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1. 发明申请

WO2012134722A3 DIBLOCK COPOLYMERS PREPARED BY CROSS METATHESIS 审中-公开
标题翻译：用交叉法制备的二嵌段共聚物
公开(公告)号：WO2012134722A3
公开(公告)日：2012-12-27
申请号：PCT/US2012027691
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , HAGADORN JOHN R , RUFF CHARLES J , GANESH RENUKA N , BRANT PATRICK
发明人： HAGADORN JOHN R , RUFF CHARLES J , GANESH RENUKA N , BRANT PATRICK
IPC分类号： C08F10/00 , C08F4/64 , C08F297/08 , C08L23/02 , C08L53/00
CPC分类号： C08G61/08 , C08F297/083 , C08G61/04 , C08G2261/418 , C08L53/00 , C08L65/00
摘要： This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO-C(R11)(R12)-C(R13)=C(R14)-C(R15)(R16)-PO*, or isomers thereof, wherein R11, R12, R13, R14, R15, and R16, are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio "Z" = 0.1 to 10 where Z is the Mn (as determined by 13C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.75(J) internal unsaturations per 1000 carbons as determined by 1H NMR spectroscopy, where J is the number of reactive groups per 1000 carbons for the mixture of vinyl terminated polyolefins that become PO and PO*, before they are coupled by an alkene metathesis catalyst.
摘要翻译：本发明涉及一种组合物，其包含由下式表示的多嵌段聚烯烃：PO-C（R11）（R12）-C（R13）= C（R14）-C（R15）（R16）-PO *或其异构体，其中R 11，R 12，R 13，R 14，R 15和R 16各自独立地为取代或未取代的C 1至C 4烃基或氢; PO和PO *是聚烯烃; PO和PO *各自独立地为具有9-4000个碳原子的取代或未取代的烃基，条件是PO和PO *中的至少一个为C20或更大，所述聚烯烃具有：1）如13C NMR所示的内不饱和度在约128和约132ppm之间的峰值; 2）Mn比率“Z”= 0.1-10，其中Z是Mn（通过13C NMR测定）除以Mn（根据凝胶渗透色谱法使用聚苯乙烯标准测定）; 和3）任选地，通过1 H NMR谱测定，每1000个碳原子有0.3（J）和0.75（J）的内部不饱和度，其中J是乙烯基封端的聚烯烃混合物每1000个碳原子的反应基团数量，其变为PO和PO *，在它们通过烯烃复分解催化剂偶联之前。

2. 发明申请

WO2012134718A2 AMINE FUNCTIONALIZED POLYOLEFIN AND METHODS FOR PREPARATION THEREOF 审中-公开
标题翻译：胺官能化聚烯烃及其制备方法
公开(公告)号：WO2012134718A2
公开(公告)日：2012-10-04
申请号：PCT/US2012027683
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , HAGADORN JOHN R , CROWTHER DONNA J , GANESH RENUKA N , BRANT PATRICK
发明人： HAGADORN JOHN R , CROWTHER DONNA J , GANESH RENUKA N , BRANT PATRICK
IPC分类号： C08F8/32 , C08F4/64 , C08F10/06 , C08L23/36
CPC分类号： C08F8/32 , C08F110/14 , C08F210/06 , C08L23/36 , C08F210/16
摘要： This invention relates to a process to functionalize polyolefins comprising contacting a transition metal amide catalyst with an amine (preferably a secondary amine), and one or more vinyl terminated materials, preferably one or more vinyl terminated polyolefins. This invention further relates to the amine-functionalized polyolefins produced thereby.
摘要翻译：本发明涉及使聚烯烃官能化的方法，其包括使过渡金属氨化物催化剂与胺（优选仲胺）和一种或多种乙烯基封端的材料，优选一种或多种乙烯基封端的聚烯烃接触。本发明还涉及由此制得的胺官能化聚烯烃。

