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1. 发明申请

WO2010007061A1 WATERBASED FORMALDEHYDE FREE ADHESIVES 审中-公开
标题翻译：含水甲醛免费粘合剂
公开(公告)号：WO2010007061A1
公开(公告)日：2010-01-21
申请号：PCT/EP2009/058988
申请日：2009-07-14
申请人： DSM IP ASSETS B.V. , TENNEBROEK, Ronald , OVERBEEK, Gerardus, Cornelis , SLOT, VAN DER, Saskia, Carolien , AABICH, Mourad , ZAMBEEK, Marcel
发明人： TENNEBROEK, Ronald , OVERBEEK, Gerardus, Cornelis , SLOT, VAN DER, Saskia, Carolien , AABICH, Mourad , ZAMBEEK, Marcel
IPC分类号： C08G18/08 , C08G18/12 , C09J175/04 , C08L33/12
CPC分类号： C08G18/0823 , B32B7/12 , B32B21/08 , B32B21/14 , B32B27/40 , B32B2307/414 , B32B2307/7265 , B32B2405/00 , C08G18/12 , C08G18/4854 , C08G18/6692 , C08G18/755 , C08L2666/04 , C09J175/04 , Y10T156/1043 , Y10T428/31551 , C08G18/3231
摘要： There is described a formaldehyde-free laminating adhesive, optionally the with less than 3% by weight of co-solvent(s), the adhesive comprising: (I) a polyurethane that comprises from 30 % to 65 % by weight of hard segments, the polyurethane being obtained and/or obtainable from a first polyurethane dispersion (PUD) comprising the reaction product of (A) an organic isocyanate and (B) at least one chain extender reacting in a respective stoichiometric ratio (NCO to NCO reactive group) from 1:1 to 1:2.5 and; optionally the NCO reactive group(s) of the chain extender comprises one or more hydrazinyl-like group(s) (denoting isocyanate reactive groups selected from the group comprising, preferably consisting of: -NRNR 2 (hydrazinyl groups); -CONRNR 2 (hydrazidyl groups), -NRCONRNR 2 (semicarbazidyl groups); and -ONR 2 (oxyamine groups), where each R is independently selected from H or C 1-10 hydrocarbo); and (II) optionally a second polymer obtained and/or obtainable from a polymer precursor comprising at least one unsaturated moiety, preferably an ethylenically unsaturated group, and where optionally the second polymer may be iminated; with the provisos that: (α) when the first polyurethane does not comprise hydrazinyl-like group(s) then the second polymer is iminated; and (β) when the second polymer is un-iminated or is absent then the first polyurethane comprises hydrazinyl-like group(s). These adhesives may be used to adhere surface veneers to wood and/or to laminate the layers within plywood.
摘要翻译：描述了不含甲醛的层压粘合剂，任选地具有小于3重量％的助溶剂，粘合剂包含：（I）包含30重量％至65重量％硬链段的聚氨酯，所述聚氨酯由包含（A）有机异氰酸酯和（B）至少一种以相应的化学计量比（NCO至NCO反应性基团）反应的至少一种扩链剂的反应产物的第一聚氨酯分散体（PUD）获得和/或获得， 1：1至1：2.5和; 任选地，扩链剂的NCO反应性基团包含一个或多个肼基 - 类基团（表示选自以下的异氰酸酯反应性基团：优选由以下基团组成：-NRNR2（腙基）; -CONRNR2（肼基），-NRCONRNR2（氨基脲基）;和-ONR2（羟胺基），其中每个R独立地选自H或C1-10氢化碳基）; 和（II）任选的第二聚合物，其由包含至少一个不饱和部分，优选烯键式不饱和基团的聚合物前体获得和/或可获得，并且其中任选地第二聚合物可以被亚胺化; 条件是：（a）当第一聚氨酯不包含肼基 - 类基团时，则第二聚合物被亚胺化; 和（ß），当第二聚合物未被或不存在时，第一聚氨酯包含类似肼基的基团。这些粘合剂可以用于将表面胶合板粘附到木材上和/或将胶层层压在胶合板中。

