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1. 发明申请

WO2004072121A2 A CATALYST SYSTEM FOR ETHYLENE (CO)POLYMERIZATION 审中-公开
标题翻译：乙烯（CO）聚合催化剂体系
公开(公告)号：WO2004072121A2
公开(公告)日：2004-08-26
申请号：PCT/US2004/002897
申请日：2004-02-02
申请人： FORMOSA PLASTICS CORPORATION, U.S.A.
发明人： KONG, Gapgoung , LIU, Zhongyang , LU, Honglan
IPC分类号： C08F
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/6555 , C08F4/651 , C08F2500/12 , C08F210/14
摘要： Disclosed is a new titanium based catalyst system for (co)-polymerizing ethylene or ethylene with alpha-olefin having 3 to 10 carbons. The catalyst is obtained by contacting a magnesium halide support with an aluminum compound and with a titanium halide compound and then treating the resulting solid with a magnesium-amide complex. The catalyst system is suitable for producing ethylene polymer and co-polymer with narrow molecular weight distribution as well as improved branching compositional distribution.
摘要翻译：公开了一种用于（共）聚合乙烯或乙烯与具有3至10个碳的α-烯烃的新的钛基催化剂体系。催化剂通过使卤化镁载体与铝化合物和卤化钛化合物接触，然后用镁 - 酰胺络合物处理所得固体而获得。催化剂体系适用于生产具有窄分子量分布的乙烯聚合物和共聚物以及改进的支链组成分布。

2. 发明申请

WO2008070126A1 A CATALYST SYSTEM FOR PRODUCING ETHYLENE (CO) POLYMER WITH IMPROVED BRANCH DISTRIBUTION 审中-公开
标题翻译：用于生产具有改进分支分布的乙烯（CO）聚合物的催化剂体系
公开(公告)号：WO2008070126A1
公开(公告)日：2008-06-12
申请号：PCT/US2007/024925
申请日：2007-12-05
申请人： FORMOSA PLASTICS CORPORATION, U.S.A. , KONG, Gapgoung , LIU, Zhongyang , LU, Honglan
发明人： KONG, Gapgoung , LIU, Zhongyang , LU, Honglan
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6567 , C08F210/14 , C08F2500/08 , C08F2500/12 , C08F2500/20
摘要： A process for synthesizing a catalyst component for manufacturing ethylene polymer and co-polymer. The present invention provides a process for synthesizing catalyst component (A), comprising forming a complex by contacting the solid intermediate (B) with an aluminum compound represented by formula X 3-n Al(OY) n , and alkyl metal (C), wherein X is halide, Y is a hydrocarbon group or chelating carbonyl group, and wherein 1 is less than or equal to n which is less than or equal to 3, and then contacting the complex with titanium halide having formula ΗX4 wherein X is halide. Solid intermediate (B) is formed by reacting magnesium metal with alkyl halide in the presence of alkoxy aluminum represented by formula Al(OR a ) 3 , silicon halide represented by formula SiX 4 and alkoxy silane represented by formula Si(OR b ) 4 , wherein R a and R b are an aromatic or aliphatic alkyl group and wherein X is halide. Alkyl metal (C) is synthesized by reacting alkyl aluminum compounds represented by formula A1R C 3 with a secondary amine having formula HNRd2 and then by reacting with alkyl magnesium compounds represented by formula R6MgR^ wherein R c , R d , Re and R f are an aromatic or aliphatic alkyl group. The catalyst component is suitable for producing ethylene polymer and co-polymer with narrow molecular weight distribution as well as improved branching compositional distribution.
摘要翻译：一种合成乙烯聚合物和共聚物制备催化剂组分的方法。本发明提供了一种合成催化剂组分（A）的方法，包括通过使固体中间体（B）与由式X 3-n Al（OY）表示的铝化合物接触而形成络合物 >烷基金属（C），其中X是卤化物，Y是烃基或螯合羰基，其中1小于或等于n小于或等于3，然后使络合物与式ⅩⅣ的卤化钛接触，其中X是卤化物。固体中间体（B）是通过使镁金属与烷基卤化物在由式Al（OR 3）3表示的烷氧基铝的存在下反应形成的，由式SiX 和由式Si（OR b）4 Si表示的烷氧基硅烷，其中R a， b为芳族或脂族烷基，其中X为卤化物。烷基金属（C）是通过使由式A1R 3

3. 发明申请

WO2007117283A3 PROCESS FOR MAKING EXFOLIATED POLYOLEFIN/CLAY NANOCOMPOSITES 审中-公开
公开(公告)号：WO2007117283A3
公开(公告)日：2007-10-18
申请号：PCT/US2006/045094
申请日：2006-11-21
申请人： FORMOSA PLASTICS CORPORATION, U.S.A. , INSTITUTE OF CHEMISTRY, CHINESE ACADEMY OF SCIENCES , LU, Honglan , LIU, Zhongyang , CHEN, Chih-Jian , HU, Youliang , LU, Yingying , KE, Yucai , GUO, Cunyue
发明人： LU, Honglan , LIU, Zhongyang , CHEN, Chih-Jian , HU, Youliang , LU, Yingying , KE, Yucai , GUO, Cunyue
IPC分类号： C08K3/34 , C08K9/04
摘要： Processes are disclosed relating to modifying clays with an olefinic functionalized surfactant containing a chain end polymerizable double bond, and to treating the thus modified organoclay with an olefin polymerization catalyst precursor, and polymerizing an olefin in the presence of the thus treated organoclay and an organoaluminum cocatalyst.

4. 发明申请

WO2004072122A2 THE PREPARATION OF A MAGNESIUM HALIDE SUPPORT FOR OLEFIN POLYMERIZATION AND A CATALYST COMPOSITION USING THE SAME 审中-公开
标题翻译：用于烯烃聚合的镁盐支持物的制备和使用其的催化剂组合物
公开(公告)号：WO2004072122A2
公开(公告)日：2004-08-26
申请号：PCT/US2004/002898
申请日：2004-02-02
申请人： FORMOSA PLASTICS CORPORATION, U.S.A.
发明人： LU, Honglan , KONG, Gapgoung , LIU, Zhongyang , CHEN, Chih-Jian
IPC分类号： C08F
CPC分类号： C08F10/00 , B01J27/138 , C08F10/02 , C08F210/16 , C08F4/6548 , C08F4/6557 , C08F4/6543 , C08F4/6546 , C08F4/651 , C08F4/6555 , C08F210/14 , C08F2500/12
摘要： A magnesium halide support material for a polyolefin catalyst is disclosed. The magnesium halide of present invention is prepared by reacting magnesium with an alkylhalide in a non-polar hydrocarbon solvent. Preparation of the support does not require the use electron donating solvents and therefore does not require extensive washing to remove the solvent from the support.
摘要翻译：公开了一种用于聚烯烃催化剂的卤化镁载体材料。本发明的卤化镁是通过使镁与烷基卤在非极性烃溶剂中反应来制备的。载体的制备不需要使用电子给体溶剂，因此不需要大量洗涤以从载体中除去溶剂。

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