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1. 发明申请

WO2021183330A1 WAX COMPOSITIONS COMPRISING HYDROGENATED OR PARTIALLY HYDROGENATED LINEAR OLEFIN DIMERS AND METHODS FOR PRODUCTION THEREOF 审中-公开
公开(公告)号：WO2021183330A1
公开(公告)日：2021-09-16
申请号：PCT/US2021/020532
申请日：2021-03-02
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： PEREZ VELEZ, Roxana , ZABULA, Alexander, V. , KRAMER, Anatoly, I. , TURNER, Elizabeth, A. , JAENSCH, Helge , BUNQUIN, Jeffrey, C. , GUZMAN, Javier , BEKKER, Madelyn , DE SMIT, Emiel , COLEMAN, John, S.
IPC分类号： C08L91/06 , C07C6/04
摘要： Wax compositions may be obtained by subjecting one or more linear alpha olefins to olefin metathesis and hydrogenating. Methods for producing wax compositions may comprise providing a hydrocarbon substance comprising at least one linear olefin dimer formed from a first linear alpha olefin having m carbon atoms and a second linear alpha olefin having n carbon atoms in the presence of a metal carbene catalyst, the first and second linear alpha olefins being the same or different, and the linear olefin dimer comprising two carbon atoms less than a sum of m and n; contacting the hydrocarbon substance with a hydrogenation catalyst under hydrogenation reaction conditions; and hydrogenating at least a portion of the at least one linear olefin dimer to form an at least partially paraffinic hydrocarbon substance comprising at least one linear paraffin. Variable m and n independently ranging from about 12 to about 100.

2. 发明申请

WO2021183327A1 WAX COMPOSITIONS COMPRISING LINEAR OLEFIN DIMERS OR HODROGENATED VARIANTS THEREOF AND METHODS FOR PRODUCTION THEREOF 审中-公开
公开(公告)号：WO2021183327A1
公开(公告)日：2021-09-16
申请号：PCT/US2021/020527
申请日：2021-03-02
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： BUNQUIN, Jeffrey, C. , KRAMER, Anatoly, I. , ZABULA, Alexander, V. , TURNER, Elizabeth, A. , PEREZ VELEZ, Roxana , JAENSCH, Helge , GUZMAN, Javier , DE MEESTER, Raf , DE SMIT, Emiel , COLEMAN, John, S. , BEKKER, Madelyn
IPC分类号： C08L91/06 , C07C6/04 , C07C7/163
摘要： Wax compositions may be obtained by providing an olefinic feed comprising a first linear alpha olefin having m carbon atoms and a second linear alpha olefin having n carbon atoms, wherein m and n are independently selected integers each ranging from about 12 to about 100, and the olefinic feed optionally comprises one or more internal olefins and/or one or more branched olefins; contacting the olefinic feed with a metal carbene catalyst in a reactor; forming ethylene and a hydrocarbon substance comprising a linear olefin dimer comprising two carbon atoms less than a sum of m and n; removing the ethylene from the reactor while forming the linear olefin dimer; and isolating a wax composition comprising the linear olefin dimer, a hydrogenated reaction product thereof, or any combination thereof.

3. 发明申请

WO2018044552A1 HYDROCARBON PYROLYSIS 审中-公开
标题翻译：碳氢化合物热解
公开(公告)号：WO2018044552A1
公开(公告)日：2018-03-08
申请号：PCT/US2017/046937
申请日：2017-08-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： BARRAI, Federico , COLEMAN, John, S. , BHANDARI, Dhaval, A. , HERSHKOWITZ, Frank , LATTNER, James, R.
IPC分类号： C10G9/26 , C10G9/00 , C10G9/16 , C07C5/327 , C07C5/32 , C07C11/02 , B01J8/04 , B01J19/24 , B01F5/06 , B01J19/02 , C07C11/24
CPC分类号： C10G9/26 , B01F5/0688 , B01J2208/00513 , C01B3/00 , C01B3/22 , C01B2203/0266 , C01B2203/1211 , C01B2203/1235 , C01B2203/1241 , C07C5/327 , C07C5/35 , C07C5/48 , C10G9/002 , C10G9/16 , C10G2300/1022 , C10G2300/1025 , C10G2300/1037 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/1081 , C10G2300/4006 , C10G2400/20 , C10G2400/22 , C10G2400/24 , C07C11/04 , C07C11/24 , C07C11/06
摘要： The invention relates to hydrocarbon pyrolysis, to equipment and materials useful for hydrocarbon pyrolysis, to processes for carrying out hydrocarbon pyrolysis, and to the use of hydrocarbon pyrolysis for, e.g., natural gas upgrading. The pyrolysis can be carried out in a reverse-flow reactor.
摘要翻译：本发明涉及烃热解，用于烃热解的设备和材料，用于进行烃热解的方法，以及烃热解用于例如天然气提质的用途。热解可以在逆流式反应器中进行。

