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1. 发明申请

WO2007011459A1 POLYALPHA-OLEFIN COMPOSITIONS AND PROCESSES TO PRODUCE THE SAME 审中-公开
标题翻译：聚烯烃组合物及其制备方法
公开(公告)号：WO2007011459A1
公开(公告)日：2007-01-25
申请号：PCT/US2006/021231
申请日：2006-06-02
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , WU, Margaret, M. , YANG, Norman , BAUGH, Lisa, S. , CANICH, Jo Ann, M. , RUCKER, Steven, P. , WALZER, John, F. , LEE, Gordon, H. , LO, Frederick, Yip-kwai , JACKSON, Andrew , HAGEMEISTER, Mark , TIRMIZI, Shakeel , JIANG, Peijun , CHEE, Chia, S.
发明人： WU, Margaret, M. , YANG, Norman , BAUGH, Lisa, S. , CANICH, Jo Ann, M. , RUCKER, Steven, P. , WALZER, John, F. , LEE, Gordon, H. , LO, Frederick, Yip-kwai , JACKSON, Andrew , HAGEMEISTER, Mark , TIRMIZI, Shakeel , JIANG, Peijun , CHEE, Chia, S.
IPC分类号： C08F210/14 , C10M143/08
CPC分类号： C07C11/02 , C07C2/02 , C07C2/34 , C07C5/05 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/14 , C08F110/14 , C08F210/04 , C08F210/14 , C10M107/10 , C10M143/08 , C10M2205/026 , C10M2205/0265 , C10M2205/028 , C10M2205/0285 , C10N2220/021 , C10N2220/022 , C10N2220/023 , C10N2220/024 , C10N2220/025 , C10N2220/026 , C10N2220/028 , C10N2220/033 , C10N2270/00 , C08F2500/03 , C08F2500/17 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a polyalpha-olefin (and hydrogenated analogs thereof) comprising more than 50 mole % of one or more C5 to C24 alpha-olefin monomers where the polyalpha-olefin has: a) 40 mole % or more of mm triads, b) a Bromine number of Y or greater, where Y is equal to 89.92 * (V)' °5863, whre V is the Kinematic Viscosity of the polyalpha-olefin measured at 100°C in cSt, and c) 1,2 disubstituted olefins present at 7 mole % or more, preferably having Z mole % or more of units represented by the formula: where j, k and m are each, independently, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, or 22, n is an integer from 1 to 350, and where Z = 8.420*Log(V)-4.048, where V is the kinematic viscosity of the polyalpha-olefin measured at 1000C in cSt This invention also relates to process to produce such polyalpha-olefins.
摘要翻译：本发明涉及包含大于50摩尔％的一种或多种C 5 -C 24α-烯烃单体的聚α-烯烃（及其氢化类似物），其中聚α-烯烃具有：a）40摩尔％或更多的三元组，b ）Y或更大的溴数，其中Y等于89.92 *（V）'°5863，v是在100℃下在cSt中测量的聚α-烯烃的运动粘度，c）1,2二取代烯烃以7摩尔％以上，优选具有Z摩尔％以上的由下式表示的单元：其中，j，k和m各自独立地为3，4，5，6，7，8，9，10，11 ，12,13,14,15,16,17,18,19,20,21或22，n为1〜350的整数，Z = 8.420 * Log（V）-4.048，其中V为在100℃下测量的聚α-烯烃的运动粘度在cSt中本发明还涉及生产这种聚α-烯烃的方法。

