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    • 7. 发明申请
    • ELECTROPLATING CHEMISTRY FOR THE CU FILLING OF SUBMICRON FEATURES OF VLSI/ULSI INTERCONNECT
    • 电磁放电化学品用于填充VLSI / ULSI互连的次级特征
    • WO2002103751A2
    • 2002-12-27
    • PCT/US2001/042964
    • 2001-11-20
    • ENTHONE INC.
    • TOO, Elena, H.GERST, Paul, R.PANECCASIO, Vincent, Jr.HURTUBISE, Richard, W.
    • H01L
    • C25D3/38H05K3/423
    • A copper electroplating bath and a method to plate substrates with the bath are provided. The bath and method are particularly effective to plate electronic components such as semiconductive wafer VLSI and ULSI interconnects with void-free fill copper plating for circuitry forming vias and trenches and other small features less than 0.2 microns with high aspect ratios. The copper bath contains a bath soluble organic divalent sulfur compound, and a bath soluble polyether compound such as a block copolymer of polyoxyethylene and polyoxypropylene, a polyoxyethylene or polyoxypropylene derivative of a polyhydric alcohol and a mixed polyoxyethylene and polyoxypropylene derivative of a polyhydric alcohol. A preferred polyether compound is a mixed polyoxyethylene and polyoxypropylene derivative of glycerine. A preferred copper bath also contains a pyridine compound derivative.
    • 提供了一种铜电镀浴和一种用浴板对基片进行印版的方法。 该浴和方法特别有效地将诸如半导体晶片VLSI和ULSI互连的电子部件用无孔填充铜电镀形成用于形成通孔和沟槽的电路以及具有高纵横比的小于0.2微米的其它小特征。 铜浴含有可溶于水的有机二价硫化合物,以及诸如聚氧乙烯和聚氧丙烯的嵌段共聚物的浴溶性聚醚化合物,多元醇的聚氧乙烯或聚氧丙烯衍生物以及多元醇的混合聚氧乙烯和聚氧丙烯衍生物。 优选的聚醚化合物是甘油的混合聚氧乙烯和聚氧丙烯衍生物。 优选的铜浴还含有吡啶化合物衍生物。