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1. 发明申请

WO2008005209A3 METHOD OF PROVIDING REPELLENCY 审中-公开
公开(公告)号：WO2008005209A3
公开(公告)日：2008-01-10
申请号：PCT/US2007/014642
申请日：2007-06-22
申请人： E. I. DU PONT DE NEMOURS AND COMPANY , REINARTZ, Stefan , MURPHY, Peter, Michael , MCCALL, Andrew, Joseph , BROWN, Gerald, Oronde
发明人： REINARTZ, Stefan , MURPHY, Peter, Michael , MCCALL, Andrew, Joseph , BROWN, Gerald, Oronde
IPC分类号： D06M15/277 , D06M15/576 , C08F220/36
摘要： A method of providing water repellency, alcohol repellency, oil repellency, and soil resistance to substrates comprising contacting said substrate with a composition comprising a copolymer having repeating units of Formula 1 in any sequence: [R f (CH 2 ) k OC(O)NH(CH 2 ) k OC(O)C(T)CH 2 ] m -[W q ] p -, wherein R f is a straight or branched perfluoroalkyl group having from about 2 to about 8 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, each k is independently a positive integer from 1 to about 6, T is hydrogen or methyl, m is a positive integer, q is zero or a positive integer, p is zero or a positive integer, and W is (formula I) or (formula II) or -[R 1 -X-Y-C(O)-CZ-CH 2 ]-, wherein X is an organic divalent linking group having from about 1 to about 20 carbon atoms, optionally containing a triazole, oxygen, nitrogen, or sulfur, or a combination thereof, Y is O or N(R) wherein R is H or C 1 to C 20 alkyl, Z is H, a straight or branched alkyl group having from about 1 to about 4 carbon atoms, or halide, Rx is C(O)O(R 1 ), C(O)N(R 2 ) 2 , OC(O)(R 1 ), SO 2 (R 1 ), C 6 (R 3 ) g H (5-g) , O(R 1 ), halide, or R 1 ; each R 1 is independently H, C n H 2n+1 , C n H 2n -CH(O)CH 2 , [CH 2 CH 2 O] i R 4 , [C n C 2n ]N(R 4 ) 2 or [C n H 2n ]C n F 2n+1 , n is 1 to about 40, R 4 is H or C s H 2s+1 , s = 0 to about 40, i = 1 to about 200, each R 2 is independently H, or C t H 2t+1 wherein t is 1 to 20, each R 3 is independently R 4 , COOR 1 , halogen, N(R 1 ) 2 , OR 1 , SO 2 NHR 1 , CH=CH 2 , or SO 3 M, g is 1 to 5, and M is H, alkali metal salt, alkaline earth metal salt, or ammonium.