2. 发明申请

WO2009091480A2 PRODUCTION OF PROPYLENE-BASED POLYMERS 审中-公开
标题翻译：生产丙烯聚合物
公开(公告)号：WO2009091480A2
公开(公告)日：2009-07-23
申请号：PCT/US2008/087664
申请日：2008-12-19
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , CANICH, Jo Ann, M. , JIANG, Peijun , CASTY, Gary, L. , KISS, Gabor , VOSKOBOYNIKOV, Alexander, Z.
发明人： CANICH, Jo Ann, M. , JIANG, Peijun , CASTY, Gary, L. , KISS, Gabor , VOSKOBOYNIKOV, Alexander, Z.
IPC分类号： C08F10/06 , C08F4/6592
CPC分类号： C08F10/06 , C08F4/65908 , C08F4/65912 , C08F210/06 , Y02P20/544 , Y10S526/943 , C08F4/65927 , C08F210/16 , C08F2500/03 , C08F2500/17 , C08F2500/20
摘要： In a process for producing a propylene-based olefin homopolymer or copolymer, a monomer composition comprising propylene is contacted with a polymerization catalyst system under homogeneous polymerization conditions (such as solution, supersolution or supercritical conditions), wherein the polymerization catalyst system includes an activator and a bridged bis-indenyl transition metal (group 4) compound substituted with a carbazole (unsubstituted or substituted) at the 4 position.
摘要翻译：在制备丙烯类烯烃均聚物或共聚物的方法中，包含丙烯的单体组合物在均相聚合条件（如溶液，超溶剂或超临界条件）下与聚合催化剂体系接触，其中聚合催化剂体系包括活化剂和在4位被咔唑（未取代或取代的）取代的桥连双茚基过渡金属（4族）化合物。

3. 发明申请

WO2005113622A1 MULTIPLE CATALYST AND REACTOR SYSTEM FOR OLEFIN POLYMERIZATION AND POLYMERS PRODUCED THEREFROM 审中-公开
标题翻译：用于烯烃聚合的多元催化剂和反应器系统及其生产的聚合物
公开(公告)号：WO2005113622A1
公开(公告)日：2005-12-01
申请号：PCT/US2005/012721
申请日：2005-04-13
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , ABHARI, Ramin , SIMS, Charles, L. , JIANG, Peijun , JOHNSRUD, David, R. , CANICH, Jo, Ann, M.
发明人： ABHARI, Ramin , SIMS, Charles, L. , JIANG, Peijun , JOHNSRUD, David, R. , CANICH, Jo, Ann, M.
IPC分类号： C08F297/08
CPC分类号： C08F297/08 , C08F4/65908 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , Y10S526/943 , C08F4/65904 , C08F2/001 , C08F2500/03 , C08F2500/09 , C08F2500/17 , C08F2500/20 , C08F210/16 , C08F210/14
摘要： This invention relates to a continuous process to produce a branched olefin polymer comprising: 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 20% or less under selected polymerization conditions; 2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% (preferably 40% or more) or more at the selected polymerization conditions; 3) contacting a catalyst component, one or more activators and one or more C2 to C40 olefins in a first reaction zone, at a temperature of greater than 70°C, and at a residence time of 120 minutes or less; and 4) transferring the contents of the first reaction zone to a second reaction zone and further contacting the contents with a catalyst component, an activator and or one or more C2 to C40 olefins, at a temperature of greater than 70°C, and at a residence time of 120 minutes or less; and 5) optionally, transferring the contents of the second reaction zone to a third reaction zone and further contacting the contents with a catalyst compound, an activator and or one or more C2 to C40 olefins, at a temperature of greater than 70°C, and at a residence time of 120 minutes or less; and 6) recovering a branched olefin polymer comprising at least 50 o mole % of one or more C3 to C40 olefins, where the first catalyst component is present in at least one reaction zone and the second catalyst component is present in a second reaction zone and where in at least one reaction zone the C2 to C40 olefin is a C3 to C40 alpha-olefin.
摘要翻译：本发明涉及一种制备支链烯烃聚合物的连续方法，包括：1）选择能够在选择的聚合条件下产生Mw为100,000以下且结晶度为20％以下的聚合物的第一催化剂组分; 2）选择能够在选定的聚合条件下产生Mw为100,000以下且聚合度为20％（优选为40％以上）的聚合物的第二催化剂成分; 3）在大于70℃的温度和120分钟以下的停留时间，在第一反应区中使催化剂组分，一种或多种活化剂和一种或多种C 2至C 40烯烃接触; 和4）将第一反应区的内容物转移到第二反应区，并进一步使内容物与催化剂组分，活化剂和/或一种或多种C 2至C 40烯烃在大于70℃的温度和停留时间为120分钟以下; 和5）任选地，将第二反应区的内容物转移到第三反应区，并在大于70℃的温度下使内容物与催化剂化合物，活化剂和/或一种或多种C 2至C 40烯烃进一步接触，停留时间为120分钟以下; 和6）回收包含至少50摩尔％的一种或多种C 3至C 40烯烃的支链烯烃聚合物，其中第一催化剂组分存在于至少一个反应区域中，第二催化剂组分存在于第二反应区域中，其中在至少一个反应区中，C 2至C 40烯烃为C 3至C 40α-烯烃。

