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    • 1. 发明申请
    • ANTI-SCORCH COMPOSITIONS, METHODS OF MAKING THE SAME, AND ARTICLES PREPARED FROM THE SAME
    • 抗分解组合物,其制备方法和由其制备的制品
    • WO2011038539A1
    • 2011-04-07
    • PCT/CN2009/074310
    • 2009-09-29
    • DOW GLOBAL TECHNOLOGIES INC.SUN, Yabin, SamMARCHAND, Gary, R.TAI, XiangyangPENG, ShuwenFENG, Shaoguang
    • SUN, Yabin, SamMARCHAND, Gary, R.TAI, XiangyangPENG, ShuwenFENG, Shaoguang
    • C08L19/00C08K3/06C08K5/19C08K5/3432C08K5/3445
    • C08K5/19C08C19/20C08J3/24C08K3/06C08K5/34C08K5/378C08L23/16C08L91/00C08L2312/00C08L2666/02
    • The invention provides a composition comprising at least the following: A) interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; B) sulfur; C) at least one phase transfer catalyst (PTC) selected from the group consisting of the following: Formula (1), wherein each R group is, independently, an alky group having from 4 to 32 carbon atoms, and X is a halogen ion; Formula (2), Wherein the R group is an alky group having from 4 to 32, and X is a halogen ion; Formula (3), wherein R1 is the alky group having from 1 to 4 carbon atoms, R2 is an alkyl group having from 1 to 32 carbon atoms, and X is a halogen ion; and combinations of (1), (2) and (3); and D) at least one primary accelerator selected from the group consisting of the following: Formula (a), wherein R is H, or a heterocyclic substituent; Formula (b), wherein M is Zn 2+ , K + , Na + , Cu 2+ or an alkyl ammonium; Formula (c), wherein R' and R" are each, independently, H, an alkyl, a cyclic alkyl, an aromatic, or a heterocyclic substituent, or wherein R' and R" together form a cyclic structure; Formula (d), wherein R, R', R" and R'" are each, independently, H, an alkyl, a cyclic alkyl, an aromatic, or a heterocyclic substituent; or wherein R and R' are each, independently, H, an alkyl, a cyclic alkyl, an aromatic, or a heterocyclic substituent, and R" and R'" together form a cyclic structure; or wherein R" and R'" are each, independently, H, an alkyl, a cyclic alkyl, an aromatic, or a heterocyclic substituent, and R and R' together form a cyclic structure; or wherein R" and R'" together form a cyclic structure, and R and R' together form a cyclic structure; and combinations thereof.
    • 本发明提供至少包含以下物质的组合物:A)以聚合形式包含乙烯,α-烯烃和非共轭多烯的共聚体; B)硫; C)选自下列的至少一种相转移催化剂(PTC):式(1),其中每个R基团独立地是具有4至32个碳原子的烷基,X是卤素离子 ; 式(2)其中,R基为4〜32的烷基,X为卤素离子; 式(3)其中R1是具有1至4个碳原子的烷基,R2是具有1至32个碳原子的烷基,X是卤素离子; 和(1),(2)和(3)的组合; 和D)选自下列的至少一种主要促进剂:式(a),其中R是H,或杂环取代基; 式(b),其中M为Zn2 +,K +,Na +,Cu2 +或烷基铵; 式(c),其中R'和R“各自独立地为H,烷基,环烷基,芳族或杂环取代基,或其中R'和R”一起形成环状结构; 式(d)其中R,R',R“和R”各自独立地为H,烷基,环烷基,芳族或杂环取代基; 或其中R和R'各自独立地为H,烷基,环烷基,芳族或杂环取代基,并且R“和R”“一起形成环状结构; 或其中R“和R”各自独立地为H,烷基,环烷基,芳族或杂环取代基,R和R'一起形成环状结构; 或其中R“和R”“一起形成环状结构,并且R和R'一起形成环状结构; 及其组合。
    • 3. 发明申请
    • AMIDO-ORGANOBORATE INITIATOR SYSTEMS
    • AMIDO-ORGANOBORATE发动机系统
    • WO2007044730A1
    • 2007-04-19
    • PCT/US2006/039575
    • 2006-10-06
    • DOW GLOBAL TECHNOLOGIES INC.FENG, ShaoguangJIANLANEILLA, Gary, L.NICKIAS, PeterRISTOSKI, Toni
    • FENG, ShaoguangJIANLANEILLA, Gary, L.NICKIAS, PeterRISTOSKI, Toni
    • C09J4/00C08F220/18
    • C08F220/18C07F5/02C08F4/52C09J4/00C09J4/06Y10T428/31504Y10T428/31855Y10T428/31909Y10T428/31913Y10T428/31928
    • In one embodiment, the invention is a system for initiating free radical polymerization comprising: a) in one part, one or more amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms and optionally containing one or more heteroatoms or heteroatom containing functional moieties, and one or more cationic counter ions and b) in a second part, a liberating compound which reacts with the nitrogen atom(s) bound to the boron atom(s) upon contact with the amido-borate to form an organoborane radical. In another embodiment, the invention is a two part polymerizable composition comprising in one part, one or more amido-borate compounds and in the second part, a liberating compound which reacts with the nitrogen atoms bound to the boron atom upon contact with the amido-borate to form an organoborane radical and one or more compounds capable of free radical polymerization. The first part may further comprise one or more compounds capable of free radical polymerization. This facilitates formulating compositions that have commercially desirable volumetric ratios of the two parts.