2. 发明申请

WO2005058995A1 STAIN RESISTANT URETHANE-VINYL AQUEOUS COATING COMPOSITIONS 审中-公开
标题翻译：耐腐蚀URETHANE-VINYL水性涂料组合物
公开(公告)号：WO2005058995A1
公开(公告)日：2005-06-30
申请号：PCT/GB2004/005227
申请日：2004-12-14
申请人： AVECIA BV , DSM IP ASSETS B.V. , SATGURUNATHAN, Rajasingham , OVERBEEK, Gerardus, Cornelis , ROELANDS, Marc , TENNEBROEK, Ronald , SWAANS, Roel, Johannes, Marinus , ROESCHER, Gerhardus, Antonius
发明人： SATGURUNATHAN, Rajasingham , OVERBEEK, Gerardus, Cornelis , ROELANDS, Marc , TENNEBROEK, Ronald , SWAANS, Roel, Johannes, Marinus , ROESCHER, Gerhardus, Antonius
IPC分类号： C08G18/12
CPC分类号： C08G18/12 , C08G18/423 , C08G18/6216 , C08G18/6275 , C08G18/6659 , C08L33/00 , C09D175/06 , C08G18/3231 , C08L2666/04
摘要： An aqueous coating composition, which when in the form of a film exhibits an MVTR of ≤ 500g/m 2 /24h comprising 20 to 80 wt% of a polyurethane A with an acid value of 8 to 40mg KOH/g and a hard segment content ≥ 40wt%, a ring structure content ≥ 48 wt% and 80 to 20 wt% of a vinyl polymer B with a Tg ≥ 20°C.
摘要翻译：一种水性涂料组合物，当其呈薄膜形式时，MVTR为<= 500G / M 2 / 24h，包含20-80wt％的酸值为8至40mg KOH / g的聚氨酯A和硬链段含量≥40wt％，环结构含量≥48wt％，Tg> = 20℃的乙烯基聚合物B为80〜20wt％。

3. 发明申请

WO2009121887A1 AQUEOUS AUTOXIDISABLE POLYESTER COATING COMPOSITION 审中-公开
标题翻译： AQUEOUS可自动氧化聚酯涂料组合物
公开(公告)号：WO2009121887A1
公开(公告)日：2009-10-08
申请号：PCT/EP2009/053822
申请日：2009-03-31
申请人： DSM IP ASSETS BV , TENNEBROEK, Ronald , OVERBEEK, Gerardus Cornelis , BERGMAN, Franciscus Adrianus Cornelis , AABICH, Mourad , COOGAN, Richard George , SWAANS, Roel Johannes Marinus
发明人： TENNEBROEK, Ronald , OVERBEEK, Gerardus Cornelis , BERGMAN, Franciscus Adrianus Cornelis , AABICH, Mourad , COOGAN, Richard George , SWAANS, Roel Johannes Marinus
IPC分类号： C08L67/08 , C08L77/12 , C09D167/08
CPC分类号： C09D133/14 , C08G18/283 , C08G18/4211 , C08G18/423 , C08G18/4233 , C08G18/606 , C08G18/755 , C09D167/08 , C09D175/04 , C09D177/12 , Y10T428/31511
摘要： An aqueous coating composition comprising an autoxidisable polyester resin having ≥ 30 wt% of fatty acid residues; a Tg in the range of from -60 °C to +35 °C; an acid value greater than 15 mg KOH/g and less than 75 mg KOH/g; a Mw in the range of from 2,500 to 100,000 g/mol; said composition having a co-solvent content less that 15 wt% by weight of total composition; a solids content > 30 wt%; and when a film, a telegraphing value of less than 20 gloss units.
摘要翻译：一种水性涂料组合物，其包含具有= 30重量％脂肪酸残基的可自动氧化的聚酯树脂; 在-60℃至+35℃范围内的Tg; 酸值大于15mg KOH / g且小于75mg KOH / g; 在2500至100,000g / mol范围内的Mw; 所述组合物的共溶剂含量小于总组合物的15重量％; 固体含量> 30wt％; 而当一部电影，电报值小于20光泽单位。

