29C45/0001 , B29K2105/16 , B29K2711/00 , B29K2995/006 , C08L1/00 , C08L3/00 , C08L3/02 , C08L23/02 , C08L23/04 , C08L23/10 , C08L89/00 , C08L2205/02 , C08L2207/066 , Y10T428/1348 , Y10T428/1352 , C08L2666/06 , C08L2666/26
摘要： An injection molding material that includes a renewable resin containing a combination of renewable polymers (e.g., starch and plant protein) and a plasticizer is provided. Although such compounds are normally difficult to process into thermoplastics, the present inventors have discovered that injection molding materials may nevertheless be formed by melt blending the renewable resin with a synthetic resin (e.g., polyolefin) while selectively controlling the nature of the resins and their relative concentrations. In this manner, a morphology may be achieved in which the renewable resin is present as a discontinuous phase that is dispersed within a continuous phase of the synthetic resin (e.g., "island-in-the-sea" morphology). The discontinuous and continuous phases may each constitute from about 30 vol.% to about 70 vol.%, and in some embodiments, from about 40 vol.% to about 60 vol.%. With such a morphology, the continuity of the synthetic resin can minimize the aggregate properties of the renewable resin such that the molding material possesses melt properties similar to that of the synthetic resin. Further, this morphology may also minimize the need to use different molding tools as the shrinkage properties of the overall composition may be substantially similar to that of the synthetic resin.
摘要翻译：提供包含含有可再生聚合物（例如淀粉和植物蛋白）和增塑剂的组合的可再生树脂的注塑材料。尽管这些化合物通常难以加工成热塑性塑料，但是本发明人已经发现注塑材料可以通过将可再生树脂与合成树脂（例如聚烯烃）熔融共混来形成，同时选择性地控制树脂及其相对性质浓度。以这种方式，可以实现可再生树脂作为分散在合成树脂的连续相内的不连续相（例如，“海中岛”形态）存在的形态。不连续相和连续相各自可以构成从约30体积％至约70体积％，并且在一些实施方案中从约40体积％至约60体积％。通过这样的形态，合成树脂的连续性可以使可再生树脂的聚集性能最小化，使得模制材料具有与合成树脂类似的熔融性质。此外，由于整个组合物的收缩性质可能与合成树脂的收缩性质基本相似，所以这种形态也可以最小化使用不同模塑工具的需要。

3. 发明申请

WO2010070469A2 BIODEGRADABLE AND RENEWABLE FILM 审中-公开
标题翻译：可生物降解和可再生膜
公开(公告)号：WO2010070469A2
公开(公告)日：2010-06-24
申请号：PCT/IB2009/054732
申请日：2009-10-26
申请人： KIMBERLY-CLARK WORLDWIDE, INC. , SHI, Bo , FUNK, Sara, A. , WANG, James, H. , WIDEMAN, Gregory, J. , KAUFMAN, Ross, T. , TOPOLKARAEV, Vasily, A.
发明人： SHI, Bo , FUNK, Sara, A. , WANG, James, H. , WIDEMAN, Gregory, J. , KAUFMAN, Ross, T. , TOPOLKARAEV, Vasily, A.
IPC分类号： C08J5/18 , C08L3/02 , C08L89/00 , C08J9/22
CPC分类号： A61L15/225 , A61L15/425 , A61L15/62 , B29C47/00 , B29C47/0026 , B29C55/005 , B29K2003/00 , B29K2105/04 , B29K2105/16 , B29K2995/006 , B32B5/022 , B32B9/02 , B32B27/08 , B32B27/12 , B32B27/20 , B32B27/22 , B32B27/30 , B32B27/32 , B32B27/36 , B32B27/40 , B32B37/153 , B32B2038/0028 , B32B2262/0238 , B32B2262/0246 , B32B2262/0253 , B32B2262/0261 , B32B2262/0276 , B32B2262/0292 , B32B2262/062 , B32B2305/20 , B32B2307/31 , B32B2307/7145 , B32B2307/7163 , B32B2307/724 , B32B2307/7265 , B32B2555/02 , C08J5/18 , C08J2300/16 , C08J2303/02 , C08L3/02 , C08L89/00 , Y10T428/24504 , Y10T442/282 , Y10T442/674 , C08L2666/26 , C08L89/02
摘要： A biodegradable and renewable film that may be employed in a wide variety of applications is provided. The film is formed from a thermoplastic composition that contains at least one starch and at least one plant protein. Even at a high renewable material content, the present inventors have discovered that films may be readily formed from plant proteins and starches by selectively controlling the individual amount of the starch and plant proteins, the nature of the starch and plant proteins, and other components used in the film. Balancing the amount of starches and plant proteins within a certain range, for instance, can reduce the likelihood of plant protein aggregation and enhance the ability of the composition to be melt processed. The composition also contains at least one plasticizer that improves the thermoplastic nature of the protein and starch components. The selection of the plasticizer may also help reduce the tendency of the plant protein to aggregate during melt processing. For example, a relatively acidic plasticizer (e.g., carboxylic acid) may be employed in certain embodiments to minimize the formation of disulfide bonds in a gluten protein, and thereby decrease its tendency to aggregate.
摘要翻译：提供了可用于各种应用的可生物降解和可再生的膜。该膜由含有至少一种淀粉和至少一种植物蛋白质的热塑性组合物形成。即使在高可再生材料含量下，本发明人也发现，通过选择性地控制淀粉和植物蛋白质的个体数量，淀粉和植物蛋白质的性质以及所使用的其它组分，可以容易地从植物蛋白质和淀粉形成膜在电影里。例如，将一定范围内的淀粉和植物蛋白质的量平衡可以降低植物蛋白质聚集的可能性并增加组合物被熔融加工的能力。该组合物还含有至少一种改善蛋白质和淀粉组分的热塑性质的增塑剂。增塑剂的选择也有助于降低植物蛋白质在熔融加工过程中聚集的趋势。例如，在某些实施方案中可以使用相对酸性的增塑剂（例如羧酸）以最小化谷蛋白中二硫键的形成，从而降低其聚集趋势。