    • 在一个实施方案中,本发明是用于引发自由基聚合的系统,其包括:a)一部分,一种或多种含有一种或多种含有机硼酸盐的阴离子酰氨基硼酸盐部分的酰氨基硼酸盐化合物,其中硼原子与氮键合 氨原子或含有一个或多个氮原子的有机化合物,例如烃基胺,烃基多胺或含有一个或多个氮原子并且任选地含有一个或多个含杂原子或杂原子的官能部分的芳族杂环,以及一个或多个 更多的阳离子抗衡离子和b)在第二部分中,释放化合物与与氨基硼酸盐接触时与硼原子结合的氮原子反应形成有机硼烷基。 在另一个实施方案中,本发明是两部分可聚合组合物,其一部分包含一种或多种酰氨基硼酸盐化合物,而在第二部分中,与氨基 - 硼酸酯接触时与氮原子结合的氮原子反应的释放化合物, 硼酸盐形成有机硼烷基和一种或多种能够进行自由基聚合的化合物。 第一部分还可以包含一种或多种能够进行自由基聚合的化合物。 这有助于配制具有商业上期望的两部分体积比的组合物。
    • 6. 发明申请
    • AMIDO-ORGANOBORATE INITIATOR SYSTEMS
    • AMIDO-ORGANOBORATE发动机系统
    • WO2007044735A2
    • 2007-04-19
    • PCT/US2006/039584
    • 2006-10-06
    • DOW GLOBAL TECHNOLOGIES INC.FENG, ShaoguangJIALANELLA, Gary, L.NICKIAS, PeterRISTOSKI, Toni
    • FENG, ShaoguangJIALANELLA, Gary, L.NICKIAS, PeterRISTOSKI, Toni
    • C08F2/00C09J4/00
    • C08F220/18C07F5/02C08F4/52C09J4/00C09J4/06Y10T428/31504Y10T428/31855Y10T428/31909Y10T428/31913Y10T428/31928
    • In one embodiment, the invention is a system for initiating free radical polymerization comprising: a) in one part, one or more amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms, and a cationic counter ion and b) in a second part, a liberating compound which reacts with the nitrogen atom(s) bound to the boron atom upon contact with the amido-borate to form an organoborane radical. In another embodiment, the invention is a two part polymerizable composition comprising in one part, one or more amido-borate compounds and in the second part, a liberating compound which reacts with the nitrogen atoms bound to the boron atom upon contact with the amido-borate to form an organoborane radical and one or more compounds capable of free radical polymerization. The first part may further comprise one or more compounds capable of free radical polymerization. This facilitates formulating compositions that have commercially desirable volumetric ratios of the two parts.
    • 在一个实施方案中,本发明是用于引发自由基聚合的系统,其包括:a)一部分,一种或多种含有一种或多种含有机硼酸盐的阴离子酰氨基硼酸盐部分的酰氨基硼酸盐化合物,其中硼原子与氮键合 原子的氨或含有一个或多个氮原子的有机化合物,例如烃基胺,烃基多胺或含有一个或多个氮原子的芳族杂环,以及阳离子抗衡离子,和b)在第二部分中, 在与酰氨基硼酸盐接触时与与硼原子结合的氮原子反应形成有机硼烷基的化合物。 在另一个实施方案中,本发明是两部分可聚合组合物,其一部分包含一种或多种酰氨基硼酸盐化合物,而在第二部分中,与氨基 - 硼酸盐接触时与氮原子结合的氮原子反应的释放化合物, 硼酸盐以形成有机硼烷基和一种或多种能够进行自由基聚合的化合物。 第一部分还可以包含一种或多种能够进行自由基聚合的化合物。 这有助于制备具有商业上期望的两部分体积比的组合物。