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1. 发明申请

WO2009091669A1 SULFONATED ORGANOPHOSPHINE COMPOUNDS AND USE IN HYDROFORMYLATION PROCESSES 审中-公开
标题翻译：硫化有机磷化合物和用于氢化方法
公开(公告)号：WO2009091669A1
公开(公告)日：2009-07-23
申请号：PCT/US2009/030553
申请日：2009-01-09
申请人： DOW GLOBAL TECHNOLOGIES INC. , TULCHINSKY, Michael, L. , PETERSON, Ronald, R.
发明人： TULCHINSKY, Michael, L. , PETERSON, Ronald, R.
IPC分类号： C07F9/50 , C07B41/06
CPC分类号： C07F9/5018
摘要： A compound comprising a sulfonated dihydrocarbyl(arylalkyl)phosphine of formula R 1 R 2 PR 3 -(SO 3 M) n , wherein the R 1 and R 2 are selected individually from alkyl, aralkyl, and alicyclic groups, and R 3 is a divalent or polyvalent arylalkylene radical such that the alkyl moiety is bonded to the phosphorus atom and the aryl moiety is bonded to the alkyl and is also substituted with one or more sulfonate groups; M is a monovalent cation, and n ranges from 1 to 3. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alkyl-aryl exchange, thereby leading to reduced ligand usage and improved ligand and transition metal, e.g., rhodium, recovery and recycling.
摘要翻译：包含式R 1 R 2 PR 3 - （SO 3 M）n的磺化二烃基（芳烷基）膦的化合物，其中R 1和R 2分别选自烷基，芳烷基和脂环基，R 3是二价或多价芳基亚烷基，使得烷基部分键合到磷原子上，芳基部分键合到烷基上并且也被一个或多个磺酸基团取代; M是一价阳离子，n在1至3的范围内。该化合物可用作过渡金属 - 配体配合物催化剂中的配体，其能够催化烯属不饱和化合物与一氧化碳和氢气的加氢甲酰化形成一个或多个更多相应的醛产品。配体不能进行烷基 - 芳基交换，从而导致配体使用减少，改进配体和过渡金属，例如铑，回收和回收。

2. 发明申请

WO2009137282A1 PROCESS FOR OLEFIN ETHERIFICATION 审中-公开
标题翻译：烯烃加工方法
公开(公告)号：WO2009137282A1
公开(公告)日：2009-11-12
申请号：PCT/US2009/041747
申请日：2009-04-27
申请人： DOW GLOBAL TECHNOLOGIES INC. , DAUGS, Edward, D. , FLICK, Derrick, W. , RAND, Cynthia, L. , TULCHINSKY, Michael, L. , YU, Wanglin
发明人： DAUGS, Edward, D. , FLICK, Derrick, W. , RAND, Cynthia, L. , TULCHINSKY, Michael, L. , YU, Wanglin
IPC分类号： C07C41/06 , C07C43/12
CPC分类号： C07C41/06 , C07C41/42 , Y02P20/127 , C07C43/12
摘要： The invention relates to processes for the etherification of olefins with alcohols. According to one aspect, a heterogeneous etherification catalyst is used under conditions that permit limiting the contact time between the desired product and the catalyst, thereby mitigation reverse reactions. According to a second aspect, a recycling process is used that significantly increases the yield of desired product.
摘要翻译：本发明涉及烯烃与醇醚化的方法。根据一个方面，在允许限制所需产物和催化剂之间的接触时间的条件下使用异相醚化催化剂，从而减轻逆向反应。根据第二方面，使用显着增加所需产物的产率的再循环方法。

3. 发明申请

WO2006047105A2 MEMBRANE SEPARATION OF A METATHESIS REACTION MIXTURE 审中-公开
标题翻译：一种细菌反应混合物的膜分离
公开(公告)号：WO2006047105A2
公开(公告)日：2006-05-04
申请号：PCT/US2005/036949
申请日：2005-10-14
申请人： DOW GLOBAL TECHNOLOGIES, INC. , BURDETT, Kenneth, A. , COLLINS, Raymond, M. , MAUGHON, Bob, R. , TULCHINSKY, Michael, L.
发明人： BURDETT, Kenneth, A. , COLLINS, Raymond, M. , MAUGHON, Bob, R. , TULCHINSKY, Michael, L.
IPC分类号： B01D61/00 , B01D61/14 , C07C7/144 , C07C6/00 , C07C6/04
CPC分类号： C07C7/144 , B01D61/027 , C07C6/04 , C07C2531/24
摘要： A process for separating a homogeneous metathesis catalyst and, optionally, one or more homogeneous metathesis catalyst degradation products from a metathesis reaction mixture containing in addition to said metathesis catalyst and said metathesis catalyst degradation product(s), one or more olefin metathesis products, one or more unconverted reactant olefins, and optionally, a solvent. The process involves contacting the metathesis reaction mixture with a nanofiltration membrane, such as a polyimide nanofiltration membrane, so as to recover a permeate containing a substantial portion of the olefin reaction products, the unconverted reactant olefins, and optional solvent, and a retentate containing the metathesis catalyst, and optionally, metathesis catalyst degradation product(s). In another aspect, this invention pertains to a continuous metathesis reaction-catalyst separation process, preferably, conducted in a nanofiltration membrane reactor.
摘要翻译：一种用于从包含所述复分解催化剂和所述复分解催化剂分解产物的复分解反应混合物中分离均相复分解催化剂和任选的一种或多种均化复分解催化剂降解产物的方法，一种或多种烯烃复分解产物，一种或更多未转化的反应物烯烃，以及任选的溶剂。该方法包括使复分解反应混合物与纳滤膜如聚酰亚胺纳滤膜接触，以回收含有大部分烯烃反应产物，未转化反应物烯烃和任选溶剂的渗透物，以及含有复分解催化剂和任选的复分解催化剂降解产物。另一方面，本发明涉及连续复分解反应 - 催化剂分离方法，优选在纳滤膜反应器中进行。

