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    • 2. 发明申请
    • CONDUCTIVE PASTES FOR SOLAR CELLS
    • WO2021240124A1
    • 2021-12-02
    • PCT/GB2021/050696
    • 2021-03-22
    • JOHNSON MATTHEY PUBLIC LIMITED COMPANY
    • ARAPOV, KirillBOOTH, JonathanCELA, BeatrizJOHNSON, SimonKATZBACH, RolandSUTTON, Patricia Ann
    • H01B1/22H01L31/0224
    • A conductive paste comprising: a solids portion comprising a silver powder and a crystalline metal compound powder; and an organic carrier medium in which the silver powder and crystalline metal compound powder are dispersed, wherein the solids portion has a glass content less than 1 wt%, wherein the crystalline metal compound powder has a lead content less than 0.5 wt% calculated as PbO; wherein the crystalline metal compound powder has a particle size with a D90 ≤ 5 µm and a D50 ≤ 2 µm, and wherein the crystalline metal compound powder has a composition comprising at least: 40 to 60 wt% Te calculated as TeO2; 12 to 25 wt% Bi calculated as Bi2O3; and 10 to 25 wt% Zn calculated as ZnO, expressed as percentage weights (wt%) relative to a total weight of the crystalline metal compound powder in the conductive paste excluding any silver compounds, and/or wherein the crystalline metal compound powder has a composition comprising at least: 20 to 40 mol% Te calculated as TeO2; 2 to 6 mol% Bi calculated as Bi2O3; and 14 to 29 mol% Zn calculated as ZnO, expressed as mole percentage (mol%) relative to a total of the crystalline metal compound powder in the conductive paste excluding any silver compounds, and/or wherein the crystalline metal compound powder has a composition comprising at least the following components expressed as a molar ratio defined by SUM(all sources of a particular element) / SUM(all sources of Ag): 0.0060 to 0.0090 Te/Ag; 0.0012 to 0.0026 Bi/Ag; and 0.0029 to 0.0074 Zn/Ag.