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    • 5. 发明申请
    • THF-BASED ELECTROLYTE FOR LOW TEMPERATURE PERFORMANCE IN PRIMARY LITHIUM BATTERIES
    • 用于初级锂离子电池低温性能的基于THF的电解质
    • WO2010014194A1
    • 2010-02-04
    • PCT/US2009/004340
    • 2009-07-27
    • EVEREADY BATTERY COMPANY, INC.HUANG, Weiwei
    • HUANG, Weiwei
    • H01M4/38H01M4/40H01M4/58H01M6/16
    • H01M6/164H01M4/38H01M4/382H01M4/40H01M4/405H01M4/581H01M4/5815H01M6/166H01M2300/0025H01M2300/0037H01M2300/004H01M2300/0091
    • An electrochemical cell (10) showing improved low temperature performance, said electrochemical cell comprises a cylindrical container (i2) having an open end; a top cover (14) sealing the open end; a jellyroll electrode assembly disposed inside of the container, the electrode assembly comprising: an anode (18) consisting essentially of lithium or a lithium-based alloy; a cathode (20) consisting of a mix comprising a conductor, a binder and at least 80 wt. % of iron disulfide coated onto a solid foil current collector (22); and a separator (26) disposed between the anode (18) and the cathode (20); and an electrolyte having a solvent blend consisting essentially of 10-95 wt.% of tetrahydrofuran and 5-90 wt% of 1, 3-dioxolane- and a solute selected from the group consisting of : lithium imide, lithium jodide and combinations thereof. Alternatively the electrolyte consists essentially of a solute dissolved in tetrahydrofuran, 1, 3-dioxolane and 1, 2 -dime thoxy ethane or the electrolyte has a solvent blend consisting essentially of 10-95 wt% of tetrahydrofuran-based solvent, 5-90 wt% of 1, 3-dioxolane and 0-40 wt% of 1, 2 -dime thoxy ethane and a solute selected from the group consisting of : lithium imide, lithium iodide and combinations thereof.
    • 一种显示改进的低温性能的电化学电池(10),所述电化学电池包括具有开口端的圆柱形容器(i2) 密封开口端的顶盖(14); 设置在容器内部的果冻电极组件,所述电极组件包括:主要由锂或锂基合金组成的阳极(18); 阴极(20)由包含导体,粘合剂和至少80wt。 涂覆在固体箔集电器(22)上的二硫化铁的%; 和设置在阳极(18)和阴极(20)之间的分离器(26)。 以及电解质,其具有基本上由10-95重量%四氢呋喃和5-90重量%1,3-二氧戊环和选自以下的溶质组成的溶剂混合物:酰亚胺锂,锂合金及其组合。 或者,电解质基本上由溶解在四氢呋喃,1,3-二氧戊环和1,2-二甲氧基乙烷中的溶质组成,或者电解质具有基本上由10-95重量%的四氢呋喃类溶剂组成的溶剂共混物,5-90重量% %的1,3-二氧戊环和0-40重量%的1,2-二羟基乙烷和选自以下的溶质:酰亚胺锂,碘化锂及其组合。