4. 发明申请

WO2009091670A1 SULFONATED ORGANOPHOSPHINE COMPOUNDS AND USE THEREOF IN HYDROFORMYLATION PROCESSES 审中-公开
标题翻译：硫化有机磷化合物及其在氢化方法中的应用
公开(公告)号：WO2009091670A1
公开(公告)日：2009-07-23
申请号：PCT/US2009/030556
申请日：2009-01-09
申请人： DOW GLOBAL TECHNOLOGIES INC. , HEFNER, Robert, E., Jr. , TULCHINSKY, Michael, L.
发明人： HEFNER, Robert, E., Jr. , TULCHINSKY, Michael, L.
IPC分类号： C07F9/50
CPC分类号： B01J31/2404 , B01J31/2447 , B01J31/4046 , B01J31/4053 , B01J2231/321 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/845 , B01J2531/96 , B01J2540/32 , B01J2540/64 , C07F9/5004 , C07F9/5018 , Y02P20/584
摘要： A compound comprising a class of sulfonated triorganophosphine compounds of formula R 1 R 2 P-R 3 [-O-(CH 2 ) n -(SO 3 M)] m , wherein the R 1 and R 2 are selected individually from alkyl, aralkyl, and alicyclic groups, wherein R 3 represents a divalent or polyvalent alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents via an alkylether link, and further wherein R 3 does not contain any aryl moieties; n is an integer reflecting a number of methylene groups in the alkylether link; M represents a monovalent cation; and m is an integer representing a total number of sulfonated alkylether substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alky-aryl exchange, thereby leading to reduced ligand usage and improving ligand and rhodium recovery and recycling.
摘要翻译：包含一类式R1R2P-R3 [-O-（CH2）n-（SO3M）] m的磺化三有机膦化合物的化合物，其中R1和R2分别选自烷基，芳烷基和脂环族基团，其中R3表示通过烷基醚连接键合到磷原子和一个或多个磺酸酯取代基的二价或多价亚烷基或脂环族基团，其中R3不含任何芳基部分; n是反映烷基链接中亚甲基数的整数; M表示一价阳离子; m为代表磺化烷基醚取代基总数的整数。该化合物可用作过渡金属 - 配体配合物催化剂中的配体，其能够催化烯属不饱和化合物与一氧化碳和氢气的加氢甲酰化形成一种或多种相应的醛产物。配体不能进行烷基 - 芳基交换，从而导致配体使用减少，并改善配体和铑的回收和再循环。

5. 发明申请

WO2010027663A1 POLYOL ETHERS AND PROCESS FOR MAKING THEM 审中-公开
标题翻译：聚合物及其制备方法
公开(公告)号：WO2010027663A1
公开(公告)日：2010-03-11
申请号：PCT/US2009/054277
申请日：2009-08-19
申请人： DOW GLOBAL TECHNOLOGIES INC. , TULCHINSKY, Michael, L. , BRIGGS, John, R. , RAND, Cynthia, L.
发明人： TULCHINSKY, Michael, L. , BRIGGS, John, R. , RAND, Cynthia, L.
IPC分类号： C07C41/01 , C07C43/13 , C07C67/08 , C07C67/31 , C07C69/708
CPC分类号： C07C69/708 , C07C41/01 , C07C67/08 , C07C67/31 , C07C2601/14 , C07C43/13 , C07C43/135 , C07C43/1785
摘要： New polyol ether compounds and a process for their preparation. The process comprises reacting a polyol, a carbonyl compound, and hydrogen in the presence of hydrogenation catalyst, to provide the polyol ether. The molar ratio of polyol to carbonyl compound in the process is greater than 5:1.
摘要翻译：新型多元醇醚化合物及其制备方法。该方法包括在氢化催化剂存在下使多元醇，羰基化合物和氢反应，得到多元醇醚。该过程中多元醇与羰基化合物的摩尔比大于5：1。

