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1. 发明申请

WO02055042A2 DEVELOPER/ DEVELOPER HYBRID DYES AND HYBRID DYE PRECURSORS 审中-公开
标题翻译：开发商/开发商杂交染料和杂交染料产品
公开(公告)号：WO02055042A2
公开(公告)日：2002-07-18
申请号：PCT/EP0200016
申请日：2002-01-03
申请人： HENKEL KGAA , NAUMANN FRANK , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST , HOLLENBERG DETLEF
发明人： NAUMANN FRANK , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST , HOLLENBERG DETLEF
IPC分类号： A61K8/49 , A61Q5/10 , A61K7/13 , C09B57/00
CPC分类号： A61K8/494 , A61K8/4926 , A61Q5/10
摘要： Hybrid dyes of structure (I), X-S-Y (I) in which X and Y are each derived from various oxidation dye precursors of the developer type and S is a direct bond or at least one spacer group, are especially suitable for colouring keratin fibres, in particular, human hair. By the use of colouring agents with the above dyes, a series of problems which occurs with the use of complex dye mixtures, can be avoided or significantly reduced.
摘要翻译：结构（I）的混合染料，XSY（I）其中X和Y各自从显影剂类型的不同的氧化染料前体衍生的，和S代表直接键或至少一个间隔基团，非常适合用于着色角蛋白纤维，特别是人的头发，通过与这些染料一起使用着色剂，使用复杂的Fabstoffmischunchungen时发生的一些问题规避或显着减少。

2. 发明申请

WO0209662A3 AGENT FOR DYEING KERATIN CONTAINING FIBERS 审中-公开
标题翻译：手段垂死角蛋白纤维
公开(公告)号：WO0209662A3
公开(公告)日：2002-06-27
申请号：PCT/EP0108656
申请日：2001-07-26
申请人： HENKEL KGAA , ROSE DAVID , NAUMANN FRANK , MEINIGKE BERND , HOEFFKES HORST
发明人： ROSE DAVID , NAUMANN FRANK , MEINIGKE BERND , HOEFFKES HORST
IPC分类号： A61K8/49 , A61Q5/10 , D06P1/642 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/494
摘要： The invention relates to an agent for dyeing keratin containing fibers which comprises as the developer at least one compound of the general formula (I), wherein R1 and R2 are the same or different and represent hydrogen, C1-4 alkyl or C1-4 hydroxyalkyl, and R3 represents a group of the formula (II), wherein R4 represents a piperazinyl group or a group -NR7(CH2)n-NR7, wherein R7 represents hydrogen or C1-4 alkyl and n is an integer of from 1 to 4, R5 and R6 are the same or different and represent hydrogen, C1-4 alkyl or C1-4 hydroxyalkyl, or else R3 represents a group (III), or a group (IV), wherein R9 represents hydrogen, C1-4 alkyl or C1-4 hydroxyalkyl, Y represents a direct bond or a straight-chain or branched C1-5 alkylene group, and A represents a saturated or unsaturated 5-, 6- or 7-membered ring optionally containing one or more heteroatoms, a group -CO-NH2, a C1-4 alkoxy group or a C1-4 dialkylamino group, wherein A may be linked with any carbon atom of the alkylene group Y.
摘要翻译：有权利用于着色包含角蛋白的纤维，其包括组合物，如显影剂部件的至少一个具有通式（I）可以是相同的或不同的，其中R1和R2，并且表示氢，C 1-4烷基或C 1-4化合物羟烷基和R 3是具有其中R 4表示哌嗪基或基团的式（II）的基团-NR 7（CH 2）n的NR 7，其中R 7是氢或C 1-4烷基，n是从一个整数 1至4可以是，R 5和R 6可以相同或不同，是氢，C 1-4烷基或C 1-4羟基烷基，基团（III）或一组（IV）其中R9是氢，C1 -4-烷基或C 1-4 - 羟基烷基，Y为直接键或直链或支链C 1-5 - 亚烷基，a是一个为饱和或不饱和的，任选地含有杂原子或更多5,6或7元环中，基团-CO-NH 2，C 1-4烷氧基或一个 ÈC1-4二烷基氨基，其中，A可以被链接到所述的亚烷基Y的任何碳原子