3. 发明申请

WO2012134717A3 VINYL TERMINATED HIGHER OLEFIN POLYMERS AND METHODS TO PRODUCE THEREOF 审中-公开
标题翻译： VINYL终止的高烯烃聚合物及其生产方法
公开(公告)号：WO2012134717A3
公开(公告)日：2012-11-22
申请号：PCT/US2012027682
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , CROWTHER DONNA J , HOLTCAMP MATTHEW W , HAGADORN JOHN R , RUFF CHARLES J , RODRIGUEZ GEORGE , BRANT PATRICK
发明人： CROWTHER DONNA J , HOLTCAMP MATTHEW W , HAGADORN JOHN R , RUFF CHARLES J , RODRIGUEZ GEORGE , BRANT PATRICK
IPC分类号： C08F210/14 , C08F4/64 , C08F210/06 , C08L23/18 , C10M107/10
CPC分类号： C10M107/10 , C08F4/65908 , C08F4/65925 , C08F4/65927 , C08F210/06 , C08F210/14 , C08L2314/06 , C10M2205/0245 , C10M2205/0265 , C10M2205/0285 , C10N2220/021 , C10N2220/022 , C10N2220/028 , C10N2270/00 , C08F2500/17
摘要： This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1H NMR) comprising: (i) from about 20 to about 99.9 mol% of at least one C5 to C40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol% of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7: 1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.
摘要翻译：本发明涉及Mn为300g / mol以上（通过1 H NMR测定）的乙烯基封端的高级烯烃共聚物，其包含：（i）约20-约99.9mol％的至少一种C 5至C 40高级烯烃单体; 和（ii）约0.1至约80mol％的丙烯; 其中所述较高级烯烃共聚物具有至少40％的烯丙基链端。该共聚物也可以具有小于0.7:1的异丁基链端与烯丙基链末端比和/或烯丙基链端与亚乙烯基链末端比大于2:1。

4. 发明申请

WO2012134721A3 VINYL TERMINATED HIGHER OLEFIN POLYMERS AND METHODS TO PRODUCE THEREOF 审中-公开
标题翻译： VINYL终止的高烯烃聚合物及其生产方法
公开(公告)号：WO2012134721A3
公开(公告)日：2012-11-29
申请号：PCT/US2012027690
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , HOLTCAMP MATTHEW W , RUFF CHARLES J , CROWTHER DONNA J , HAGADORN JOHN R , BRANT PATRICK
发明人： HOLTCAMP MATTHEW W , RUFF CHARLES J , CROWTHER DONNA J , HAGADORN JOHN R , BRANT PATRICK
IPC分类号： C08F10/14 , C08F4/64 , C08F4/6592 , C08F210/16
CPC分类号： C08F10/14 , C08F4/65908 , C08F4/65912 , C08F210/14 , C08F4/65925 , C08F4/65927 , C08F2500/02
摘要： This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by lR NMR) including of one or more C4 to C4Q higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.
摘要翻译：本发明涉及具有至少200g / mol（通过1MRI测量）的Mn的高级烯烃乙烯基封端聚合物，其包含一个或多个C4-C4Q高级烯烃衍生单元，其中较高级烯烃乙烯基封端的聚合物基本上不含丙烯单位; 并且其中所述较高级烯烃聚合物具有至少5％的烯丙基链末端及其生产方法。这些乙烯基封端的较高级烯烃聚合物可以任选地包括乙烯衍生的单元。

