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1. 发明申请

WO2006072766A1 PROCESS FOR THE MANUFACTURE OF ETHYLENE OXIDE 审中-公开
标题翻译：乙烯氧化物的制造方法
公开(公告)号：WO2006072766A1
公开(公告)日：2006-07-13
申请号：PCT/GB2005/005031
申请日：2005-12-22
申请人： INNOVENE EUROPE LIMITED , MAUVEZIN, Mathias
发明人： MAUVEZIN, Mathias
IPC分类号： C07D301/10 , C07D301/32 , C07D303/04
CPC分类号： C07D301/32 , C07D301/10 , C07D303/04
摘要： A process for the manufacture of ethylene oxide successively comprising: (a) a stage of synthesis of the ethylene oxide carried out by bringing ethylene into contact with oxygen in the presence of a catalyst, so as to form a gaseous reaction mixture comprising ethylene oxide and impurities, in particular aldehyde impurities, (b) a stage of absorption carried out by bringing the gaseous reaction mixture into contact with water, so as to form a dilute aqueous ethylene oxide solution, (c) a stage of desorption carried out by entrainment with steam of the dilute aqueous ethylene oxide solution, so as to form a mixture of water enriched in ethylene oxide and to separate, from the said mixture, an aqueous solution depleted in ethylene oxide which is preferably returned to the stage (b) of absorption, and (d) a stage of purification of the ethylene oxide by distillation of the mixture of water enriched in ethylene oxide, so as to isolate and recover a purified ethylene oxide, which process is characterized in that an alkali metal borohydride is employed after the stage (a) of synthesis but before or during the stage (d) of purification is disclosed.
摘要翻译：一种制备环氧乙烷的方法，其连续包括：（a）通过在催化剂存在下使乙烯与氧接触进行的环氧乙烷的合成阶段，以便形成包含环氧乙烷和杂质，特别是醛杂质，（b）通过使气态反应混合物与水接触进行吸收的阶段，以便形成稀的环氧乙烷水溶液，（c）通过夹带进行解吸阶段蒸发稀释的环氧乙烷水溶液，以形成富含环氧乙烷的水的混合物，并从所述混合物中分离出贫氧环氧乙烷的水溶液，该水溶液优选返回到吸收阶段（b）和（d）通过蒸馏富含环氧乙烷的水的混合物来纯化环氧乙烷的阶段，以便分离和回收纯化的环氧乙烷，该方法是其特征在于在合成阶段（a）之后使用碱金属硼氢化物，但在纯化阶段（d）之前或过程中公开。

2. 发明申请

WO2004056463A1 PROCESS FOR MANUFACTURING ETHYLENE OXIDE 审中-公开
标题翻译：制造乙烯氧化物的方法
公开(公告)号：WO2004056463A1
公开(公告)日：2004-07-08
申请号：PCT/GB2003/005203
申请日：2003-12-03
申请人： BP CHEMICALS LIMITED , BP CORPORATION NORTH AMERICA INC. , MAUVEZIN, Mathias , POULAIN, Christine , RGHIOUI, Mehdi , TAHERI, Hassan
发明人： MAUVEZIN, Mathias , POULAIN, Christine , RGHIOUI, Mehdi , TAHERI, Hassan
IPC分类号： B01J8/06
CPC分类号： F28F13/08 , B01J8/008 , B01J8/067 , B01J2208/00212 , F28D7/16
摘要： The present invention relates to a process for manufacturing ethylene oxide by the catalytic oxidation reaction of ethylene by molecular oxygen in a tube reactor. The reactor comprises a bundle of reaction tubes (5) which are immersed in a heat exchange fluid and filled with a solid silver-based catalyst (8) and which are traversed by a reactive gas current containing ethylene and molecular oxygen, which in contact with the catalyst forms the ethylene oxide. The area of the internal cross-section of the reaction tubes (5) decreases between the inlet (1) and the outlet (3) of the tubes over at least a portion of the length of the tubes and remains constant over any remaining portion. The process makes it possible to increase the selectivity of the reaction to ethylene oxide for a given production of ethylene oxide. It also makes it possible to use a maximum charge of active catalyst per unit of internal tube volume available in the reactor, owing in particular to an optimum heat exchange capable more particularly of supplying a relatively stable reaction temperature profile over the whole length of the reaction tubes and preventing in particular reaction runaways.
摘要翻译：本发明涉及通过在管式反应器中通过分子氧的乙烯的催化氧化反应来制造环氧乙烷的方法。反应器包括一束反应管（5），其被浸入热交换流体中并填充有固体银基催化剂（8），并且其被包含乙烯和分子氧的反应气流横穿，所述反应气流与催化剂形成环氧乙烷。反应管（5）的内部横截面的面积在管的入口（1）和出口（3）之间在管的长度的至少一部分上减小，并且在任何剩余部分上保持恒定。该方法使得可以在给定的环氧乙烷生产环境中提高反应对环氧乙烷的选择性。它还使得可以在反应器中使用每单位内管体积的最大电荷的活性催化剂，这尤其是最佳的热交换能力，特别是在反应的整个长度上提供相对稳定的反应温度分布并防止特别是反应逃逸。