4. 发明申请

WO2004046214A2 MULTIPLE CATALYST SYSTEM FOR OLEFIN POLYMERIZATION AND POLYMERS PRODUCED THEREFROM 审中-公开
标题翻译：用于烯烃聚合的多元催化剂体系及其生产的聚合物
公开(公告)号：WO2004046214A2
公开(公告)日：2004-06-03
申请号：PCT/US2003/032910
申请日：2003-10-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , JIANG, Peijun , DEKMEZIAN, Armenag , CANICH, Jo, Ann, M. , SIMS, Charles, L. , ABHARI, Ramin , GARCIA-FRANCO, Cesar, A. , JOHNSRUD, David, R.
发明人： JIANG, Peijun , DEKMEZIAN, Armenag , CANICH, Jo, Ann, M. , SIMS, Charles, L. , ABHARI, Ramin , GARCIA-FRANCO, Cesar, A. , JOHNSRUD, David, R.
IPC分类号： C08F210/06
CPC分类号： C09J123/12 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08L57/02 , C08L2666/02 , C09J5/00 , C09J7/20 , C09J123/10 , C09J2201/606 , C09J2201/622 , C09J2205/31 , C09J2401/006 , C09J2421/00 , C09J2423/006 , C09J2423/046 , C09J2423/106 , C09J2427/006 , C09J2433/00 , Y10S526/943 , C08F4/65904 , C08F2500/15 , C08F2500/05 , C08F2500/20 , C08F2500/17 , C08F2500/09 , C08F2500/12 , C08F236/20 , C08F2500/03 , C08F210/16 , C08F4/63904
摘要： This invention relates to a polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 15 mole % of ehtylene, where the polymer has: a) a Dot T-Peel of 1 Newton or more; and b) a branching index (g’) of 0.95 or less measured at the Mz of the polymer; c) an Mw of 100,000 or less. This invention also relates a polymer comprising one or more C3 to C40 olefins where the polymer has: a) a Dot T-Peel of 1 Newton or more on Kraft paper; b) a branching index (g’) of 0.95 or less measured at the Mz of the polymer; c) a Mw of 10,000 to 100,000; and d) a heat of fusion of 1 to 70 J/g. This invention also relates a polymer comprising one or more C3 to C40 olefins where the polymer has: a) a Dot T-Peel of 1 Newton or more on Kraft paper; b) a branching index (g’) of 0.98 or less measured at the Mz of the polymer; c) a Mw of 10,000 to 60,000; d) a heat of fusion of 1 to 50 J/g. This invention also relates to a homopolypropylene or a copolymer of propylene and up to 5 mole % ehtylene having: a) an isotactic run length of 1 to 3o (isotactic run length “IRL” is defined to be the percent of mmmm pentad divided by 0.5 x percent of mmmr pentad) as determined by Carbon 13 NMR, preferably 3 to 25, more preferably 4 to 20, b) a percent of r dyad of greater than 20%, preferably from 20 to 70% as determined by Carbon 13 NMR, and c) a heat of fusion of 70 J/g or less, preferably 60 J/g or less, more