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1. 发明申请

WO1997030687A2 FRAGRANCE PRECURSORS 审中-公开
公开(公告)号：WO1997030687A2
公开(公告)日：1997-08-28
申请号：PCT/EP1997000705
申请日：1997-02-14
申请人： GIVAUDAN-ROURE (INTERNATIONAL) S.A. , ANDERSON, Denise , FRATER, Georg , GYGAX, Peter
发明人： GIVAUDAN-ROURE (INTERNATIONAL) S.A.
IPC分类号： A61K07/46
CPC分类号： A61Q15/00 , A61K8/37 , A61K8/44 , C07C69/708 , C07C69/716 , C07C233/47 , C07F9/091 , C07F9/113 , C11D3/507
摘要： The invention relates to fragrance precursors. In particular, the invention relates to the use of several classes of compounds which can act as fragrance precursors, e.g. in consumer, e.g. cosmetic products, such as deodorants and antiperspirants. These compounds are normally odourless or nearly so, but upon contacting theskin as, for example, in skin care compositions or in personal care compositions, produce fragrances by liberating an odoriferous alcohol.
摘要翻译：本发明涉及香料前体。特别地，本发明涉及可用作香料前体的几类化合物的用途，例如，在消费者中，例如化妆品，如除臭剂和止汗剂。这些化合物通常是无臭或几乎这样的，但是例如在皮肤护理组合物或个人护理组合物中接触皮肤时，通过释放有气味的醇产生香料。

2. 发明申请

WO1992020690A1 ORGANOSILOXANES FOR USE AS SUNSCREEN AGENTS 审中-公开
标题翻译：用作SUNSCREEN药剂的有机硅氧烷
公开(公告)号：WO1992020690A1
公开(公告)日：1992-11-26
申请号：PCT/EP1992001001
申请日：1992-05-07
申请人： GIVAUDAN-ROURE (INTERNATIONAL) S.A. , FRATER, Georg , SCHWARZENBACH, Rolf , VAN OYCKE, Stephane, François, Marie
发明人： GIVAUDAN-ROURE (INTERNATIONAL) S.A.
IPC分类号： C07F07/08
CPC分类号： C08G77/38 , A61K8/585 , A61K8/895 , A61K2800/57 , A61Q17/04 , C07F7/0838 , C08G77/20
摘要： Novel organosiloxane compounds have at least one unit (i), any other units being present in this organosiloxane are (ii), wherein R is a C1-8 alkyl or aryl, R is H or a C1-5 alkyl, R is H, C1-5 alkyl or OR , R is a C1-5 alkyl, R" is H, a monovalent C1-8 hydrocarbon or halogenated hydrocarbon group, a is 0, 1 or 2, b 0, 1, 2 or 3 and n 1 to 6, provided the group (1) and the two R groups are linked to the aromatic ring at the para- and meta-positions in relation to the group -CH=C[C(O)OR ]2. The compounds are useful as UV sunscreens. Compositions containing them are also included.
摘要翻译：新的有机硅氧烷化合物具有至少一个单元（i），存在于该有机硅氧烷中的任何其它单元是（ⅱ），其中R是C 1-8烷基或芳基，R 1是H或C 1-5烷基，R 2是H，C 1-5烷基或OR 1，R 3是C 1-5烷基，R“是H，一价C 1-8烃或卤代烃基，a是0,1或2 ，b 0，1,2或3和n 1至6，条件是基团（1）和两个R 2基团相对于基团-CH的对位和间位连接到芳环上 = C [C（O）OR 3] 2。这些化合物可用作紫外线防晒剂，也包括含有它们的组合物。