4. 发明申请

WO2009138885A3 WATER-SENSITIVE FILM CONTAINING THERMOPLASTIC POLYURETHANE 审中-公开
公开(公告)号：WO2009138885A3
公开(公告)日：2009-11-19
申请号：PCT/IB2009/051204
申请日：2009-03-23
申请人： KIMBERLY-CLARK WORLDWIDE, INC. , SHI, Bo , WANG, James, H. , WIDEMAN, Gregory, J.
发明人： SHI, Bo , WANG, James, H. , WIDEMAN, Gregory, J.
IPC分类号： C08J5/18 , C08L29/04 , C08L75/04 , C08K5/053 , B29C55/06 , B29C55/08
摘要： A film that contains a thermoplastic polyurethane and water-soluble polymer is provided. The film is both elastic and water-sensitive (e.g., water-soluble, water- dispersible, etc.) in that it loses its integrity over time in the presence of water. The dual attributes of elasticity and water-sensitivity may be achieved by reducing the tendency of the thermoplastic polyurethane and water-soluble polymer to form separate phases. Namely, phase separation may cause the elastomer to act as a barrier and limit the ability of the water-soluble polymer to contact water and thereby disperse. To minimize such phase separation, a variety of aspects of the film construction may be selectively controlled, such as the nature of the thermoplastic polyurethane and water-soluble polymer, the relative amount of each component, and so forth. For example, thermoplastic polyurethanes are polar in nature and thus may be generally compatible with water-soluble polymers (e.g., polyvinyl alcohol), which are also polar in nature. Further, water-soluble polymers having a relatively low molecular weight and viscosity typically possess better melt compatibility with polar thermoplastic polyurethanes. By carefully controlling the nature of the polymers used to form the film, the present inventors have discovered that a film may be formed that is generally free of distinct phases.

