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1. 发明申请

WO02055042A2 DEVELOPER/ DEVELOPER HYBRID DYES AND HYBRID DYE PRECURSORS 审中-公开
标题翻译：开发商/开发商杂交染料和杂交染料产品
公开(公告)号：WO02055042A2
公开(公告)日：2002-07-18
申请号：PCT/EP0200016
申请日：2002-01-03
申请人： HENKEL KGAA , NAUMANN FRANK , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST , HOLLENBERG DETLEF
发明人： NAUMANN FRANK , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST , HOLLENBERG DETLEF
IPC分类号： A61K8/49 , A61Q5/10 , A61K7/13 , C09B57/00
CPC分类号： A61K8/494 , A61K8/4926 , A61Q5/10
摘要： Hybrid dyes of structure (I), X-S-Y (I) in which X and Y are each derived from various oxidation dye precursors of the developer type and S is a direct bond or at least one spacer group, are especially suitable for colouring keratin fibres, in particular, human hair. By the use of colouring agents with the above dyes, a series of problems which occurs with the use of complex dye mixtures, can be avoided or significantly reduced.
摘要翻译：结构（I）的混合染料，XSY（I）其中X和Y各自从显影剂类型的不同的氧化染料前体衍生的，和S代表直接键或至少一个间隔基团，非常适合用于着色角蛋白纤维，特别是人的头发，通过与这些染料一起使用着色剂，使用复杂的Fabstoffmischunchungen时发生的一些问题规避或显着减少。

2. 发明申请

WO02055609A2 INDOLE/INDOLINE BASED HYBRID DYES AND INDOLE/INDOLINE BASED HYBRID DYE INTERMEDIATE PRODUCTS 审中-公开
标题翻译：吲哚/吲哚啉混合染料和-HYBRIDFARBSTOFFVORPRODUKTE
公开(公告)号：WO02055609A2
公开(公告)日：2002-07-18
申请号：PCT/EP0200013
申请日：2002-01-03
申请人： HENKEL KGAA , HOLLENBERG DETLEF , NAUMANN FRANK , HOEFFKES HORST , ROSE DAVID
发明人： HOLLENBERG DETLEF , NAUMANN FRANK , HOEFFKES HORST , ROSE DAVID
IPC分类号： C07D401/04 , A61K8/00 , A61K8/18 , A61K8/46 , A61K8/49 , A61Q1/00 , A61Q1/02 , A61Q5/00 , A61Q5/10 , C07D209/08 , C09B57/00 , C09B67/42 , C09B69/00 , D06P1/32 , D06P3/08 , C09B
CPC分类号： A61K8/492 , A61K8/4926 , A61Q5/10 , C09B69/00
摘要： The invention relates to indole and indoline based hybrid dyes and indole and indoline based hybrid dye intermediate products having a structure (I): X - S - Y; wherein X represents a group which is derived from a derivative of indole or indoline as a precursor of melanin; Y represents a group which is derived from an oxidation dye based intermediate product of a coupler or developer variety, or a derivative of indole or indoline as a precursor of melanin; and S represents a structural element which is a common component of groups X and Y, a direct bond or at least one spacer group. The inventive products are particularly suitable for dyeing keratin fibres, particularly human hair. By using colouring agents with said dye, a series of problems which occur when using complex dye mixtures are avoided or significantly reduced
摘要翻译：吲哚和二氢吲哚混合染料和-hybridfarbstoffvorprodukte结构（I）：X - S - ÿ; 其中X是从吲哚或二氢吲哚作为黑色素前体的衍生物衍生的基团; Y表示选自氧化染料耦合器或初级中间类型，或吲哚或二氢吲哚作为黑色素前体的衍生物衍生的基团; 和S代表的是基团X和Y，直接键合或至少一个间隔基团的共同的构成的结构元件，非常适合用于着色角蛋白纤维，特别是人的头发。通过使用含有这些染料的颜色的产品，与使用复杂的染料混合物的发生许多问题离开，旁路或显著最小化。