3. 发明申请

WO1994005621A1 PROCESS FOR THE MANUFACTURE OF CINNAMIC ACID DERIVATIVES 审中-公开
标题翻译：生成酸性衍生物的方法
公开(公告)号：WO1994005621A1
公开(公告)日：1994-03-17
申请号：PCT/EP1993002317
申请日：1993-08-27
申请人： GIVAUDAN-ROURE (INTERNATIONAL) S.A. , GYGAX, Peter
发明人： GIVAUDAN-ROURE (INTERNATIONAL) S.A.
IPC分类号： C07C67/343
CPC分类号： C07C51/367 , C07C51/347 , C07C67/347 , C07C59/64 , C07C69/734
摘要： A novel process for the manufacture of a cinnamic acid derivative of formula (I) wherein R signifies hydrogen or C1-8-alkyl and R signifies hydrogen, C1-10-alkyl, C1-10-hydroxyalkyl or C1-4-hydroxyalkyl or C1-4-alkoxy-C1-10-alkyl, is described in which a 4-R O-halobenzene is reacted with acrylic acid or an acrylic acid ester CH2=CHCOOR using a heterogeneous palladium catalyst in the presence of the alkanoic acid ammonium salt formed from a C2-5-alkanoic acid and an aliphatic mono-, di- or trialkylamine or heterocyclic amine. In the case of the manufacture of the cinnamic acid derivative (I) in which R signifies hydrogen, the reaction can be carried out in the presence of the amine in place of the alkanoic acid ammonium salt. A further aspect of the described invention comprises reacting the 4-R 0-iodobenzene with the product of the Michael addition of an acrylic acid ester CH2=CHCOOR , wherein R has the above significance of R except hydrogen, with an aliphatic or heterocyclic primary or secondary amine using a heterogeneous palladium catalyst and in the presence of a C2-5-alkanoic acid in order to manufacture the above cinnamic acid derivatives with the exception of the substituted cinnamic acid itself. In view of their UV-B absorbing properties the thus-manufactured cinnamic acid derivatives are suitable as UV-B filters for cosmetic agents, e.g. sunscreen agents.
摘要翻译：一种制备式（I）的肉桂酸衍生物的新方法，其中R 1表示氢或C 1-8烷基，R 2表示氢，C 1-10 - 烷基，C 1-10 - 羟基烷基或C 1 - -4-羟基烷基或C 1-4 - 烷氧基-C 1-10 - 烷基，其中使用异构体将4-R 1 O-卤代苯与丙烯酸或丙烯酸酯CH 2 = CHCOOR 2反应在由C2-5链烷酸和脂族单 - ，二 - 或三烷基胺或杂环胺形成的链烷酸铵盐存在下，制备钯催化剂。在制备其中R 2表示氢的肉桂酸衍生物（I）的情况下，反应可以在胺的存在下代替链烷酸铵盐进行。所述发明的另一方面包括使4-R 1 O-碘苯与迈克尔加成丙烯酸酯CH 2 = CHCOOR 2的产物反应，其中R 2'具有上述意义 R 2除了氢以外，与使用异相钯催化剂的脂族或杂环伯或仲胺在C2-5链烷酸的存在下制备上述肉桂酸衍生物，除了取代的肉桂酸本身。鉴于它们的UV-B吸收性质，如此制得的肉桂酸衍生物适用于化妆品的UV-B过滤剂，例如，防晒剂。

4. 发明申请

WO1997016512A1 NITRILE 审中-公开
标题翻译：丁腈
公开(公告)号：WO1997016512A1
公开(公告)日：1997-05-09
申请号：PCT/CH1996000377
申请日：1996-10-24
申请人： GIVAUDAN-ROURE (INTERNATIONAL) S.A. , PESARO, Mario
发明人： GIVAUDAN-ROURE (INTERNATIONAL) S.A.
IPC分类号： C11B09/00
CPC分类号： C11B9/0065
摘要： The invention relates to the use of cyclohexylidene phenyl acetonitrile as an odoriferous substance.
摘要翻译：本发明涉及使用亚环己基苯基乙腈作为香料。

