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1. 发明申请

WO1997009453A1 COPPER RECOVERY PROCESS 审中-公开
标题翻译：铜回收工艺
公开(公告)号：WO1997009453A1
公开(公告)日：1997-03-13
申请号：PCT/US1996013814
申请日：1996-09-05
申请人： HENKEL CORPORATION
发明人： HENKEL CORPORATION , VIRNIG, Michael, J. , SUDDERTH, Brantley, R.
IPC分类号： C22B15/00
CPC分类号： C22B3/0021 , C22B3/0017 , C22B15/0078 , Y02P10/234 , Y02P10/236
摘要： An improvement in the process of recovery of copper from aqueous ammoniacal solutions containing copper values in which the copper values are extracted from the aqueous ammoniacal solution by an organic phase comprised of a diketone copper extractant dissolved in a water-immiscible organic hydrocarbon solvent, by improving the stripping of the copper from the organic extractant phase, in which the improved stripping results from the incorporation into, or addition to the diketone extractant phase of a catalytic amount of a hydroxy aryl oxime. Also an improved extractant composition is provided comprised of the mixture of a diketone copper extractant and a catalytic amount (preferably about 0.5 to about 5 mole % in relation to the diketone) of a hydroxy aryl oxime, such as nonyl or dodecyl salicylaldoxime.
摘要翻译：通过改善含铜溶解于与水不混溶的有机烃溶剂中的二酮铜提取剂的有机相，从含氨水溶液中提取铜的值，从含有铜值的氨水溶液中回收铜的改进，从有机萃取剂相中汽提铜，其中改进的汽提来自催化量的羟基芳基肟掺入或添加到二酮萃取相中。还提供了改进的萃取剂组合物，其由二酮铜萃取剂和催化量（相对于二酮优选约0.5至约5摩尔％）的羟基芳基肟如壬基或十二烷基水杨醛肟的混合物组成。

2. 发明申请

WO1998017363A1 CONCENTRATED SOLUTIONS OF OXIME METAL EXTRACTANTS AND METHOD OF FORMULATING EXTRACTANT COMPOSITIONS THEREFROM 审中-公开
标题翻译：含氧金属萃取剂的浓缩溶液及其制备提取物组合物的方法
公开(公告)号：WO1998017363A1
公开(公告)日：1998-04-30
申请号：PCT/US1997018237
申请日：1997-10-20
申请人： HENKEL CORPORATION
发明人： HENKEL CORPORATION , SUDDERTH, R., Brantley , WOLFE, George, A. , JENSEN, Ralph, L. , KORDOSKY, Gary, A. , VIRNIG, Michael, J. , CASEY, Mary , OLAFSON, Stephen, M. , CRANDELL, Terry, L. , HEIN, Hans, C.
IPC分类号： B01D11/02
CPC分类号： C01G3/003 , C22B3/0017 , Y02P10/234
摘要： The preparation of concentrated solutions of oxime metal extractants, such as aldoximes and ketoximes, or mixtures of aldoxime and ketoxime and the use thereof in formulating or preparing extraction reagent compositions for use in extracting metals from aqueous solutions containing metal values; and in particular, to extraction reagent compositions which are solutions of mixtures of water insoluble hydroxy aryl oximes, aldoximes and ketoximes, in varying ratios by weight of 1:99 aldoxime to ketoxime or conversely 1:99 ketoxime to aldoxime, in water immiscible hydrocarbon solvents. The extraction compositions may also optionally contain equilibrium modifiers or kinetic additives.
摘要翻译：制备肟金属萃取剂如肟和酮肟的浓缩溶液，或醛肟和酮肟的混合物及其在配制或制备用于从含有金属含量的水溶液中萃取金属的萃取剂组合物中的用途; 特别是提取试剂组合物，其是水不溶性羟基芳基肟，肟和酮肟的混合物的溶液，其以1:99的醛肟的重量比与酮肟的不同比例或相反的1:99酮肟与醛肟在水不混溶烃溶剂。提取组合物还可任选地含有平衡改性剂或动力学添加剂。