3. 发明申请

WO0076977A3 OXIDATION COLORANT STARTING PRODUCTS 审中-公开
标题翻译：氧化染料前体
公开(公告)号：WO0076977A3
公开(公告)日：2002-05-02
申请号：PCT/EP0005151
申请日：2000-06-06
申请人： HENKEL KGAA , NAUMANN FRANK , ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
发明人： NAUMANN FRANK , ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
IPC分类号： C07D213/74 , A61K7/13
CPC分类号： C07D213/74 , A61K8/4926 , A61Q5/10
摘要： The invention relates to oxidation colorants for coloring keratin fibers, especially human hair. The inventive colorants contain, dissolved in a medium that is appropriate for coloring, at least one 2,5-diaminopyridine derivative of the general formula (I) wherein R and R may independently represent hydrogen, a C1 to C4 alkyl group or a C1 to C4 hydroxyalkyl group or, together with the nitrogen atom to which they are bound, form an optionally substituted, saturated heterocyclic 5- or 6-membered ring that may contain another nitrogen atom or an oxygen atom, R is hydrogen, a C1 to C4 alkyl group or a C1 to C4 hydroxyalkyl group, R and R independently represent hydrogen, a C1 to C4 alkyl group or a C3 to C8 cycloalkyl group, R and R independently represent hydrogen, a halogen atom, a C1 to C4 alkyl group, a C1 to C4 hydroxyalkyl group, a C1 to C4 aminoalkyl group or a C1 to C4 alkoxy group and n is 1 or 2, or a physiologically acceptable salt of the above compounds. The inventive agents are characterized by intense colorations especially in the red/brown range and by excellent color fastness properties.
摘要翻译：本发明涉及角蛋白纤维，特别是人的头发，在介质中的适当的染色，在通式（I），其中R <1>和R <2>独立地表示氢中的至少一种2,5-二氨基吡啶衍生物的氧化染色，站立或一个C1至C4烷基或与氮原子一C 1至C 4羟烷基一起形成它们所连接形成任选取代的饱和杂环含有一个额外的氮原子的5元或6元环，或一个可含有氧原子，R <3>代表氢，C1至C4烷基或C1-至C4-羟烷基是，R <4>和R <5>独立地为氢，C1至C4烷基或包括C3〜C8环烷基，R <6>和R <7>独立地是氢，卤原子，C1-C4烷基，一个C 1至C 4羟烷基，C1 至C4氨基烷基，或C1-C4烷氧基，n为1或2，或含有这些化合物的生理学上可接受的盐中的一种。新型组合物的特征在于强烈着色，尤其是在棕红色范围内具有优异的坚牢度性能，从。

