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1. 发明申请

WO2014182430A1 VACUUM-ASSISTED PROCESS FOR PREPARING AN ION-EXCHANGED ZEOLITE MEMBRANE 审中-公开
标题翻译：用于制备离子交换的沸石膜的真空辅助方法
公开(公告)号：WO2014182430A1
公开(公告)日：2014-11-13
申请号：PCT/US2014/034891
申请日：2014-04-22
申请人： DOW GLOBAL TECHNOLOGIES LLC , GEORGIA TECH RESEARCH CORPORATION
发明人： NAIR, Sankar , KIM, Seok Jhin , LIU, Yujun , PENDERGAST, John G. , DIXIT, Ravindra S. , MOORE, Jason S.
IPC分类号： B01D67/00 , B01J29/08 , B01J29/40 , B01J29/70 , B01D69/02 , B01D71/02 , B01J35/06 , C01B39/08
CPC分类号： B01J35/065 , B01D67/0051 , B01D67/0093 , B01D69/02 , B01D71/028 , B01D2323/08 , B01D2323/10 , B01D2325/42 , B01J20/186 , B01J20/28035 , B01J20/3085 , B01J29/085 , B01J29/405 , B01J29/7053 , B01J2229/186 , C01B39/08 , C01B39/082 , C01B39/40
摘要： Effect ion-exchange of an alpha-alumina supported zeolite (e.g. a MFI zeolite, an LTA zeolite or a FAU zeolite)membrane, which process comprises: a) placing the membrane, which has a first surface and a spaced apart second surface, the first and second surfaces defining therebetween the membrane, in an ion exchange apparatus such that the first surface is in contact with an ion exchange solution and the second surface is in contact with a vapor space that is connected to a source of reduced pressure; b) actuating the source of reduced pressure to create a pressure differential between the first and second membrane surfaces of at least 0.4 atmosphere (0.405 x 10 5 pascals); and c) maintaining the pressure differential under ion exchange conditions for a period of time sufficient to effect exchange of an ion contained in the ion exchange solution with an ion in the zeolite membrane in an amount that is greater than an amount of ion exchange attained using an apparatus that places the second surface in contact with a liquid solvent that is at a pressure of at least one atmosphere (1.013 x 10 5 pascals) and the first surface in contact with the ion exchange solution at a pressure of at least two atmospheres (2.026 x 10 5 pascals) so as to establish a pressure differential between the two surfaces of at least one atmosphere (1.013 x 10 5 pascals), maintaining the pressure differential for the same period of time, and using the same ion exchange membrane, ion exchange solution and ion exchange temperature, the greater amount of ion exchange yielding an improved ion exchange membrane that a ratio of the ion that entered the membrane from the solution to the ion that left the membrane that is greater than that of the ion exchanged membrane prepared with the second surface in contact with the liquid solvent.
摘要翻译：影响α-氧化铝负载的沸石（例如MFI沸石，LTA沸石或FAU沸石）膜的离子交换，该方法包括：a）将具有第一表面和间隔开的第二表面的膜，在离子交换装置中，使得第一表面与离子交换溶液接触并且第二表面与连接到减压源的蒸汽空间接触，在隔膜之间限定隔膜的第一和第二表面; b）致动减压源以在第一和第二膜表面之间产生至少0.4个大气压（0.405×105帕斯卡）的压力差; 和c）在离子交换条件下保持压差足以使离子交换溶液中包含的离子与沸石膜中的离子以大于使用的离子交换量进行交换的时间使第二表面与处于至少一个气压（1.013×10 5帕斯卡）的压力的液体溶剂接触并且在至少两个大气压的压力下与离子交换溶液接触的第一表面（2.026 以便在至少一个气氛（1.013×105帕斯卡）的两个表面之间建立压力差，保持相同时间段的压力差，并使用相同的离子交换膜，离子交换溶液和离子交换温度，更大量的离子交换产生改进的离子交换膜，即从溶液到离子的膜进入离子的比例在离开膜处，该膜比用与液体溶剂接触的第二表面制备的离子交换膜的膜大。