2. 发明申请

WO2009055561A1 HYDROPHILLIC FLUORINATED SOIL RESIST COPOLYMERS 审中-公开
标题翻译：亲水氟化土壤树脂共聚物
公开(公告)号：WO2009055561A1
公开(公告)日：2009-04-30
申请号：PCT/US2008/080947
申请日：2008-10-23
申请人： E. I. DU PONT DE NEMOURS AND COMPANY , MURPHY, Peter, Michael , REINARTZ, Stefan
发明人： MURPHY, Peter, Michael , REINARTZ, Stefan
IPC分类号： C08F214/18 , C08F220/06 , D06M15/256 , D06M15/263
CPC分类号： C08F214/186 , C08F214/18 , C08F220/06 , D06M15/263 , D06M15/277 , D06M15/576
摘要： A copolymer of Formula (I) -[R f Q-OC(O)NHC(CH 3 ) 2 C 6 H 4 C(CH 3 )CH 2 -] x - [CH 2 C(R)(COOH)-] y - (I) wherein R f is a straight or branched perfluoroalkyl group having from about 2 to about 8 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, Q is alkylene of 1 to about 15 carbon atoms, hydroxyalkylene of from about 2 to about 15 carbon atoms, -0(C n H 2n )-, -(CH 2 CF 2 ) m (CH2) n -, -OCHFCF 2 (CH 2 ) n -, -CONR 1 (C n H 2n )-, -(C n H 2n )OCONR 1 (C n H 2n )-, (-CONR 1 CH 2 ) 2 CH-, -SO 2 N(R 1 )(C n H 2n )-, or -(C n H 2n )SO 2 N(R 1 )(C n H 2n )-, each R 1 is independently H or alkyl of 1 to about 4 carbon atoms, each n is independently 1 to about 15, each m is independently 1 to about 4, and R is H or CH 3 , x is a positive integer, and y is a positive integer, and a method of its use for imparting soil resistance to substrates while imparting minimal water repellency is disclosed.
摘要翻译：式（I） - [RfQ-OC（O）NHC（CH3）2C6H4C（CH3）CH2-] x - [CH2C（R）（COOH） - ] y-（Ⅰ）的共聚物，其中Rf是直链或支链具有约2至约8个碳原子的全氟烷基或其混合物，其任选被至少一个氧原子间隔，Q为1至约15个碳原子的亚烷基，约2至约15个碳原子的羟基亚烷基，（C n H 2n） - ， - （CH 2 CF 2）m（CH 2）n - ， - OCH 2 F 2 F（CH 2）n - ， - CONR 1（C n H 2n） - ， - （C n H 2n） -SO 2 N（R 1）（C n H 2n） - 或 - （C n H 2n）SO 2 N（R 1）（C n H 2n） - ，每个R 1独立地为H或1至约4个碳原子的烷基，每个n独立地为1至约15，独立地为1〜约4，R为H或CH 3，x为正整数，y为正整数，并公开了赋予基材耐污性的方法，同时具有极小的防水性。

3. 发明申请

WO2006066026A1 DURABLE COATING COMPOSITIONS CONTAINING NOVEL ASPARTIC AMINE COMPOUNDS 审中-公开
标题翻译：含有新型氨基甲酸酯化合物的耐久涂料组合物
公开(公告)号：WO2006066026A1
公开(公告)日：2006-06-22
申请号：PCT/US2005/045474
申请日：2005-12-15
申请人： E. I. DU PONT DE NEMOURS AND COMPANY , LENGES, Christian, Peter , BARSOTTI, Domenic, J. , BARSOTTI, Robert, John , DOGRA, Kalindi , LU, Helen, S. M. , REINARTZ, Stefan , ALLGEIER, Alan, Martin , CORCORAN, Patrick, Henry
发明人： LENGES, Christian, Peter , BARSOTTI, Domenic, J. , BARSOTTI, Robert, John , DOGRA, Kalindi , LU, Helen, S. M. , REINARTZ, Stefan , ALLGEIER, Alan, Martin , CORCORAN, Patrick, Henry
IPC分类号： C08G18/38 , C09D175/04
CPC分类号： C09D175/04 , C08G18/3821
摘要： A coating composition comprising a binder of a. polyisocyanate crosslinking agent; b. an isocyanate-reactive component having at least one compound having the following formula: (I) wherein X, R 1 , R 2 , p, m and n are described in the specification, or isomer or mixture of isomers thereof, two component compositions, articles coated with the novel composition and novel hydroxy amines are also part of the invention.
摘要翻译：一种涂料组合物，其包含a。多异氰酸酯交联剂; 湾具有至少一种具有下式的化合物的异氰酸酯反应性组分：（I）其中X，R 1，R 2，p，m和n在规格或异构体或其异构体混合物，双组分组合物，用新组合物和新型羟基胺包被的制品也是本发明的一部分。

