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1. 发明申请

WO2011146792A2 PROCESS FOR THE PREPARATION OF FLUORINATED CIS-ALKENE 审中-公开
标题翻译：制备氟化苯乙烯的方法
公开(公告)号：WO2011146792A2
公开(公告)日：2011-11-24
申请号：PCT/US2011/037268
申请日：2011-05-20
申请人： HONEYWELL INTERNATIONAL INC. , POSS, Andrew Joseph , VAN DER PUY, Michael , SINGH, Rajiv Ratna , NALEWAJEK, David , NAIR, Haridasan K.
发明人： POSS, Andrew Joseph , VAN DER PUY, Michael , SINGH, Rajiv Ratna , NALEWAJEK, David , NAIR, Haridasan K.
CPC分类号： C07C17/23 , C07B2200/09 , C07C17/10 , C07C17/206 , C07C17/278 , C07C21/18 , C07C19/10
摘要： Disclosed is a process for the preparation of fluorine-containing olefins comprising contacting a chlorofluoroalkane with hydrogen in the presence of a catalyst at a temperature sufficient to cause replacement of the chlorine substituents of the chlorofluoroalkane with hydrogen to produce a fluorine-containing olefin. Also disclosed are catalyst compositions for the hydrodechlorination of chlorofluoroalkanes comprising copper metal deposited on a support, and comprising palladium deposited on calcium fluoride, poisoned with lead and reducing the in the presence or absence of a dehydrochlorination catalyst under conditions effective to form a product stream comprising cis-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336).
摘要翻译：公开了一种制备含氟烯烃的方法，包括在催化剂存在下，使氯氟烷烃与氢气在足以使氯氟烷烃的氯取代基被氢取代以产生含氟烯烃的温度下接触。还公开了用于加氢脱氯氯氟烷烃的催化剂组合物，其包含沉积在载体上的铜金属，并且包含沉积在氟化钙上的钯，由铅中毒并在有效形成产物流的条件下在脱氯化氢催化剂存在或不存在下还原，包含顺式-1,1,1,4,4,4-六氟-2-丁烯（HFO-1336）。

2. 发明申请

WO2011146820A3 PROCESS FOR CIS-1,1,1,4,4,4,-HEXAFLUORO-2-BUTENE 审中-公开
公开(公告)号：WO2011146820A3
公开(公告)日：2011-11-24
申请号：PCT/US2011/037310
申请日：2011-05-20
申请人： HONEYWELL INTERNATIONAL INC. , POSS, Andrew Joseph , NALEWAJEK, David , NAIR, Haridasan K. , VAN DER PUY, Michael
发明人： POSS, Andrew Joseph , NALEWAJEK, David , NAIR, Haridasan K. , VAN DER PUY, Michael
IPC分类号： C07C17/25 , C07C17/23 , C07C21/18
摘要： Disclosed is a process for preparing cis-1,1,1,4,4,4-hexafluoropropene comprising the steps of (a) reacting CCl 4 with a compound having the formula CF 3 CX=CXH, where each X is independently halogen or hydrogen, to form a compound having the formula CF 3 CXClCXHCCl 3 ; (b) fluorinating the compound formed in step (a) to form a compound having the formula CF 3 CXHCXHCF 3 ; (c) converting the compound formed in step (b) by a reaction selected from the group consisting of dehydrohalogenation, dehalogenation and both reactions, to form a compound having the formula CF 3 C = CCF 3 ; and (d) catalytically reducing the compound formed in step (c) with hydrogen to form the compound having the formula (I).

3. 发明申请

WO2011146812A3 PROCESS FOR THE PREPARATION OF HEXAFLUORO-2-BUTYNE 审中-公开
公开(公告)号：WO2011146812A3
公开(公告)日：2011-11-24
申请号：PCT/US2011/037298
申请日：2011-05-20
申请人： HONEYWELL INTERNATIONAL INC. , POSS, Andrew Joseph , NALEWAJEK, David , NAIR, Haridasan K. , VAN DER PUY, Michael , SINGH, Rajiv Ratna
发明人： POSS, Andrew Joseph , NALEWAJEK, David , NAIR, Haridasan K. , VAN DER PUY, Michael , SINGH, Rajiv Ratna
IPC分类号： C07C17/23 , C07C17/25 , C07C21/22
摘要： Disclosed is a process for making hexafluoro-2-butyne comprising the steps of: (a) providing a composition comprising CF 3 CX=CXCF 3 , where X = halogen; and (b) treating CF 3 CX=CXCF 3 with a dehalogenation catalyst in the presence of a halogen acceptor compound Y, where Y is not hydrogen. The halogen acceptor compound Y is a material capable of being halogenated, preferably a compound having a multiple bond, such as an alkyne, alkene, allene, or carbon monoxide. Another suitable material capable of being halogenated is a cyclopropane. A catalyst effectively transfers halogen from CF 3 CX=CXCF 3 to the halogen acceptor compound. Since Y is not hydrogen, the formation of CF 3 CX=CHCF 3 is greatly reduced or eliminated.