2. 发明申请

WO2017156139A1 FABRICATION OF MICRON-THIN, SELECTIVE, SAPO-34 ZEOLITE MEMBRANES WITH ENHANCED GAS PERMEANCE 审中-公开
标题翻译：增强气体渗透率的微薄选择性SAPO-34分子筛膜的制备
公开(公告)号：WO2017156139A1
公开(公告)日：2017-09-14
申请号：PCT/US2017/021377
申请日：2017-03-08
申请人： DOW GLOBAL TECHNOLOGIES LLC , GEORGIA TECH RESEARCH CORPORATION
发明人： NAIR, Sankar , PENDERGAST, John, G. , JONES, Christopher, W. , KIM, Seok, Jhin , MOORE, Jason, S. , LIU, Yujun , DIXIT, Ravindra, S.
IPC分类号： B01D67/00 , B01D53/22 , B01D69/10 , B01D71/02 , C01B37/08 , C07C5/32 , C01B39/54 , B01J37/02 , B01D69/12
CPC分类号： B01D71/028 , B01D53/228 , B01D67/0051 , B01D67/0083 , B01D69/10 , B01D69/105 , B01D69/12 , B01D2256/24 , B01D2257/108 , B01D2311/13 , B01D2313/42 , B01D2323/08 , B01D2323/18 , B01D2323/24 , B01D2323/48 , B01D2325/04 , B01D2325/10 , C07C5/32 , C07C5/321 , C07C11/02
摘要： The invention relates to a process for making SAPO-34 membranes with less than 2 micron thickness and good H2 selectivity, and the use of these membranes as hb-selective zeolite membranes in the PDH process.
摘要翻译：本发明涉及用于制造具有小于2微米厚度和良好的H 2选择性的SAPO-34膜的方法，以及在PDH方法中将这些膜用作hb选择性沸石膜的方法。 p>

3. 发明申请

WO2022241689A1 PROCESSES FOR PURIFYING GLYCOL ETHERS 审中-公开
公开(公告)号：WO2022241689A1
公开(公告)日：2022-11-24
申请号：PCT/CN2021/094703
申请日：2021-05-19
申请人： DOW GLOBAL TECHNOLOGIES LLC , JIANG, Qi , OHBA, Kaoru , LIU, Yujun
发明人： JIANG, Qi , OHBA, Kaoru , LIU, Yujun
IPC分类号： B01J41/07 , B01J41/12 , C08G65/30 , B01J39/07 , B01J39/05
摘要： A processes for purifying glycol ethers, comprises (a) providing a glycol ether to a first vessel, the glycol ether, the glycol ether having the following formula: R 1-O- (CHR 2CHR 3) O) nR 4; wherein R 1 is an alkyl group having 1 to 9 carbon atoms or a phenyl group; wherein R 2 and R 3 each individually is hydrogen, a methyl group or an ethyl group, provided that when R 3 is a methyl group or an ethyl group, R 2 is hydrogen and provided that when R 2 is a methyl group or an ethyl group, R 3 is hydrogen; wherein R 4 is hydrogen, an alkyl group having 1 to 4 carbon atoms, an acetyl group, or a propionyl group; and wherein n is an integer of 1 to 3; (b) filling the first vessel with inert gas; (c) heating the glycol ether in the first vessel to a sub-boiling temperature, wherein the sub-boiling temperature is at least 15℃ less than the normal boiling point of the glycol ether; (d) cooling the vapor from the first vessel in a second vessel to provide a liquid; and (e) contacting the glycol ether with a mixed bed of ion exchange resins comprising cationic exchange resins and anionic ion exchange resins.