4. 发明申请

WO0209662A3 AGENT FOR DYEING KERATIN CONTAINING FIBERS 审中-公开
标题翻译：手段垂死角蛋白纤维
公开(公告)号：WO0209662A3
公开(公告)日：2002-06-27
申请号：PCT/EP0108656
申请日：2001-07-26
申请人： HENKEL KGAA , ROSE DAVID , NAUMANN FRANK , MEINIGKE BERND , HOEFFKES HORST
发明人： ROSE DAVID , NAUMANN FRANK , MEINIGKE BERND , HOEFFKES HORST
IPC分类号： A61K8/49 , A61Q5/10 , D06P1/642 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/494
摘要： The invention relates to an agent for dyeing keratin containing fibers which comprises as the developer at least one compound of the general formula (I), wherein R1 and R2 are the same or different and represent hydrogen, C1-4 alkyl or C1-4 hydroxyalkyl, and R3 represents a group of the formula (II), wherein R4 represents a piperazinyl group or a group -NR7(CH2)n-NR7, wherein R7 represents hydrogen or C1-4 alkyl and n is an integer of from 1 to 4, R5 and R6 are the same or different and represent hydrogen, C1-4 alkyl or C1-4 hydroxyalkyl, or else R3 represents a group (III), or a group (IV), wherein R9 represents hydrogen, C1-4 alkyl or C1-4 hydroxyalkyl, Y represents a direct bond or a straight-chain or branched C1-5 alkylene group, and A represents a saturated or unsaturated 5-, 6- or 7-membered ring optionally containing one or more heteroatoms, a group -CO-NH2, a C1-4 alkoxy group or a C1-4 dialkylamino group, wherein A may be linked with any carbon atom of the alkylene group Y.
摘要翻译：有权利用于着色包含角蛋白的纤维，其包括组合物，如显影剂部件的至少一个具有通式（I）可以是相同的或不同的，其中R1和R2，并且表示氢，C 1-4烷基或C 1-4化合物羟烷基和R 3是具有其中R 4表示哌嗪基或基团的式（II）的基团-NR 7（CH 2）n的NR 7，其中R 7是氢或C 1-4烷基，n是从一个整数 1至4可以是，R 5和R 6可以相同或不同，是氢，C 1-4烷基或C 1-4羟基烷基，基团（III）或一组（IV）其中R9是氢，C1 -4-烷基或C 1-4 - 羟基烷基，Y为直接键或直链或支链C 1-5 - 亚烷基，a是一个为饱和或不饱和的，任选地含有杂原子或更多5,6或7元环中，基团-CO-NH 2，C 1-4烷氧基或一个 ÈC1-4二烷基氨基，其中，A可以被链接到所述的亚烷基Y的任何碳原子

5. 发明申请

WO0100142A3 DEVELOPER-COUPLER COMBINATIONS 审中-公开
标题翻译：开发商耦合器组合
公开(公告)号：WO0100142A3
公开(公告)日：2002-03-28
申请号：PCT/EP0005155
申请日：2000-06-06
申请人： HENKEL KGAA , NAUMANN FRANK , ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
发明人： NAUMANN FRANK , ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
IPC分类号： A61K8/34 , A61K8/41 , A61K8/49 , A61Q5/10 , A61K7/13
CPC分类号： A61K8/347 , A61K8/415 , A61K8/4926 , A61Q5/10
摘要： The invention relates to oxidation colorants, used to colour keratin fibres, in particular, human hair, which contain the following in a medium suitable for coloration: (a) at least one pyridine derivative of the general formula (I), or one of the physiologically compatible salts of these compounds as the developer component; in said formula, R and R represent, independently of one another, hydrogen, a C1 to C4 alkyl group or a C1 to C4 hydroxyalkyl group, or together with the nitrogen atom, to which they are bonded, form an optionally substituted, saturated heterocyclic 5 or 6 membered ring which can contain an additional nitrogen atom or an oxygen atom, R represents hydrogen, a C1 to C4 alkyl group or a C1 to C4 hydroxyalkyl group, R and R represent, independently of one another, hydrogen, a C1 to C4 alkyl group or a C3 to C8 cycloalkyl group, R and R represent, independently of one another, hydrogen, a halogen atom, a C1 to C4 alkyl group, a C1 to C4 hydroxyalkyl group, a C1 to C4 aminoalkyl group or a C1 to C4 alkoxy group and n is a whole number from 1 to 8; and (b) at least one specific coupler component.
摘要翻译：主题vorgliegenden发明涉及角蛋白纤维，特别是人的头发，在介质中的适合于染色的氧化染色：（1）通式（I），其中R <1>和R <2>独立地表示氢中的至少一种吡啶衍生物，站立或一个C1至C4烷基或与氮原子一C 1至C 4羟烷基一起形成它们所连接形成任选取代的饱和杂环含有一个额外的氮原子的5元或6元环，或一个 [R <3>代表氢，C1至C4烷基或C1可以含有氧原子，代表到C4羟烷基的基团R <4>和R <5>独立地为氢，C1至C4烷基或 C3是〜C8环烷基，R <6>和R <7>独立地是氢，卤原子，C1-C4烷基，一个C 1至C 4 - 羟烷基，C1至C4 氨基烷基基团或C1-C4烷氧基，n是从1到8，或这些化合物作为主要中间体和（b）至少一种特别的偶合剂成分的生理学上相容的盐之一的整数。

