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    • 2. 发明申请
    • DENTAL MATERIALS BASED ON MONOMERS HAVING DEBONDING-ON-DEMAND PROPERTIES
    • 基于具有脱粘随需特性的单体的牙科材料
    • WO2013034777A3
    • 2013-06-20
    • PCT/EP2012067679
    • 2012-09-10
    • IVOCLAR VIVADENT AGMOSZNER NORBERTLAMPARTH IRISBOCK THORSTENFISCHER URS KARLSALZ ULRICHRHEINBERGER VOLKERLISKA ROBERT
    • MOSZNER NORBERTLAMPARTH IRISBOCK THORSTENFISCHER URS KARLSALZ ULRICHRHEINBERGER VOLKERLISKA ROBERT
    • A61K6/00A61K6/083
    • A61K6/0835A61K6/0002A61K6/0023A61K6/083C07D239/47C07F3/06C08F122/22C08L33/00
    • The invention relates to a dental material which comprises a thermolabile or photolabile polymerizable compound of the formula (I): [(Z1)n-Q1-X)]k-T-[Y-Q2-(Z2)n]l (formula (I)), in which T is a thermolabile or photolabile group, Z1 and Z2 each independently are a polymerizable group selected from vinyl groups, CH2=CR1-CO-O- and CH2=CR1-CO-NR2- or are an adhesive group selected from -Si(OR)3, -COOH, -O-PO(OH)2, -PO(OH)2, -SO2OH and -SH, with at least one Z1 or Z2 being a polymerizable group, Q1 independently in each case is absent or is an (m+1)-valent linear or branched aliphatic C1-C20 radical, which may be interrupted by -O-, -S-, -CO-O-, -O-CO-, -CO-NR3-, -NR3-CO-, -O-CO-NR3-, -NR3-CO-O- or -NR3-CO-NR3-, Q2 independently in each case is absent or is an (n+1)-valent linear or branched aliphatic C1-C20 radical, which may be interrupted by -O-, -S-, -CO-O-, -O-CO-, -CO-NR3-, -NR3-CO-, -O-CO-NR3-, -NR3-CO-O- or -NR3-CO-NR3-, X and Y in each case independently are absent or are -O-, -S-, CO-O-, -O-CO-, -CO-NR3-, -NR3-CO-, -O-CO-NR3-, -NR3-CO-O- or -NR3-CO-NR3-, R, R1, R2 and R3 each independently are H or C1-C7 alkyl radical, and k, l, m and n each independently are 1, 2 or 3.
    • 本发明涉及含有式(I)的热不稳定或光不稳定聚合化合物的牙科用材料:[(Z1)N-Q1-X)] KT [Y-Q2(Z2)N] 1(式(I)) ,其中T是热不稳定或光不稳定基团,Z 1和Z Z 2各自独立地表示选自乙烯基,CH 2 = CR-CO-O-和CH 2 = CR1-CO-NR 2或从-Si选择的粘合剂组中选出的聚合性基团 (OR)3,-COOH,-O- PO(OH)2,-PO(OH)2, - SO 2 OH,和-SH,其中至少一个Z 1或Z 2为可聚合基团,Q 1在每种情况下省略独立地,或用于( M + 1)价的直链或支链脂族C1-C20基团,被-O - , - S - , - CO-O-,-O-CO - , - CO - NR3,-NR 3-CO-中断 ,-O-CO-NR 3,-NR 3-CO-O-或-NR 3 - CO-NR 3可以被中断,Q2各自独立地不存在或为 - 价第(n + 1)的直链或支链脂族C1-C20 基基团,被-O - , - S - , - CO-O-,-O-CO - , - CO-NR 3,-NR 3 - CO - , - O-CO-NR 3,-NR 3-C中断 OO-或-NR 3-CO-NR3可以被中断,X和Y各自独立地省略或为-O - , - S - ,CO-O-,-O - CO - , - CO-NR 3,NR 3 - 是CO-,-O-CO-NR 3,-NR 3-CO-O-或-NR 3 - CO-NR 3,R,R1,R2和R3各自独立为H或C1-C7烷基,和 k,1,m和n各自独立地为1,2或3。