4. 发明申请

WO2008118494A2 FLUOROALKYL SURFACTANTS 审中-公开
标题翻译：荧光素表面活性剂
公开(公告)号：WO2008118494A2
公开(公告)日：2008-10-02
申请号：PCT/US2008/004080
申请日：2008-03-27
申请人： E. I. DU PONT DE NEMOURS AND COMPANY , ACOSTA, Erick, Jose , REINARTZ, Stefan
发明人： ACOSTA, Erick, Jose , REINARTZ, Stefan
IPC分类号： C07C229/08 , C07C229/12 , C07C229/24 , C08K5/17 , C08K5/19
CPC分类号： B01F17/0035 , C07C229/08 , C07C229/12 , C07C229/24 , C08K5/17
摘要： A composition of formula (I) wherein m and d are each independently an integer of 1 or 2; n is independently O or 1;each R is independently hydrogen or a C 1 to C 4 alkyl group; A is independently hydrogen or -C(O)-O-B;R o is a linear, branched or cyclic aliphatic group, or combination thereof, having from about 2 to about 100 carbon atoms, interrupted or substituted by 1 to about 50 hydrophilic groups, said hydrophilic groups selected from the group consisting of hydroxyl, amino, ether and mixtures thereof; wherein the ratio of hydrophilic groups to carbon atoms is from about 1 :1.1 to about 1 : 10, each carbon atom has at most one hydrophilic group bonded to it, and covalent bonding between hydrophilic groups is absent; each B is independently a monovalent group of formula (IIa), (IIb) or (IIc): (IIa) R f 1 (CH 2 ) t (R) r- (lib) R f 2 (CH 2 CF 2 )p(CH 2 CH 2 ) q (R 1 ) r- (lie) R f 3 O(CF 2 CF 2 )p(CH 2 CH 2 )q(R 1 ) r- wherein each of R f 1 and R f 2 are C 1 - C 6 linear or branched perfluoroalkyl; R f 3 is a C 1 to C 7 linear or branched perfluoroalkyl group, optionally interrupted by one, two or three ether oxygen atoms; t is an integer of 1 to about 10; p and q are each independently integers of 1 to about 3; r is 0 or 1; R1 is a divalent radical selected from -S(CH 2 )r; and provided that when m is 1, n is 1; when m is 2, n is 0, A is hydrogen, and d is 1; and when d is 2, m is 1, A is -C(O)-O-B, R 0 has at least three carbon atoms, and nitrogens and hydrophilic groups are bonded to different carbon atoms, and its use as a surfactant is disclosed.
摘要翻译：式（I）的组合物，其中m和d各自独立地为1或2的整数; n独立地为O或1;每个R独立地为氢或C 1至C 4烷基; A独立地是氢或-C（O）-O-B; R o O

5. 发明申请

WO2006066031A1 DURABLE COATING COMPOSITIONS CONTAINING NOVEL ASPARTIC AMINE COMPOUNDS 审中-公开
标题翻译：含有新型氨基甲酸酯化合物的耐久涂料组合物
公开(公告)号：WO2006066031A1
公开(公告)日：2006-06-22
申请号：PCT/US2005/045480
申请日：2005-12-15
申请人： E. I. DU PONT DE NEMOURS AND COMPANY , LENGES, Christian, Peter , BARSOTTI, Domenic, J. , BARSOTTI, Robert, John , DOGRA, Kalindi , LU, Helen, S., M. , REINARTZ, Stefan
发明人： LENGES, Christian, Peter , BARSOTTI, Domenic, J. , BARSOTTI, Robert, John , DOGRA, Kalindi , LU, Helen, S., M. , REINARTZ, Stefan
IPC分类号： C07C233/82 , C08G18/38 , C09D175/02
CPC分类号： C07C237/06 , C07C2601/14 , C07C2602/42 , C08G18/3821 , C08G18/3844 , C09D175/02
摘要： A coating composition comprising a binder of a. polyisocyanate crosslinking agent; b. an isocyanate-reactive component having at least one compound having the following formula (I) including isomers and mixtures of isomers thereof: (I) wherein R, R 1 , R 2 , X, Y, Z, m, n, p, q, r and s are described in the specification and a two component composition formulated with the above constituents and substrates, such as, automotive and truck bodies and parts coated with the novel composition and novel amine and/or hydroxy amine compounds are also part of the invention.
摘要翻译：一种涂料组合物，其包含a。多异氰酸酯交联剂; 湾具有至少一种具有下列通式（I）的化合物的异氰酸酯反应性组分，包括异构体及其异构体的混合物：（I）其中R，R 1，R 2，在说明书中描述了X，Y，Z，m，n，p，q，r和s，并且用上述组分和底物配制的双组分组合物，例如汽车和卡车体以及涂有新组合物的部件并且新的胺和/或羟基胺化合物也是本发明的一部分。