3. 发明申请

WO1997010367A1 RECOVERY OF GOLD USING EXTRACTION REAGENTS HAVING GUANIDYL FUNCTIONALITY 审中-公开
标题翻译：使用具有官能度功能的提取试剂恢复金
公开(公告)号：WO1997010367A1
公开(公告)日：1997-03-20
申请号：PCT/US1996013817
申请日：1996-09-09
申请人： HENKEL CORPORATION
发明人： HENKEL CORPORATION , VIRNIG, Michael, J.
IPC分类号： C22B11/08
CPC分类号： B01J45/00 , C22B3/24 , C22B11/08 , Y02P10/234
摘要： Recovery of gold from alkaline cyanide leach solutions using ion exchange adsorbents, comprising (a) contacting the cyanide leach solution containing the gold with an extraction reagent comprised of a solid adsorbent carrying an organic base functionality of a compound having a pKa between about 9-14, such as a guanidyl functionality, to adsorb gold and eluting the adsorbed gold from the solid adsorbent with an aqueous alkaline eluant solution having a pH above about 12 and containing an alkali metal salt of an aromatic or aliphatic carboxylic acid having from about 4-14 carbon atoms, the eluant solution having incorporated therein from about 0.001 moles to about 0.2 moles per liter of an alkali metal cyanide salt. The solid adsorbent containing the aurocyanide complex may be contacted with a concentrated aqueous solution of a zinc tetracyanide salt whereby the aurocyanide complex is displaced with a zinc tetracyanide complex before treatment with the eluant solution.
摘要翻译：使用离子交换吸附剂从碱性氰化物浸出溶液中回收金，其包括（a）使含有金的氰化物浸出溶液与由含有pKa在约9-14之间的化合物的有机碱官能团的固体吸附剂组成的提取试剂接触，例如胍基官能团，用pH高于约12的含水碱性洗脱剂溶液吸附金并从固体吸附剂中洗脱金，并含有具有约4-14的芳族或脂族羧酸的碱金属盐碳原子，洗脱剂溶液中加入约0.001摩尔至约0.2摩尔/升碱金属氰化物盐。可以将含有氰化亚胺配合物的固体吸附剂与浓缩的四氰化锌盐水溶液接触，由此在用洗脱剂溶液处理之前，用四氰化锌络合物置换亚硝酰胺络合物。

4. 发明申请

WO1993019212A2 RECOVERY OF PRECIOUS METAL 审中-公开
标题翻译：恢复重金属
公开(公告)号：WO1993019212A2
公开(公告)日：1993-09-30
申请号：PCT/US1993001994
申请日：1993-03-11
申请人： HENKEL CORPORATION
发明人： HENKEL CORPORATION , VIRNIG, Michael, J.
IPC分类号： C22B03/24
CPC分类号： C22B11/08 , C22B3/24 , C22B3/42 , C22B11/04 , Y02P10/234 , Y10S423/14
摘要： An improved process for recovery of precious metals such as gold or silver using novel ion exchnage resins having aryl guanidyl functionality from aryl guanidine compounds having a pKa at 25 DEG C less than 13 and preferably less than 12. The resins have improved elution properties compared to known guanidine reagents using caustic eluant solutions, particularly improved eluant solutions such as a mixture of sodium hydroxide and sodium benzoate. A selective elution of base metals may be carried out before elution of the precious metals from the resins having guanidyl functionality.
摘要翻译：一种改进的贵金属如金或银的回收方法，使用具有芳基胍基化合物的新型离子交换树脂，其具有25℃下pKa小于13，优选小于12的芳基胍化合物。该树脂与使用苛性洗脱剂溶液的已知胍试剂，特别是改进的洗脱液如氢氧化钠和苯甲酸钠的混合物。在从具有胍官能度的树脂中洗脱贵金属之前，可以进行碱金属的选择性洗脱。