5. 发明申请

WO1994007461A1 PERFUME COMPOSITIONS 审中-公开
标题翻译： PERFUME组合物
公开(公告)号：WO1994007461A1
公开(公告)日：1994-04-14
申请号：PCT/EP1993002555
申请日：1993-09-21
申请人： GIVAUDAN-ROURE (INTERNATIONAL) S.A. , O'ROURKE, Brian , SHORT, John, Norman
发明人： GIVAUDAN-ROURE (INTERNATIONAL) S.A.
IPC分类号： A61K07/46
CPC分类号： A61Q13/00 , A61K8/345 , A61K8/4993 , A61K8/585 , A61K8/922
摘要： The invention concerns non-sticky, non-ethanolic fragrance formulations containing conventional odoriferous material at a level of ca. 2 %, preferably ca. 5 % to ca. 30 % which is solubilised by a combination of (a) a solubiliser and (b) a cosolubiliser in water.
摘要翻译：本发明涉及含有常规气味材料的非粘性非乙醇香精配方， 2％，优选约 5％到约 30％，其通过（a）增溶剂和（b）共增溶剂在水中的组合溶解。

6. 发明申请

WO1992017461A1 LIGHT SCREENING AGENT 审中-公开
标题翻译：轻型筛选剂
公开(公告)号：WO1992017461A1
公开(公告)日：1992-10-15
申请号：PCT/EP1992000635
申请日：1992-03-23
申请人： GIVAUDAN-ROURE (INTERNATIONAL) S.A. , HUBER, Ulrich
发明人： GIVAUDAN-ROURE (INTERNATIONAL) S.A.
IPC分类号： C07D261/12
CPC分类号： C08G65/33396 , C07D261/12 , C07D413/04 , C07D413/10 , C07D413/12
摘要： Light screening compositions which contain a compound of formula (I), wherein R represents H, C1-19-alkyl, C2-29-alkenyl, C2-29-alkynyl, optionally lower-alkyl or oxy-lower alkyl substituted phenyl, R represents H, C1-29-alkyl, C2-29-alkenyl, C2-29-alkynyl, optionally lower-alkyl or oxy-lower alkyl substituted phenyl, R represents H, C1-19-alkyl, C1-19-hydroxyalkyl, C1-19-polyhydroxyalkyl, C2-29-alkenyl, C2-29-alkynyl, optionally lower-alkyl or oxy-lower alkyl substituted phenyl or optionally lower-alkyl or oxy-lower alkyl substituted pyridyl, a polyether residue, a phenylsulphonic acid residue and R and R together with the N atom can also form a ring.
摘要翻译：含有式（I）化合物的轻筛选组合物，其中R 1表示H，C 1-19 - 烷基，C 2-9-29 - 烯基，C 2-9-29 - 炔基，任选的低级烷基或氧 - 低级烷基取代的苯基 R 2表示H，C 1-29烷基，C 2-9-29烯基，C 2-9-29炔基，任选的低级烷基或羟基 - 低级烷基取代的苯基，R 3表示H，C 1-19 - 烷基 C 1-19 - 羟基烷基，C 1-19 - 多羟基烷基，C 2-9-29烯基，C 2-9-29 - 炔基，任选的低级烷基或羟基 - 低级烷基取代的苯基或任选的低级烷基或羟基 - 低级烷基取代的吡啶基，聚醚残基，苯基磺酸残基和R 2和R 3与N原子一起也可以形成环。

