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1. 发明申请

WO2010120794A1 BICYCLIC ORGANOSILICON COMPOUNDS AS ELECTRON DONORS FOR POLYOLEFIN CATALYSTS 审中-公开
标题翻译：双金属有机硅化合物作为聚烯烃催化剂的电子助剂
公开(公告)号：WO2010120794A1
公开(公告)日：2010-10-21
申请号：PCT/US2010/030910
申请日：2010-04-13
申请人： FORMOSA PLASTICS CORPORATION, U.S.A. , FANG, Yiqun , LU, Honglan
发明人： FANG, Yiqun , LU, Honglan
IPC分类号： B01J37/00
CPC分类号： C08F10/00 , C07F7/025 , C07F7/045 , C08F110/06 , C08F4/6495 , C08F4/6465 , C08F2500/04 , C08F2500/12
摘要： Cyclic organo silicon compounds that may be employed as an electron donor for polymerization catalyst systems, polymerization catalyst systems employing the cyclic organosilicon compounds as an electron donor, methods of making the polymerization catalyst systems, and polymerization processes to produce polyolefin are disclosed. The organosilicon compounds, which are useful as electron donors in polymerization catalyst systems for the production of polyolefins, are represented by the formula (I): where Q 1 , Q 2 , Q 3 , and Q 4 may be identical or different and are each hetero-atoms selected from the group consisting of N, O, S, Si, B, and P. R 1 , R 2 , R 3 , and R 4 may be identical or different and are each hydrocarbon-based substituents to Q 1 , Q 2 , Q 3 , and Q 4 , respectively. The subscripts i, j, m, and n are independently 0 to 3. R 5 and R 6 may be identical or different and are each a bridging group with a backbone chain length between the two hetero-atoms Q 1 and Q 3 , and Q 2 and Q 4 , respectively, being 1-8 atoms. The bridging group is selected from the group consisting of aliphatic, alicyclic, and aromatic bivalent radicals.
摘要翻译：公开了可用作聚合催化剂体系的电子供体的循环有机硅化合物，使用环状有机硅化合物作为电子给体的聚合催化剂体系，制备聚合催化剂体系的方法和聚合方法以制备聚烯烃。在聚烯烃生产的聚合催化剂体系中可用作电子供体的有机硅化合物由式（I）表示：其中Q1，Q2，Q3和Q4可以相同或不同，并且各自是杂原子选择的由N，O，S，Si，B和P组成的组中，R1，R2，R3和R4可以相同或不同，分别为Q1，Q2，Q3和Q4的烃基取代基。下标i，j，m和n独立地为0至3.R 5和R 6可以相同或不同，并且各自为两个杂原子Q1和Q3之间的主链长度的桥连基团，以及Q2和Q4，分别为1-8个原子。桥连基团选自脂族，脂环族和芳族二价基团。

