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    • 3. 发明申请
    • PROCESS FOR PREPARING POLYISOCYANURATE POLYURETHANE MATERIAL
    • 制备聚异氰酸酯聚氨酯材料的方法
    • WO2007042411A1
    • 2007-04-19
    • PCT/EP2006/066889
    • 2006-09-29
    • HUNTSMAN INTERNATIONAL LLCBLEYS, Gerhard JozefHUYGENS, EricROEKAERTS, StijnVANDERVESSE, MarcVERBEKE, Hans Godelieve Guido
    • BLEYS, Gerhard JozefHUYGENS, EricROEKAERTS, StijnVANDERVESSE, MarcVERBEKE, Hans Godelieve Guido
    • C08G18/09C08G18/48C08G18/76
    • C08G18/092C08G18/4837C08G18/7671
    • A process for preparing a polyisocyanurate polyurethane material, which process comprises reacting a polyisocyanate and an isocyanate-reactive composition, wherein the reaction is conducted at an isocyanate index of 1600 to 100,000 and in the presence of a trimerisation catalyst, wherein the polyisocyanate comprises a) 75-100% by weight of diphenylmethane diisocyanate comprising at least 40%, preferably at least 60% and most preferably at least 85% by weight of 4,4'- diphenylmethane diisocyanate and/or a variant of said diphenylmethane diisocyanate which variant is liquid at 25°C and has an NCO value of at least 20% by weight (polyisocyanate a), and b) 25-0% by weight of another polyisocyanate (polyisocyanate b), the amount of polyisocyanate a) and polyisocyanate b) being calculated on the total amount of this polyisocyanate a) and polyisocyanate b), and wherein the isocyanate-reactive composition comprises a) 80-100% by weight of a polyether polyol having an average nominal functionality of 2-6, an average equivalent weight of 1100-5000 and an oxyethylene (EO) content of 65-100% by weight and b) 20-0% by weight of one or more other isocyanate-reactive compounds, the amount of polyol a) and isocyanate-reactive compound b) being calculated on the total amount of this polyol a) and compound b).
    • 一种制备聚异氰脲酸酯聚氨酯材料的方法,该方法包括使多异氰酸酯和异氰酸酯反应性组合物反应,其中反应在异氰酸酯指数为1600至100,000的条件下和三聚催化剂存在下进行,其中多异氰酸酯包含a) 75-100重量%的二苯基甲烷二异氰酸酯,其包含至少40重量%,优选至少60重量%,最优选至少85重量%的4,4'-二苯基甲烷二异氰酸酯和/或所述二苯基甲烷二异氰酸酯的变体,该变体是液体 在25℃下具有至少20重量%的NCO值(多异氰酸酯a),和b)25-0重量%的另一多异氰酸酯(多异氰酸酯b),多异氰酸酯a)和多异氰酸酯b)的量被计算 关于该多异氰酸酯a)和多异氰酸酯b)的总量,并且其中异氰酸酯反应性组合物包含a)80-100重量%的具有平均标称功能的聚醚多元醇 平均当量为1100-5000,氧化乙烯(EO)含量为65-100重量%,b)20-0重量%的一种或多种其它异氰酸酯反应性化合物,其量为 多元醇a)和异氰酸酯反应性化合物b)根据该多元醇a)和化合物b)的总量计算。
    • 4. 发明申请
    • PROCESS FOR PREPARING A POLYISOCYANURATE POLYURETHANE MATERIAL
    • 制备聚异氰酸酯聚氨酯材料的方法
    • WO2007042407A1
    • 2007-04-19
    • PCT/EP2006/066874
    • 2006-09-29
    • HUNTSMAN INTERNATIONAL LLCBLEYS, Gerhard JozefHUYGENS, EricROEKAERTS, StijnVANDERVESSE, MarcVERBEKE, Hans Godelieve Guido
    • BLEYS, Gerhard JozefHUYGENS, EricROEKAERTS, StijnVANDERVESSE, MarcVERBEKE, Hans Godelieve Guido
    • C08G18/09C08G18/48C08G18/76
    • C08G18/4837C08G18/092C08G18/7671
    • A process for preparing a polyisocyanurate polyurethane material, which process comprises reacting a polyisocyanate and an isocyanate-reactive composition, wherein the reaction is conducted at an isocyanate index of 150 to 5000 and in the presence of a trimerisation catalyst, wherein the polyisocyanate comprises a) 80- 100% by weight of diphenylmethane diisocyanate comprising at least 40%, preferably at least 60% and most preferably at least 85% by weight of 4,4'- diphenylmethane diisocyanate and/or a variant of said diphenylmethane diisocyanate which variant is liquid at 25°C and has an NCO value of at least 20% by weight (polyisocyanate a), and b) 20-0% by weight of another polyisocyanate (polyisocyanate b), the amount of polyisocyanate a) and polyisocyanate b) being calculated on the total amount of this polyisocyanate a) and polyisocyanate b), and wherein the isocyanate-reactive composition comprises a) 80-100% by weight of a polyether polyol having an average nominal functionality of 2-6, an average equivalent weight of 1100-5000 and an oxyethylene (EO) content of 50-90% by weight and b) 20-0% by weight of one or more other isocyanate-reactive compounds, the amount of polyo l a) and isocyanate-reactive compound b) being calculated on the total amount of this polyol a) and compound b) and wherein the hardblock content is at most 49%.