4. 发明申请

WO2011146802A3 PROCESS FOR THE PRODUCTION OF FLUORINATED ALKENES 审中-公开
公开(公告)号：WO2011146802A3
公开(公告)日：2011-11-24
申请号：PCT/US2011/037284
申请日：2011-05-20
申请人： HONEYWELL INTERNATIONAL INC. , POSS, Andrew Joseph , NALEWAJEK, David , VAN DER PUY, Michael , NAIR, Haridasan K.
发明人： POSS, Andrew Joseph , NALEWAJEK, David , VAN DER PUY, Michael , NAIR, Haridasan K.
IPC分类号： C07C17/23 , C07C17/25 , C07C21/18
摘要： The present invention provides a method for the preparation of suitable chlorofluorocarbon and hydrochlorofluorocarbon materials or chlorofluorocarbon and hydrochlorofluorocarbon alkene and alkyne intermediates which serve as useful feedstock for fluorination and reduction to cis-1,1,1,4,4,4-hexafluoro-2-butene. Also presented is a continuous process for the production of cis-1,1,1,4,4,4-hexafluoro-2-butene from the alkene and alkyne intermediates.

5. 发明申请

WO2012112827A2 PROCESS FOR CIS-1-CHLORO-3,3,3,TRIFLUOROPROPENE 审中-公开
标题翻译： CIS-1-氯-3,3,3，三氟丙烯的方法
公开(公告)号：WO2012112827A2
公开(公告)日：2012-08-23
申请号：PCT/US2012/025537
申请日：2012-02-17
申请人： HONEYWELL INTERNATIONAL INC. , NAIR, Haridasan K. , POSS, Andrew Joseph , SINGH, Rajiv Ratna , VAN DER PUY, Michael , HULSE, Ryan J.
发明人： NAIR, Haridasan K. , POSS, Andrew Joseph , SINGH, Rajiv Ratna , VAN DER PUY, Michael , HULSE, Ryan J.
IPC分类号： C07C21/04 , C07C21/18 , C07C19/10 , B01J23/44
CPC分类号： C07C17/25 , C07B2200/09 , C07C17/354 , C07C21/22 , C07C21/18
摘要： Disclosed is a process for making one isomer of CF 3 CH=CHCl. More particularly, the invention comprises the production of CF 3 C≡CCl and its selective reduction to cis-1-chloro-3,3,3-trifluoropropene (CF 3 CH=CHCl).
摘要翻译：公开了制备CF 3 CH = CHCl的一种异构体的方法。更具体地说，本发明包括CF 3C≡CCl的生产及其选择性还原成顺式-1-氯-3,3,3-三氟丙烯（CF 3 CH =氯仿）。

6. 发明申请

WO2002102758A1 FLUORINE-CONTAINING COMPOUNDS AND POLYMERS DERIVED THEREFROM 审中-公开
标题翻译：含氟化合物和衍生自其的聚合物
公开(公告)号：WO2002102758A1
公开(公告)日：2002-12-27
申请号：PCT/US2002/019375
申请日：2002-06-18
申请人： HONEYWELL INTERNATIONAL, INC. , BRADLEY, David , MA, Jing-Ji , NALEWAJEK, David , SAMUELS, George, J. , STACHURA, Leonard, M. , VAN DER PUY, Michael , NAIR, Haridasan, K.
发明人： BRADLEY, David , MA, Jing-Ji , NALEWAJEK, David , SAMUELS, George, J. , STACHURA, Leonard, M. , VAN DER PUY, Michael , NAIR, Haridasan, K.
IPC分类号： C07C69/52
CPC分类号： D06M15/21 , C07C69/653 , C07C233/20 , C08F20/22 , C08F20/28 , D06M15/277 , D06M2200/12
摘要： Provided are fluorine-containing compounds, and polymers derived therefrom, for use in compositions used for treating textile substrates. Also provided are methods of making fluorine-containing compounds and polymers derived therefrom, compositions comprising the compounds and/or polymers of the present invention, methods of treating substrates, and the treated products derived therefrom.
摘要翻译：提供含氟化合物及其衍生的聚合物，用于处理织物基材的组合物中。还提供了制备含氟化合物和由其衍生的聚合物的方法，包含本发明的化合物和/或聚合物的组合物，处理底物的方法和由其衍生的处理产物。