2. 发明申请

WO2010120331A1 CYCLIC ORGANOSILICON COMPOUNDS AS ELECTRON DONORS FOR POLYOLEFIN CATALYSTS 审中-公开
标题翻译：循环有机硅化合物作为聚烯烃催化剂的电子助剂
公开(公告)号：WO2010120331A1
公开(公告)日：2010-10-21
申请号：PCT/US2009/067371
申请日：2009-12-09
申请人： FORMOSA PLASTICS CORPORATION, U.S.A. , FANG, Yiqun , LU, Honglan
发明人： FANG, Yiqun , LU, Honglan
IPC分类号： B01J31/14 , C07F7/10 , C08F4/18
CPC分类号： B01J31/143 , B01J31/1608 , B01J31/1616 , B01J2231/122 , B01J2531/46 , C08F10/00 , C08F110/06 , C08F4/6495 , C08F4/6465 , C08F2500/12 , C08F2500/11
摘要： Cyclic organosilicon compounds that may be employed as an electron donor for polymerization catalyst systems, polymerization catalyst systems employing the cyclic organosilicon compounds as an electron donor, methods of making the polymerization catalyst systems, and polymerization processes to produce polyolefin are disclosed. The organosilicon compounds, which are useful as electron donors in polymerization catalyst systems for the production of polyolefins, are represented by the following formula I (I) wherein Q1 and Q2 may be identical or different and are each hetero-atoms selected from the group consisting of N, O, S, Si, B, and P, with the proviso that Q1 and Q2 cannot both be N or both be O. R1 and R2 may be identical or different and are each hydrocarbon-based substituents to Q1 and Q2, respectively. The subscripts m and n are independently O to 3. R3 is an aliphatic, alicyclic or aromatic group. R4 is a hydrocarbon group with 1 to 6 carbon atoms. R5 is a bridging group with a backbone chain length between the two hetero-atoms Q1 and Q2 being 1-8 atoms. The bridging group is selected from the group consisting of aliphatic, alicyetic, and aromatic bivalent radicals.
摘要翻译：公开了可用作聚合催化剂体系的电子给体的循环有机硅化合物，使用环状有机硅化合物作为电子给体的聚合催化剂体系，制备聚合催化剂体系的方法和聚合方法以制备聚烯烃。可用作聚烯烃生产聚合催化剂体系中的电子给体的有机硅化合物由下式I（I）表示，其中Q 1和Q 2可以相同或不同，并且各自是选自以下的杂原子：的N，O，S，Si，B和P，条件是Q1和Q2不能都是N或两者均为O.R 1和R 2可以相同或不同，并且各自为Q1和Q2的基于烃的取代基，分别。下标m和n独立地为O至3.R 3是脂族，脂环族或芳族基团。 R4是具有1至6个碳原子的烃基。 R5是两个杂原子Q1和Q2之间的主链长度为1-8个原子的桥连基团。桥连基团选自脂族，糖基和芳族二价基团。

3. 发明申请

WO2008027479A3 HIGHLY ACTIVE ALPHA-OLEFIN COPOLYMERIZATION CATALYST SYSTEM 审中-公开
公开(公告)号：WO2008027479A3
公开(公告)日：2008-03-06
申请号：PCT/US2007/019079
申请日：2007-08-30
申请人： FORMOSA PLASTICS CORPORATION, U.S.A. , XU, Guangxue , LU, Honglan , CHEN, Chih-Jian
发明人： XU, Guangxue , LU, Honglan , CHEN, Chih-Jian
IPC分类号： B01J31/00
摘要： A high activity magnesium-based supported catalyst component useful in a catalyst system for the compolymerization of ethylene and alpha-olefin and a process for preparing the catalyst component is described. In the process, alkoxysilane ester is contacted with a halogen-substituted silane to form an organic silicon complex. Optionally, the organic silicon complex is contacted with an aminosilane compound to form an organic silicon complex containing nitrogen. The organic silicon complex containing nitrogen or the organic silicon complex is contacted with a transition metal compound to form an organic silicon complex containing transition metal. The organic silicon complex containing transition metal is then contacted with a substituted aromatic ring nitrogen compound to form a fourth reaction complex, which is then contacted with a magnesium-based composite support that has been prepared in situ by reacting metallic magnesium with an alkyl or aromatic halide to form the catalyst component.

