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1. 发明申请

WO2013101345A1 FORMATION OF HIGHER MOLECULAR WEIGHT CYCLIC POLYAMINE COMPOUNDS FROM CYCLIC POLYAMINE COMPOUNDS 审中-公开
标题翻译：从环状聚氨酯化合物形成较高分子量的环状聚氨酯化合物
公开(公告)号：WO2013101345A1
公开(公告)日：2013-07-04
申请号：PCT/US2012/064971
申请日：2012-11-14
申请人： DOW GLOBAL TECHNOLOGIES LLC , KING, Stephen W.
发明人： KING, Stephen W.
IPC分类号： C07D295/13
CPC分类号： C07D295/13
摘要： The present invention provides strategies for making higher weight, cyclic polyamines from lower molecular weight, cyclic polyamine starting compounds via transamination. The higher molecular weight, cyclic polyamines are structurally similar to the lower molecular weight, cyclic polyamine starting compounds. The reactants used in the present invention include a cyclic polyamine component that comprises at least two amine groups separated from one another by at least a binary carbon atom spacing, and that can be transaminated to form a higher molecular weight, cyclic polyamine compound. The higher molecular weight, cyclic polyamine has at least two cyclic rings joined to one another through a nitrogen-containing hydrocarbyl group. Each of the cyclic rings contains two amine groups separated from one another by binary carbon atom spacing.
摘要翻译：本发明提供从较低分子量制备较高重量的环状多胺，通过氨基转移的环状多胺起始化合物的策略。较高分子量的环状多胺在结构上类似于较低分子量的环状多胺起始化合物。本发明中使用的反应物包括环状多胺组分，其包含至少两个通过至少二元碳原子间隔彼此分开的胺基，并且可以被转氨酸以形成较高分子量的环状多胺化合物。较高分子量的环状多胺具有通过含氮烃基彼此连接的至少两个环状环。每个环状环包含通过二元碳原子间隔彼此分开的两个胺基。

2. 发明申请

WO2013148140A1 RHENIUM RECOVERY FROM USED REDUCTIVE AMINATION CATALYSTS 审中-公开
标题翻译：使用还原胺化催化剂回收铑
公开(公告)号：WO2013148140A1
公开(公告)日：2013-10-03
申请号：PCT/US2013/030233
申请日：2013-03-11
申请人： DOW GLOBAL TECHNOLOGIES LLC , KING, Stephen W. , HOFFMAN, William C.
发明人： KING, Stephen W. , HOFFMAN, William C.
IPC分类号： C22B7/00 , C22B61/00 , B01J23/656
CPC分类号： B01J23/8896 , B01J23/92 , B01J23/94 , B01J37/0201 , B01J38/12 , B01J38/58 , B01J38/60 , B01J38/64 , B01J38/70 , C07C209/16 , C07C213/02 , C07D295/027 , C22B7/009 , C22B61/00 , Y02P10/214 , Y02P20/584
摘要： The present invention provides techniques that selectively recover Re from reductive amination catalysts. In particular, the present invention allows Re to be recovered selectively relative to Ni, Co, and/or Cu, and particularly Ni, that are often present on reductive amination catalysts. The present invention uses a combination of oxidation and extraction techniques to selectively recover Re relative to Ni, Co, and/or Cu. Advantageously, the recovery is selective even when using aqueous solutions for extraction.
摘要翻译：本发明提供从还原胺化催化剂中选择性回收Re的技术。特别地，本发明允许Re相对于通常存在于还原胺化催化剂上的Ni，Co和/或Cu，特别是Ni选择性地回收。本发明使用氧化和萃取技术的组合来相对于Ni，Co和/或Cu选择性地回收Re。有利的是，即使使用水溶液进行萃取，回收率也是选择性的。