7. 发明申请

WO1995012379A1 PERFUME FORMULATIONS 审中-公开
标题翻译： PERFUME配方
公开(公告)号：WO1995012379A1
公开(公告)日：1995-05-11
申请号：PCT/EP1994003541
申请日：1994-10-27
申请人： GIVAUDAN-ROURE (INTERNATIONAL) S.A. , McGEE, Thomas , SUBRAMANIAN, Saroja , YEAGER, Caryl, E.
发明人： GIVAUDAN-ROURE (INTERNATIONAL) S.A.
IPC分类号： A61K07/00
CPC分类号： A61K8/068 , A61Q13/00
摘要： Oil-in-water (O/W) and water-in-oil (W/O) microemulsions of fragrance product formulations are provided. The microemulsions are clear or at least translucent, sprayable, and nonsticky. Novel combinations of anionic surfactant components (a) and hydrophilic coactives (highly water soluble component (b) or a mixture of highly water soluble (b)(i) and less water soluble polar (b)(ii) components) are used to obtain fragrance product formulations that are free or substantially free of ethanol. The anionic surfactants have a hydrophilic-lipophilic balance ("HLB") modified by the use of classes of anionic surfactant components (a) and commercially available hydrophilic component coactives ((b) or mixture of (b)(i) and (b)(ii)), not previously recognized as effective in this type of system. Highly, preferably infinitely, water soluble coactives (b) as well as mixtures of highly, preferably infinitely, water soluble coactives (b)(i) with other less water soluble polar coactives (b)(ii), modify the HLB of anionic surfactants in such a way as to enable the formation of stable, clear microemulsions of fragrance product compositions. These compositions contain lower ratios of surfactant to oil than conventional nonionic (or ionic surfactants with lipophilic coactives) aqueous or alcohol free compositions. As such, the present fragrance compositions are sprayable and nonsticky.
摘要翻译：提供香水产品配方的水包油（O / W）和油包水（W / O）微乳液。微乳液是透明的或至少是半透明的，可喷涂的和不粘的。使用阴离子表面活性剂组分（a）和亲水共活化剂（高度水溶性组分（b）或高度水溶性（b）（i）和较少水溶性极性（b）（ii）组分的混合物）的新型组合以获得不含或基本上不含乙醇的香料产品配方。阴离子表面活性剂具有通过使用各种阴离子表面活性剂组分（a）和市售亲水组分共活化剂（（b）或（b）（i）和（b））的混合物改性的亲水亲油平衡（“HLB” （ii）），以前未被认定为在此类型的系统中有效。高度优选无限水溶性共活化剂（b）以及高度优选无限水溶性共活化剂（b）（i）与其他较少水溶性极性共活化剂（b）（ii））的混合物改性阴离子表面活性剂的HLB 以使得能够形成稳定，透明的香料产物组合物的微乳液。这些组合物比常规非离子（或具有亲脂性共活化剂的离子表面活性剂）含水或无醇组合物含有较低的表面活性剂与油的比例。因此，本发明的香料组合物是可喷涂和不粘的。

8. 发明申请

WO1997016078A1 AROMATIC GRANULATED MATERIAL 审中-公开
标题翻译：香精GRANULAT
公开(公告)号：WO1997016078A1
公开(公告)日：1997-05-09
申请号：PCT/CH1996000373
申请日：1996-10-23
申请人： GIVAUDAN-ROURE (INTERNATIONAL) S.A. , MENZI, Heini , PERREN, Matthias , RINGGENBERG, Rudolf
发明人： GIVAUDAN-ROURE (INTERNATIONAL) S.A.
IPC分类号： A23L01/22
CPC分类号： A61Q13/00 , A23F3/405 , A23L2/39 , A23L2/56 , A23L7/196 , A23L27/72 , A23L33/15 , A23P10/22 , A23P10/30 , A23P10/35 , A61K8/025 , A61Q11/00
摘要： The present invention relates to a process for the preparation of spherical, or substantially spherical, practically dust-free aromatic and odoriferous granulated material which is free-flowing, mechanically stable and has a narrow grain-size distribution.
摘要翻译：本发明涉及一种用于制造球形或基本上球形的，基本上无粉尘，自由流动的，机械稳定的食用香料和有味物质的颗粒具有窄的粒度分布。