5. 发明申请

WO2011056884A2 CARBENE COMPLEXES OF LITHIUM AND/OR MAGNESIUM METAL SALTS, AND USES THEREOF 审中-公开
标题翻译：锂和/或镁金属盐的碳复合物及其用途
公开(公告)号：WO2011056884A2
公开(公告)日：2011-05-12
申请号：PCT/US2010055313
申请日：2010-11-03
申请人： EXXONMOBIL CHEM PATENTS INC , HAGADORN JOHN R , HOLTCAMP MATTHEW W , BEDOYA MATTHEW S , GANESH RENUKA N
发明人： HAGADORN JOHN R , HOLTCAMP MATTHEW W , BEDOYA MATTHEW S , GANESH RENUKA N
IPC分类号： C07F1/02 , B01J31/22 , C07C2/34 , C07C11/00 , C07F3/02
CPC分类号： C07F15/0046 , B01J31/2269 , B01J31/2273 , B01J31/2278 , B01J2231/543 , B01J2531/0205 , B01J2531/11 , B01J2531/22 , B01J2531/821 , C07C6/04 , C07C67/333 , C07C2531/22 , C07C11/02 , C07C69/533
摘要： This invention relates to a carbene complex of metal salt represented by the formula: [T-M(R)c]n wherein, R is a monoanionic group; c is 1 or 2; M is a Li or Mg; T is a cyclic carbene ligand; and n is selected from the group of integers comprising 1 to 24 wherein the complex has 50% or less decomposition when stored in 0.01 molar benzene at 23°C for a period of 1 hour. This invention also relates to transition-metal-carbene complexes prepared from such carbene complexes of metal salts, where the transition-metal-carbene complex is represented by the formula: [M*(T)(L0)q(L1-)s(L2-)t]g, where M* is a transition metal from Group 6, 7, 8, 9, 10, 11 or 12, T is a cyclic carbene ligand, L0 is a neutral ligand, L1- is a monoanionic ligand, L2- is a dianionic ligand, q is 0, 1, 2, 3 or 4, s is 0, 1, 2, 3, or 4, t is 0, 1, 2, 3,or 4, g is the overall charge of the molecule. The transition-metal-carbene complexes may be used for synthesis reactions, including metathesis of olefins.
摘要翻译：本发明涉及由式[T-M（R）c] n表示的金属盐的卡宾络合物，其中R是单阴离子基团; c为1或2; M是Li或Mg; T是环卡宾配体; 并且n选自包含1至24的整数组，其中当在23℃下在0.01摩尔苯中储存1小时时，所述络合物具有50％或更少的分解。本发明还涉及由金属盐的这种卡宾络合物制备的过渡金属 - 卡宾络合物，其中过渡金属 - 卡宾络合物由下式表示：[M *（T）（L0）q（L1-）s L2-）t] g，其中M *是第6,7,8,9,10,11或12族的过渡金属，T是环卡宾配体，L 0是中性配体，L1-是单阴离子配体， L2-是二阴离子配体，q是0,1,2,3或4，s是0,1,2,3或4，t是0,1,2,3或4，g是总电荷的分子。过渡金属 - 卡宾络合物可用于合成反应，包括烯烃的复分解。

6. 发明申请

WO2012134613A2 PYRIDYLDIAMIDO TRANSITION METAL COMPLEXES, PRODUCTION AND USE THEREOF 审中-公开
标题翻译： PYRIDYLDIAMIDO过渡金属复合物，生产和使用
公开(公告)号：WO2012134613A2
公开(公告)日：2012-10-04
申请号：PCT/US2012022473
申请日：2012-01-25
申请人： EXXONMOBIL CHEM PATENTS INC , HAGADORN JOHN R , GANESH RENUKA N , UBORSKY DMITRY V , BORISOV IIYA S , PRUSS IVAN V , VOSKOBOYNIKOV ALEXANDER Z
发明人： HAGADORN JOHN R , GANESH RENUKA N , UBORSKY DMITRY V , BORISOV IIYA S , PRUSS IVAN V , VOSKOBOYNIKOV ALEXANDER Z
IPC分类号： C07F7/28 , C07F3/00 , C07F7/00 , C07F9/00 , C07F11/00 , C07F13/00
CPC分类号： C07F7/006 , B01J31/143 , B01J31/146 , B01J31/1815 , B01J31/183 , B01J2531/0241 , B01J2531/0297 , B01J2531/48 , B01J2531/49 , C07D213/38 , C07D213/48 , C07D213/53 , C07F7/00 , C07F7/003 , C08F10/00 , C08F110/06 , C08F210/16 , C08F2500/03 , C08F210/14 , C08F4/64148 , C08F4/64144
摘要： Pyridyldiamido transition metal complexes are disclosed for use in alkene polymerization.
摘要翻译：公开了用于烯烃聚合的吡啶基二酰氨基过渡金属络合物。