6. 发明申请

WO2009091671A1 SULFONATED ORGANOPHOSPHINE COMPOUNDS AND USE THEREOF IN HYDROFORMYLATION PROCESSES 审中-公开
标题翻译：硫化有机磷化合物及其在氢化方法中的应用
公开(公告)号：WO2009091671A1
公开(公告)日：2009-07-23
申请号：PCT/US2009/030560
申请日：2009-01-09
申请人： DOW GLOBAL TECHNOLOGIES INC. , TULCHINSKY, Michael, L. , ABATJOGLOU, Anthony, G.
发明人： TULCHINSKY, Michael, L. , ABATJOGLOU, Anthony, G.
IPC分类号： C07F9/50
CPC分类号： C07F9/5004 , C07F9/5018
摘要： A compound comprising a sulfonated triorganophosphine of formula R 1 R 2 PR 3 [SO 3 M)] n , wherein R 1 and R 2 are selected individually from alkyl, aralkyl, and alicyclic groups; wherein R 3 represents a branched divalent or polyvalent, alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents, and further wherein R 3 does not contain any aryl moieties; M represents a monovalent cation; and n is an integer representing a total number of sulfonated substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alkyl-aryl exchange, thereby leading to reduced ligand usage and improving ligand and transition metal, e.g., rhodium, recovery and recycling, as compared with prior art ligands.
摘要翻译：包含式R 1 R 2 PR 3 [SO 3 M]] n的磺化三有机膦化合物的化合物，其中R 1和R 2分别选自烷基，芳烷基和脂环基; 其中R3表示与磷原子和一个或多个磺酸酯取代基结合的支链二价或多价亚烷基或脂环族基团，其中R3不含任何芳基部分; M表示一价阳离子; n为代表磺化取代基总数的整数。该化合物可用作过渡金属 - 配体配合物催化剂中的配体，其能够催化烯属不饱和化合物与一氧化碳和氢气的羰基化形成一种或多种相应的醛产物。与现有技术的配体相比，配体不能进行烷基 - 芳基交换，从而导致配体使用减少并改善配体和过渡金属，例如铑，回收和再循环。

7. 发明申请

WO2007092071A1 1,3/1,4-CYCLOHEXANE DIMETHANOL BASED MONOMERS AND POLYMERS 审中-公开
标题翻译： 1,3 / 1,4-环己烷基二甲基甲硅烷基单体和聚合物
公开(公告)号：WO2007092071A1
公开(公告)日：2007-08-16
申请号：PCT/US2006/046696
申请日：2006-12-07
申请人： DOW GLOBAL TECHNOLOGIES INC. , BAIKERIKAR, Kiran, K. , TULCHINSKY, Michael, L. , ARGYROPOULOS, John, N.
发明人： BAIKERIKAR, Kiran, K. , TULCHINSKY, Michael, L. , ARGYROPOULOS, John, N.
IPC分类号： C07C29/80 , C07C69/533 , C07C69/54 , C08G63/199
CPC分类号： C08G63/47 , C07C29/80 , C07C2601/14 , C08G63/199 , C08G64/42 , C09D175/16 , C07C31/276
摘要： A mixture of compounds useful to make a polymer or a prepolymer, the mixture of compounds including compounds having the formula I; wherein R 1 is H, acryloyl, methacryloyl or vinyl, wherein R 2 is acryloyl, methacryloyl or vinyl, wherein compounds having the formula I consist of a mixture of cis and trans-1,3- and 1 ,4-substituted cyclohexane and wherein the trans- 1,4-substituted cyclohexane content of the compounds having the formula I is less than forty mole percent. A process for producing a mixture of compounds including compounds having the formula II: wherein compounds having the formula II consist of a mixture of cis and trans- 1,3- and 1 ,4- methanol substituted cyclohexane and wherein the trans- 1,4-methanol substituted cyclohexane content of the compounds having the formula II is less than twenty five mole percent.
摘要翻译：可用于制备聚合物或预聚物的化合物的混合物，化合物的混合物包括具有式I的化合物; 其中R 1是H，丙烯酰基，甲基丙烯酰基或乙烯基，其中R 2是丙烯酰基，甲基丙烯酰基或乙烯基，其中具有式I的化合物由顺式和反式 1,3-和1,4-取代的环己烷，其中具有式I的化合物的反式-1,4-取代的环己烷含量小于40摩尔％。一种制备包括具有式II化合物的化合物的混合物的方法：其中具有式II的化合物由顺式和反式-1,3-和1,4-甲醇取代的环己烷的混合物组成，其中反式-1,4 具有式II的化合物的甲醇取代的环己烷含量小于25摩尔％。