7. 发明申请

WO2005108333A1 PROCESSES FOR SYNTHESIS OF 1,3,3,3-TETRAFLUOROPROPENE 审中-公开
标题翻译：合成1,3,3,3-四氯丙烯的方法
公开(公告)号：WO2005108333A1
公开(公告)日：2005-11-17
申请号：PCT/US2005/014950
申请日：2005-04-29
申请人： HONEYWELL INTERNATIONAL, INC. , TUNG, Hsueh, S. , NAIR, Haridasan, K. , MUKHOPADHYAY, Sundip , VAN DER PUY, Michael , MA, Jing Ji
发明人： TUNG, Hsueh, S. , NAIR, Haridasan, K. , MUKHOPADHYAY, Sundip , VAN DER PUY, Michael , MA, Jing Ji
IPC分类号： C07C21/18
CPC分类号： C07C17/206 , C07C17/00 , C07C17/26 , C07C17/269 , C07C17/272 , C07C17/278 , C07C21/18
摘要： Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene which comprises, in one embodiment, reacting a compound of CF3X1 with a compound of CX2H=CHX3, wherein X1, X2, and X3 are each independently selected from the group consisting of fluorine, chlorine, bromine and iodine, to produce a reaction product comprising a compound of CF3CH=CHX3, wherein X3 is as described above; and when X3 is not fluorine, fluorinating the compound to produce 1,3,3,3-tetrafluoropropene. The process in another embodiment comprises preparing tetrafluoropropene comprising thermally cracking one or more compounds capable of producing a reaction mixture which preferably comprises diflurocarbene radicals and vinylidene fluoride, and converting said reaction mixture into -tetrafluoropropene (1,3,3,3-tetrafluoropropene).
摘要翻译：公开了合成1,3,3,3-四氟丙烯的方法，其在一个实施方案中包括CF 3 X 1的化合物与CX 2 H = CHX 3的化合物反应，其中X 1，X 2和X 3各自独立地选自由氟，氯，溴和碘组成的组，以产生包含CF 3 CH = CHX 3的化合物的反应产物，其中X 3如上所述; 当X3不是氟时，氟化该化合物以产生1,3,3,3-四氟丙烯。在另一个实施方案中的方法包括制备四氟丙烯，其包括热裂化一种或多种能够产生反应混合物的化合物，所述化合物优选包含二氟丙烯基和偏二氟乙烯，并将所述反应混合物转化为四氟丙烯（1,3,3,3-四氟丙烯）。

8. 发明申请

WO2005108332A1 PROCESSES FOR SYNTHESIS OF 1,3,3,3-TETRAFLUOROPROPENE 审中-公开
标题翻译：合成1,3,3,3-四氯丙烯的方法
公开(公告)号：WO2005108332A1
公开(公告)日：2005-11-17
申请号：PCT/US2005/015124
申请日：2005-04-29
申请人： HONEYWELL INTERNATIONAL, INC. , TUNG, Hsueh, S. , NAIR, Haridasan, K. , MUKHOPADHYAY, Sundip, S.M. , VAN DER PUY, Michael
发明人： TUNG, Hsueh, S. , NAIR, Haridasan, K. , MUKHOPADHYAY, Sundip, S.M. , VAN DER PUY, Michael
IPC分类号： C07C17/25
CPC分类号： C07C17/206 , C07C17/00 , C07C17/25 , C07C17/275 , C07C17/278 , C07C21/18 , C07C19/10 , C07C19/16 , C07C19/14 , C07C19/01
摘要： Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene that comprises reacting a compound of the formula (I) CHFX 2 with a compound of formula (II) CH 2 =CF 2 to produce a reaction product comprising a compound of formula (III) CHXFCH 2 CXF 2 , wherein each X is independently selected from the group consisting of chlorine, bromine and iodine, and exposing said compound of formula (III) to reaction conditions effective to convert said compound to 1,3,3,3-tetrafluoropropene.
摘要翻译：公开了合成1,3,3,3-四氟丙烯的方法，其包括使式（I）CHFX 2的化合物与式（II）的化合物CH 2 = CF 2反应，以产生包含式（III）CHXFCH2CXF2，其中每个X独立地选自氯，溴和碘，并将所述式（III）化合物暴露于有效将所述化合物转化为1,3,3,3-四氟丙烯的反应条件。