7. 发明申请

WO2012134725A3 AMPHIPHILIC BLOCK POLYMERS PREPARED BY ALKENE METATHESIS 审中-公开
标题翻译：由ALKENE METATHESIS制备的聚合物嵌段聚合物
公开(公告)号：WO2012134725A3
公开(公告)日：2013-01-31
申请号：PCT/US2012027704
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , HAGADORN JOHN R , BRANT PATRICK
发明人： HAGADORN JOHN R , BRANT PATRICK
IPC分类号： C08F10/00 , C08F4/6592 , C08F297/08 , C08L23/02 , C08L53/00
CPC分类号： C08F210/06 , C08F4/65908 , C08F4/65925 , C08F4/65927 , C08F290/062 , C08F297/08 , C08F299/00 , C08F210/16 , C08F2500/15 , C08F210/14
摘要： The invention relates to a multiblock polyolefin, and methods to make a multiblock polyolefin, represented by the formula (X) or (XII): PO-C(R11)R12-CR13C(R14-C)-C(O)-((CR15R16) ZVC17R18)m-O)n-R19 (X) or PO-C(R11)R12-CR13C(R14-C)-C(O)-((CR15R16) ZVC17R18)mO)n-C(O)- C(R14C=(R13)-C(R12)(R11)-PO (XX) wherein R11, R12, R13, and R14 are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; R15, R16, R17, and R18 are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; R19 is a C1 to a C20 substituted or unsubstituted hydrocarbyl group or a hydrogen; z is = 1 to about 5; m is = 1 to about 5; PO is a polyolefin hydrocarbyl group comprising 10 to 4000 carbon atoms; and n is from 1 to about 10,000.
摘要翻译：本发明涉及一种多嵌段聚烯烃，以及制备由式（X）或（XII）表示的多嵌段聚烯烃的方法：PO-C（R11）R12-CR13C（R14-C）-C（O） - （（（R 15）C（O） - （CR 15 R 16）Z C 17 R 18）m O）n R 19（X）或PO-C（R 11）R 12 -C 13 C（R 14 -C （R 13）-C（R 12）（R 11）-PO（XX）其中R 11，R 12，R 13和R 14各自独立地为取代或未取代的C 1 -C 4烃基或氢; R 15，R 16，R 17和R 18为各自独立地为取代或未取代的C1至C4烃基或氢; R19为C1至C20取代或未取代的烃基或氢; z为1至约5; m为1至约5; PO为包含10至4000个碳原子的聚烯烃烃基; n为1至约10,000。

8. 发明申请

WO2009155517A8 OLEFIN FUNCTIONALIZATION BY METATHESIS REACTION 审中-公开
标题翻译：烯烃反应的烯烃功能化
公开(公告)号：WO2009155517A8
公开(公告)日：2011-03-24
申请号：PCT/US2009047953
申请日：2009-06-19
申请人： EXXONMOBIL CHEM PATENTS INC , HAGADORN JOHN R , HOLTCAMP MATTHEW W , NARVAEZ ANDREW G , CROWTHER DONNA J , BRANT PATRICK
发明人： HAGADORN JOHN R , HOLTCAMP MATTHEW W , NARVAEZ ANDREW G , CROWTHER DONNA J , BRANT PATRICK
IPC分类号： C08F10/06 , C08F4/64 , C08F10/02
CPC分类号： C08F210/06 , C08F210/16 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol% propylene and 10 to 90 mol% of ethylene, wherein the oligomer has at least X% allyl chain ends, where: 1) X = (-0.94 (mole% ethylene incorporated) + 100), when 10 to 60 mole% ethylene is present in the co-oligomer, and 2) X = 45, when greater than 60 and less than 70 mole% ethylene is present in the co-oligomer, and 3) X = (1.83* (mole% ethylene incorporated) -83), when 70 to 90 mole% ethylene is present in the co-oligomer. This invention also relates to a process to functionalize propylene homo-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8: 1 to 1.2: 1.0, and less than 100 ppm aluminum.
摘要翻译：本发明涉及官能化丙烯共聚低聚物的方法，包括使烯烃复分解催化剂与含杂原子的烯烃接触，以及丙烯，共聚低聚物，其Mn为300至30,000g / mol，包含10至90mol％的丙烯和10 至90mol％的乙烯，其中所述低聚物具有至少X％的烯丙基链端，其中：1）X =（ - 0.94（摩尔％乙烯掺入）+ 100），当共聚物中存在10至60摩尔％的乙烯 - 低聚物，和2）X = 45，当共聚物中存在大于60且小于70摩尔％的乙烯时，和3）X =（1.83 *（摩尔％乙烯加入）-83），当70〜共聚低聚物中存在90摩尔％的乙烯。本发明还涉及使丙烯均聚物低聚物官能化的方法，包括使烯烃复分解催化剂与含杂原子的烯烃和包含丙烯的丙烯均聚物接触，其中低聚物具有：至少93％的烯丙基链端，Mn 约500至约20,000g / mol，异丁基链端至烯丙基乙烯基的比例为0.8:1至1.2:1.0，低于100ppm的铝。

