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    • 1. 发明申请
    • GROWTH OF A-B CRYSTALS WITH NO CURVATURE OF THE CRYSTAL LATTICE
    • AB选育晶体不含结晶格曲线
    • WO2016150850A3
    • 2017-01-26
    • PCT/EP2016055956
    • 2016-03-18
    • FREIBERGER COMPOUND MAT GMBH
    • WEINERT BERNDTHABEL FRANKLEIBIGER GUNNAR
    • C30B25/02C30B29/40
    • C30B29/40C30B25/02
    • The invention relates to a method for producing III-V-, IV- IV- or II-VI- compound semiconductor crystals. The method starts with the provision of a substrate having optionally one crystal layer (buffer layer). This is followed by the provision of a gas phase which has at least two reactants of elements for the compound semiconductor (II, III, IV, V, VI), the reactants being gaseous at a reaction temperature in the crystal growth reactor and being capable of reacting together under the selected reactor conditions. The ratio of the concentrations of two of the reactants is adjusted such that the compound semiconductor crystal can crystallize from the gas phase, a concentration being chosen that is sufficiently high to facilitate crystal formation and the activity of the III-, IV- or II-compound being reduced in the gas phase by the addition or adjustment of reducing agent and co-reactant, such that the growth rate of the crystal is lower compared to a state without the co-reactant. The compound semiconductor crystal is deposited on a surface of the substrate, whilst a liquid phase can form on the growing crystal. In addition, auxiliary substances can be added which can also be contained in the liquid phase but which are only incorporated in negligible amounts into the compound semiconductor crystal. This allows 3D and 2D growth modes to be controlled selectively. The addition of auxiliary substances and the presence of a liquid phase promote these measures. The product is a single crystal of a III-V-, IV-IV- or II-VI-compound semiconductor crystal, which contains lower concentrations of inclusions or precipitates compared to conventional compound semiconductor crystals and which nevertheless has no or only a negligible curvature.
    • 本发明涉及一种用于III-V,IV-IV族或II-VI族化合物半导体晶体的制备方法。 该方法开始于提供具有可选的结晶层(缓冲层)的基板。 随后,在具有至少两个在所述化合物半导体的元件的所选择的反应器条件的反应物的气态和相互反应的晶体生长反应器的反应温度,提供了一种气相(II,III,IV,V,VI)。 两种反应物的浓度比进行调整,使得所述化合物半导体晶体能够从气相中,其中的浓度是如此之高,晶体的形成是可能的,由还原剂和共反应物的添加或调整结晶出来是的活性 III,IV或II化合物降低在气相中,该晶体的与在没有共反应剂是低的状态相比的生长速率。 在此,化合物半导体晶体沉积在基底的表面上,同时可以在生长的晶体中形成液相。 进一步的辅助物质可以被添加,其也可以包含在液相中,但只被安装在化合物半导体晶体中的少量。 这里,3D和2D生长模式可以具体控制。 辅助物质的加入和液相利于这些措施的存在。 该产品是由具有每个III-V,IV-IV族或II-VI族化合物半导体晶体的单晶一个与每个常规化合物半导体晶体的夹杂物或析出物的浓度较低,但没有或只有非常低的比较 弯曲了。