3. 发明申请

WO2008084075A1 CATALYST SYSTEM AND PROCESS FOR THE PRODUCTION OF EPOXIDES 审中-公开
标题翻译：催化剂体系和生产环氧化物的方法
公开(公告)号：WO2008084075A1
公开(公告)日：2008-07-17
申请号：PCT/EP2008/050235
申请日：2008-01-10
申请人： INEOS EUROPE LIMITED , BASSET, Jean-Marie , LLINAS, Jean-Richard , MAUVEZIN, Mathias , TAOUFIK, Mostafa , THIVOLLE-CAZAT, Jean
发明人： BASSET, Jean-Marie , LLINAS, Jean-Richard , MAUVEZIN, Mathias , TAOUFIK, Mostafa , THIVOLLE-CAZAT, Jean
IPC分类号： C07D301/10 , C07D301/22 , B01J23/50 , B01J23/847 , B01J35/00 , B01J23/89
CPC分类号： C07D301/10 , B01J21/04 , B01J23/50 , B01J23/8474 , B01J23/898 , B01J35/0006 , B01J37/04
摘要： The present invention relates to a catalyst system which is a mixture of at least two catalytic species, the first catalytic species being a dehydrogenation catalyst and the second catalytic species being an epoxidation catalyst and comprising silver. The present invention also relates to a process for the production of epoxides, in particular a process for the production of an epoxide from an alkane or a mixture comprising an alkane and an alkene, which process comprises contacting said alkane or mixture comprising said alkane and said alkene and a source of oxygen with such a catalyst system comprising a mixture of at least two catalytic species, the first catalytic species providing dehydrogenation activity and the second catalytic species providing epoxidation activity and comprising silver.
摘要翻译：本发明涉及一种催化剂体系，其是至少两种催化物质的混合物，第一催化物质是脱氢催化剂，第二催化物质是环氧化催化剂并包含银。本发明还涉及生产环氧化物的方法，特别是一种由烷烃或包含烷烃和烯烃的混合物生产环氧化物的方法，该方法包括将所述烷烃或包含所述烷烃和所述烯烃和氧源，其中包含至少两种催化物质的混合物的催化剂体系，所述第一催化物质提供脱氢活性和第二催化物质提供环氧化活性并包含银。

4. 发明申请

WO2005058795A1 CATALYST TREATMENT PROCESS FOR IMPROVING THE COLOUR OF ALKANOLAMINE 审中-公开
标题翻译：用于改善烷基胺颜色的催化剂处理方法
公开(公告)号：WO2005058795A1
公开(公告)日：2005-06-30
申请号：PCT/GB2004/005098
申请日：2004-12-03
申请人： BP CHEMICALS LIMITED , COQ, Bernard , DURAND, Robert , FINIELS, Annie , GENESTE, Patrick , LONGUET, Claire , MAUVEZIN, Mathias , TICHIT, Didier
发明人： COQ, Bernard , DURAND, Robert , FINIELS, Annie , GENESTE, Patrick , LONGUET, Claire , MAUVEZIN, Mathias , TICHIT, Didier
IPC分类号： C07C215/12
CPC分类号： C07C213/10 , C07C215/12
摘要： The invention relates to a process for the treatment of an alkanolamine, e.g. triethanolamine, having an improved colour stability over time. The process comprises contacting the alkanolamine with hydrogen in the presence of a supported catalyst comprising, as an active component, at least one metal chosen from Ni, Cu, Ru, Rh, Pd, Ag, Re, Os, Ir and Pt, and a, support component formed by heat treatment of a solid precursor based on a layered double hydroxide comprising at least one divalent metal cation and at least one trivalent metal cation, e.g. the hydrotalcite. The invention also relates to the use of a supported catalyst in a process for the treatment of an alkanolamine for improving the colour stability over time, the process comprising contacting the alkanolamine with hydrogen in the presence of the supported catalyst, as previously described.
摘要翻译：本发明涉及一种用于处理链烷醇胺的方法，例如，三乙醇胺，具有随时间改善的颜色稳定性。该方法包括在负载型催化剂存在下使链烷醇胺与氢气接触，该催化剂包含选自Ni，Cu，Ru，Rh，Pd，Ag，Re，Os，Ir和Pt中的至少一种金属作为活性组分，和基于包含至少一种二价金属阳离子和至少一种三价金属阳离子的层状双氢氧化物热固化前体而形成的载体组分，例如水滑石。本发明还涉及在用于处理链烷醇胺的方法中使用负载型催化剂以改进随时间的颜色稳定性的方法，该方法包括如上所述在负载型催化剂存在下使链烷醇胺与氢气接触。