8. 发明申请

WO2011106194A3 PROCESS FOR MAKING POLYOL ETHERS 审中-公开
标题翻译：制备多元醇醚的方法
公开(公告)号：WO2011106194A3
公开(公告)日：2011-09-01
申请号：PCT/US2011/024844
申请日：2011-02-15
申请人： DOW GLOBAL TECHNOLOGIES LLC , OLKEN, Michael, M. , TULCHINSKY, Michael, L.
发明人： OLKEN, Michael, M. , TULCHINSKY, Michael, L.
IPC分类号： B01J23/44 , B01J23/54 , B01J37/02 , C07C41/28 , C07C43/13
摘要： The present invention generally relates to a process for making polyol ethers by reacting a polyol and a carbonyl compound together in the presence of hydrogen gas and a palladium hydrogenation catalyst on an acidic mesoporous carbon support.
摘要翻译：本发明一般涉及通过使多元醇和羰基化合物在氢气和钯氢化催化剂存在下在酸性介孔碳载体上反应来制备多元醇醚的方法。

9. 发明申请

WO2013062679A1 SURFACTANTS DERIVED FROM OLIGOLYCEROLS 审中-公开
标题翻译：来自低聚糖的表面活性剂
公开(公告)号：WO2013062679A1
公开(公告)日：2013-05-02
申请号：PCT/US2012/054639
申请日：2012-09-11
申请人： DOW GLOBAL TECHNOLOGIES LLC , TULCHINSKY, Michael, L. , YU, Wanglin , NG, Sze Sze , RAND, Cynthia, L.
发明人： TULCHINSKY, Michael, L. , YU, Wanglin , NG, Sze Sze , RAND, Cynthia, L.
IPC分类号： C11D1/72
CPC分类号： C11D7/263 , C11D1/72 , C11D7/06 , C11D7/3218
摘要： Provided is a surfactant composition comprising an oligoglycerol compound of formula I, wherein R and m are as defined above. The compounds exhibit favorable surfactancy properties. Advantageously, the compounds may be prepared from renewable materials.
摘要翻译：提供了包含式I的低聚甘油化合物的表面活性剂组合物，其中R和m如上所定义。该化合物表现出有利的表面活性。有利地，化合物可以由可再生材料制备。

10. 发明申请

WO2011136844A1 POLYCYCLOPENTADIENE POLYPHENOL AND POLYCYANATE POLYCYCLOPENTADIENE POLYPHENOL COMPOUNDS 审中-公开
标题翻译：聚环己二烯多元醇和聚氰酸酯多环戊二烯多元醇化合物
公开(公告)号：WO2011136844A1
公开(公告)日：2011-11-03
申请号：PCT/US2011/000706
申请日：2011-04-21
申请人： DOW GLOBAL TECHNOLOGIES LLC , HEFNER, Robert, E. , MULLINS, Michael, J. , TULCHINSKY, Michael, L. , OCCHIELLO, Ernesto
发明人： HEFNER, Robert, E. , MULLINS, Michael, J. , TULCHINSKY, Michael, L. , OCCHIELLO, Ernesto
IPC分类号： C07C39/17 , C07C261/02
CPC分类号： C07C261/02 , C07C39/17 , C07C2603/68 , C07C2603/91
摘要： Embodiments of the present disclosure include polycyclopentadiene compounds represented by Formula (I) : in which each X is either a hydrogen or a cyano group ( N≡C-), n has an average value from zero to 20; each m independently has a value of zero to 3; p has a value of zero to 20; each R is independently a halogen, a nitrile group, a nitro group, an alkyl group, an alkoxy group, an alkenyl group, or an alkenyloxy group, where the alkyl group, the alkoxy group, the alkenyl group, and the alkenyloxy group each independently contain 1 to 6 carbon atoms; and each Q is independently hydrogen or an alkyl group containing 1 to 6 carbon atoms. Embodiments of the present disclosure also include a curable composition that includes the polycyclopentadiene compound(s) of Formula (I) and a curing amount of a resin or a catalyst amount of a catalyst and/or a cure accelerating amount of an accelerating agent.
摘要翻译：本公开的实施方案包括由式（I）表示的聚环戊二烯化合物：其中每个X为氢或氰基（N = C-），n的平均值为0至20; 每个m独立地具有零到3的值; p的值为零到20; 每个R独立地是卤素，腈基，硝基，烷基，烷氧基，烯基或烯氧基，其中烷基，烷氧基，烯基和烯氧基各自独立地含有1至6个碳原子; 并且每个Q独立地为氢或含有1至6个碳原子的烷基。本公开的实施方案还包括包含式（I）的聚环戊二烯化合物和树脂的固化量或催化剂的催化剂量和/或加速剂的固化促进量的可固化组合物。

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