3. 发明申请

WO0141716A3 COLOURING COMBINATION BASED ON A M-PHENYLENEDIAMINE DERIVATIVE 审中-公开
标题翻译： DYE组合基于阿间苯二胺衍生物
公开(公告)号：WO0141716A3
公开(公告)日：2002-04-04
申请号：PCT/EP0012096
申请日：2000-12-01
申请人： HENKEL KGAA , ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
发明人： ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
IPC分类号： A61K8/41 , A61K8/49 , A61Q5/10 , A61K7/13
CPC分类号： A61K8/494 , A61K8/411 , A61K8/415 , A61Q5/10
摘要： The invention relates to oxidative colouring agents for colouring keratin fibres, in particular human hair, which contain, in a medium suitable for colouring, (a) at least one m-phenylenediamine derivative of formula (I) as coupling component, where R = a branched or unbranched C1- to C8-alkyl group and R = a branched or unbranched C1 to C8 alkyl group or a phenyl group, optionally substituted by one or several C1 to C4 alkyl group(s) or, by one or several halogen atom(s), or a physiologically acceptable salt thereof; (b) at least one developing component selected from 4-amino-2-((diethylamino)methyl)phenol, 2-chloro-4-aminophenol, 2,6-dichloro-4-aminophenol, 4-amino-3-methylphenol, 1-(2'-hydroxyethyl)-2,5-diaminobenzene, 1,10-bis-(2,5-diaminophenyl)-1,4,7,10-tetraoxadecane, bis-(2-hydroxy-5-aminophenyl)-methane, 2-aminomethyl-4-aminophenol, N,N'-bis-(4-aminophenyl)-1,4-diazacycloheptane, 1,3-bis-(N-(2-hydroxyethyl)-N-(4-aminophenylamino))-2-propanol, N,N-bis-(2-hydroxyethyl)-p-phenylendiamine, 4,5-diamino-1-(
摘要翻译：本发明涉及角蛋白纤维，特别是人的毛发的氧化染色的，包括（a）在培养基中适当用于染色，作为偶合剂成分的至少一种式（I）其中R <1>为支链或的间苯二胺衍生物无支链的C1至C8烷基和R <2>是支链或无支链的C1至C8烷基或苯基基团，其是任选取代的（被一个或多个C1-C4烷基基团或由一个或多个卤素原子 e）可以被取代，或其生理学上可接受的盐中的一种，和（b）至少一种显色剂组分由4-氨基-2-选择 - （（二乙基氨基）甲基）苯酚，2-氯-4-氨基苯酚，2,6-二氯 -4-氨基苯酚，4-氨基-3-甲基苯酚，1-（2'-羟乙基）-2,5-二氨基苯，1,10-双（2,5-二氨基苯基）-1,4,7,10- 四氧杂癸，双 - （2-羟基-5-氨基苯基）甲烷，2- Aminomehtyl -4-氨基苯酚，N，N'-双（4-氨基苯基）-1,4- diazacycl oheptan，1,3-双（N（2-羟乙基）-N（4-氨基苯基氨基）） - 2-丙醇，N，N-双（2-羟乙基） - 对苯二胺，4,5-二氨基 1-（β-羟乙基）吡唑和邻氨基苯酚含有。通过突出的着色性质，本发明的组合物的特征特别在于。