5. 发明申请

WO2004113268A1 PROCESS FOR PREPARING ETHANOLAMINE WITH IMPROVED COLOUR 审中-公开
标题翻译：用改进的颜料制备乙醇胺的方法
公开(公告)号：WO2004113268A1
公开(公告)日：2004-12-29
申请号：PCT/GB2004/002023
申请日：2004-05-12
申请人： BP CHEMICALS LIMITED , BRUN-BUISSON, Daniel , MAUVEZIN, Mathias , PONSI, Florence
发明人： BRUN-BUISSON, Daniel , MAUVEZIN, Mathias , PONSI, Florence
IPC分类号： C07C213/10
CPC分类号： C07C213/08 , C07C213/10 , C07C215/08 , C07C215/10
摘要： The present invention relates to a process for preparing an ethanolamine having an improved colour quality. The process comprises contacting ethanolamine with an activated carbon free of one or more metals chosen from Re, Ru, Rh, Pd, Os, Ir, Pt and Ag. The contacting can be carried out at a temperature of from 10 to 200°C, and during.a period sufficient to reduce the colour of the ethanolamine, in particular a period such that the colour index (as measured according to the ASTM standard D 1209) of the ethanolamine becomes equal to or less than 50 or 40 Pt/Co. The contacting can be carried out during or after the stage of preparation of the ethanolamine, preferably during or after the stage of purification of the ethanolamine. The invention also relates to a process for manufacturing a triethanolamine (TEA) having an improved colour quality, comprising a stage (i) of synthesis of the TEA by contacting ammonia with ethylene oxide in aqueous medium, a stage (ii) of separation of a crude TEA from the aqueous medium and a stage (iii) of purification of the TEA by distillation. The process in addition comprises contacting the crude or purified TEA with an activated carbon free of one or more metals chosen from Re, Ru, Rh, Pd, Os, Ir, Pt and Ag, after the separation stage (ii), or during and after the purification stage (iii). The advantage of the claimed invention is to provide an ethanolamine which has an improved colour quality far more resistant over time, and which is obtained in the absence of any additive or metal catalyst known to contaminate the ethanolamine.
摘要翻译：本发明涉及一种具有改进的颜色品质的乙醇胺的制备方法。该方法包括使乙醇胺与不含选自Re，Ru，Rh，Pd，Os，Ir，Pt和Ag的一种或多种金属的活性炭接触。接触可以在10至200℃的温度下进行，并且足以降低乙醇胺颜色的时间，特别是使颜色指数（根据ASTM标准D 1209测量））等于或小于50或40 Pt / Co。接触可以在乙醇胺的制备阶段期间或之后进行，优选在乙醇胺纯化阶段期间或之后进行。本发明还涉及一种制备具有改善的颜色质量的三乙醇胺（TEA）的方法，其包括通过在水介质中接触氨与环氧乙烷合成TEA的步骤（i），分离步骤来自水介质的粗TEA和通过蒸馏纯化TEA的阶段（iii）。该方法还包括在分离阶段（ii）之后，或者在分离阶段（ii）期间，或者在和/或之前，将粗制或纯化的TEA与不含选自Re，Ru，Rh，Pd，Os，Ir，Pt和Ag的一种或多种金属的活性炭接触在纯化阶段（iii）之后。所要求保护的发明的优点是提供一种具有改善的颜色质量的乙醇胺，其随着时间的推移变得更加耐受，并且在没有任何已知污染乙醇胺的添加剂或金属催化剂的情况下获得。

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