4. 发明申请

WO2003082999A1 AQUEOUS COATING COMPOSITION COMPRISING NON-CROSSLINKABLE OLIGOMERS(S) AND DISPERSED POLYMERS(S) 审中-公开
标题翻译：包含不可交联的低聚物（S）和分散聚合物（S）的水性涂料组合物
公开(公告)号：WO2003082999A1
公开(公告)日：2003-10-09
申请号：PCT/GB2003/001215
申请日：2003-03-21
申请人： AVECIA BV , AVECIA LIMITED , MARTIN, Emilio , SCHEERDER, Jurgen , OVERBEEK, Gerardus, Cornelis , TENNEBROEK, Ronald , NABUURS, Tijs , STEENWINKEL, Pablo
发明人： MARTIN, Emilio , SCHEERDER, Jurgen , OVERBEEK, Gerardus, Cornelis , TENNEBROEK, Ronald , NABUURS, Tijs , STEENWINKEL, Pablo
IPC分类号： C09D201/00
CPC分类号： C09D167/00 , C09D175/04 , C08L2666/04
摘要： An aqueous coating composition comprising a non-crosslinkable water-dispersible oligomer(s); a dispersed polymer(s); water and optionally co-solvent wherein the composition has an open time of at least 20 min; a wet edge time of at least 10 min; a tack free time of ≤ 24 hours and an equilibrium viscosity of 5,000 Pa.s.
摘要翻译：一种包含不可交联的水分散性低聚物的水性涂料组合物; 分散的聚合物; 水和任选的共溶剂，其中组合物的开放时间为至少20分钟; 湿边缘时间至少为10分钟; 无粘性时间<= 24小时，平衡粘度为5000帕。

5. 发明申请

WO2006002864A1 LOW NMP AQUEOUS POLYURETHANE COMPOSITION WITH A REACTIVE DILUENT 审中-公开
标题翻译：低NMP水性聚氨酯组合物与反应性稀释剂
公开(公告)号：WO2006002864A1
公开(公告)日：2006-01-12
申请号：PCT/EP2005/006932
申请日：2005-06-28
申请人： DSM IP ASSETS BV , VAN CASTEREN, Ilse , ROELANDS, Marc , OVERBEEK, Gerardus, Cornelis , COOGAN, Richard, George , TENNEBROEK, Ronald , KUZMIN, Ann
发明人： VAN CASTEREN, Ilse , ROELANDS, Marc , OVERBEEK, Gerardus, Cornelis , COOGAN, Richard, George , TENNEBROEK, Ronald , KUZMIN, Ann
IPC分类号： C08G18/08
CPC分类号： C08G18/0852 , C08G18/0823 , C08G18/12 , C08G18/283 , C08G18/6692 , C08G18/724 , C08G18/7607 , C08L33/10 , C09D175/04 , Y10T428/31591 , Y10T428/31601 , Y10T428/31609 , Y10T428/31678 , Y10T428/31989 , C08G18/3231 , C08L2666/04
摘要： An aqueous composition comprising a polyurethane dispersion with a sediment content ≤ 5%, wherein the polyurethane has an acid value in the range of from 25 to 65 mgKOH/g and comprises (i) 36 to 60 wt% of at least one aromatic polyisocyanate and where the polyurethane is prepared in the presence of (a) ≤ 5 wt% of 1-methyl-2-pyrrolidinone by weight of the polyurethane and (b) at least one reactive diluent.
摘要翻译：一种水性组合物，其包含沉降物含量= 5％的聚氨酯分散体，其中所述聚氨酯的酸值在25至65mgKOH / g范围内，并且包含（i）36至60重量％的至少一种芳族多异氰酸酯和其中聚氨酯在（a）= 5重量％的1-甲基-2-吡咯烷酮存在下由聚氨酯重量和（b）至少一种反应性稀释剂制备。