4. 发明申请

WO0197763A8 OXIDATION DYEING AGENT CONTAINING 2-HYDROXY-5-AMINOBENZYL PIPERAZINES 审中-公开
标题翻译：含有2-羟基-5-氨基苄基 - 哌嗪的氧化着色剂
公开(公告)号：WO0197763A8
公开(公告)日：2002-01-24
申请号：PCT/EP0106558
申请日：2001-06-09
申请人： HENKEL KGAA , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
发明人： ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
IPC分类号： A61K8/49 , A61K8/67 , A61Q5/08 , A61Q5/10 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/494 , A61K8/673 , A61Q5/08
摘要： The invention relates to the paraaminophenol derivatives of formula (I), wherein R , R , R and R independently represent hydrogen, a C1-C4 alkyl group, a C2-C4 hydroxyalkyl group, R and R further represent fluoro, chloro, bromo, a C1-C4 alkoxy group or a hydroxy C2-C4 alkoxy group, R may also represent an acyl group having 1-8 C atoms or a group of formula (II), and R represents a hydrogen atom, an alkyl group, a C2-C4 hydroxyalkyl group, fluoro, chloro, bromo or a C1-C4 alkoxy group, and to their water-soluble salts, which are suitable as a developer component for producing an oxidative coloration. The preferred compounds are binuclear compounds, wherein R represents a group of formula (II). The inventive oxidation colorants for keratin fibers, especially hair, contain the compounds of formula (I) preferably combined with further developers and/or coupling components and optionally combined with direct dyes.
摘要翻译：式（I）的对氨基苯酚衍生物，其中R <1>，R <2>，R <3>，和R <5>独立地是氢，C1-C4烷基，C2-C4羟烷基，R <2>和R <3>另外，氟，氯，溴，C1-C4的烷氧基或羟基-C 2 -C 4 - 烷氧基，R <5>和酰基具有1-8个C- 是代表一个氢原子，一个烷基，一个C 2 -C 4羟烷基，氟，氯，溴和C1-C4烷氧基可以是原子或基团式（II）和R <4>。和水溶性的盐是作为显影剂组分用于生产氧化着色是有用的。双核是优选的，其中R <5>是一组式（II）的化合物。氧化着色剂用于角蛋白纤维，特别是对头发，含有式（I）优选在与其他开发者和/或偶合剂组分和，任选地，用直接染料组合的化合物。

5. 发明申请

WO0076977A3 OXIDATION COLORANT STARTING PRODUCTS 审中-公开
标题翻译：氧化染料前体
公开(公告)号：WO0076977A3
公开(公告)日：2002-05-02
申请号：PCT/EP0005151
申请日：2000-06-06
申请人： HENKEL KGAA , NAUMANN FRANK , ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
发明人： NAUMANN FRANK , ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
IPC分类号： C07D213/74 , A61K7/13
CPC分类号： C07D213/74 , A61K8/4926 , A61Q5/10
摘要： The invention relates to oxidation colorants for coloring keratin fibers, especially human hair. The inventive colorants contain, dissolved in a medium that is appropriate for coloring, at least one 2,5-diaminopyridine derivative of the general formula (I) wherein R and R may independently represent hydrogen, a C1 to C4 alkyl group or a C1 to C4 hydroxyalkyl group or, together with the nitrogen atom to which they are bound, form an optionally substituted, saturated heterocyclic 5- or 6-membered ring that may contain another nitrogen atom or an oxygen atom, R is hydrogen, a C1 to C4 alkyl group or a C1 to C4 hydroxyalkyl group, R and R independently represent hydrogen, a C1 to C4 alkyl group or a C3 to C8 cycloalkyl group, R and R independently represent hydrogen, a halogen atom, a C1 to C4 alkyl group, a C1 to C4 hydroxyalkyl group, a C1 to C4 aminoalkyl group or a C1 to C4 alkoxy group and n is 1 or 2, or a physiologically acceptable salt of the above compounds. The inventive agents are characterized by intense colorations especially in the red/brown range and by excellent color fastness properties.
摘要翻译：本发明涉及角蛋白纤维，特别是人的头发，在介质中的适当的染色，在通式（I），其中R <1>和R <2>独立地表示氢中的至少一种2,5-二氨基吡啶衍生物的氧化染色，站立或一个C1至C4烷基或与氮原子一C 1至C 4羟烷基一起形成它们所连接形成任选取代的饱和杂环含有一个额外的氮原子的5元或6元环，或一个可含有氧原子，R <3>代表氢，C1至C4烷基或C1-至C4-羟烷基是，R <4>和R <5>独立地为氢，C1至C4烷基或包括C3〜C8环烷基，R <6>和R <7>独立地是氢，卤原子，C1-C4烷基，一个C 1至C 4羟烷基，C1 至C4氨基烷基，或C1-C4烷氧基，n为1或2，或含有这些化合物的生理学上可接受的盐中的一种。新型组合物的特征在于强烈着色，尤其是在棕红色范围内具有优异的坚牢度性能，从。

