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1. 发明申请

WO2003082999A1 AQUEOUS COATING COMPOSITION COMPRISING NON-CROSSLINKABLE OLIGOMERS(S) AND DISPERSED POLYMERS(S) 审中-公开
标题翻译：包含不可交联的低聚物（S）和分散聚合物（S）的水性涂料组合物
公开(公告)号：WO2003082999A1
公开(公告)日：2003-10-09
申请号：PCT/GB2003/001215
申请日：2003-03-21
申请人： AVECIA BV , AVECIA LIMITED , MARTIN, Emilio , SCHEERDER, Jurgen , OVERBEEK, Gerardus, Cornelis , TENNEBROEK, Ronald , NABUURS, Tijs , STEENWINKEL, Pablo
发明人： MARTIN, Emilio , SCHEERDER, Jurgen , OVERBEEK, Gerardus, Cornelis , TENNEBROEK, Ronald , NABUURS, Tijs , STEENWINKEL, Pablo
IPC分类号： C09D201/00
CPC分类号： C09D167/00 , C09D175/04 , C08L2666/04
摘要： An aqueous coating composition comprising a non-crosslinkable water-dispersible oligomer(s); a dispersed polymer(s); water and optionally co-solvent wherein the composition has an open time of at least 20 min; a wet edge time of at least 10 min; a tack free time of ≤ 24 hours and an equilibrium viscosity of 5,000 Pa.s.
摘要翻译：一种包含不可交联的水分散性低聚物的水性涂料组合物; 分散的聚合物; 水和任选的共溶剂，其中组合物的开放时间为至少20分钟; 湿边缘时间至少为10分钟; 无粘性时间<= 24小时，平衡粘度为5000帕。

2. 发明申请

WO2005023947A1 AQUEOUS POLYMER COMPOSITIONS 审中-公开
标题翻译：水性聚合物组合物
公开(公告)号：WO2005023947A1
公开(公告)日：2005-03-17
申请号：PCT/GB2004/003229
申请日：2004-07-26
申请人： AVECIA BV , AVECIA LIMITED , SATGURUNATHAN, Rajasingham , MARTIN, Emilio , OVERBEEK, Gerardus, Cornelis , ROELANDS, Marc
发明人： SATGURUNATHAN, Rajasingham , MARTIN, Emilio , OVERBEEK, Gerardus, Cornelis , ROELANDS, Marc
IPC分类号： C09D175/04
CPC分类号： C08G18/12 , C08G18/6692 , C09D175/04 , C08G18/3231 , C08L2666/20 , C08L2666/04
摘要： An aqueous coating composition comprising: (i) (10) to (80) wt% of a polyurethane A which exhibits a minimum film forming temperature of ≤ ambient temperature and which comprises a polyurethane obtained by the reaction of: (a) an isocyanate-terminated pre-polymer formed from components which comprise: (1) 10 to 30 wt% of a polyisocyanate; (2) 0.1 to 10 wt% of a polyol of weight average molecular weight less than 500, containing ionic or potentially ionic water-dispersing groups, and having two or more isocyanate-reactive groups; (3) 0 to 15 wt% of a polyol containing non-ionic water dispersing groups having two or more isocyanate-reactive groups; (4) 40 to 80 wt% of a polyol other than (2) or (3), having two or more isocyanate-reactive groups; where (1), (2), (3) and (4) add up to 100 %; and (b) an active-hydrogen chain extending compound; and (ii) 20 to 90 wt% of a polymer dispersion B which exhibits a minimum film forming temperature of above ambient temperature; wherein (i) and (ii) add up to 100 %. Processes for manufacture of said composition and methods of application to substrates are also described.
摘要翻译：一种水性涂料组合物，其包含：（i）（10） - （80）wt％的聚氨酯A，其表现出最小成膜温度<=环境温度，并且其包含通过以下反应获得的聚氨酯：（a）异氰酸酯由包含以下组分的组分形成的终止预聚物：（1）10至30重量％的多异氰酸酯; （2）0.1〜10重量％的重均分子量小于500的多元醇，其含有离子或潜在离子性水分散基团，并且具有两个或多个异氰酸酯反应性基团; （3）含有2个以上异氰酸酯反应性基团的非离子性水分散基团的多元醇0〜15重量％（4）40〜80重量％的具有2个以上异氰酸酯反应性基团的（2）或（3）以外的多元醇; 其中（1），（2），（3）和（4）加起来为100％; 和（b）活性氢链增长化合物; 和（ii）20〜90重量％的表现出最高成膜温度高于环境温度的聚合物分散体B; 其中（i）和（ii）加起来为100％。还描述了用于制造所述组合物的方法和施加于基材的方法。

