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1. 发明申请

WO2008124040A8 SOFT HETEROGENEOUS ISOTACTIC POLYROPLENE COMPOSITIONS 审中-公开
标题翻译：软异构异构聚异戊二烯组合物
公开(公告)号：WO2008124040A8
公开(公告)日：2009-02-19
申请号：PCT/US2008004352
申请日：2008-04-03
申请人： EXXONMOBIL CHEM PATENTS INC , DATTA SUDHIN , SIMS CHARLES L , JIANG PEIJUN , SAHNOUNE ABDELHADI , THURMAN DEREK W
发明人： DATTA SUDHIN , SIMS CHARLES L , JIANG PEIJUN , SAHNOUNE ABDELHADI , THURMAN DEREK W
IPC分类号： C08L23/10 , C08L23/14
CPC分类号： C08L23/10 , C08L23/142 , C08L2666/06
摘要： The present invention also discloses a heterogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C to 105° C, and wherein the Melt Flow Rate (MFR @ 230 C) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C, wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent.
摘要翻译：本发明还公开了一种非均相共混组合物，其包含： a）1重量％至99重量％的第一聚合物组分的共混物，其包含5重量％至35重量％的主要由α-烯烃衍生单元组成的第一聚合物组分和65重量％至95重量％来自全同立构聚丙烯序列的结晶度为0.1％至约25％的丙烯衍生单元的第一聚合物组分，熔点为45℃至105℃，并且其中熔体流动速率（MFR @ 230℃）为第一聚合物组分在300g / 10min至5000g / 10min之间b）1重量％至99重量％的包含全同立构聚丙烯的第二聚合物组分和全同立构丙烯的无规共聚物的共混物，其中共聚的共聚物中的α-烯烃的含量在第二聚合物组分的0.0％至9％之间，其中第二聚合物组分的熔点大于约110℃，其中第一聚合物组分具有小于1000ppm的反应产物由此产生分子降解剂的化学反应。

2. 发明申请

WO2004046214A3 MULTIPLE CATALYST SYSTEM FOR OLEFIN POLYMERIZATION AND POLYMERS PRODUCED THEREFROM 审中-公开
标题翻译：用于烯烃聚合的多元催化剂体系及其生产的聚合物
公开(公告)号：WO2004046214A3
公开(公告)日：2004-08-05
申请号：PCT/US0332910
申请日：2003-10-15
申请人： EXXONMOBIL CHEM PATENTS INC , JIANG PEIJUN , DEKMEZIAN ARMENAG , CANICH JO ANN M , SIMS CHARLES L , ABHARI RAMIN , GARCIA-FRANCO CESAR A , JOHNSRUD DAVID R
发明人： JIANG PEIJUN , DEKMEZIAN ARMENAG , CANICH JO ANN M , SIMS CHARLES L , ABHARI RAMIN , GARCIA-FRANCO CESAR A , JOHNSRUD DAVID R
IPC分类号： C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F210/06 , C08K5/01 , C08L57/02 , C09J123/10
CPC分类号： C09J123/12 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08L57/02 , C08L2666/02 , C09J5/00 , C09J7/20 , C09J123/10 , C09J2201/606 , C09J2201/622 , C09J2205/31 , C09J2401/006 , C09J2421/00 , C09J2423/006 , C09J2423/046 , C09J2423/106 , C09J2427/006 , C09J2433/00 , Y10S526/943 , C08F4/65904 , C08F2500/15 , C08F2500/05 , C08F2500/20 , C08F2500/17 , C08F2500/09 , C08F2500/12 , C08F236/20 , C08F2500/03 , C08F210/16 , C08F4/63904
摘要： This invention relates to a polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 15 mole % of ehtylene, where the polymer has: a) a Dot T-Peel of 1 Newton or more; and b) a branching index (g') of 0.95 or less measured at the Mz of the polymer; c) an Mw of 100,000 or less and to a continuous process to produce a branched olefin polymer comprising 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 5% or less under selected polymerization conditions; 2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% or more at the selected polymerization conditions; 3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, and, optionally one or more diolefins; 4) at a temperature of greater than 100°C; 5) at a residence time of 120 minutes or less; 6) wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 50:1; 7) wherein the activity of the catalyst components is at least 100 kilograms of polymer per gram of the catalyst components; and wherein at least 20% of the olefins are converted to polymer.
摘要翻译：本发明涉及包含一种或多种C 3至C 40烯烃，任选一种或多种二烯烃和小于15摩尔％乙炔的聚合物，其中聚合物具有：a）1tonton或更高的Dot T-Peel; 和b）在聚合物的Mz处测量的支化指数（g'）为0.95或更小; c）100,000或更小的Mw，以及产生支链烯烃聚合物的连续方法，包括：1）选择能够在所选聚合条件下产生Mw为100,000以下且结晶度为5％以下的聚合物的第一催化剂组分条件; 2）选择能够在选择的聚合条件下产生Mw为100,000以下且结晶度为20％以上的聚合物的第二催化剂成分; 3）在一种或多种活化剂存在下使催化剂组分与一种或多种C 3至C 40烯烃和任选的一种或多种二烯烃接触; 4）在大于100℃的温度下; 5）停留时间为120分钟以下; 6），其中第一催化剂与第二催化剂的比例为1:1至50:1; 7）其中催化剂组分的活性为每克催化剂组分至少100千克聚合物; 并且其中至少20％的烯烃转化为聚合物。

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