5. 发明申请

WO1997049474A1 PROCESS FOR THE RECOVERY OF PRECIOUS METAL VALUES FROM AQUEOUS AMMONIACAL THIOSULFATE LEACH SOLUTIONS 审中-公开
标题翻译：从酸性硫酸钠浸出液中回收重金属元素的方法
公开(公告)号：WO1997049474A1
公开(公告)日：1997-12-31
申请号：PCT/US1997008654
申请日：1997-05-28
申请人： HENKEL CORPORATION
发明人： HENKEL CORPORATION , VIRNIG, Michael, J. , SIEROKOSKI, J., Michael
IPC分类号： B01D11/04
CPC分类号： C22B11/04 , C01G5/003 , C01G7/003 , C07C279/16 , C07C2601/14 , C07G17/00 , C22B3/0012 , Y02P10/234
摘要： The process of recovering precious metal from ores containing precious metals, such as gold and silver, from an aqueous ammoniacal thiosulfate leach solution to provide a significant practical and economical process for the recovery of gold or silver. After leaching of the ore with an aqueous ammoniacal thiosulfate solution, the leach solution is contacted with a precious metal extraction reagent to extract the precious metal values from the leach solution, after which the precious metal values are stripped from the extraction reagent to form a concentrated solution of the precious metal values from which the precious metals may be recovered by conventional methods such as electrolysis. The extraction reagents are those having guanidyl functionality or a quaternary amine functionality mixed with a weak organic acid such as a phenol. In the process, novel thiosulfate complexes of the precious metals are formed with the guanidyl or the quaternary amine extractants.
摘要翻译：从含有氨基硫代硫酸盐浸出溶液的贵金属（如金和银）的矿石中回收贵金属的过程，为回收金或银提供了重要的实用和经济的过程。在用含硫代硫酸铵水溶液浸出矿石后，将浸出溶液与贵金属萃取剂接触，从浸出溶液中提取贵金属值，然后从提取试剂中汽提出贵金属离子形成浓缩的可以通过电解等常规方法回收贵金属的贵金属值的溶液。提取试剂是具有胍基官能度的那些或与弱有机酸如苯酚混合的季胺官能团。在此过程中，贵金属的新型硫代硫酸盐络合物与胍基或季胺萃取剂形成。

6. 发明申请

WO1997029215A1 IMPROVED BETA-DIKETONES FOR THE EXTRACTION OF COPPER FROM AQUEOUS AMMONIACAL SOLUTIONS 审中-公开
标题翻译：从水溶液中提取铜的改进的BETA-DIKETONES
公开(公告)号：WO1997029215A1
公开(公告)日：1997-08-14
申请号：PCT/US1997000541
申请日：1997-01-30
申请人： HENKEL CORPORATION
发明人： HENKEL CORPORATION , VIRNIG, Michael, J. , KORDOSKY, Gary, A.
IPC分类号： C22B15/00
CPC分类号： C07C49/782 , C07C45/68 , C07C49/76 , C22B3/0021 , C22B15/0078 , Y02P10/234 , Y02P10/236
摘要： Novel modified and improved beta-diketones and their use in the extraction of copper from aqueous ammoniacal solutions containing copper values, resulting from commercial processes, including, but not limited to, leaching of copper containing ores, such as sulfidic ores, or concentrates resulting from flotation of such sulfidic ores. The novel diketones are those highly sterically hindered, which may be represented by formula (I) or (II) where in formula (I), R1 through R7 are the same or different, and are chosen from the group consisting of hydrogen, an aryl radical, an alkaryl radical containing from 6 to about 18 carbon atoms, and an alkyl radical containing from 1 to about 13 carbon atoms, with the provisos that (a) any two of R1 through R7 may together form a carbocyclic ring, (b) no more than four of R1 through R7 may be hydrogen, and (c) the overall molecule contains at least 14 carbon atoms. In formula (II), R is phenyl or alkyl substituted phenyl, R' is alkyl, and R'', R''' and R'''' are the same or different and are chosen from the group consisting of H, alkyl having from 1 to about 8 carbon atoms, and aralkyl having from 7 to about 14 carbon atoms, with the proviso that (a) no more than two of R'', R''' and R'''' are H and (b) the total number of carbons in all R groups is at least 13. The preferred beta-diketones of Formula (II) are selected from the group consisting of 1-phenyl-2-benzyl-3-isoheptyl-1,3-propanedione, 1-phenyl-2-methyl-3-isoheptyl-1,3-propanedione, 1-phenyl-4-ethyl-1,3-nonanedione and 1-phenyl-4,4-dimethyl-1,3-undecanedione.
摘要翻译：新型改性和改进的β-二酮及其在从包含铜值的含水氨溶液中提取铜的用途，由商业过程产生，包括但不限于浸出含铜矿石如硫化矿石或由浮选这种硫化矿石。新型二酮是高度空间位阻的，其可以由式（I）或（II）表示，其中在式（I）中，R 1至R 7相同或不同，并且选自氢，芳基自由基，含有6至约18个碳原子的烷芳基和含有1至约13个碳原子的烷基，条件是（a）R 1至R 7中的任何两个可以一起形成碳环，（b）不超过四个R 1至R 7可以是氢，和（c）整个分子含有至少14个碳原子。在式（II）中，R是苯基或烷基取代的苯基，R'是烷基，R“，R”和R“”相同或不同，并且选自H，烷基具有1至约8个碳原子的芳烷基和具有7至约14个碳原子的芳烷基，条件是（a）不超过两个R“，R”“和R”'分别为H和（ b）所有R基团中的总碳数为至少13.式（II）的优选β-二酮选自1-苯基-2-苄基-3-异庚基-1,3-丙二酮，1-苯基-2-甲基-3-异庚基-1,3-丙二酮，1-苯基-4-乙基-1,3-壬二酮和1-苯基-4,4-二甲基-1,3-十一烷二酮。