preferably between 1 and 55 J/g, more preferably between 4 and 60 J/g. This invention further relates to a process to produce an olefin polymer comprising: 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 5% or less at selected polymerization conditions; 2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% or more at the selected polymerization conditions; 3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, at the selected polymerization conditions in a reaction zone; 4) obtaining the polymer. This invention further relates to a continuous process to produce a branched olefin polymer comprising: 1) selecting a first catalyst component capable of producing a polymer having an Mw of 1000,000 or less and a crystallinity of 5% or less under selected polymerization conditions; 2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% or more at the selected polymerization conditions; 3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, and, optionally one or more diolefins; 4) at a temperature of greater than 100 °C; 5) at a residence time of 120 minutes or less; 6) wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 50:1; 7) wherein the activity of the catalyst components is at least 100 kilograms of polymer per gram of the catalyst components; and wherein at least 20% of the olefins are converted to polymer.
摘要翻译：本发明涉及包含一种或多种C 3至C 40烯烃，任选一种或多种二烯烃和小于15摩尔％乙炔的聚合物，其中聚合物具有：a）1tonton或更大的Dot T-Peel; 和b）在聚合物的Mz下测量的支化指数（g'）为0.95或更小; c）Mw为100,000或更小。本发明还涉及一种包含一种或多种C 3至C 40烯烃的聚合物，其中聚合物具有：a）在牛皮纸上的1牛顿或更多的点T皮; b）在聚合物的Mz处测量的支化指数（g'）为0.95或更小; c）10,000至100,000的Mw; 和d）1至70J / g的熔化热。本发明还涉及一种包含一种或多种C 3至C 40烯烃的聚合物，其中聚合物具有：a）在牛皮纸上的1牛顿或更多的点T皮; b）在聚合物的Mz测量的支化指数（g'）为0.98或更小; c）10,000至60,000的Mw; d）熔化热为1〜50J / g。本发明还涉及丙烯和至多5摩尔％乙炔的均聚丙烯或共聚物，其具有：a）全同立构游程长度为1至3o（全同立构游程长度“IRL”定义为mmmm五元组的百分比除以0.5 通过碳13 NMR测定，优选3至25，更优选4至20，b）通过碳13 NMR测定的r二重比例大于20％，优选20至70％的百分比，和c）70J / g以下，优选为60J / g以下，更优选为1〜55J / g，更优选为4〜60J / g的熔融热。本发明还涉及一种生产烯烃聚合物的方法，包括：1）选择能够在选定的聚合条件下产生Mw为100,000以下且聚合度为5％以下的聚合物的第一催化剂组分; 2）选择能够在选定的聚合条件下产生Mw为100,000以下且结晶度为20％以上的聚合物的第二催化剂成分; 3）在一个或多个活化剂存在下，使催化剂组分与一种或多种C 3至C 40烯烃在选定的聚合条件下在反应区中接触; 4）获得聚合物。本发明还涉及一种制备支链烯烃聚合物的连续方法，包括：1）选择能够在选择的聚合条件下产生Mw为1000,000以下且结晶度为5％以下的聚合物的第一催化剂组分; 2）选择能够在选定的聚合条件下产生Mw为100,000以下且结晶度为20％以上的聚合物的第二催化剂成分; 3）在一种或多种活化剂存在下与一种或多种C 3至C 40烯烃和任选的一种或多种二烯烃接触催化剂组分; 4）在大于100℃的温度下; 5）停留时间为120分钟以下; 6），其中第一催化剂与第二催化剂的比例为1:1至50:1; 7）其中催化剂组分的活性为每克催化剂组分至少100千克聚合物; 并且其中至少20％的烯烃转化为聚合物。