4. 发明申请

WO2021203255A1 ORGANIC AMINE PURIFICATION METHOD 审中-公开
公开(公告)号：WO2021203255A1
公开(公告)日：2021-10-14
申请号：PCT/CN2020/083624
申请日：2020-04-08
申请人： DOW GLOBAL TECHNOLOGIES LLC , DOW CHEMICAL KOREA LIMITED , JIANG, Qi , LIU, Yujun , OHBA, Kaoru , KIM, Jongcheol , CHEN, Xue , MU, Li , MU, Jianhai , KING, Stephen, W.
发明人： JIANG, Qi , LIU, Yujun , OHBA, Kaoru , KIM, Jongcheol , CHEN, Xue , MU, Li , MU, Jianhai , KING, Stephen, W.
IPC分类号： C07C211/63 , C07C213/10
摘要： A method for purification of organic amines, comprising introducing a resin polymer matrix to a liquid containing at least an organic amine bonded to at least one metallic element, wherein the resin polymer matrix is embedded with an amino compound selected from the group consisting of iminodiacetic acid, aminomethylphosphonic acid or a combination thereof, and wherein the embedded resin polymer matrix binds the at least one metallic element, and the at least one metallic element is removed from the organic amine.

5. 发明申请

WO2018067298A1 SELECTIVE REMOVAL OF HYDROGEN SULFIDE FROM A GAS STREAM USING A QUARTERNARY AMMONIUM AMINE FUNCTIONALIZED CROSS-LINKED MACROPOROUS POLYMER 审中-公开
标题翻译：用季铵盐官能化交联大孔聚合物选择性去除气流中的硫化氢
公开(公告)号：WO2018067298A1
公开(公告)日：2018-04-12
申请号：PCT/US2017/052125
申请日：2017-09-19
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： TAN, Runyu , BADHWAR, Ajay N. , GOLTZ, H. Robert , LIU, Yujun , TEGEN, Marvin H.
IPC分类号： B01D53/02 , B01J20/26
CPC分类号： B01D53/02 , B01D53/047 , B01D2253/202 , B01D2253/306 , B01D2256/245 , B01D2257/304 , B01J20/267 , B01J20/28057 , B01J20/321 , B01J20/3219 , B01J20/3248
摘要： A pressure swing adsorption (PSA) process is disclosed for the removal of hydrogen sulfide (H2S) from natural. This PSA process provides for passing a fluid stream, preferably a natural gas feedstream comprising H2S though a regenerable adsorbent media which adsorbs H2S to provide an H2S-lean natural gas product and H2S. The regenerable adsorbent media of the present invention is a quaternary amine functionalized crosslinked macroporous polymeric adsorbent media.
摘要翻译：公开了用于从天然气中除去硫化氢（H 2 S）的变压吸附（PSA）方法。该PSA方法提供流体流，优选包含H 2 S的天然气进料流通过吸附H 2 S的可再生吸附介质以提供贫H 2 S天然气产物和H 2 S. 本发明的可再生吸附介质是季胺官能化的交联大孔聚合物吸附介质。

6. 发明申请

WO2022203986A1 PURIFICATION OF AMINES BY ADSORPTION USING A SUPER ADSORBENT 审中-公开
公开(公告)号：WO2022203986A1
公开(公告)日：2022-09-29
申请号：PCT/US2022/021082
申请日：2022-03-21
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： LIU, Yujun , CHEN, Xue , KING, Stephen W. , HASAN, Towhid , RUDDICK, Jerrod , YORK, James , SINGH, Amarnath
IPC分类号： B01D15/02 , B01D15/08 , B01D15/18 , B01D15/20 , B01D15/36 , B01J20/10 , B01J20/26
摘要： The present invention describes a method to remove metals present in a mixture comprising one or more organic amines comprising the step of contacting the mixture with a silica-polyethyleneimine adsorbent.

7. 发明申请

WO2021242864A1 COMPOSITION WITH MIXED C13-C14 ALCOHOLS AND SURFACTANTS 审中-公开
公开(公告)号：WO2021242864A1
公开(公告)日：2021-12-02
申请号：PCT/US2021/034264
申请日：2021-05-26
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： YU, Wanglin , BRAMMER, Michael A. , DEMAIO-TURNER, Sally , KU, Sung-Yu , YANG, Jin , SHI, Haifeng , HOOK, Bruce D. , LIU, Yujun , JOHNSON, Jeff
IPC分类号： C11D1/14 , C11D1/29 , C11D1/72 , C07C31/125
摘要： The present disclosure provides a composition. In an embodiment, the composition includes a mixture of an alcohol (1) and an alcohol (2). Alcohol (1) has the Structure (1) : alcohol (2) has the Structure (2): wherein a is an integer from 1 to 2, R1 and R2 each independently is selected from the group consisting of hydrogen and an alkyl group, with the proviso that the total number of carbon atoms of R1 and R2 is 7, and R3 is selected from the group consisting of a butyl group, an isobutyl group, a pentyl group, and an isopentyl group.