7. 发明申请

WO1996025525A1 MODIFIERS FOR ALDOXIME EXTRACTANT OF METAL VALUES 审中-公开
标题翻译： ALDOXIME金属催化剂的改性剂
公开(公告)号：WO1996025525A1
公开(公告)日：1996-08-22
申请号：PCT/US1996001116
申请日：1996-02-12
申请人： HENKEL CORPORATION
发明人： HENKEL CORPORATION , VIRNIG, Michael, J. , MATTISON, Phillip, L. , KRBECHEK, Leroy, O. , MACKENZIE, Murdoch
IPC分类号： C22B15/00
CPC分类号： C22B15/00 , C07C251/48 , C22B3/0017 , Y02P10/234
摘要： Alternative equilibrium modifiers for use with aldoxime extractants, such as hydroxyl aryl aldoxime extractants, employed in the process for extraction of metal values, particularly copper values, in the extraction from aqueous solutions, in which the extractant and modifiers are employed in an organic solvent phase, the solvent being a water insoluble, water immiscible hydrocarbon solvent, such as a kerosene.
摘要翻译：用于从水溶液萃取中提取金属值，特别是铜值的醛脱氧肟萃取剂（如羟基芳基醛肟萃取剂）的替代性平衡改性剂，其中萃取剂和改性剂用于有机溶剂相溶剂是水不溶性的，与水不混溶的烃溶剂，例如煤油。

8. 发明申请

WO1996004981A1 METHOD FOR SEPARATING MATERIALS 审中-公开
标题翻译：分离材料的方法
公开(公告)号：WO1996004981A1
公开(公告)日：1996-02-22
申请号：PCT/US1995009679
申请日：1995-08-04
申请人： HENKEL CORPORATION
发明人： HENKEL CORPORATION , KOZAK, William, G. , CHOVATIA, Dharmesh , SMITH, George, A. , VIRNIG, Michael, J. , MATTISON, Phillip, L. , WEERTS, Keith, E.
IPC分类号： B01D61/20
CPC分类号： B01D61/02 , C02F1/26
摘要： A process for the separation of naphthalenesulfonate-based carbonyl condensates from water is provided. The process comprises contacting a mixture comprised of water and a naphthalenesulfonate-based carbonyl condensate (preferably a material selected from the group consisting of formaldehyde condensates of naphthalenesulfonic acids, formaldehyde condensates of lower-alkyl substituted naphthalenesulfonic acids, and mixtures of two or more of such materials) with a liquid organic phase comprised of a cationic lipophilic amine to form an aqueous phase depleted with respect to said mixture of naphthalenesulfonate-based carbonyl condensate and a liquid organic phase enriched in naphthalenesulfonate-based carbonyl condensate. The process further comprises separating said aqueous phase depleted with respect to said mixture of naphthalenesulfonate-based carbonyl condensate and said liquid organic phase enriched with respect to naphthalenesulfonate-based carbonyl condensate. The liquid organic phase can then be stripped with an alkaline stripping solution to regenerate the cationic lipophilic amine.
摘要翻译：提供了一种从水中分离萘磺酸盐基羰基缩合物的方法。该方法包括将由水和萘磺酸盐基羰基缩合物组成的混合物（优选选自萘磺酸的甲醛缩合物，低级烷基取代的萘磺酸的甲醛缩合物，以及两种或更多种材料）与由阳离子亲油胺组成的液体有机相形成相对于所述萘磺酸盐基羰基缩合物的混合物和富含萘磺酸盐的羰基缩合物的液体有机相贫化的水相。该方法还包括相对于所述萘磺酸盐基羰基缩合物的混合物和相对于萘磺酸盐羰基缩合物富集的所述液体有机相来分离所述水相。然后可以用碱性剥离溶液汽提液态有机相以再生阳离子亲脂胺。