6. 发明申请

WO0141714A3 NEW COLOURING COMBINATION 审中-公开
标题翻译：新组合DYE
公开(公告)号：WO0141714A3
公开(公告)日：2002-02-14
申请号：PCT/EP0012094
申请日：2000-12-01
申请人： HENKEL KGAA , ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
发明人： ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
IPC分类号： A61K8/34 , A61K8/41 , A61K8/49 , A61Q5/10 , A61K7/13
CPC分类号： A61K8/411 , A61K8/347 , A61K8/415 , A61K8/492 , A61K8/4926 , A61Q5/10
摘要： The invention relates to oxidative colouring agents for colouring keratin fibres, in particular human hair, which contain, in a medium suitable for colouring, at least one developer component and (a) at least one m-phenylenediamine derivative of formula (I) as coupling component, where R = a branched or unbranched C1- to C8-alkyl group and R = a branched or unbranched C1 to C8 alkyl group or a phenyl group, optionally substituted by one or several C1 to C4 alkyl group(s) or, by one or several halogen atom(s), or a physiologically acceptable salt thereof; (b) at least one further coupling component, selected from 2-amino-3-hydroxy-5-chlorpyridine, 2,6-dihydroxy-3,4-dimethylpyridine, 2,6-bis-( beta -hydroxyethylamino)-toluene, 2,4-dichlor-3-aminophenol, 3-amino-2-chloro-6-methylphenol, 5-amino-4-chloro-2-methylphenol, 5-(2'-hydroxyethyl)-amino-2-methylphenol, 5-amino-2-methylphenol, 2-amino-3-hydroxypyridine, 3-amino-2-methylamino-6-methoxypyridine, 2-methylresorcinol, 2,4-diaminophenoxyethanol, 1,3-bis-(2,4-diaminophenoxy)-propane, resorcinol, m-aminophenol, 3,5-diamino-2,6-dimethoxypyridine, 1,7-, 2,7- and 1,5-dihydroxynaphthalene, and 4-hydroxyindole and 6-hydroxyindole. According to the invention, the disclosed hair colouring agents are characterised by the excellent colouring properties thereof.
摘要翻译：本发明涉及角蛋白纤维氧化染色，特别是人的头发，在合适的染色的介质中的至少一种显色剂组分和（a）作为偶合剂成分的至少一种间苯二胺的式（I），其中R <1>是衍生物有支链或无支链的C1至C8烷基和R <2>是支链或无支链的C1至C8烷基或苯基基团，其任选地一个被一个或多个C1-C4烷基基团（一个或多个），或通过可被取代或多个卤素原子（一个或多个），或它的生理上可接受的盐中的一种，和（b）在选自至少一个另外的偶合剂成分的2-氨基-3-羟基-5-氯吡啶，2,6- Dihydroxa -3,4- 二甲基吡啶，2,6-双（β-羟基乙基氨基）甲苯，2,4-二氯-3-氨基苯酚，3-氨基-2-氯-6-甲基苯酚，5-氨基-4-氯-2-甲基苯酚， 5-（2'-羟基乙基）氨基-2-甲基苯酚，5-氨基-2- methylphen 醇，2-氨基-3-羟基吡啶，3-氨基-2-甲氨基-6-甲氧基吡啶，2-甲基间苯二酚，2,4-二氨基苯氧乙醇，1,3-双 - （2,4-二氨基苯氧基） - 丙烷，间苯二酚，间氨基苯酚，3,5-二氨基-2,6-二甲氧基吡啶1,7-，2,7-和1,5-二羟基萘和4-羟基吲哚和6-羟基吲哚，包括在内。本发明的染发剂特别是其出色的着色性能区别。