6. 发明申请

WO2009121891A1 COATING COMPOSITION COMPRISING AUTOXIDISABLE COMPONENT 审中-公开
标题翻译：包含可自动化组分的涂料组合物
公开(公告)号：WO2009121891A1
公开(公告)日：2009-10-08
申请号：PCT/EP2009/053829
申请日：2009-03-31
申请人： DSM IP ASSETS BV , CASTEREN, VAN, Ilse , OVERBEEK, Gerardus Cornelis , TENNEBROEK, Ronald
发明人： CASTEREN, VAN, Ilse , OVERBEEK, Gerardus Cornelis , TENNEBROEK, Ronald
IPC分类号： C08F8/14 , C08F20/28 , C08F20/32 , C09D133/14 , C08F8/06 , C08J3/24 , C08J3/05
CPC分类号： C09D137/00 , C08F8/14 , C08F8/44 , C08F120/06 , C08F212/08 , C08F220/28 , C08F220/32 , C08F2220/325 , C08F2810/30 , C08F2810/50 , C08J5/18 , C09D139/06 , Y10T428/31938
摘要： An aqueous emulsion coating composition comprising an autoxidisable vinyl oligomer having ≥ 20 wt% of unsaturated fatty acid residue; Tg from - 50 to + 15 °C; Mw from 2,500 to 40,000 g/mol; polydispersity from 2 to 12, said composition having ≤ 15% co-solvent by weight of solids, ≤13% NMP by weight of solids ≥ 38% solids by weight of composition; said composition when in the form of a coating having a telegraphing value defined as the difference in gloss at a 20° angle of between a film cast on rough PVC and a film cast on smooth PVC of 10 gloss units.
摘要翻译：一种水乳液涂料组合物，其包含具有= 20重量％的不饱和脂肪酸残基的可自动氧化的乙烯基低聚物; Tg为-50〜+ 15℃; Mw为2,500至40,000g / mol; 多分散性为2至12，所述组合物具有= 15重量％固体重量的共溶剂，= 13重量％固体的固体重量=组合物重量的38重量％所述组合物当以具有透光值形式的涂层的形式时，所述透射值定义为在粗糙PVC上铸造的膜和在10个光泽单元的光滑PVC上铸造的膜之间的20°角的光泽差。

7. 发明申请

WO2009121889A1 COATING COMPOSITION COMPRISING AUTOXIDISABLE COMPONENT 审中-公开
标题翻译：包含可自动化组分的涂料组合物
公开(公告)号：WO2009121889A1
公开(公告)日：2009-10-08
申请号：PCT/EP2009/053824
申请日：2009-03-31
申请人： DSM IP ASSETS BV , CASTEREN, VAN, Ilse , OVERBEEK, Gerardus Cornelis , TENNEBROEK, Ronald , NABUURS, Tijs , COOGAN, Richard George
发明人： CASTEREN, VAN, Ilse , OVERBEEK, Gerardus Cornelis , TENNEBROEK, Ronald , NABUURS, Tijs , COOGAN, Richard George
IPC分类号： C08L67/08 , C08L77/12 , C09D167/08
CPC分类号： C09D133/14 , C08G18/283 , C08G18/4211 , C08G18/423 , C08G18/4233 , C08G18/606 , C08G18/755 , C09D167/08 , C09D175/04 , C09D177/12 , Y10T428/31511
摘要： An aqueous solution coating composition comprising an autoxidisable polyvinyl polymer having ≥ 20% of fatty acid residue by weight of polymer; T g from -60 to + 15°C; acid value of 15 to 75 mg KOH / g, M w from 2500 to 100000 g/mol; polydispersity ≤ 30, said composition having ≤ 25% co-solvent by weight of solids, ≥30% solids by weight of composition; said composition when in the form of a coating having a telegraphing value defined as the difference in gloss at a 20° angle of between a film cast on rough PVC and a film cast on smooth PVC of 10 gloss units.
摘要翻译：一种水溶液涂料组合物，其包含具有20重量％聚合物脂肪酸残基的可自动氧化的聚乙烯基聚合物; Tg从-60到+ 15℃; 酸值为15至75mg KOH / g，Mw为2500至100000g / mol; 多分散性= 30，所述组合物具有= 25重量％的固体重量的共溶剂，=组合物的30重量％固体; 所述组合物当以具有透光值形式的涂层的形式时，所述透射值定义为在粗糙PVC上铸造的膜和在10个光泽单元的光滑PVC上铸造的膜之间的20°角的光泽差。