4. 发明申请

WO2022256132A1 PROCESSES FOR REGENERATING CATALYSTS AND FOR UPGRADING ALKANES AND/OR ALKYL AROMATIC HYDROCARBONS 审中-公开
公开(公告)号：WO2022256132A1
公开(公告)日：2022-12-08
申请号：PCT/US2022/027986
申请日：2022-05-06
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： BAO, Xiaoying , DIAZ URRUTIA, Christian, A. , BAI, Chuansheng , COLEMAN, John, S. , KUECHLER, Keith, H.
IPC分类号： B01J23/96 , B01J38/12 , B01J38/06 , B01J23/62 , B01J23/89 , C07C5/333
摘要： Processes for regenerating an at least partially deactivated catalyst that can include a Group (10) element, an inorganic support, and a contaminant. The Group (10) element can have a concentration of from 0.001 wt% to 6 wt%, based on the weight of the inorganic support. The process can include (I) heating the deactivated catalyst using a heating gas mixture that includes H2O at a concentration > 5 mol%, based on the total moles in the mixture to produce a precursor catalyst. The process can also include (II) providing an oxidative gas that includes ≤ 5 mol% of H2O, based on the total moles in the oxidative gas, and (III) contacting the precursor catalyst at an oxidizing temperature with the oxidative gas for a duration of at least 30 seconds to produce an oxidized precursor catalyst. The process can also include (IV) obtaining a regenerated catalyst from the oxidized precursor catalyst.

5. 发明申请

WO2020163421A1 PRIMARY FRACTIONATOR WITH REDUCED FOULING 审中-公开
公开(公告)号：WO2020163421A1
公开(公告)日：2020-08-13
申请号：PCT/US2020/016703
申请日：2020-02-05
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： LAWRENCE, Selma, S. , MORAN, Michael , COLEMAN, John, S. , BARTEL, Robert, S. , SINGH, Vikram , MALHOTRA, Monica
IPC分类号： C10G9/36 , C10G75/00 , C10G7/00 , B01D3/42 , B01D3/14
摘要： Systems and methods are provided for reducing or minimizing fouling within the primary fractionator of a pyrolysis reaction system. The reduced or minimized fouling can be achieved in part by providing one or more pump-around trays in the primary fractionator below the level of the fractionation trays for an intermediate product produced by the fractionator. Including a pump-around section below the fractionation trays can improve vapor distribution within the fractionation trays, which are believed to have an increased likelihood of accumulation of foulant deposits. Optionally, other vapor distribution devices can be included along with the pump-around section.

6. 发明申请

WO2019164611A1 HEAVY OIL HYDROPROCESSING SYSTEM 审中-公开
公开(公告)号：WO2019164611A1
公开(公告)日：2019-08-29
申请号：PCT/US2019/014266
申请日：2019-01-18
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： LATTNER, James, R. , COLEMAN, John, S.
IPC分类号： C10G21/28 , C10G47/26 , C10G49/12 , C10G67/04 , C10G21/00 , C10G21/14
摘要： Systems and methods are provided for hydroprocessing of feeds including a heavy oil fraction, such as feeds including a ~1050°F+ (~566°C+) fraction. The systems and methods can facilitate processing of feeds including a heavy oil fraction in a fluidized hydroprocessing environment while reducing or minimizing hydrogen consumption during the hydroprocessing.