3. 发明申请

WO2013102097A2 CYCLIC AMINE COMPOUNDS, COMPOSITIONS, AND POLYURETHANE FOAMS MADE THEREFROM 审中-公开
标题翻译：环胺类化合物，组合物和由此制备的聚氨酯泡沫
公开(公告)号：WO2013102097A2
公开(公告)日：2013-07-04
申请号：PCT/US2012/072095
申请日：2012-12-28
申请人： DOW GLOBAL TECHNOLOGIES LLC , LATHAM, Dwight D. , ATHEY, Phillip S. , KING, Stephen W.
发明人： LATHAM, Dwight D. , ATHEY, Phillip S. , KING, Stephen W.
IPC分类号： C07D295/13 , C08G18/32
CPC分类号： C08G18/2081 , C07D295/13 , C08G18/14 , C08G18/18 , C08G18/2027 , C08G18/3218 , C08G18/4816 , C08G18/4829 , C08G18/4841 , C08G18/7657 , C08G18/7664 , C08G2101/00 , C08G2101/005 , C08G2101/0083 , C08J9/144 , C08J9/146 , C08J2375/08
摘要： The present invention describes cyclic amine compounds useful for catalysts for polyurethane form-forming compositions. The cyclic amine compounds of the invention provide distinct benefits for reaction compositions, methods, and polyurethane foams based on their desirable physical and catalytic properties.
摘要翻译：本发明描述了用于形成聚氨酯形式的组合物的催化剂的环胺化合物。基于它们所需的物理和催化性质，本发明的环胺化合物为反应组合物，方法和聚氨酯泡沫提供了明显的益处。

4. 发明申请

WO2012087553A1 PROCESSES FOR SEPARATING ONE OR MORE AMINE BYPRODUCTS FROM ONE OR MORE DESIRED AMINES 审中-公开
标题翻译：从一个或多个所需的氨基酸分离一个或多个氨基酸的方法
公开(公告)号：WO2012087553A1
公开(公告)日：2012-06-28
申请号：PCT/US2011/063373
申请日：2011-12-06
申请人： DOW GLOBAL TECHNOLOGIES LLC , PETRAITIS, David M. , KING, Stephen W.
发明人： PETRAITIS, David M. , KING, Stephen W.
IPC分类号： C07C209/86 , C07C209/84 , C07C211/10
CPC分类号： C07C209/84 , C07C209/86 , C07C211/10
摘要： The present invention relates to separating one or more amine byproducts from one or more desired amines. More particularly, the invention involves forming a byproduct component with one or more amine byproducts and a first adjuvant component. The byproduct component has an enhanced separation characteristic relative to separating the amine byproducts from the desired amines in the absence of an adjuvant. Preferably, the byproduct component is separated in the presence of a second adjuvant component that preferably has a boiling point less than the boiling point of the first adjuvant component.
摘要翻译：本发明涉及从一种或多种所需胺分离一种或多种胺副产物。更具体地，本发明涉及用一种或多种胺副产物和第一佐剂组分形成副产物组分。相对于在没有佐剂的情况下将胺副产物与所需胺分离，副产物组分具有增强的分离特性。优选地，副产物组分在第二佐剂组分存在下分离，其优选的沸点低于第一助剂组分的沸点。

5. 发明申请

WO2012064484A1 TRANSAMINATION OF NITROGEN-CONTAINING COMPOUNDS TO HIGH MOLECULAR WEIGHT POLYALKYLENEAMINES 审中-公开
标题翻译：含氮化合物向高分子量聚氨基甲酸铵的分解
公开(公告)号：WO2012064484A1
公开(公告)日：2012-05-18
申请号：PCT/US2011/057047
申请日：2011-10-20
申请人： DOW GLOBAL TECHNOLOGIES LLC , KING, Stephen W.
发明人： KING, Stephen W.
IPC分类号： C07C209/64
CPC分类号： C07C209/54 , C07C209/64 , C07C211/14
摘要： A process for preparing high molecular weight acyclic polyamines comprising providing a reaction mixture that includes at least a first component comprising a first organic, nitrogen-containing compound that contains at least two non-tertiary amine groups separated from one another by a ternary or higher carbon atom spacing that can be transaminated in the presence of a hydrogenation/dehydrogenation catalyst to form a mixture of higher molecular weight, acyclic polyamines while minimizing the formation of cyclic polyamines.
摘要翻译：一种制备高分子量无环多胺的方法，包括提供反应混合物，该反应混合物包括至少第一组分，其包含第一有机含氮化合物，其含有通过三元或更高碳彼此分离的至少两个非叔胺基团原子间隔可以在氢化/脱氢催化剂存在下进行转氨以形成较高分子量的无环多胺的混合物，同时最小化环状多胺的形成。