5. 发明申请

WO2012077002A3 MELT PROCESSED ANTIMICROBIAL COMPOSITION 审中-公开
公开(公告)号：WO2012077002A3
公开(公告)日：2012-06-14
申请号：PCT/IB2011/054828
申请日：2011-10-31
申请人： KIMBERLY-CLARK WORLDWIDE, INC. , WANG, James, H. , SHI, Bo , LEE, JaeHong , TOPOLKARAEV, Vasily, A. , SCHOLL, Neil, T. , KIM, YoungSook
发明人： WANG, James, H. , SHI, Bo , LEE, JaeHong , TOPOLKARAEV, Vasily, A. , SCHOLL, Neil, T. , KIM, YoungSook
IPC分类号： A01N65/00 , A01N43/04 , A61K31/70 , A01P1/00
摘要： A method for forming a composition that includes mixing an antimicrobially active botanical oil (e.g., thymol, carvacrol, etc.) and a modified starch polymer within a melt blending device (e.g., extruder) is provided. Unlike the problems associated with proteins, the use of starch polymers allows for a greater degree of flexibility in the processing conditions and is still able to achieve good properties in the resulting composition. The present inventors have also discovered that a plasticizer may be employed to facilitate melt processing of the starch, as well as to enhance the ability of the botanical oil to flow into the internal structure of the starch where it can be retained in a stable manner. The composition is also typically generally free of solvents. In this manner, the starch will not generally disperse before use and prematurely release the botanical oil. Due to the water sensitivity of the modified starch, however, it may be subsequently dispersed by moisture when it is desired to release the botanical oil.

6. 发明申请

WO2010125490A3 ALGAE-BLENDED COMPOSITIONS FOR THERMOPLASTIC ARTICLES 审中-公开
公开(公告)号：WO2010125490A3
公开(公告)日：2010-11-04
申请号：PCT/IB2010/051633
申请日：2010-04-14
申请人： KIMBERLY-CLARK WORLDWIDE, INC. , SHI, Bo , WANG, James, H.
发明人： SHI, Bo , WANG, James, H.
IPC分类号： C08K11/00 , C08K13/08 , C08L3/02 , C08L67/00 , C08J5/18
摘要： A thermoplastic material composition containing certain biodegradable and renewable components is described. The thermoplastic composition that includes a least one kind of algae or a blend of at least one kind of algae and a plant polymer a blend of algae and/or plant-based polymers, such as proteins and starches, as relatively low cost feedstock. The algae or blend may be plasticized. Additionally, a method adapted for large scale fabrication of fibers, films, or extruded articles is also described.

7. 发明申请

WO2009118665A3 THERMOPLASTIC STARCH FOR USE IN MELT-EXTRUDED SUBSTRATES 审中-公开
公开(公告)号：WO2009118665A3
公开(公告)日：2009-10-01
申请号：PCT/IB2009/050478
申请日：2009-02-05
申请人： KIMBERLY-CLARK WORLDWIDE, INC. , SHI, Bo , WANG, James, H.
发明人： SHI, Bo , WANG, James, H.
IPC分类号： C08L3/04 , C08L3/06 , C08L3/08 , C08L3/14 , C08L67/04 , C08J5/18 , B32B9/00 , C08J7/04
摘要： A meit-extruded substrate (e.g., fiim, nonwoven web, etc.) that contains a thermoplastic starch formed from a starch and plasticizer is provided. The starch and plasticizer are melt blended together in the presence of a weak organic acid (e.g., lactic acid, formic acid, acetic acid, etc.). By selectively controlling certain parameters of the melt blending process (e.g., extrusion temperature, content of the components, etc.), the present inventors have discovered that the starch may be hydrolyzed in a highly efficient manner to form compositions having a comparably lower weight average molecular weight, polydispersity index, and viscosity, which are particularly suitable for use in the formation of melt-extruded substrates.

8. 发明申请

WO2009024876A2 BIODEGRADABLE WATER-SENSITIVE FILMS 审中-公开
标题翻译：可生物降解的水敏膜
公开(公告)号：WO2009024876A2
公开(公告)日：2009-02-26
申请号：PCT/IB2008/051967
申请日：2008-05-19
申请人： KIMBERLY-CLARK WORLDWIDE, INC. , WANG, James, H. , SHI, Bo
发明人： WANG, James, H. , SHI, Bo
CPC分类号： C08L67/02 , C08J5/18 , C08J2367/00 , C08L3/02 , C08L3/08 , C08L29/04 , C08L67/04 , Y10T428/1345 , Y10T428/31786 , C08L2666/18 , C08L2666/26 , C08L2666/02
摘要： A film that is biodegradable and water-sensitive (e.g., water-soluble, water- dispersible, etc.) in that it loses its integrity over time in the presence of water is provided. The film contains a biodegradable polyester, starch, water-soluble polymer, and plasticizer. The desired water-sensitive attributes of film may be achieved in the present invention by selectively controlling a variety of aspects of the film construction, such as the nature of the components employed, the relative amount of each component, the manner in which the film is formed, and so forth.
摘要翻译：提供了一种可生物降解和对水敏感（例如水溶性，水分散性等）的薄膜，因为它在水存在下随着时间流逝失去其完整性。该薄膜含有可生物降解的聚酯，淀粉，水溶性聚合物和增塑剂。在本发明中，通过选择性地控制膜结构的各种方面，例如所用组分的性质，每种组分的相对量，膜的方式形成，等等。