4. 发明申请

WO2008070126A1 A CATALYST SYSTEM FOR PRODUCING ETHYLENE (CO) POLYMER WITH IMPROVED BRANCH DISTRIBUTION 审中-公开
标题翻译：用于生产具有改进分支分布的乙烯（CO）聚合物的催化剂体系
公开(公告)号：WO2008070126A1
公开(公告)日：2008-06-12
申请号：PCT/US2007/024925
申请日：2007-12-05
申请人： FORMOSA PLASTICS CORPORATION, U.S.A. , KONG, Gapgoung , LIU, Zhongyang , LU, Honglan
发明人： KONG, Gapgoung , LIU, Zhongyang , LU, Honglan
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6567 , C08F210/14 , C08F2500/08 , C08F2500/12 , C08F2500/20
摘要： A process for synthesizing a catalyst component for manufacturing ethylene polymer and co-polymer. The present invention provides a process for synthesizing catalyst component (A), comprising forming a complex by contacting the solid intermediate (B) with an aluminum compound represented by formula X 3-n Al(OY) n , and alkyl metal (C), wherein X is halide, Y is a hydrocarbon group or chelating carbonyl group, and wherein 1 is less than or equal to n which is less than or equal to 3, and then contacting the complex with titanium halide having formula ΗX4 wherein X is halide. Solid intermediate (B) is formed by reacting magnesium metal with alkyl halide in the presence of alkoxy aluminum represented by formula Al(OR a ) 3 , silicon halide represented by formula SiX 4 and alkoxy silane represented by formula Si(OR b ) 4 , wherein R a and R b are an aromatic or aliphatic alkyl group and wherein X is halide. Alkyl metal (C) is synthesized by reacting alkyl aluminum compounds represented by formula A1R C 3 with a secondary amine having formula HNRd2 and then by reacting with alkyl magnesium compounds represented by formula R6MgR^ wherein R c , R d , Re and R f are an aromatic or aliphatic alkyl group. The catalyst component is suitable for producing ethylene polymer and co-polymer with narrow molecular weight distribution as well as improved branching compositional distribution.
摘要翻译：一种合成乙烯聚合物和共聚物制备催化剂组分的方法。本发明提供了一种合成催化剂组分（A）的方法，包括通过使固体中间体（B）与由式X 3-n Al（OY）表示的铝化合物接触而形成络合物 >烷基金属（C），其中X是卤化物，Y是烃基或螯合羰基，其中1小于或等于n小于或等于3，然后使络合物与式ⅩⅣ的卤化钛接触，其中X是卤化物。固体中间体（B）是通过使镁金属与烷基卤化物在由式Al（OR 3）3表示的烷氧基铝的存在下反应形成的，由式SiX 和由式Si（OR b）4 Si表示的烷氧基硅烷，其中R a， b为芳族或脂族烷基，其中X为卤化物。烷基金属（C）是通过使由式A1R 3

5. 发明申请

WO2007117283A3 PROCESS FOR MAKING EXFOLIATED POLYOLEFIN/CLAY NANOCOMPOSITES 审中-公开
公开(公告)号：WO2007117283A3
公开(公告)日：2007-10-18
申请号：PCT/US2006/045094
申请日：2006-11-21
申请人： FORMOSA PLASTICS CORPORATION, U.S.A. , INSTITUTE OF CHEMISTRY, CHINESE ACADEMY OF SCIENCES , LU, Honglan , LIU, Zhongyang , CHEN, Chih-Jian , HU, Youliang , LU, Yingying , KE, Yucai , GUO, Cunyue
发明人： LU, Honglan , LIU, Zhongyang , CHEN, Chih-Jian , HU, Youliang , LU, Yingying , KE, Yucai , GUO, Cunyue
IPC分类号： C08K3/34 , C08K9/04
摘要： Processes are disclosed relating to modifying clays with an olefinic functionalized surfactant containing a chain end polymerizable double bond, and to treating the thus modified organoclay with an olefin polymerization catalyst precursor, and polymerizing an olefin in the presence of the thus treated organoclay and an organoaluminum cocatalyst.

6. 发明申请

WO2005061109A1 A CATALYST SYSTEM FOR ETHYLENE (CO)-POLYMERIZATION 审中-公开
标题翻译：用于乙烯（CO） - 聚合的催化剂体系
公开(公告)号：WO2005061109A1
公开(公告)日：2005-07-07
申请号：PCT/US2004/038415
申请日：2004-11-16
申请人： FORMOSA PLASTICS CORPORATION, U.S.A. , KONG, Gapgoung , LU, Honglan
发明人： KONG, Gapgoung , LU, Honglan
IPC分类号： B01J31/00
CPC分类号： B01J31/128 , B01J31/122 , B01J31/143 , B01J31/2295 , B01J2531/46 , B01J2531/48 , B01J2531/56 , C08F10/02 , C08F110/02 , C08F210/16 , Y02P20/52 , C08F4/6557 , C08F4/651 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F210/14
摘要： A catalyst system for (co)-polymerizing ethylene or ethylene with α-olefin is disclosed. The catalyst system utilizes a catalyst component that contains the product of a reaction of an early transition metal complex such as a titanium alkoxide with a cyclic diene-containing compound such as indene. The catalyst system also utilizes a solid magnesium halide support and an alkylaluminum co-catalyst. The catalyst system of present invention produces polyethylene with a narrow molecular weight distribution and a narrow compositional distribution.
摘要翻译：公开了一种用于（共）聚合乙烯或乙烯与α-烯烃的催化剂体系。催化剂体系使用含有早期过渡金属络合物如烷氧化钛与含环状含二烯烃的化合物如茚的反应产物的催化剂组分。催化剂体系还使用固体卤化镁载体和烷基铝助催化剂。本发明的催化剂体系生产分子量分布窄，组成分布窄的聚乙烯。