5. 发明申请

WO2005108442A1 POLYOLEFIN ADHESIVE COMPOSITIONS AND ARTICLES MADE THEREFROM 审中-公开
标题翻译： POLYOLEFIN粘合剂组合物及其制品
公开(公告)号：WO2005108442A1
公开(公告)日：2005-11-17
申请号：PCT/US2003/033163
申请日：2003-10-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , JIANG, Peijun , NELSON, Keith, A. , CURRY, Christopher, L. , DEKMEZIAN, Armengag , CANICH, Jo, Ann, M. , SIMS, Charles, L. , ABHARI, Ramin , GARCIA-FRANCO, Cesar, A. , KNAPPES, Nicholas , FAISSET, Michael, L. , JACOB, Lutz, E.
发明人： JIANG, Peijun , NELSON, Keith, A. , CURRY, Christopher, L. , DEKMEZIAN, Armengag , CANICH, Jo, Ann, M. , SIMS, Charles, L. , ABHARI, Ramin , GARCIA-FRANCO, Cesar, A. , KNAPPES, Nicholas , FAISSET, Michael, L. , JACOB, Lutz, E.
IPC分类号： C08F210/06
CPC分类号： C09J123/12 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08L57/02 , C08L2666/02 , C09J5/00 , C09J7/20 , C09J123/10 , C09J2201/606 , C09J2201/622 , C09J2205/31 , C09J2401/006 , C09J2421/00 , C09J2423/006 , C09J2423/046 , C09J2423/106 , C09J2427/006 , C09J2433/00 , Y10S526/943 , C08F4/65904 , C08F2500/15 , C08F2500/05 , C08F2500/20 , C08F2500/17 , C08F2500/09 , C08F2500/12 , C08F236/20 , C08F2500/03 , C08F210/16 , C08F4/63904
摘要： Embodiments of the present invention relate to article comprising a polymer comprising one or more C to C40 olefins, optionally one or more diolefins, and less than 5 mole % of ethylene having a Dot T-Peel of 1 Newton or more, a branching index (g') of 0.95 or less measured at the Mz of the polymer; and an Mw of 100,000 or less. This invention further relates to a process to produce an olefin polymer comprising: 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 20% or less; 2) selecting a second catalyst component A0@0bl5 of producing polymer having an Mw of 100,000 or less and a crystallinity of 40% or more; 3) contacting the catalyst components in the presence of one or more activators with one or more C to C40 olefins, in a reaction zone.
摘要翻译：本发明的实施方案涉及包含含有一种或多种C至C40烯烃，任选的一种或多种二烯烃和小于5摩尔％的具有1牛顿或更多的点T形剥离的乙烯的聚合物，支化指数（ g'）在聚合物的Mz下测量为0.95或更小; Mw为100,000以下。本发明还涉及一种生产烯烃聚合物的方法，包括：1）选择能够产生Mw为100,000以下且结晶度为20％以下的聚合物的第一催化剂组分; 2）选择产生Mw为100,000以下且结晶度为40％以上的聚合物的第二催化剂组分A0 @ 0bl5; 3）在一个或多个活化剂存在下，将催化剂组分与一种或多种C至C40烯烃在反应区中接触。

6. 发明申请

WO2006025917A3 POLYMERIZATION PROCESS 审中-公开
公开(公告)号：WO2006025917A3
公开(公告)日：2006-03-09
申请号：PCT/US2005/021730
申请日：2005-06-20
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HAGERTY, Robert, O. , CHEE, Chia, S. , LAIRD, Randall, B. , RISCH, Michael, A. , SHIRODKAR, Pradeep, P. , JIANG, Peijun
发明人： HAGERTY, Robert, O. , CHEE, Chia, S. , LAIRD, Randall, B. , RISCH, Michael, A. , SHIRODKAR, Pradeep, P. , JIANG, Peijun
IPC分类号： C08F10/06 , C08F4/649
摘要： This invention is directed to processes of making polymer in the presence of a fluorinated hydrocarbon and recovering the polymer. The processes provided enable polymerization processes to be practiced with minimal fouling in the reaction system, and allows for the recovery of the fluorinated hydrocarbon and other hydrocarbons such as hydrocarbons for reuse in the process or hydrocarbon by-products from the polymerization process. The invention is particularly beneficial in the production of propylene based polymers using Ziegler Natta catalyst systems.

7. 发明申请

WO2008010865A2 PROCESS TO PRODUCE HIGH VISCOSITY FLUIDS 审中-公开
标题翻译：生产高粘度流体的方法
公开(公告)号：WO2008010865A2
公开(公告)日：2008-01-24
申请号：PCT/US2007/011089
申请日：2007-05-08
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , WU, Margaret, May-Som , COKER, Catalina, L. , WALZER, Jr., John, F. , JIANG, Peijun , RUCKER, Steven, P.
发明人： WU, Margaret, May-Som , COKER, Catalina, L. , WALZER, Jr., John, F. , JIANG, Peijun , RUCKER, Steven, P.
IPC分类号： C08F110/14 , C08F110/06 , C08F4/659
CPC分类号： C08F110/06 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/08 , C08F110/14 , C08F4/65925 , C08F2500/02 , C08F2500/17 , C08F2500/03
摘要： This invention relates to processes to produce liquid poly-alpha-olefins (PAOs) having a kinematic viscosity at 100 0 C of more than 20 cSt in the presence of a metallocene catalyst with a non-coordinating anion activator and hydrogen.
摘要翻译：本发明涉及在具有非配位阴离子活化剂的茂金属催化剂存在下，在100℃下具有大于20cSt的运动粘度的液态聚-α-烯烃（PAO）的方法和氢气。