    • 3. 发明申请
    • DENTAL MATERIALS BASED ON COMPOUNDS HAVING DEBONDING-ON-DEMAND PROPERTIES
    • 基于具有脱粘随需特性的化合物的牙科材料
    • WO2013034778A3
    • 2013-06-20
    • PCT/EP2012067680
    • 2012-09-10
    • IVOCLAR VIVADENT AGMOSZNER NORBERTHIRT THOMASRIST KAISALZ ULRICHWEDER CHRISTOPHFIORE GINAHEINZMANN CHRISTIANRHEINBERGER VOLKER
    • MOSZNER NORBERTHIRT THOMASRIST KAISALZ ULRICHWEDER CHRISTOPHFIORE GINAHEINZMANN CHRISTIANRHEINBERGER VOLKER
    • A61K6/00A61K6/083
    • A61K6/0835A61K6/0002A61K6/0023A61K6/083C07D239/47C07F3/06C08F122/22C08L33/00
    • The invention relates to a dental material which comprises a thermolabile compound of the formula (I): [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]l, in which T is a thermolabile unit which comprises at least one thermolabile group based on non-covalent interactions, Z1 and Z2 each independently are a polymerizable group selected from vinyl groups, CH2=CR1-CO-O- and CH2=CR1-CO-NR2- or are an adhesive group selected from -Si(OR)3, -COOH, -O-PO(OH)2, -PO(OH)2, -SO2OH and -SH, Q1 independently in each case is absent or is an (m+1)-valent linear or branched aliphatic C1-C20 radical, which may be interrupted by -O-, -S-, -CO-O-, -O-CO-, -CO-NR3-, -NR3-CO-, -O-CO-NR3-, -NR3-CO-O- or -NR3-CO-NR3-, Q2 independently in each case is absent or is an (n+1)-valent linear or branched aliphatic C1-C20 radical, which may be interrupted by -O-, -S-, -CO-O-, -O-CO-, -CO-NR3-, -NR3-CO-, -O-CO-NR3-, -NR3-CO-O- or -NR3-CO-NR3-, X and Y in each case independently are absent or are -O-, -S-, CO-O-, -O-CO-, -CO-NR3- or -NR3-CO-, R, R1, R2 and R3 each independently are H or a C1-C7 alkyl radical, k and l each independently are 0, 1, 2 or 3, and m and n each independently are 1, 2 or 3.
    • 本发明涉及含有式(I)的不耐热化合物的牙科用材料:[(Z1)M-Q1-X)] KT [Y-Q2(Z2)n]的升,其中T是一个耐热的单元 其中包含基于非共价相互作用的至少一个热不稳定基团,Z1和Z2各自独立地表示从乙烯基,CH 2 = CR-CO-O-和CH 2 = CR1-CO-NR 2或粘合剂组中选出的聚合性基团 从-Si(OR)3,选择-COOH,-O-PO(OH)2,-PO(OH)2,-SO 2 OH,和-SH是,Q1为不存在或各自独立地为价为第(m + 1)的线性 或由-O - , - S - , - CO-O - , - O-CO-, - CO-NR 3 - , - NR 3 -CO-,-O-CO-NR 3表示的支链C 1 -C 20脂族基团 - , - NR 3-CO-O-或-NR 3 - CO-NR 3可以被中断,Q2各自独立地不存在或表示(n + 1)价的直链或支链脂族C1-C20基团由-O - , - S - , - CO-O-,-O-CO - , - CO-NR 3,-NR 3-CO-,-O-CO-NR 3,-NR 3-CO-O-或-NR 3-CO -NR3-被中断 可以,X和Y各自独立地省略或为-O - , - S - ,CO-O-,-O-CO-,-CO-NR 3或-NR 3-CO-,R,R1,R2和R3各自是 独立地为H或C 1 -C 7烷基,k和l各自独立地为0,1,2或3,m和n各自独立地为1,2或3。