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    • 2. 发明申请
    • PROCESS FOR THE PRODUCTION OF DI- AND POLYAMINES OF THE DIPHENYLMETHANE SERIES
    • 生产二苯乙烯系列二 - 和多聚酰胺的方法
    • WO2009037088A1
    • 2009-03-26
    • PCT/EP2008/061350
    • 2008-08-28
    • HUNTSMAN INTERNATIONAL LLCCARR, RobertKOOLE, Johannes LodewijkVAN DER BORDEN, Willem
    • CARR, RobertKOOLE, Johannes LodewijkVAN DER BORDEN, Willem
    • C07C209/78C07C209/86C07C211/50C07C263/10C08G18/76C08G73/02
    • C07C209/78C07C263/10C08G12/08C08G73/0266C07C211/50C07C265/14
    • Process for the production of di- and poly( diamino diphenyl methane) comprising the steps of (a) reacting aniline and formaldehyde in the presence of an acid catalyst to produce a reaction mixture containing di- and poly amines; (b) neutralising the reaction mixture containing di- and poly amines; (c) separating the neutralised reaction mixture into an organic phase containing di- and polyamines and an aqueous phase; (d) further treating the organic phase separated off in step (c) by (d1) washing with water followed by (d2) separating the washed mixture into an organic phase and an aqueous phase and (d3) further fractionation of the organic phase to produce purified di- and polyamines on the one hand and aniline/water on the other hand; (e) further treating the aqueous phase separated off in step (c) by (el) washing with aniline followed by (e2) separating the washed mixture into an aqueous phase and an organic phase and (e3) further treatment of the aqueous phase to remove the aniline thereby leaving an effluent stream; wherein phase separation in step (c) and/or step (d2) is facilitated by using any of the following methods either on its own or in combination with one or more of the other methods: (A) removal of some of the aromatic amine from the neutralised reaction mixture obtained in step (b) or the organic phase separated in step (c); (B) addition of di- and poly amine to the organic phase separated in step (c); (C) return of some of the organic phase obtained in step (d2) or (d3) to the washed mixture in step (d1).
    • 包括以下步骤的制备二 - 和二(二氨基二苯基甲烷)的方法:(a)在酸催化剂存在下使苯胺和甲醛反应以产生含有二胺和多胺的反应混合物; (b)中和含有二胺和多胺的反应混合物; (c)将中和的反应混合物分离成含有二胺和多胺及水相的有机相; (d)通过(d1)用水洗涤进一步处理在步骤(c)中分离的有机相,然后用(d2)将洗涤的混合物分离成有机相和水相,和(d3)将有机相进一步分级分离成 另一方面,一方面产生纯化的二胺和多胺,另一方面生产苯胺/水; (e)通过(e)用苯胺洗涤进一步处理在步骤(c)中分离的水相,然后(e2)将洗涤的混合物分离成水相和有机相,和(e3)将水相进一步处理 除去苯胺,从而留下流出物流; 其中步骤(c)和/或步骤(d2)中的相分离通过使用任何以下方法自身或与一种或多种其它方法组合来促进:(A)除去一些芳族胺 从步骤(b)中获得的中和反应混合物或步骤(c)中分离的有机相中获得; (B)在步骤(c)中分离的有机相中加入二胺和多胺; (C)在步骤(d1)中将步骤(d2)或(d3)中获得的一些有机相返回到洗涤的混合物中。
    • 3. 发明申请
    • PROCESS FOR THE PRODUCTION OF DI- AND POLYAMINES OF THE DIPHENYLMETHANE SERIES
    • 生产二苯乙烯系列二 - 和多聚酰胺的方法
    • WO2009037087A1
    • 2009-03-26
    • PCT/EP2008/061349
    • 2008-08-28
    • HUNTSMAN INTERNATIONAL LLCCARR, RobertKOOLE, Johannes LodewijkVAN DER BORDEN, Willem
    • CARR, RobertKOOLE, Johannes LodewijkVAN DER BORDEN, Willem
    • C07C209/78C07C211/50C08G18/76C08G73/02
    • C08G12/08C07C209/78C08G73/0266C07C211/50
    • Process for the production of di- and poly( diamino diphenyl methane) comprising the steps of (a) reacting aniline and formaldehyde in the presence of an acid catalyst to produce a reaction mixture containing di- and polyamines; (b) neutralising the reaction mixture containing di- and polyamines; (c) separating the neutralised reaction mixture into an organic phase containing di- and polyamines and an aqueous phase; (d) further treating the organic phase separated off in step (c) by (d1) washing with water followed by (d2) separating the washed mixture into an organic phase and an aqueous phase and (d3) further fractionation of the organic phase to produce purified di- and polyamines on the one hand and aniline/water on the other hand; (e) further treating the aqueous phase separated off in step (c) by (e1) washing with aniline followed by (e2) separating the washed mixture into an aqueous phase and an organic phase and (e3) further treatment of the aqueous phase to remove the aniline thereby leaving an effluent stream wherein phase separation in step (c) and/or step (e2) is facilitated by using any of the following methods either on its own or in combination with one or more of the other methods: (A) removal of some of the water from the neutralised reaction mixture obtained in step (b) or the aqueous phase separated in step (c); (B) addition of inorganic salt to the neutralised reaction mixture obtained in step (b) or the aqueous phase separated in step (c); (C) return of some of the aqueous phase obtained in step (e2) or (e3) to the neutralised reaction mixture obtained in step (b) or to the washed mixture in step (e1).
    • 包括以下步骤的制备二 - 和多(二氨基二苯基甲烷)的方法:(a)在酸催化剂存在下使苯胺和甲醛反应以产生含有二胺和多胺的反应混合物; (b)中和含有二胺和多胺的反应混合物; (c)将中和的反应混合物分离成含有二胺和多胺和水相的有机相; (d)通过(d1)用水洗涤进一步处理在步骤(c)中分离的有机相,然后用(d2)将洗涤的混合物分离成有机相和水相,和(d3)将有机相进一步分级分离成 另一方面,一方面产生纯化的二胺和多胺,另一方面生产苯胺/水; (e)通过(e1)用苯胺洗涤进一步处理在步骤(c)中分离出的水相,然后(e2)将洗涤的混合物分离成水相和有机相,和(e3)进一步处理水相至 除去苯胺,从而留下流出物流,其中步骤(c)和/或步骤(e2)中的相分离通过使用任何以下方法自身或与一种或多种其它方法相结合来促进:(A )从步骤(b)中获得的中和反应混合物中的一些水或在步骤(c)中分离的水相中除去一些水; (B)将步骤(b)中获得的中和反应混合物中的无机盐或在步骤(c)中分离的水相中加入无机盐; (C)将步骤(e2)或(e3)中获得的一些水相返回到步骤(b)中获得的中和反应混合物或步骤(e1)中洗涤的混合物。