8. 发明申请

WO2009123663A1 ISOTACTIC POLYPROPYLENE PRODUCED FROM SUPERCRITICAL POLYMERIZATION PROCESS 审中-公开
标题翻译：由超临界聚合工艺生产的异辛烯聚丙烯
公开(公告)号：WO2009123663A1
公开(公告)日：2009-10-08
申请号：PCT/US2008/080434
申请日：2008-10-20
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , MEHTA, Aspy, K. , VARMA-NAIR, Manika , KISS, Gabor , BRANT, Patrick , REYNOLDS, Robert, P. , CHU, John, W. , RUCKER, Steven, P. , JIANG, Peijun
发明人： MEHTA, Aspy, K. , VARMA-NAIR, Manika , KISS, Gabor , BRANT, Patrick , REYNOLDS, Robert, P. , CHU, John, W. , RUCKER, Steven, P. , JIANG, Peijun
IPC分类号： C08F110/06 , C08F2/06 , C08F4/6592
CPC分类号： C08F110/06 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F10/06 , Y02P20/544 , C08F4/65927 , C08F2/14 , C08F2/06 , C08F2500/17 , C08F2500/09 , C08F2500/12 , C08F2500/20 , C08F2500/03 , C08F2500/15
摘要： This invention relates to an isotactic propylene homopolymer having: more than 15 and less than 100 regio defects (sum of 2,1-erythro and 2,1-threo insertions and 3,1-isomerizations ) per 10,000 propylene units; an Mw of 35000 g/mol or more; a peak melting temperature of greater than 149 0C; anmmmm pentad fraction of 0.85 or more; a heat of fusion of 80 J/g or more; and a peak melting temperature minus peak crystallization temperature (Tmp-Tcp) of less than or equal to (0.907 times Tmp) minus 99.64 (Tmp-Tcp
摘要翻译：本发明涉及全同立构丙烯均聚物，其具有：每10,000个丙烯单元多于15个且小于100个区域缺陷（2,1-赤式和2,1-苏式插入和3,1-异构化的总和）; Mw为35000g / mol以上; 峰值熔融温度大于149℃; 0.85mm以上的五元组分数; 融合热量为80J / g以上; 并且峰值熔融温度减去峰值结晶温度（Tmp-Tcp）小于或等于（0.907倍Tmp）减去99.64（Tmp-Tcp <（0.907×Tmp）-99.64）），其在0℃下对0wt ％成核剂。