8. 发明申请

WO2022241690A1 PROCESSES FOR PURIFYING ORGANIC AMINES 审中-公开
公开(公告)号：WO2022241690A1
公开(公告)日：2022-11-24
申请号：PCT/CN2021/094704
申请日：2021-05-19
申请人： DOW GLOBAL TECHNOLOGIES LLC , DOW CHEMICAL KOREA LIMITED , JIANG, Qi , OHBA, Kaoru , LIU, Yujun , KIM, Jongcheol , CHEN, Xue , MU, Li
发明人： JIANG, Qi , OHBA, Kaoru , LIU, Yujun , KIM, Jongcheol , CHEN, Xue , MU, Li
IPC分类号： C07C209/84
摘要： It is related to a process for purifying organic amines. The process comprises (a) providing an organic amine to a first vessel(5), the organic amine having a normal boiling point at one bar; (b) filling the first vessel(5) with inert gas; (c) heating the organic amine in the first vessel(5) to a sub-boiling temperature, wherein the sub-boiling temperature is at least 15°C less than the normal boiling point; (d) cooling the vapor from the first vessel(5) in a second vessel (20) to provide a liquid; and (e) contacting the organic amine with a resin polymer matrix, wherein the resin polymer matrix is embedded with an amino compound selected from the group consisting of iminodiacetic acid, aminomethylphosphonic acid or a combination thereof.

9. 发明申请

WO2021242971A2 COMPOSITION WITH MIXED C8-C18 ALCOHOLS AND SURFACTANTS THEREOF 审中-公开
公开(公告)号：WO2021242971A2
公开(公告)日：2021-12-02
申请号：PCT/US2021/034439
申请日：2021-05-27
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： YU, Wanglin , BRAMMER, Michael A. , DEMAIO-TURNER, Sally , KU, Sung-Yu , HOOK, Bruce D. , SHI, Haifeng , YANG, Jin , LIU, Yujun , JOHNSON, Jeff
IPC分类号： C07C43/11 , C07C31/125 , C07C29/141 , C07C45/45 , C07C45/50 , C07C47/02 , C07C47/21
摘要： The present disclosure provides a composition. In an embodiment, the composition includes 2-heptylundecanol; a member selected from the group consisting of 2-ethyhexanol and 2-propylheptanol; and a mixture of an alcohol (1) and an alcohol (2), alcohol (1) having the Structure (1) wherein R1 is selected from the group consisting of an ethyl group and a propyl group, R2 and R3 each independently is selected from the group consisting of hydrogen and an alkyl group, with the proviso that the total number of carbon atoms of R1 and R2 is 7, and alcohol (2) having the Structure (2) wherein R4 is selected from the group consisting of an n-propyl group, an isopropyl group, an n-butyl group, and an isobutyl group.

10. 发明申请

WO2021242962A1 PROCESS FOR PRODUCING MIXED ALCOHOLS FROM PURGE STREAM CONTAINING OCTENE 审中-公开
公开(公告)号：WO2021242962A1
公开(公告)日：2021-12-02
申请号：PCT/US2021/034425
申请日：2021-05-27
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： BRAMMER, Michael A. , EWART, Sean W. , YU, Wanglin , HOOK, Bruce D. , DEMAIO-TURNER, Sally , KU, Sung-Yu , LIU, Yujun , YANG, Jin , ZENG, Jianping
IPC分类号： C07C45/50 , C07C47/02
摘要： The present disclosure provides a process. In an embodiment, the process includes providing a purge stream composed of octene isomers. The process includes subjecting the purge stream to hydroformylation conditions, and forming a reaction product composed of nonanals.

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