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    • 2. 发明申请
    • COMPOSITION AND METHOD FOR CHROMATING TREATMENT OF METAL
    • 用于金属处理的组合物和方法
    • WO1992003594A1
    • 1992-03-05
    • PCT/US1991006017
    • 1991-08-23
    • HENKEL CORPORATIONSUDA, ArataOGINO, Takao
    • HENKEL CORPORATION
    • C23C22/33
    • C23C22/38C23C22/33
    • A chromate conversion coating with excellent cold workability and protection against corrosion after subsequent painting can be formed on metal surfaces, particularly on galvanized steel sheet, by drying in place on the metal an amount of an acidic aqueous composition comprising (A) from 4.0 to 51.0 g/L of hexavalent chromium; (B) from 6.0 to 38.0 g/L of trivalent chromium; (C) from 0.5 to 97.0 g/L of phosphate ions; (D) a component selected from the group consisting of sulfate ions, nitrate ions, fluoride ions, and mixtures thereof; and (E) a component selected from the group consisting of cations of Cu, Co, Ni, Sn, Fe, and Pb and mixtures thereof, wherein the trivalent chromium/hexavalent chromium weight ratio is in the range from 0.2 to 1.4. Preferably the amount of aqueous composition used is such as to produce a chromium add-on of from 20-160 mg/m .
    • 可以在金属表面,特别是镀锌钢板上,通过在金属上适当地干燥一定量的含有(A)4.0〜51.0的酸性水性组合物的量,可以在金属表面,特别是镀锌钢板上形成具有优异的冷加工性和耐腐蚀性的铬酸盐转化涂层 g / L六价铬; (B)6.0〜38.0g / L三价铬; (C)0.5〜97.0g / L的磷酸根离子; (D)选自硫酸根离子,硝酸根离子,氟离子及其混合物的组分; 和(E)选自Cu,Co,Ni,Sn,Fe和Pb的阳离子及其混合物的组分,其中三价铬/六价铬重量比在0.2至1.4的范围内。 优选地,所用的水性组合物的量可以产生20-160mg / m 2的铬添加剂。