6. 发明申请

WO2006076724A2 DURABLE COATING COMPOSITIONS CONTAINING ASPARTIC AMINE COMPOUNDS WITH IMPROVED POTLIFE 审中-公开
标题翻译：含有具有改进的糊精的氨基甲酸酯化合物的耐久涂料组合物
公开(公告)号：WO2006076724A2
公开(公告)日：2006-07-20
申请号：PCT/US2006/001635
申请日：2006-01-13
申请人： E.I. DUPONT DE NEMOURS AND COMPANY , REINARTZ, Stefan , BARSOTTI, Robert, John , CORCORAN, Patrick, Henry , DOGRA, Kalindi , LENGES, Christian, Peter , LEWIN, Laura, Ann , WISSING, Klaus
发明人： REINARTZ, Stefan , BARSOTTI, Robert, John , CORCORAN, Patrick, Henry , DOGRA, Kalindi , LENGES, Christian, Peter , LEWIN, Laura, Ann , WISSING, Klaus
CPC分类号： C08G18/3821 , C08G18/0823 , C08G18/3228 , C08G18/346 , C08G18/792 , C09D175/02 , Y10T428/31551 , Y10T428/31605
摘要： A coating composition useful for coating automobile and truck bodies comprising a binder of: a. polyisocyanate crosslinking agent; b. an isocyanate-reactive component having at least one compound having the following formula: (I) wherein X, Y, R 1 , R 2 , m and n are described in the specification, and c. 0.05 to 10 % by weight, based on the total weight of the coating composition, of a metal alkoxide compound; and containing optional additional polymeric components, oligomeric components and antioxidants, light absorbers and light stabilizers.
摘要翻译：用于涂覆汽车和卡车车身的涂料组合物，其包含以下粘合剂：a。多异氰酸酯交联剂; 湾具有至少一种具有下式的化合物的异氰酸酯反应性组分：（I）其中X，Y，R 1，R 2，m和n在规格和c。 0.05至10重量％，基于涂料组合物的总重量;金属醇盐化合物; 并含有任选的另外的聚合物组分，低聚组分和抗氧化剂，光吸收剂和光稳定剂。

7. 发明申请

WO2004058777A1 TITANIUM CENTERED CATALYSTS FOR THE LIVING POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于生物聚合烯烃的钛中心催化剂
公开(公告)号：WO2004058777A1
公开(公告)日：2004-07-15
申请号：PCT/US2002/037616
申请日：2002-12-19
申请人： CORNELL RESEARCH FOUNDATION, INC. , COATES, Geoffrey, W. , REINARTZ, Stefan , MASON, Andrew, F.
发明人： COATES, Geoffrey, W. , REINARTZ, Stefan , MASON, Andrew, F.
IPC分类号： C07F7/28
CPC分类号： C08F10/00 , C07F7/006 , C08F4/65908 , C08F4/65912 , C08F110/02 , C08F4/659 , C08F4/64048 , C08F2500/03
摘要： Catalysts for the living; polymerization of α-olefins are phenoxyketimine compounds with titanium centers. The phenoxyketimine compounds are prepared by Friedel Crafts acylation of a phenol with imidoyl chloride in the presence of a Lewis acid to form phenoxyketimine ligand, and deprotonating the ligand and reacting with TiC1 4 , or by reacting with TiBz 4 .
摘要翻译：生活催化剂 α-烯烃的聚合是具有钛中心的苯氧基亚胺化合物。苯氧基亚胺化合物通过Friedel Crafts在路易斯酸存在下用亚氨酰氯酰化苯酚制备，形成苯氧基酮亚胺配体，并使配体去质子化并与TiCl 4反应，或与TiBz4反应。

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