    • 一种制备聚异氰脲酸酯聚氨酯材料的方法,该方法包括使多异氰酸酯和异氰酸酯反应性组合物反应,其中反应在异氰酸酯指数为150至5000的条件下并且在三聚催化剂存在下进行,其中多异氰酸酯包含a) 80-100重量%的二苯基甲烷二异氰酸酯,其包含至少40重量%,优选至少60重量%,最优选至少85重量%的4,4'-二苯基甲烷二异氰酸酯和/或所述二苯基甲烷二异氰酸酯的变体,该变体是液体 在25℃下具有至少20重量%的NCO值(多异氰酸酯a),和b)20-0重量%的另一多异氰酸酯(多异氰酸酯b),多异氰酸酯a)和多异氰酸酯b)的量被计算 关于该多异氰酸酯a)和多异氰酸酯b)的总量,并且其中异氰酸酯反应性组合物包含a)80-100重量%的具有平均标称官能度的聚醚多元醇 y为2-6,平均当量为1100-5000,氧化乙烯(EO)含量为50-90重量%,b)20-0重量%的一种或多种其它异氰酸酯反应性化合物, 多元醇)和异氰酸酯反应性化合物b)根据该多元醇a)和化合物b)的总量计算,其中硬嵌段含量为至多49%。
    • 5. 发明申请
    • PREPOLYMER, POLYOL COMPOSITION AND PROCESS FOR MAKING A FLEXIBLE FOAM
    • 制备聚合物,多元醇组合物和制备柔性泡沫的方法
    • WO2004014976A1
    • 2004-02-19
    • PCT/EP2003/007053
    • 2003-07-02
    • HUNTSMAN INTERNATIONAL LLCCHAN, Koon, YeowHUYGENS, EricMOUREAU, Herman, Eugene, GermainVANHALLE, AnjaYU, Jianming
    • CHAN, Koon, YeowHUYGENS, EricMOUREAU, Herman, Eugene, GermainVANHALLE, AnjaYU, Jianming
    • C08G18/10
    • C08G18/4841C08G18/10C08G2101/0008C08G2101/0058C08G2101/0083C08G18/48C08G18/725
    • Isocyanate-terminated prepolymer having an NCO-value of 5-30% by weight and being the reaction product of an excessive amount of diphenylmethane diisocyanate comprising at least 80% by weight of 4,4'-diphenylmethane diisocyanate and a polyoxyethylene-polyoxypropylene polyol having an average molecular weight of 2000-10000, an average nominal hydroxy functionality of 2-6, an oxyethylene content of 21-45% by weight and a structure of the type -PO-PO/EO-EO wherein the PO block comprises 60-90% of the PO and the ratio of tipped EO : random is 3:1 to 1:3, and a process for preparing a flexible foam by reacting in a mould and at an index of 70-120, the above prepolymer or a composition comprising this prepolymer and b 1) a polyoxyethylene-polyoxypropylene polyol, having an average nominal hydroxy functionality of 2-6, and a oxyethylene (EO) content of more than 50% by weight; and optionally 2) a polyoxyethylene-polyoxypropylene polyol, having an average nominal hydroxy functionality of 2-6, an EO content of between 20-50% by weight and a primary hydroxy content of at least 50%, calculated on the number of primary and secondary hydroxyl groups; and c) water; and optionally d) additives and auxiliaries known per se.
    • 异氰酸酯封端的预聚物,其NCO值为5-30重量%,是过量的二苯基甲烷二异氰酸酯的反应产物,其包含至少80重量%的4,4'-二苯基甲烷二异氰酸酯和聚氧乙烯 - 聚氧丙烯多元醇,其具有 平均分子量为2000-10000,平均标称羟基官能度为2-6,氧化乙烯含量为21-45重量%,以及-PO-PO / EO-EO型结构,其中PO嵌段包含60- PO的90%和倾斜的EO:无规比例为3:1至1:3,以及通过在模具中以70-120的指数反应制备柔性泡沫的方法,上述预聚物或组合物 包含该预聚物和b 1)平均标称羟基官能度为2-6,氧乙烯(EO)含量大于50重量%的聚氧乙烯 - 聚氧丙烯多元醇; 和任选的2)聚氧乙烯 - 聚氧丙烯多元醇,其平均标称羟基官能度为2-6,EO含量为20-50重量%,主要羟基含量为至少50重量% 仲羟基; 和c)水; 和任选的d)本身已知的添加剂和助剂。