6. 发明申请

WO0121144A3 NEW DIRECT HAIR COLORANTS 审中-公开
标题翻译：新的直接染发剂
公开(公告)号：WO0121144A3
公开(公告)日：2001-10-11
申请号：PCT/EP0008774
申请日：2000-09-08
申请人： HENKEL KGAA , NAUMANN FRANK , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
发明人： NAUMANN FRANK , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
IPC分类号： A61K8/41 , A61Q5/06 , C07C211/29 , A61K7/13
CPC分类号： A61K8/418 , A61Q5/065
摘要： The invention relates to agents for dyeing and coloring keratin fibers, especially human hair. Said agents contain as the direct colorant at least one 2-nitro-p-phenylene diamine derivative of the formula (I), wherein R to R independently represent hydrogen, a C1-4 hydroxyalkyl group or a saturated, a mono- or polyunsaturated C7-8 ring that is optionally substituted with a C1-4 alkyl group, a halogen atom, a hydroxy group or an amino group, and X represents hydrogen or a halogen atom, with the proviso that at least one of the substituents R to R is a C7-8 ring. The inventive agents facilitate intensive colorations with excellent color fastness properties.
摘要翻译：本发明的目的是用于着色和着色角蛋白纤维，更具体地讲人的毛发，如直接染料，式（I）中的至少一种2-硝基 - 对苯二胺衍生物剂是在R <1>至R <4>彼此独立地代表氢，C 1-4羟烷基或可任选地用C 1-4烷基，卤素原子，羟基或氨基取代的饱和的，单或多不饱和的C 7-8环，X是氢或卤素原子，含有其条件是取代基R <1>至R中的至少一个<4>是一个C7-8环。根据本发明的装置使密集的颜色具有优异的牢度性能。

7. 发明申请

WO0100152A8 NEW COUPLING COMPONENTS FOR OXIDATION HAIR COLORANTS 审中-公开
标题翻译：新合剂成分氧化发色
公开(公告)号：WO0100152A8
公开(公告)日：2001-04-05
申请号：PCT/EP0005156
申请日：2000-06-06
申请人： HENKEL KGAA , NAUMANN FRANK , ROSE DAVID , HOEFFKES HORST
发明人： NAUMANN FRANK , ROSE DAVID , HOEFFKES HORST
IPC分类号： D06P3/10 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/415
摘要： The invention relates to oxidation colorants for coloring keratin fibers, especially human hair. The inventive colorants contain, dissolved in a medium that is appropriate for coloring, at least one developer component and at least one m-aminophenol derivative of formula (I), wherein R and R independently represent hydrogen, a C1-C4 alkyl group or a C1-C4 hydroxyalkyl group or, together with the nitrogen atom to which they are bound, form an optionally substituted, saturated heterocyclic 5- or 6-membered ring that may contain another nitrogen atom or an oxygen atom, R represents hydrogen, a C1-C4 alkyl group or a C1-C4 hydroxyalkyl group, R represents hydrogen, a C1-C4 alkyl group or a C3-C8 cycloalkyl group and R and R independently represent hydrogen, a halogen atom, a C1-C4 alkyl group, a C1-C4 hydroxyalkyl group, a C1-C4 aminoalkyl group or a C1-C4 alkoxy group and n is an integer from 1 to 8, or they contain a physiologically acceptable salt of one of these compounds, with the proviso that, if a tetraaminopyrimidine is used as the developer component, at least one additional colorant precursor is present. The inventive agents are characterized by intense colorations especially in the brown range and by excellent color fastness properties.
摘要翻译：本发明涉及角蛋白纤维，特别是人的毛发的氧化染色，含有在适当的染色的介质中的至少一种显色剂组分和式（I）中的至少一种间氨基苯酚衍生物，其中R <1>和R <2>各自独立地是氢，C1至C4烷基或C1-至C4羟烷基，或一起与氮原子到它们所连接形成任选取代的饱和杂环含有一个额外的氮原子的5-或6-元环或可以含有氧原子，R <3>代表氢，C1至C4烷基或C1-至C4-羟烷基是，R <4>为氢，C1至C4烷基或C3至C8 环烷基，并且R <5>和R <6>独立地为氢，卤原子，C1-C4烷基，一个C 1至C 4羟烷基，C1 是C4-氨基烷基，或C1-C4烷氧基，n是从1到8的整数，或含有这些化合物的生理学上可接受的盐中的一种，其条件是，当四氨基被用作显影剂的部件，至少一个另外的是染料前体存在。本发明的组合物的特征在于强烈着色，尤其是在具有优异的牢度性能棕色区域。