8. 发明申请

WO2009121892A1 COATING COMPOSITION COMPRISING AUTOXIDISABLE COMPONENT 审中-公开
标题翻译：包含可自动化组分的涂料组合物
公开(公告)号：WO2009121892A1
公开(公告)日：2009-10-08
申请号：PCT/EP2009/053830
申请日：2009-03-31
申请人： DSM IP ASSETS BV , OVERBEEK, Gerardus Cornelis , CASTEREN, VAN, Ilse , TENNEBROEK, Ronald , WERF, VAN DER, Jelle Bernardus Otto
发明人： OVERBEEK, Gerardus Cornelis , CASTEREN, VAN, Ilse , TENNEBROEK, Ronald , WERF, VAN DER, Jelle Bernardus Otto
IPC分类号： C08F8/14 , C08F20/28 , C09D133/14 , C08F8/06 , C08J3/24
CPC分类号： C09D133/14 , C08F8/14 , C08F8/44 , C08F220/28 , C08F220/32 , C08F2810/30 , C08F2810/50 , C09D133/068 , Y10T428/31855 , C08F120/06 , C08F2220/325 , C08F220/14 , C08F2220/1825 , C08F212/08
摘要： There is described (pref. non-adhesive) coating compositions (which may be either water or solvent borne) that comprise an autoxidisable vinyl polymer, the autoxidisable polymer having a vinyl polymer backbone 25% to 75% by wt of the autoxidisable polymer; fatty acid residue 25% to 75% by wt of the autoxidisable polymer; T g from -6O°C to +2O°C, M w from 3500 to 50000 g/mol; and polydispersity from 2 to 10; the autoxidisable polymer obtained by a process of: (A) polymerising ethylenically unsaturated vinyl monomers comprising: at least one epoxy functional vinyl monomer 15% to 100% by wt total monomers in (A); 0 to 85% of at least one other ethylenically unsaturated vinyl monomer, (preferably other than styrenic monomers) by wt total monomers in (A); (B) reacting the epoxy functional polymer from (A) with fatty acids having an average iodine value from 30 to 250 g I 2 / 100 g fatty acid; where composition has: a) a opt. co-solvent content ≤ 40% by wt of the composition; b) a solids content either ≥ 30% (aqueous) ≥ 60% (solvent based) by wt of the composition, the composition as a coating film having a telegraphing value of less than 10 gloss units (difference between an initial smooth gloss minus an initial rough gloss of the film).
摘要翻译：描述了包含可自动氧化的乙烯基聚合物的（优先非粘性）涂料组合物（其可以是水或溶剂载体），所述可自动氧化聚合物具有25重量％至75重量％的可自动氧化聚合物的乙烯基聚合物主链; 脂肪酸残基25％至75％重量的可自动氧化聚合物; Tg为-60℃至+ 20℃，Mw为3500至50000g / mol; 多分散性为2〜10; 通过以下方法获得的可自动氧化聚合物：（A）烯键式不饱和乙烯基单体的聚合，包括：（A）中至少一种15重量％至100重量％的单体的至少一种环氧官能乙烯基单体; 0至85％的（A）中的总单体的至少一种其它烯属不饱和乙烯基单体（优选不同于苯乙烯类单体）; （B）使来自（A）的环氧官能聚合物与平均碘值为30-250g I2 / 100g脂肪酸的脂肪酸反应; 其中组合有：a）选择。共溶剂含量= 40重量％的组合物; b）固体含量=组合物重量的30％（水性）= 60％（溶剂基），作为涂膜的组合物，其透印值小于10个光泽单位（初始平滑光泽度减去初始粗糙的光泽度）。