9. 发明申请

WO1996020185A2 TETRAHYDROFURANS AND TETRAHYDROPYRANS 审中-公开
标题翻译：四氢呋喃和四氢呋喃
公开(公告)号：WO1996020185A2
公开(公告)日：1996-07-04
申请号：PCT/EP1995005002
申请日：1995-12-18
申请人： GIVAUDAN-ROURE (INTERNATIONAL) S.A.
发明人： GIVAUDAN-ROURE (INTERNATIONAL) S.A. , NOIRE, Paul, David
IPC分类号： C07D309/04
CPC分类号： C11B9/0076 , C07D307/06 , C11B9/008
摘要： Novel odorants or odorant compositions which are characterized by a content of one or more compounds selected from the group consisting of tetrahydrofurans of structures (I) or tetrahydropyrans of structure (I"), wherein R can be an aliphatic chain, namely a chain of at least four carbon atoms substituted with at least three methyl groups in the chain, a monocarbocyclic residue, where monocarbocyclic refers to one ring of 5-8 carbon atoms, and with at least two methyl groups, e.g. on the ring, or the residue of a bicyclic ring system, where bicyclic refers to two carbon rings, having between 5-8 carbon atoms, fused together, the bicyclic system substituted with at least two methyl groups, or R + R can also form a spirocyclic moiety in case of the tetrahydrofurans, and wherein R = H or CH3, or a higher alkyl group, R = H, CH3, or a higher alkyl group, R = H, or CH3, R and R = H, CH3, or a higher alkyl group, and wherein R = R NOTEQUAL H.
摘要翻译：特征在于一种或多种选自结构（I）的结构（I）的四氢呋喃或结构（I“）的四氢吡喃的化合物的含量的新颖的气味剂或气味组合物，其中R可以是脂族链，即，在链中被至少三个甲基取代的至少四个碳原子，单碳环残基，其中单环是指5-8个碳原子的一个环，以及至少两个甲基，例如在环上，或双环系统，其中双环是指具有5-8个碳原子的两个碳环，稠合在一起，被至少两个甲基取代的双环系统或R + R 3也可以形成螺环部分，以便在四氢呋喃，其中R 1 = H或CH 3，或高级烷基，R 2 = H，CH 3或高级烷基，R 3 = H或CH 3，R 4和 R 5 = H，CH 3或高级烷基，并且其中R 1 = R 2。

10. 发明申请

WO1994007887A1 OPTICALLY ACTIVE LACTONES 审中-公开
标题翻译：光学活性乳杆菌
公开(公告)号：WO1994007887A1
公开(公告)日：1994-04-14
申请号：PCT/EP1993002554
申请日：1993-09-21
申请人： GIVAUDAN-ROURE (INTERNATIONAL) S.A. , BOURDINEAUD, Jean-Paul , EHRET, Charles , PETRZILKA, Martin
发明人： GIVAUDAN-ROURE (INTERNATIONAL) S.A.
IPC分类号： C07D309/30
CPC分类号： C07D315/00 , A23L27/24 , C07D309/30 , C07D309/32 , C11B9/008 , C12P17/06 , C12P41/003 , C12Y301/01003
摘要： The present invention relates primarily to the field of optically active lactones of formula (I) as defined below. The invention relates also to the utilisation of compounds of formula (I) so obtained as perfuming or flavoring ingredients. The process for producing the individual optically active lactones of formula (I), wherein the asterisk indicates a chirality center, n stands for zero or 1, R represents a C5- or C6-alkyl radical, which optionally may contain an additional double bond of either Z- or E-configuration, such additional bond being compulsory in case of n = 0, comprises the stereoselective enzymatic hydrolysis of the ester bond of the corresponding racemates in the presence of an esterase, recovering the enzyme-spared isomer, and, if desired, subjecting the hydrolysed isomer to lactonisation, provided the enzymatic hydrolysis is carried out in the presence of potassium ions in case of n = 1.
摘要翻译：本发明主要涉及如下定义的式（I）的光学活性内酯的领域。本发明还涉及如此获得的式（I）化合物作为加香或调味成分的用途。制备式（I）的各种光学活性内酯的方法，其中星号表示手性中心，n表示0或1，R表示C5-或C6-烷基，其任选地可以含有另外的双键 Z-或E-构型，在n = 0的情况下这样的附加键是强制性的，包括在酯酶存在下相应的外消旋体的酯键的立体选择性酶水解，回收酶保留的异构体，如果所需的，使水解的异构体进行内酯化，条件是在n = 1的情况下，在钾离子存在下进行酶促水解。

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