9. 发明申请

WO1998028454A1 IMPROVEMENT IN THE PROCESS OF RECOVERY OF METALS 审中-公开
标题翻译：金属回收过程中的改进
公开(公告)号：WO1998028454A1
公开(公告)日：1998-07-02
申请号：PCT/US1997022988
申请日：1997-12-22
申请人： HENKEL CORPORATION
发明人： HENKEL CORPORATION , VIRNIG, Michael, J. , KORDOSKY, Gary, A. , WOLFE, George, A. , MACKENZIE, J., Murdoch
IPC分类号： C22B15/00
CPC分类号： C01G3/003 , C01G9/003 , C01G53/003 , C22B3/0017 , C22B15/0078 , C22B23/0446 , Y02P10/234 , Y02P10/236
摘要： An improved process for the extraction of a metal from an aqueous ammoniacal solution comprising: (i) contacting the aqueous ammoniacal solution with an extraction reagent comprised of a water insoluble extractant for the metal, to provide an organic phase, now containing metal values, and an aqueous phase from which metal values have been extracted; (ii) contacting the organic phase with an aqueous stripping solution to provide an aqueous strip phase, now containing metal values, and an organic phase from which metal values have been stripped; and (iii) recovering the metal values from the aqueous stripping solution; the improvement wherein (a) the extraction reagent contains an ammonia antagonist having only hydrogen bond acceptor properties; (b) the stripping solution is an aqueous highly acidic solution; and (c) the organic phase is washed with a weakly acidic aqueous solution prior to stripping with the highly acidic aqueous stripping solution. The extractant is preferably an oxime extractant, either a ketoxime or an aldoxime. The preferred hydrocarbon solvent is kerosene and the preferred antagonist is 2,2,4-trimethylpentane-1,3-diol diisobutyrate.
摘要翻译：一种用于从氨水溶液中萃取金属的改进方法，包括：（i）使氨水溶液与由金属的水不溶性萃取剂组成的萃取剂接触，以提供现在含有金属值的有机相，和提取金属价值的水相; （ii）使有机相与水性剥离溶液接触以提供现在含有金属值的水性带状相和金属值被剥离的有机相; 和（iii）从水性剥离溶液中回收金属值; 其中（a）提取试剂含有仅具有氢键受体性质的氨拮抗剂; （b）剥离溶液是高浓度水溶液; 和（c）有机相用弱酸性水溶液洗涤，然后用高度酸性的水性剥离溶液汽提。萃取剂优选为肟萃取剂，酮肟或醛肟。优选的烃溶剂是煤油，优选的拮抗剂是2,2,4-三甲基戊烷-1,3-二醇二异丁酸酯。

10. 发明申请

WO1997043023A1 PROCESS FOR THE RECOVERY OF NICKEL 审中-公开
标题翻译：回收镍的工艺
公开(公告)号：WO1997043023A1
公开(公告)日：1997-11-20
申请号：PCT/US1997005405
申请日：1997-05-02
申请人： HENKEL CORPORATION
发明人： HENKEL CORPORATION , VIRNIG, Michael, J. , MACKENZIE, J., Murdoch
IPC分类号： B01D11/00
CPC分类号： C01G53/003 , C22B3/0017 , C22B23/0461 , Y02P10/138 , Y02P10/234
摘要： A process for the recovery of nickel from a nickel containing ore in which the ore, particularly a laterite ore, is initially leached with an aqueous acid solution, after which the nickel is precipitated as nickel hydroxide by adding a hydroxide to the aqueous acid leach solution containing the nickel, followed by a re-leaching of the nickel with an aqueous ammoniacal solution and recovery of the nickel by a solvent extraction of the nickel from the aqueous ammoniacal solution with an organic phase of a water insoluble oxime extractant dissolved in a water-immiscible hydrocarbon solvent and the nickel recovered by electrowinning the nickel from the aqueous acid stripping solution employed to strip the nickel from the organic phase.
摘要翻译：一种从含镍矿石中回收镍的方法，其中矿石，特别是红土矿石最初用酸水溶液浸出，之后通过向酸浸液溶液中加入氢氧化物将镍沉淀为氢氧化镍含有镍，然后用氨水溶液再次浸出镍，通过溶解在水溶性肟提取剂的有机相中，从氨水溶液中溶剂萃取镍回收镍，通过从用于从有机相剥离镍的酸性汽提溶液中电解镍来回收镍。

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