8. 发明申请

WO0141714A3 NEW COLOURING COMBINATION 审中-公开
标题翻译：新组合DYE
公开(公告)号：WO0141714A3
公开(公告)日：2002-02-14
申请号：PCT/EP0012094
申请日：2000-12-01
申请人： HENKEL KGAA , ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
发明人： ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
IPC分类号： A61K8/34 , A61K8/41 , A61K8/49 , A61Q5/10 , A61K7/13
CPC分类号： A61K8/411 , A61K8/347 , A61K8/415 , A61K8/492 , A61K8/4926 , A61Q5/10
摘要： The invention relates to oxidative colouring agents for colouring keratin fibres, in particular human hair, which contain, in a medium suitable for colouring, at least one developer component and (a) at least one m-phenylenediamine derivative of formula (I) as coupling component, where R = a branched or unbranched C1- to C8-alkyl group and R = a branched or unbranched C1 to C8 alkyl group or a phenyl group, optionally substituted by one or several C1 to C4 alkyl group(s) or, by one or several halogen atom(s), or a physiologically acceptable salt thereof; (b) at least one further coupling component, selected from 2-amino-3-hydroxy-5-chlorpyridine, 2,6-dihydroxy-3,4-dimethylpyridine, 2,6-bis-( beta -hydroxyethylamino)-toluene, 2,4-dichlor-3-aminophenol, 3-amino-2-chloro-6-methylphenol, 5-amino-4-chloro-2-methylphenol, 5-(2'-hydroxyethyl)-amino-2-methylphenol, 5-amino-2-methylphenol, 2-amino-3-hydroxypyridine, 3-amino-2-methylamino-6-methoxypyridine, 2-methylresorcinol, 2,4-diaminophenoxyethanol, 1,3-bis-(2,4-diaminophenoxy)-propane, resorcinol, m-aminophenol, 3,5-diamino-2,6-dimethoxypyridine, 1,7-, 2,7- and 1,5-dihydroxynaphthalene, and 4-hydroxyindole and 6-hydroxyindole. According to the invention, the disclosed hair colouring agents are characterised by the excellent colouring properties thereof.
摘要翻译：本发明涉及角蛋白纤维氧化染色，特别是人的头发，在合适的染色的介质中的至少一种显色剂组分和（a）作为偶合剂成分的至少一种间苯二胺的式（I），其中R <1>是衍生物有支链或无支链的C1至C8烷基和R <2>是支链或无支链的C1至C8烷基或苯基基团，其任选地一个被一个或多个C1-C4烷基基团（一个或多个），或通过可被取代或多个卤素原子（一个或多个），或它的生理上可接受的盐中的一种，和（b）在选自至少一个另外的偶合剂成分的2-氨基-3-羟基-5-氯吡啶，2,6- Dihydroxa -3,4- 二甲基吡啶，2,6-双（β-羟基乙基氨基）甲苯，2,4-二氯-3-氨基苯酚，3-氨基-2-氯-6-甲基苯酚，5-氨基-4-氯-2-甲基苯酚， 5-（2'-羟基乙基）氨基-2-甲基苯酚，5-氨基-2- methylphen 醇，2-氨基-3-羟基吡啶，3-氨基-2-甲氨基-6-甲氧基吡啶，2-甲基间苯二酚，2,4-二氨基苯氧乙醇，1,3-双 - （2,4-二氨基苯氧基） - 丙烷，间苯二酚，间氨基苯酚，3,5-二氨基-2,6-二甲氧基吡啶1,7-，2,7-和1,5-二羟基萘和4-羟基吲哚和6-羟基吲哚，包括在内。本发明的染发剂特别是其出色的着色性能区别。