6. 发明申请

WO2012064483A1 TRANSAMINATION OF NITROGEN-CONTAINING COMPOUNDS TO MAKE CYCLIC AND CYCLIC/ACYCLIC POLYAMINE MIXTURES 审中-公开
标题翻译：含氮化合物的复合以制备环状和环状/环状聚胺混合物
公开(公告)号：WO2012064483A1
公开(公告)日：2012-05-18
申请号：PCT/US2011/057045
申请日：2011-10-20
申请人： DOW GLOBAL TECHNOLOGIES LLC , KING, Stephen W.
发明人： KING, Stephen W.
IPC分类号： C07D243/08 , C07D295/023
CPC分类号： C07D295/023 , C07D243/08 , C07D295/13
摘要： A transamination process is described to prepare polyamine product mixtures from reactants comprising mixed nitrogen-containing compounds with binary carbon spacing between nitrogen-containing groups (a binary component). A second nitrogen-containing component with a second carbon atom spacing between nitrogen-containing groups may also be employed. The molar ratio between the binary and second components can be adjusted to customize the product composition for desired end uses.
摘要翻译：描述了一种转氨过程，以从包含含氮基团（二元组分）之间的二元碳间隔的混合含氮化合物的反应物制备多胺产物混合物。也可以使用在含氮基团之间具有第二碳原子间隔的第二含氮组分。可以调整二元和第二成分之间的摩尔比以定制所需最终用途的产品组成。

7. 发明申请

WO2021035673A1 PHOTORESIST STRIPPING COMPOSITION 审中-公开
公开(公告)号：WO2021035673A1
公开(公告)日：2021-03-04
申请号：PCT/CN2019/103614
申请日：2019-08-30
申请人： DOW GLOBAL TECHNOLOGIES LLC , JIANG, Xin , KING, Stephen W.
发明人： JIANG, Xin , KING, Stephen W.
IPC分类号： G03F7/42
摘要： A photoresist stripping composition comprising an organic amine and a method is provided. The photoresist stripping composition comprising an organic amine having the following formula (1).

8. 发明申请

WO2013095810A1 REDUCTIVE AMINATION OF DIETHANOLAMINE AND RESULTING PRODUCT MIXTURE 审中-公开
标题翻译：二乙胺和还原产物混合物的还原胺化
公开(公告)号：WO2013095810A1
公开(公告)日：2013-06-27
申请号：PCT/US2012/064966
申请日：2012-11-14
申请人： DOW GLOBAL TECHNOLOGIES LLC , KING, Stephen W. , ONAM, Sadeka , SRNAK, Thomas Z.
发明人： KING, Stephen W. , ONAM, Sadeka , SRNAK, Thomas Z.
IPC分类号： C07D295/023 , C07C209/14
CPC分类号： C07C213/02 , B01J21/12 , B01J23/8896 , B01J23/89 , B01J37/0201 , C07C2529/89 , C07D295/00 , C07D295/023 , C07C215/14
摘要： The invention provides a method for the reductive amination of diethanolamine to form a product composition that includes piperazine (PIP) and aminoethylethanolamine (AEEA). A catalyst with a transitional alumina/second metal oxide support and a mixture of catalytic metals is used for the reaction which results in low levels of non-PIP and non-AEEA side products.
摘要翻译：本发明提供二乙醇胺还原胺化以形成包括哌嗪（PIP）和氨基乙基乙醇胺（AEEA））的产品组合物的方法。使用具有过渡氧化铝/第二金属氧化物载体和催化金属的混合物的催化剂用于反应，其导致低水平的非PIP和非AEEA副产物。