7. 发明申请

WO0147475A3 AGENT FOR DYEING KERATIN CONTAINING FIBERS 审中-公开
标题翻译：手段垂死角蛋白纤维
公开(公告)号：WO0147475A3
公开(公告)日：2001-11-22
申请号：PCT/EP0012813
申请日：2000-12-15
申请人： HENKEL KGAA , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
发明人： ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
IPC分类号： A61K8/41 , A61K8/49 , A61Q5/10 , C07D231/38 , A61K7/13
CPC分类号： A61K8/415 , A61K8/494 , A61Q5/10
摘要： The invention relates to oxidation dyes for dyeing keratin containing fibers, which dyes contain a combination of at least one 4,5-diaminopyrazole derivative or one of its physiologically acceptable salts as the developer component and at least one halogenated m-aminophenol of the general formula (I) or one of its physiologically acceptable salts as the coupling component, wherein R represents hydrogen or a halogen atom, and R represents a halogen atom. The invention also relates to a method for producing said agents.
摘要翻译：本发明涉及一种氧化染色角蛋白纤维，含有至少一个4,5-二氨基衍生物或其生理学上可接受的盐之一物作为显色剂组分和通式中的至少一种卤化间氨基苯酚（Ⅰ）或它的生理上可接受的一种的组合盐作为偶合剂成分，其中R <2>是氢或卤素原子，并且R <3>表示卤素原子，以及相应的方法。

8. 发明申请

WO9931054A3 NOVEL P-AMINOPHENOL DERIVATIVES AND THE USE THEREOF 审中-公开
标题翻译：新的对氨基苯酚衍生物及其用途
公开(公告)号：WO9931054A3
公开(公告)日：1999-09-10
申请号：PCT/EP9807961
申请日：1998-12-08
申请人： HENKEL KGAA , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
发明人： ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
IPC分类号： A61K8/00 , A61K8/33 , A61K8/41 , A61K8/46 , A61K8/49 , A61Q5/10 , C07C215/76 , C07C217/76 , C07C317/18 , C07C317/28 , C07C323/27 , D06P3/10 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/415 , C07C215/76
摘要： Compounds of general formula (I), wherein A, B,C and D represent, independently from each other, an -OH- or -NHR- group, wherein R stands for a hydrogen atom or a C1-4 alkyl radical, with the proviso that A, B, C or D respectively stands for a hydroxy group, X stands for oxygen, sulphur, a sulfoxy or sulfoxyl group, R and R represent, independently from each other, hydrogen, fluorine, chlorine, a C1-4 alkyl or hydroxyalkyl group or a C2-4-dihydroxy-alkyl group, preferably a C2-dihydroxy alkyl group, and the physically acceptable salts of these compounds are highly suitable for use as developer components in oxidation coloring agents.
摘要翻译：其中A，B，C和D相互独立的通式（I）化合物代表-OH或-NHR基团，其中R代表氢原子或C 1-4 - 烷基，条件是 A或B以及C或D中的每一个表示羟基，X表示氧，硫，亚砜基或亚砜基，R 1和R 2独立地表示氢，氟，氯，C1 4-烷基或羟烷基或C2-4-二羟烷基，优选C2-二羟烷基，并且这些化合物的生理学上可接受的盐非常适合作为氧化染料中的显色剂组分。