9. 发明申请

WO2007011973A1 PROCESS TO PRODUCE LOW VISCOSITY POLY-ALPHA-OLEFINS 审中-公开
标题翻译：生产低粘度聚α-烯烃的方法
公开(公告)号：WO2007011973A1
公开(公告)日：2007-01-25
申请号：PCT/US2006/027943
申请日：2006-07-19
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , WU, Margaret , COKER, Catalina, L. , WALZER, John, F. , JIANG, Peijun
发明人： WU, Margaret , COKER, Catalina, L. , WALZER, John, F. , JIANG, Peijun
IPC分类号： C08F210/14 , C10M143/08 , C08F210/04
CPC分类号： C07C11/02 , C07C2/02 , C07C2/34 , C07C5/05 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/14 , C08F110/14 , C08F210/04 , C08F210/14 , C10M107/10 , C10M143/08 , C10M2205/026 , C10M2205/0265 , C10M2205/028 , C10M2205/0285 , C10N2220/021 , C10N2220/022 , C10N2220/023 , C10N2220/024 , C10N2220/025 , C10N2220/026 , C10N2220/028 , C10N2220/033 , C10N2270/00 , C08F2500/03 , C08F2500/17 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a process to produce a polyalpha-olefin comprising: 1) contacting one or more alpha-olefm monomers having 3 to 24 carbon atoms with an unbridged substituted bis cyclopentadienyl transition metal compound having: 1) at least one non-isoolefm substitution on both cyclopentadientyl rings, or 2) at least two substitutions on at least one cyclopentadienyl ring, a non-coordinating anion activator, and optionally an alkyl- aluminum compound, where the molar ratio of transition metal compound to activator is 10:1 to 0.1 :1, and if the alkyl aluminum compound is present then the molar ratio of alkyl aluminum compound to transition metal compound is 1 :4 to 4000:1, under polymerization conditions wherein: i) hydrogen is present at a partial pressure of Q.I to 50 psi, based upon the total pressure of the reactor or the concentration of the hydrogen is from 1 to 10,000 ppm or less by weight ; ii) wherein the alpha-olefin monomer(s) having 3 to 24 carbon atoms are present at 10 volume % or more based upon the total volume of the catalyst/activator/alkylaluminum compound solutions, monomers, and any diluents or solvents present in the reaction; iii) the residence time of the reaction is at least 5 minutes; iv) the productivity of the process is at least 43,000 grams of total product per gram of transition metal compound; v) the process is continuous or semi-continuous, and vi) the temperature in the reaction zone does not rise by more than 10 °C during the reaction; and vii) ethylene is not present at more than 30 volume % of the monomers entering the reaction zone; and 2) obtaining a polyalpha-olefin (PAO), optionally hydrogenating the PAO, wherein the PAO comprises at least 50 mole% of a C3 to C24 alpha-olefin monomer, and wherein the PAO has a kinematic viscosity at 1000C of 20 cSt or less.
摘要翻译：本发明涉及一种生产聚α-烯烃的方法，包括：1）使一个或多个具有3至24个碳原子的α-烯烃单体与未桥连的取代的双环戊二烯基过渡金属化合物接触，所述化合物具有：1）至少一个非等摩尔取代基在两个环戊二烯基环上，或2）至少一个环戊二烯基环上的至少两个取代基，非配位阴离子活化剂和任选的烷基铝化合物，其中过渡金属化合物与活化剂的摩尔比为10:1至0.1 ：1，如果存在烷基铝化合物，则在聚合条件下，烷基铝化合物与过渡金属化合物的摩尔比为1:4至4000:1，其中：i）氢分压为QI至50 基于反应器的总压力或氢的浓度为1至10,000ppm或更低的重量比; ii）其中基于催化剂/活化剂/烷基铝化合物溶液，单体和存在于所述催化剂/活化剂/烷基铝化合物溶液中的任何稀释剂或溶剂的总体积，其中具有3至24个碳原子的α-烯烃单体以10体积％或更多存在反应; iii）反应停留时间为至少5分钟; iv）该方法的生产率至少为每克过渡金属化合物总产品43,000克; v）该方法是连续或半连续的，和vi）反应区中的温度在反应期间不会升高超过10℃; 和vii）在超过30体积％的进入反应区的单体中不存在乙烯; 和2）获得聚α-烯烃（PAO），任选地氢化PAO，其中PAO包含至少50摩尔％的C 3至C 24α-烯烃单体，并且其中PAO在1000℃下的运动粘度为20cSt或减。

10. 发明申请

WO2009123800A1 PRODUCTION OF SHEAR-STABLE HIGH VISCOSITY PAO 审中-公开
标题翻译：生产耐磨高粘度PAO
公开(公告)号：WO2009123800A1
公开(公告)日：2009-10-08
申请号：PCT/US2009/034391
申请日：2009-02-18
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HAGEMIESTER, Mark, Paul , JIANG, Peijun , WU, Margaret, May-Som , YANG, Norman
发明人： HAGEMIESTER, Mark, Paul , JIANG, Peijun , WU, Margaret, May-Som , YANG, Norman
IPC分类号： C08F10/08 , C08F10/14
CPC分类号： C08F10/14 , C08F10/08 , C08F210/08 , C08F2/00 , C08F210/14 , C08F2500/17 , C08F2500/03
摘要： The invention is directed to a process for the preparation of high viscosity lubricant base stocks by contacting alphaolefin feedstocks with single-site metallocene catalysts in a mixed flow or continuous stirred tank reactors.
摘要翻译：本发明涉及通过在混合流动或连续搅拌釜反应器中使α-烯烃原料与单中心金属茂催化剂接触来制备高粘度润滑剂基础油料的方法。

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