9. 发明申请

WO0147475A3 AGENT FOR DYEING KERATIN CONTAINING FIBERS 审中-公开
标题翻译：手段垂死角蛋白纤维
公开(公告)号：WO0147475A3
公开(公告)日：2001-11-22
申请号：PCT/EP0012813
申请日：2000-12-15
申请人： HENKEL KGAA , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
发明人： ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
IPC分类号： A61K8/41 , A61K8/49 , A61Q5/10 , C07D231/38 , A61K7/13
CPC分类号： A61K8/415 , A61K8/494 , A61Q5/10
摘要： The invention relates to oxidation dyes for dyeing keratin containing fibers, which dyes contain a combination of at least one 4,5-diaminopyrazole derivative or one of its physiologically acceptable salts as the developer component and at least one halogenated m-aminophenol of the general formula (I) or one of its physiologically acceptable salts as the coupling component, wherein R represents hydrogen or a halogen atom, and R represents a halogen atom. The invention also relates to a method for producing said agents.
摘要翻译：本发明涉及一种氧化染色角蛋白纤维，含有至少一个4,5-二氨基衍生物或其生理学上可接受的盐之一物作为显色剂组分和通式中的至少一种卤化间氨基苯酚（Ⅰ）或它的生理上可接受的一种的组合盐作为偶合剂成分，其中R <2>是氢或卤素原子，并且R <3>表示卤素原子，以及相应的方法。

10. 发明申请

WO9931054A3 NOVEL P-AMINOPHENOL DERIVATIVES AND THE USE THEREOF 审中-公开
标题翻译：新的对氨基苯酚衍生物及其用途
公开(公告)号：WO9931054A3
公开(公告)日：1999-09-10
申请号：PCT/EP9807961
申请日：1998-12-08
申请人： HENKEL KGAA , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
发明人： ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
IPC分类号： A61K8/00 , A61K8/33 , A61K8/41 , A61K8/46 , A61K8/49 , A61Q5/10 , C07C215/76 , C07C217/76 , C07C317/18 , C07C317/28 , C07C323/27 , D06P3/10 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/415 , C07C215/76
摘要： Compounds of general formula (I), wherein A, B,C and D represent, independently from each other, an -OH- or -NHR- group, wherein R stands for a hydrogen atom or a C1-4 alkyl radical, with the proviso that A, B, C or D respectively stands for a hydroxy group, X stands for oxygen, sulphur, a sulfoxy or sulfoxyl group, R and R represent, independently from each other, hydrogen, fluorine, chlorine, a C1-4 alkyl or hydroxyalkyl group or a C2-4-dihydroxy-alkyl group, preferably a C2-dihydroxy alkyl group, and the physically acceptable salts of these compounds are highly suitable for use as developer components in oxidation coloring agents.
摘要翻译：其中A，B，C和D相互独立的通式（I）化合物代表-OH或-NHR基团，其中R代表氢原子或C 1-4 - 烷基，条件是 A或B以及C或D中的每一个表示羟基，X表示氧，硫，亚砜基或亚砜基，R 1和R 2独立地表示氢，氟，氯，C1 4-烷基或羟烷基或C2-4-二羟烷基，优选C2-二羟烷基，并且这些化合物的生理学上可接受的盐非常适合作为氧化染料中的显色剂组分。

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