9. 发明申请

WO2012027139A3 FUNCTIONALIZABLE SYNTHETIC HYDROCARBON FLUIDS AND INTEGRATED METHOD OF FOR PRODUCTION THEREOF 审中-公开
标题翻译：可合成的合成碳氢化合物及其生产方法
公开(公告)号：WO2012027139A3
公开(公告)日：2012-05-10
申请号：PCT/US2011047641
申请日：2011-08-12
申请人： EXXONMOBIL CHEM PATENTS INC , HOLTCAMP MATTHEW W , HAGADORN JOHN R , BEDOYA MATTHEW S
发明人： HOLTCAMP MATTHEW W , HAGADORN JOHN R , BEDOYA MATTHEW S
IPC分类号： C08F10/00 , C08F4/52 , C08F4/60 , C08F10/14 , C08F210/00
CPC分类号： C08F236/20 , C08C2019/09 , C08F4/65908 , C08F210/14 , C08F4/65927 , C08F2500/17
摘要： This invention relates to a process to produce a poly(alpha-olefin)(alpha, internally unsaturated, nonconjugated olefin) comprising: contacting at least one renewable feedstream with at least one lower olefin in the presence of a metathesis catalyst, wherein a mixture of at least one C4 to C40 linear alpha-olefm and at least one alpha, internally unsaturated, nonconjugated olefin is produced; and contacting the mixture with a metallocene catalyst system, wherein a poly(alpha-olefm)(alpha, internally unsaturated, nonconjugated olefin) is produced.
摘要翻译：本发明涉及一种生产聚（α-烯烃）（α，内部不饱和的非共轭烯烃）的方法，包括：在复分解催化剂存在下使至少一种可再生的原料流与至少一种低级烯烃接触，其中将产生至少一种C 4至C 40直链α-烯烃和至少一种α内部不饱和非共轭烯烃; 并使该混合物与金属茂催化剂体系接触，其中制备聚（α-烯烃）（α，内部不饱和的非共轭烯烃）。

10. 发明申请

WO2011100022A3 METATHESIS CATALYST AND PROCESS FOR USE THEREOF 审中-公开
标题翻译： METATHESIS催化剂及其使用方法
公开(公告)号：WO2011100022A3
公开(公告)日：2011-11-17
申请号：PCT/US2010059703
申请日：2010-12-09
申请人： EXXONMOBIL CHEM PATENTS INC , HOLTCAMP MATTHEW W , FALER CATHERINE A , HUFF CAOL P , BEDOYA MATTHEW S , HAGADORN JOHN R
发明人： HOLTCAMP MATTHEW W , FALER CATHERINE A , HUFF CAOL P , BEDOYA MATTHEW S , HAGADORN JOHN R
IPC分类号： B01J31/22 , C07B37/00 , C07C6/06 , C07C11/02 , C07F15/00
CPC分类号： C07F15/0046 , B01J31/2208 , B01J31/2252 , B01J31/2273 , B01J31/2278 , B01J2231/543 , B01J2531/821 , B01J2540/22 , C07C6/04 , C07C67/03 , C07C67/333 , C07C2531/24 , C11C3/00 , Y02E50/13 , C07C11/02 , C07C69/52 , C07C69/533
摘要： This invention relates to a catalyst compound for the metathesis of olefins represented by the formula (I): wherein M is a Group 8 metal; X and X1 are anionic ligands; L is a neutral two electron donor; L1 is N, O, P, or S, preferably N or O; R is a C1 to C30 hydrocarbyl or a C1 to C30 substituted hydrocarbyl; G* is selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; R1 is selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; and G is independently selected from the group consisting of hydrogen, halogen, C1 to C30 hydrocarbyls and C1 to C30 substituted hydrocarbyls. This invention also relates to process to make alphaolefms comprising contacting an olefin, such as ethylene, with a feed oil containing a triacylglyceride (typically a fatty acid ester (such as methyl oleate)) with the catalyst compound described above. The fatty acid ester may be a fatty acid methyl ester derived from biodiesel.
摘要翻译：本发明涉及由式（I）表示的用于烯烃复分解的催化剂化合物：其中M是第8族金属; X和X1是阴离子配体; L是中性二电子给体; L1是N，O，P或S，优选N或O; R是C1至C30烃基或C1至C30取代的烃基; G *选自氢，C1至C30烃基和C1至C30取代的烃基; R1选自氢，C1至C30烃基和C1至C30取代的烃基; 并且G独立地选自氢，卤素，C 1至C 30烃基和C 1至C 30取代的烃基。本发明还涉及制备α-烯烃的方法，包括使烯烃如乙烯与含有三酰基甘油酯（通常为脂肪酸酯（如油酸甲酯））的进料油与上述催化剂化合物接触。脂肪酸酯可以是衍生自生物柴油的脂肪酸甲酯。

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