3. 发明申请

WO2009007232A1 PROCESS FOR MAKING A CATIONIC VINYL OLIGOMER COMPOSITION 审中-公开
标题翻译：制备阳离子乙烯低聚物组合物的方法
公开(公告)号：WO2009007232A1
公开(公告)日：2009-01-15
申请号：PCT/EP2008/058007
申请日：2008-06-24
申请人： DSM IP ASSETS B.V. , SCHEERDER, Jurgen , MARTIN, Emilio , OVERBEEK, Gerardus Cornelis
发明人： SCHEERDER, Jurgen , MARTIN, Emilio , OVERBEEK, Gerardus Cornelis
IPC分类号： C08F2/28 , C08F220/34 , C08F220/10
CPC分类号： C08F2/28 , C08F220/14 , C08F220/18 , C08F220/34 , C08F265/00 , C08F265/04 , C08F291/00 , C08L51/003 , C09D4/00 , C09D151/003 , Y10T428/31935 , C08L2666/02
摘要： A process is described for making an aqueous coating composition comprising a cationic vinyl oligomer comprising the following steps: I. preparation of a cationic vinyl oligomer by solution or bulk polymerisation of components: i) 2 to 50 wt% of vinyl monomers bearing amine functional groups selected from the group consisting of non-ionic amine functional groups (a), permanent quaternary ammonium functional groups (b), neutralised amine functional groups (c) and mixtures thereof; and ii) 20 to 98 wt% of Ci to Ci8 alkyl (meth)acrylates; and II. dispersion of the cationic vinyl oligomer in an aqueous medium and neutralisation of non-ionic amine functional groups.
摘要翻译：描述了一种制备包含阳离子乙烯基低聚物的水性涂料组合物的方法，其包括以下步骤：I.通过组分的溶液或本体聚合制备阳离子乙烯基低聚物：i）2至50重量％的带有胺官能团的乙烯基单体选自非离子胺官能团（a），永久性季铵官能团（b），中和胺官能团（c）及其混合物; 和ii）20至98重量％的C 1-8烷基（甲基）丙烯酸酯; 和II。阳离子乙烯基低聚物在水性介质中的分散和非离子胺官能团的中和。

4. 发明申请

WO2011073404A1 POLYMERIC COMPOSITION 审中-公开
标题翻译：聚合物组合物
公开(公告)号：WO2011073404A1
公开(公告)日：2011-06-23
申请号：PCT/EP2010/070107
申请日：2010-12-17
申请人： DSM IP Assets B.V. , SATGURUNATHAN, Rajasingham , MARTIN, Emilio , GEEL, VAN, Adrianus Antonius Johannes , SUYKERBUYK, Franciscus Adrianus Johannes , SENATORE, Daniela , BÜCKMANN, Alfred Jean Paul
发明人： SATGURUNATHAN, Rajasingham , MARTIN, Emilio , GEEL, VAN, Adrianus Antonius Johannes , SUYKERBUYK, Franciscus Adrianus Johannes , SENATORE, Daniela , BÜCKMANN, Alfred Jean Paul
IPC分类号： C09D11/10
CPC分类号： C09D11/107 , B05D3/06 , C09D11/101
摘要： There is described a substantially solid, solvent free, radiation curable composition comprising a) optionally from 0.1 % to 99.9% by weight of a colorant; and b) from 0.1 % to 99.9% of radiation curable polymer obtained and/or obtainable from at least one mono-(terminal functional forming) monomer of formula I: R 1 (R 2 )C=CR 3 (C=O)(X 1 ) n R 4 Formula 1, where n is 0 or 1, X 1 is oxy or -NR 5 - (where R 5 represents H or optionally substituted organo), R 1 independently represents optionally substituted C 1-10 hydrocarbo, hydroxyl, optionally substituted C 2-10 hydrocarbo-oxy comprising a ring moiety, and/or carboxy; and R 2 , R 3 and R 4 each independently represent H, an optional substituent and/or optionally substituted organo groups and where n is 0, R 3 may also represent oxy or -NR 5 -; and c) optionally from 0.1 % to 90% of a radiation curable high molecular weight reactive diluent; and d) optionally from 0.01 to 10% of at least one photo-initiator; and where the radiation curable polymer (b) is i) obtained and/or obtainable in a suspension polymerisation process using a cobalt catalyst as a chain transfer agent; ii) is solid under standard conditions; and iii) is mono-(terminal functional) comprising one terminally located activated unsaturated moiety (such as of Formula 1 herein). where the composition has at least one of the properties (A) to (F): A) is substantially free of volatile organic compounds (VOCs); B) has a residual concentration of initiator (such as peroxide) of less than 0.025 g per g of polymer; C) comprises a polymer having a total ethylenic unsaturation (for example from moiet(ies) of Formula 1, such as C=C and/or (meth)acrylate) greater than 0.1 milli-equivalents C=C per g polymer; D) is substantially-free of sulphur comprising species; E) is substantially free of cobalt (II) species; and/or F) has a weight average molecular weight (M w ) of less then 25kDa.
摘要翻译：描述了基本上固体的，无溶剂的可辐射固化组合物，其包含a）任选地0.1至99.9重量％的着色剂; 和b）从式I的至少一种（末端功能形成）单体获得和/或可获得的可辐射固化聚合物的0.1％至99.9％：R1（R2）C = CR3（C = O）（X1）nR4 式1其中n为0或1，X 1为氧或-NR 5 - （其中R 5表示H或任选取代的有机基），R 1独立地表示任选取代的C 1-10烃基，羟基，任选取代的C 2-10氢氧代 - ，和/或羧基; 并且R 2，R 3和R 4各自独立地表示H，任选的取代基和/或任选取代的有机基团，并且其中n是0，R 3也可以表示氧基或-NR 5 - ; 和c）任选地0.1％至90％的可辐射固化高分子量反应性稀释剂; 和d）任选的0.01至10％的至少一种光引发剂; 并且其中可辐射固化聚合物（b）是i）在使用钴催化剂作为链转移剂的悬浮聚合方法中获得和/或获得的; ii）在标准条件下是固体; 和iii）是包含一个末端定位的活化不饱和部分（例如本文的式1）的单 - （末端官能团）。其中组合物具有性质（A）至（F）中的至少一种：A）基本上不含挥发性有机化合物（VOC）; B）具有小于0.025g / g聚合物的引发剂（例如过氧化物）的残留浓度; C）包含大于0.1毫当量C = C / g聚合物的总烯属不饱和度（例如从式1的不饱和度，例如C = C和/或（甲基）丙烯酸酯））的聚合物; D）基本上不含含硫物质; E）基本上不含钴（II）物质; 和/或F）的重均分子量（Mw）小于25kDa。

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