7. 发明申请

WO2004072121A2 A CATALYST SYSTEM FOR ETHYLENE (CO)POLYMERIZATION 审中-公开
标题翻译：乙烯（CO）聚合催化剂体系
公开(公告)号：WO2004072121A2
公开(公告)日：2004-08-26
申请号：PCT/US2004/002897
申请日：2004-02-02
申请人： FORMOSA PLASTICS CORPORATION, U.S.A.
发明人： KONG, Gapgoung , LIU, Zhongyang , LU, Honglan
IPC分类号： C08F
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/6555 , C08F4/651 , C08F2500/12 , C08F210/14
摘要： Disclosed is a new titanium based catalyst system for (co)-polymerizing ethylene or ethylene with alpha-olefin having 3 to 10 carbons. The catalyst is obtained by contacting a magnesium halide support with an aluminum compound and with a titanium halide compound and then treating the resulting solid with a magnesium-amide complex. The catalyst system is suitable for producing ethylene polymer and co-polymer with narrow molecular weight distribution as well as improved branching compositional distribution.
摘要翻译：公开了一种用于（共）聚合乙烯或乙烯与具有3至10个碳的α-烯烃的新的钛基催化剂体系。催化剂通过使卤化镁载体与铝化合物和卤化钛化合物接触，然后用镁 - 酰胺络合物处理所得固体而获得。催化剂体系适用于生产具有窄分子量分布的乙烯聚合物和共聚物以及改进的支链组成分布。

8. 发明申请

WO2021247996A1 LONG-CHAIN BRANCHED ETHYLENE COPOLYMER WITH NOVEL COMPOSITION DISTRIBUTION AND FILMS FORMED FROM THE SAME 审中-公开
公开(公告)号：WO2021247996A1
公开(公告)日：2021-12-09
申请号：PCT/US2021/035900
申请日：2021-06-04
申请人： FORMOSA PLASTICS CORPORATION, U.S.A.
发明人： LI, Peng , LEE, Ming-Yung , LI, Tieqi , LU, Honglan
IPC分类号： C08J9/00 , C08J9/14 , C08L23/12 , C08F210/16 , C08J2323/08 , C08J5/18
摘要： What is disclosed is a Ziegler-Natta catalyzed ethylene and alpha-olefin LLDPE copolymer having a unique composition distribution and long chain-branching. The polymers of the present invention inherently exhibit outstanding melt strength with great bubble stability, sufficient flexibility, excellent gel performance, as well as desirable mechanical properties such as balanced toughness and stiffness, which are desirable properties for thick gauge film applications. Specifically, the polymers of the present invention.

9. 发明申请

WO2004072122A2 THE PREPARATION OF A MAGNESIUM HALIDE SUPPORT FOR OLEFIN POLYMERIZATION AND A CATALYST COMPOSITION USING THE SAME 审中-公开
标题翻译：用于烯烃聚合的镁盐支持物的制备和使用其的催化剂组合物
公开(公告)号：WO2004072122A2
公开(公告)日：2004-08-26
申请号：PCT/US2004/002898
申请日：2004-02-02
申请人： FORMOSA PLASTICS CORPORATION, U.S.A.
发明人： LU, Honglan , KONG, Gapgoung , LIU, Zhongyang , CHEN, Chih-Jian
IPC分类号： C08F
CPC分类号： C08F10/00 , B01J27/138 , C08F10/02 , C08F210/16 , C08F4/6548 , C08F4/6557 , C08F4/6543 , C08F4/6546 , C08F4/651 , C08F4/6555 , C08F210/14 , C08F2500/12
摘要： A magnesium halide support material for a polyolefin catalyst is disclosed. The magnesium halide of present invention is prepared by reacting magnesium with an alkylhalide in a non-polar hydrocarbon solvent. Preparation of the support does not require the use electron donating solvents and therefore does not require extensive washing to remove the solvent from the support.
摘要翻译：公开了一种用于聚烯烃催化剂的卤化镁载体材料。本发明的卤化镁是通过使镁与烷基卤在非极性烃溶剂中反应来制备的。载体的制备不需要使用电子给体溶剂，因此不需要大量洗涤以从载体中除去溶剂。

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