7. 发明申请

WO2014189623A1 PROCESS FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的方法
公开(公告)号：WO2014189623A1
公开(公告)日：2014-11-27
申请号：PCT/US2014/033475
申请日：2014-04-09
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： COLEMAN, John, S. , PATEL, Bryan, A.
IPC分类号： C07C37/08 , C07C39/04 , C07C45/53 , C07C49/403 , C07C2/74 , C07C13/28 , C07C409/14
CPC分类号： C07C37/50 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2529/70 , C07C2601/14 , C07C39/04 , C07C49/403 , C07C13/28
摘要： In a process for producing phenol and cyclohexanone, reaction components comprising cyclohexylbenzene hydroperoxide and an acid catalyst are supplied to a cleavage reaction zone, mixed under mixing conditions effective to combine the reaction components into a reaction mixture and at least part of the cyclohexylbenzene hydroperoxide in the reaction mixture is converted under cleavage conditions to into phenol and cyclohexanone; and a cleavage effluent is recovered from the cleavage reaction zone. The cleavage and mixing conditions are controlled such that the ratio t R / t M is at least 10, where t R is the half-life of cyclohexylbenzene hydroperoxide under the cleavage conditions and t M is the time required after injection of a tracer material into the reaction mixture under the mixing conditions for at least 95% by volume of the entire reaction mixture to attain at least 95% of the volume-averaged tracer material concentration.
摘要翻译：在生产酚和环己酮的方法中，将包含环己基苯氢过氧化物和酸催化剂的反应组分供应至裂解反应区，在有效将反应组分混合成反应混合物和至少部分环己基苯氢过氧化物的混合条件下混合，在裂解条件下将反应混合物转化成苯酚和环己酮; 并从裂解反应区回收裂解流出物。控制裂解和混合条件使得t R / t M的比例至少为10，其中t R是在切割条件下环己基苯氢过氧化物的半衰期，t M是将示踪材料注入后所需的时间反应混合物在混合条件下至少95％体积的整个反应混合物，以达到体积平均示踪剂材料浓度的至少95％。

8. 发明申请

WO2019203981A1 PROCESSING PYROLYSIS TAR PARTICULATES 审中-公开
公开(公告)号：WO2019203981A1
公开(公告)日：2019-10-24
申请号：PCT/US2019/023187
申请日：2019-03-20
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： COLEMAN, John, S. , GALVAN, Kendele, S. , MONSON, John, J. , BURCHAM, Denise, M. , KANDEL, Kapil
IPC分类号： C10G69/06
摘要： Systems and methods are provided for increasing the portion of a pyrolysis tar fraction that can be hydroprocessed by using a physical particle size reduction process on at least a portion of the pyrolysis tar fraction. The physical particle size reduction process can reduce the percentage of particles in the pyrolysis tar fraction that have a particle size of 50nm or greater. It has been unexpectedly discovered that at least a portion of the particles having a size of 50nm or less, can be effectively hydroprocessed to form products of greater value while still reducing or minimizing the amount of fouling or plugging in a hydroprocessing catalyst bed. By increasing the number of particles having a size of 50nm or less, while selectively removing larger particles from the SCT fraction, a higher yield of hydrocarbon products can be achieved for a feed containing an SCT fraction. This can reduce or minimize the amount of particulates that are disposed of by incineration or another disposal method for fractions that have a lesser value.

9. 发明申请

WO2018111577A1 PYROLYSIS TAR UPGRADING 审中-公开
公开(公告)号：WO2018111577A1
公开(公告)日：2018-06-21
申请号：PCT/US2017/064176
申请日：2017-12-01
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： XU, Teng , KANDEL, Kapil , HEETER, Glenn, A. , FERRUGHELLI, David, T. , COLEMAN, John, S. , CLEMMONS, Michael, J. , MCMANUS, Jesse, R.
IPC分类号： C10G45/00 , C10G45/72 , C10G69/06 , C10G1/00 , C10G1/02 , C10G31/10
摘要： A process is disclosed for upgrading tars, typically those resulting from hydrocarbon refining processes, to products suitable for other uses, such as blending with other hydrocarbons to provide low-sulfur fuel oils or Emission Control Area-acceptable fuels. A low-sulfur hydrocarbon product obtained from the process is also disclosed.

10. 发明申请

WO2018044555A1 HYDROCARBON PYROLYSIS 审中-公开
标题翻译：碳氢化合物热解
公开(公告)号：WO2018044555A1
公开(公告)日：2018-03-08
申请号：PCT/US2017/046951
申请日：2017-08-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： BARRAI, Federico , MAHONEY, Elizabeth, G. , COLEMAN, John, S. , BHANDARI, Dhaval, A. , WEISS, Brian, M. , CHUN, ChangMin , HERSHKOWITZ, Frank
IPC分类号： C10G9/26
CPC分类号： C10G9/26
摘要： The invention relates to hydrocarbon pyrolysis, to equipment and materials useful for hydrocarbon pyrolysis, to processes for carrying out hydrocarbon pyrolysis, and to the use of hydrocarbon pyrolysis for, e.g., hydrocarbon gas upgrading. The pyrolysis is carried out in a reactor which includes at least one thermal mass having an open frontal area ≤55%.
摘要翻译：本发明涉及烃热解，用于烃热解的设备和材料，用于进行烃热解的方法，以及烃热解用于例如烃气升级的用途。热解在包含至少一种具有≤55％的正面面积的热质量的反应器中进行。

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