9. 发明申请

WO2006002866A1 LOW NWP AQUEOUS POLYURETHANE COMPOSITION 审中-公开
标题翻译：低NWP水性聚氨酯组合物
公开(公告)号：WO2006002866A1
公开(公告)日：2006-01-12
申请号：PCT/EP2005/006934
申请日：2005-06-28
申请人： DSM IP ASSETS BV , VAN CASTEREN, Ilse , ROELANDS, Marc , OVERBEEK, Gerardus, Cornelis , TENNEBROEK, Ronald
发明人： VAN CASTEREN, Ilse , ROELANDS, Marc , OVERBEEK, Gerardus, Cornelis , TENNEBROEK, Ronald
IPC分类号： C08G18/08
CPC分类号： C08G18/0823 , C08G18/0852 , C08G18/12 , C08G18/283 , C08G18/6692 , C08G18/724 , C08G18/7607 , C08L33/10 , C08L75/04 , Y10T428/31551 , Y10T428/31591 , Y10T428/31598 , Y10T428/31601 , Y10T428/31605 , Y10T428/31609 , C08G18/3231 , C08L2666/04
摘要： An aqueous composition with a sediment content ≤ 5%, comprising a polyurethane dispersion wherein the polyurethane has an acid value in the range of from 25 to 65 mgKOH/g and comprises (i) 36 to 60 wt% of at least one aromatic polyisocyanate and where the polyurethane is prepared in the presence of (a) ≤ 5 wt% of 1-methyl-2-pyrrolidinone by weight of the polyurethane , (b) 5 to 100 wt% of 1 -ethyl-2-pyrrolid i none by weight of polyurethane and (c) water.
摘要翻译：沉淀物含量为5％的含水组合物，其包含聚氨酯分散体，其中所述聚氨酯的酸值为25至65mgKOH / g，并且包含（i）36至60重量％的至少一种芳族多异氰酸酯和其中聚氨酯在（a）= 5重量％的1-甲基-2-吡咯烷酮的存在下制备，以聚氨酯的重量计，（b）5-100重量％的1-乙基-2-吡咯烷的聚氨酯和（c）水。

10. 发明申请

WO2006002865A1 LOW NMP AQUEOUS POLYURETHANE COMPOSITION WITH A DILUENT 审中-公开
标题翻译：低NMP水性聚氨酯组合物与DILUENT
公开(公告)号：WO2006002865A1
公开(公告)日：2006-01-12
申请号：PCT/EP2005/006933
申请日：2005-06-28
申请人： DSM IP ASSETS BV , VAN CASTEREN, Ilse , ROELANDS, Marc , OVERBEEK, Gerardus, Cornelis , COOGAN, Richard, George , TENNEBROEK, Ronald , KUZMIN, Ann
发明人： VAN CASTEREN, Ilse , ROELANDS, Marc , OVERBEEK, Gerardus, Cornelis , COOGAN, Richard, George , TENNEBROEK, Ronald , KUZMIN, Ann
IPC分类号： C08G18/08
CPC分类号： C08G18/0852 , C08G18/12 , C08G18/6692 , C08G18/7607 , C08L33/10 , C09D175/04 , C08G18/3231 , C08G18/3228 , C08L2666/04
摘要： An aqueous composition with a sediment content
摘要翻译：沉淀物含量<5％的水性组合物，其包含聚氨酯分散体，其中所述聚氨酯的酸值在25至65mgKOH / g范围内，并且包含（i）36至60重量％的至少一种芳族多异氰酸酯和其中聚氨酯是在（a）<5wt％的1-甲基-2-吡咯烷酮（以重量计）的聚氨酯存在下制备的，（b）至少一种稀释剂和（c）水。

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