9. 发明申请

WO2005108334A1 PROCESSES FOR SYNTHESIS OF 1,3,3,3-TETRAFLUOROPROPENE AND 2,3,3,3-TETRAFLUOROPROPENE 审中-公开
标题翻译：合成1,3,3,3-四氯丙烯和2,3,3,3-四氯丙烯的方法
公开(公告)号：WO2005108334A1
公开(公告)日：2005-11-17
申请号：PCT/US2005/015125
申请日：2005-04-29
申请人： HONEYWELL INTERNATIONAL, INC. , TUNG, Hsueh, S. , NAIR, Haridasan, K. , MUKHOPADHYAY, Sundip, S.M. , VAN DER PUY, Michael
发明人： TUNG, Hsueh, S. , NAIR, Haridasan, K. , MUKHOPADHYAY, Sundip, S.M. , VAN DER PUY, Michael
IPC分类号： C07C21/18
CPC分类号： C07C17/06 , C07C17/04 , C07C17/206 , C07C17/21 , C07C17/25 , C07C21/18 , C07C19/14 , C07C19/16 , C07C19/01 , C07C19/10
摘要： Disclosed in one embodiment is a process for the synthesis of 1,3,3,3-tetrafluoropropene that comprises (a) reacting a compound of formula (I) X 1 X 2 with a compound of formula (II) CF 3 CH=CH 2 to produce a reaction product comprising a compound of formula (III) CF 3 CHX 1 CH 2 X 2 , wherein X 1 and X 2 are each independently selected from the group consisting of hydrogen, chlorine, bromine and iodine, provided that X 1 and X 2 are not both hydrogen; (b) when X 2 in formula (III) is not fluorine, fluorinating the compound of formula (III) to produce a reaction product comprising a compound of formula (III) wherein X 1 is as described above and X 2 is fluorine; and (c) exposing said compound of formula (III) to reaction conditions effective to convert said compound to 1,3,3,3,-tetrafluoropropene. In another embodiment, the process comprises (a) reacting chlorine with a compound of formula ( I) CH 3 CH=CH 2 to produce a reaction product comprising a compound of formula ( II) CCI 3 CHC1CH 2 C1; (b) fluorinating the compound of formula ( II) to produce a reaction product comprising a compound of formula ( III ) CF 3 CHC1CH 2 F; and (c) exposing said compound of said formula ( III ) to reaction conditions effective to convert said compound to 1,3,3,3-tetrafluoropropene.
摘要翻译：在一个实施方案中公开了一种用于合成1,3,3,3-四氟丙烯的方法，其包括（a）使式（I）X 1 X 2的化合物与式（II）的化合物与CF 3 CH = CH 2，以产生包含式（III）化合物的反应产物，其中X 1和X 2各自独立地选自氢，氯，溴和碘条件是X 1和X 2不同时为氢; （b）当式（III）中的X 2不是氟时，氟化式（III）化合物以产生包含其中X 1如上所述的式（III）化合物的反应产物， 2>是氟; 和（c）将所述式（III）化合物暴露于有效将所述化合物转化为1,3,3,3-四氟丙烯的反应条件。在另一个实施方案中，该方法包括（a）使氯与式（I）CH 3 CH = CH 2的化合物反应以产生包含式（II）化合物的反应产物：CCI 3 CHClCH 2 Cl; （b）氟化式（II）化合物以产生包含式（III）化合物的反应产物：CF 3 CHClCH 2 F; 和（c）将所述式（III）的所述化合物暴露于有效将所述化合物转化为1,3,3,3-四氟丙烯的反应条件。

10. 发明申请

WO2002103103A3 FLUORINE-CONTAINING COMPOUNDS AND POLYMERS DERIVED THEREFROM 审中-公开
公开(公告)号：WO2002103103A3
公开(公告)日：2002-12-27
申请号：PCT/US2002/019232
申请日：2002-06-18
申请人： HONEYWELL INTERNATIONAL INC. , BRADLEY, David , MA, Jing-Ji , NALEWAJEK, David , SAMUELS, George, J. , STACHURA, Leonard, M. , VAN DER PUY, Michael
发明人： BRADLEY, David , MA, Jing-Ji , NALEWAJEK, David , SAMUELS, George, J. , STACHURA, Leonard, M. , VAN DER PUY, Michael
IPC分类号： C08F220/10
摘要： Provided are fluorine-containing compounds, and polymers derived therefrom, for use in compositions used for treating textile subtrates. The present invention further provides methods of making fluorine-containing compounds and polymers derived therefrom, compositions comprising the compounds and/or polymers of the present invention, methods of treating substrates, and the treated procucts derived therefrom.

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