9. 发明申请

WO0206207A3 NOVEL COUPLING COMPONENTS FOR OXIDATION COLOURING AGENTS 审中-公开
标题翻译：新偶联剂成分氧化染料
公开(公告)号：WO0206207A3
公开(公告)日：2002-04-18
申请号：PCT/EP0107828
申请日：2001-07-07
申请人： HENKEL KGAA , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
发明人： ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
IPC分类号： C07C209/00 , C07C211/51 , C07C211/53 , C07C217/78 , C07D295/12 , C07D295/135 , D06P1/32 , D06P1/645 , A61K7/13
CPC分类号： C07D295/135 , A61K8/411 , A61Q5/10 , C07C211/53
摘要： The invention relates to N,N'-(3-amino phenyl)-alkylene diamines of general formula (I), wherein R , R , R , R , R and R independently mean hydrogen, a C1-C4 alkyl group, a C2-C4 hydroxy alkyl group, an allyl group or a benzyl group wherein R and R optionally form a C1-C4 alkyl bridge, .R , R , R and R independently mean hydrogen, halogen, a C1-C4 alkyl group, a C2-C4 hydroxy alkyl group, a C1-C4 alkoxy or hydroxy alkoxy group; n is a whole number from 2 - 8; and the water soluble salts thereof. The inventive products are suitable as couplers for producing oxidation colourings with known developer components. The invention also relates to oxidation colouring agents for colouring keratin fibres, particularly hair fibres, contained in a aqueous substrate of at least one developing component, preferably from the group of p-phenylene diamines, p amino phenoles, amino pyrimidines or 2.5 diamino pyridines or the derivatures thereof and at least one coupling compound of formula (I).
摘要翻译： N，N'-双（3-氨基苯基）通式（I），其中R1，R2，R7，R8，R9和R10独立地为氢，C1-C4烷基，C2的亚烷基二胺 C4-羟烷基，烯丙基或苄基，其中R <1>和R <2>任选地形成C 1 -C 4亚烷基; [R <3>，R <4>，R <5>和R <6>独立地是氢，卤素，一个C1-C4烷基，C2-C4羟烷基，C1-C4烷氧基或羟基烷氧基 ; n是2至8的整数; 和水溶性盐，如成色剂与已知显影剂组分生产氧化着色是有用的。氧化着色剂用于着色角蛋白纤维，特别是头发，含有在含水载体中的至少一种显色剂组分，优选选自对苯二胺，对氨基苯酚，对氨基嘧啶或2,5-二氨基吡啶或其衍生物和至少一种偶合剂化合物的式（I）。

10. 发明申请

WO0147477A3 AGENT FOR DYEING KERATIN CONTAINING FIBERS 审中-公开
标题翻译：手段垂死角蛋白纤维
公开(公告)号：WO0147477A3
公开(公告)日：2002-02-07
申请号：PCT/EP0012893
申请日：2000-12-18
申请人： HENKEL KGAA , ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
发明人： ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
IPC分类号： A61K20060101 , A61K8/49 , A61Q5/06 , C09B23/06 , C09B67/00 , A61K7/13
CPC分类号： A61K8/4946 , A61K8/49 , A61Q5/065
摘要： The invention relates to an agent for dyeing keratin containing fibers, especially human hair. The inventive agent contains as the dyeing component compounds of the formula (I), wherein =B- represents a group =CR - or a group (1), A represents (2), and A' represents (3). The inventive agents are especially useful for dyeing keratin containing fibers, particularly in the absence of oxidizing agents.
摘要翻译：制剂用于着色包含角蛋白的纤维，尤其是人的头发，含有如式（I），其中= B-是基团=铬着色成分的化合物<1> - 或基团（1），A（2）和A“是（3）。他们是理想的着色角蛋白纤维，特别是在没有氧化剂。

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