9. 发明申请

WO2017048711A1 HEAT TRANSFER FLUID COMPRISING FUNCTIONALIZED CARBON NANOMATERIAL AND METHOD OF MAKING IT 审中-公开
标题翻译：包含功能性碳纳米管的热转移流体及其制备方法
公开(公告)号：WO2017048711A1
公开(公告)日：2017-03-23
申请号：PCT/US2016/051516
申请日：2016-09-13
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： GANAPATIBHOTLA, Lalitha V. , KING, Stephen W. , MALANGA, Michael T. , PENDERGAST, John G.
IPC分类号： C09K5/10 , C01B31/04 , C01B31/02
CPC分类号： C09K5/10 , C01B32/174 , C01B32/194
摘要： The present disclosure describes a nanofluid comprising a polar fluid medium; and a functionalized carbon nanomaterial. The present disclosure further describes a process for preparing a nanofluid comprising providing a functionalized carbon nanomaterial; providing a polar fluid medium; and dispersing the functionalized carbon nanomaterial in the polar fluid medium by ultrasonication.
摘要翻译：本公开描述了包含极性流体介质的纳米流体; 和官能化碳纳米材料。本公开进一步描述了制备纳米流体的方法，其包括提供官能化的碳纳米材料; 提供极性流体介质; 并通过超声波将官能化碳纳米材料分散在极性流体介质中。

10. 发明申请

WO2016204981A1 AUTOCATALYTIC POLYOL USEFUL FOR POLYURETHANE FOAM MANUFACTURE 审中-公开
标题翻译：自由基聚合物用于聚氨酯泡沫制造
公开(公告)号：WO2016204981A1
公开(公告)日：2016-12-22
申请号：PCT/US2016/035642
申请日：2016-06-03
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： MALANGA, Michael T. , KING, Stephen W. , FRYCEK, George J. , MASY, Jean-Paul , FREGNI, Sabrina
IPC分类号： C08G18/48 , C08G18/50 , C08G18/63 , C08G18/66 , C08G18/76 , C08G18/32 , C08G73/02
CPC分类号： C08G18/2027 , C08G18/1825 , C08G18/3206 , C08G18/3275 , C08G18/4804 , C08G18/4816 , C08G18/482 , C08G18/4841 , C08G18/4845 , C08G18/5024 , C08G18/5027 , C08G18/632 , C08G18/667 , C08G18/6674 , C08G18/7621 , C08G18/7664 , C08G73/024 , C08G73/0273 , C08G73/0633 , C08G2101/0008 , C08J9/14 , C08J2205/06 , C08J2375/08
摘要： The present invention discloses a tertiary amine initiator and polymeric polyol compositions made therefrom useful for making polyurethane polymers, especially polyurethane foams. Said polyurethane polymer foams demonstrate a good balance of mechanical properties, physical properties, and low emissions. The tertiary amine initiator is one or more partially alkylated amine compound have the Structure II: RR 1 N - (R'-NH) y - (R'-NR 4 ) x-y - R' - NR 2 R 3 wherein R' is a C 1 to C 6 linear or branched alkyl group, R, R 1 , R 2 , and R 3 are independently a hydrogen or a C 1 to C 6 linear or branched alkyl group with the proviso that at least one of R, R 1 , R 2 , and R 3 is not hydrogen, R 4 is a hydrogen or a C 1 to C 6 linear or branched alkyl group, x is from 1 to 33, y is from 0 to 32, and z is from 0 to 15, with the proviso that x-y is equal to or greater than 1 and the number of N-H bonds in (II) is greater than 0 and less than 8.
摘要翻译：本发明公开了由其制备的叔胺引发剂和聚合多元醇组合物，其用于制备聚氨酯聚合物，特别是聚氨酯泡沫塑料。所述聚氨酯聚合物泡沫体表现出机械性能，物理性能和低排放物的良好平衡。叔胺引发剂是具有结构II：RR1N - （R'-NH）y - （R'-NR4）xy-R'-NR2R3的一种或多种部分烷基化的胺化合物，其中R'是C1至C6直链或支链烷基，R，R 1，R 2和R 3独立地是氢或C 1至C 6直链或支链烷基，条件是R，R 1，R 2和R 3中的至少一个不是氢，R 4是氢或 C1至C6直链或支链烷基，x为1至33，y为0至32，z为0至15，条件是xy等于或大于1，NH键数在（II）中大于0且小于8。

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