9. 发明申请

WO2011077280A2 BIODEGRADABLE AND BREATHABLE FILM 审中-公开
标题翻译：生物可降解和可渗透膜
公开(公告)号：WO2011077280A2
公开(公告)日：2011-06-30
申请号：PCT/IB2010/055309
申请日：2010-11-19
申请人： KIMBERLY-CLARK WORLDWIDE, INC. , WANG, James, H. , SHI, Bo
发明人： WANG, James, H. , SHI, Bo
IPC分类号： C08J5/18 , C08L3/02 , C08L67/00 , C08L101/16 , C08K13/02
CPC分类号： A61F13/51401 , A61B46/00 , A61B46/40 , A61F13/15252 , A61F13/15707 , B29C55/005 , B29K2003/00 , B29K2105/04 , B29K2105/16 , B29K2995/0065 , Y10T428/249953
摘要： Breathable and biodegradable polymeric film materials of the invention are highly suitable for use in personal care absorbent articles and other articles. The film includes a biodegradable polymer resin, a thermoplastic starch, a filler and optionally, a protein. The breathable film has a renewable natural polymer component.
摘要翻译：本发明的透气和可生物降解的聚合物薄膜材料非常适用于个人护理吸收制品和其它制品。该膜包括可生物降解的聚合物树脂，热塑性淀粉，填料和任选的蛋白质。透气膜具有可再生的天然聚合物组分。

10. 发明申请

WO2012077003A2 ELASTIC FILM CONTAINING A RENEWABLE STARCH POLYMER 审中-公开
标题翻译：包含可再生淀粉聚合物的弹性薄膜
公开(公告)号：WO2012077003A2
公开(公告)日：2012-06-14
申请号：PCT/IB2011/054830
申请日：2011-10-31
申请人： KIMBERLY-CLARK WORLDWIDE, INC. , WANG, James, H. , SHI, Bo
发明人： WANG, James, H. , SHI, Bo
IPC分类号： C08J5/18 , C08L3/02 , C08L23/00 , C08L75/04 , B01J20/22
CPC分类号： C08L23/0807 , A61F13/49011 , A61F13/49017 , A61F13/4902 , B29C47/0004 , B29C47/0014 , B29C47/0021 , B29C47/0057 , B29C47/0066 , B29C47/065 , B29C47/8805 , B29C47/8845 , B29C47/8865 , B29C47/887 , B29C47/8875 , B29C55/005 , B29C55/06 , B29C55/143 , B29K2003/00 , B29K2021/003 , B29K2067/003 , B29K2067/043 , B29K2067/046 , B29K2077/00 , B29K2105/0038 , B29K2105/04 , B29K2995/006 , C08G18/76 , C08J5/18 , C08J2323/08 , C08J2403/02 , C08K5/053 , C08L3/00 , C08L3/02 , C08L23/14 , C08L23/16 , C08L67/00 , C08L67/02 , C08L75/08 , C08L2314/06
摘要： A film that contains a thermoplastic composition having a substantial portion of a renewable, natural starch polymer, and yet is elastic and exhibits good strength properties, is provided. Although starch is normally chemically incompatible with most elastomeric polymers due to their different polarities, the present inventors have discovered that phase separation may be minimized by selectively controlling certain aspects of the film, such as the nature of the elastomeric polymer and the starch polymer, and other film components, the relative amount of the film components, and the process for making the film.
摘要翻译：提供了含有具有可再生天然淀粉聚合物的大部分的热塑性组合物的薄膜，并且具有弹性并具有良好的强度性能。尽管淀粉由于其极性不同而通常与大多数弹性体聚合物化学不相容，但是本发明人已经发现，通过选择性地控制膜的某些方面，例如弹性体聚合物和淀粉聚合物的性质，可以使相分离最小化，以及其他膜成分，膜成分的相对量，以及膜的制造方法。

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