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1. 发明申请

WO0149774A3 ORGANOSILOXANE COMPOSITIONS 审中-公开
标题翻译：有机硅氧烷组合物
公开(公告)号：WO0149774A3
公开(公告)日：2002-02-07
申请号：PCT/US0100221
申请日：2001-01-04
申请人： DOW CORNING , DOW CORNING ASIA LTD , DOW CORNING TORAY SILICONE , DOW CORNING SA , DEBUYL FRANCOIS , LUEDER TIMOTHY B , PALMER RICHARD A , TALCOTT DAVID M , ZHANG LOU CHENG , TACHIKAWA MAMORU , SARUYAMA TOSHIO , OKABE KAZUTOSHI
发明人： DEBUYL FRANCOIS , LUEDER TIMOTHY B , PALMER RICHARD A , TALCOTT DAVID M , ZHANG LOU CHENG , TACHIKAWA MAMORU , SARUYAMA TOSHIO , OKABE KAZUTOSHI
IPC分类号： C08K5/00 , C08K5/07 , C08L83/04 , C08L83/14
CPC分类号： C08K5/07 , C08G77/16 , C08G77/18 , C08G77/50 , C08K5/0091 , C08L83/04 , C08L83/14 , C08L2666/28
摘要： A composition formed by mixing (i) a compound having the general formula M [OR] 4, where M represents a metal having a valence of 4 selected from Group IVB of the Periodic Table, and each R is the same or different and is selected from methyl and tertiary aliphatic hydrocarbon groups; with (ii) a compound of the general formula (1) wherein R is selected from a methylene group or a substituted methylene radical having 1 to 6 carbon atoms, A represents -(CX2)nC(R )3, wherein n is from 0 to 5, each X is the same or different and is selected from a halogen radical and hydrogen, each R is the same or different and is selected from the group of a halogen radical and an alkyl radical having 1 to 8 carbon atoms; and B has the general formula OR , where R is selected from methyl, ethyl, t-butyl, and amyl groups is disclosed as a catalyst for a moisture curable composition. The resulting moisture curable composition has improved green strengh and working time.
摘要翻译：通过混合（i）具有通式M [OR] 4的化合物，其中M表示选自元素周期表IVB族中的价数4的金属和每个R相同或不同，并且被选择来自甲基和叔脂族烃基; 与（ii）通式（1）的化合物，其中R 1选自亚甲基或具有1至6个碳原子的取代的亚甲基，A表示 - （CX2）nC（R 2）3 ，其中n为0至5，每个X相同或不同，并且选自卤素基团和氢，每个R 2相同或不同，并且选自卤素基团和具有1至8个碳原子的烷基; 和B具有通式OR 3，其中R 3选自甲基，乙基，叔丁基和戊基作为可湿气固化组合物的催化剂。所得到的湿固化组合物具有改善的绿色强度和工作时间。

2. 发明申请

WO0149789A8 ORGANOSILOXANE COMPOSITIONS 审中-公开
标题翻译：有机硅氧烷组合物
公开(公告)号：WO0149789A8
公开(公告)日：2002-10-10
申请号：PCT/EP0100070
申请日：2001-01-04
申请人： DOW CORNING SA , DOW CORNING ASIA LTD , DOW CORNING TORAY SILICONE , TACHIKAWA MAMORU , SARUYAMA TOSHIO , OKABE KAZUTOSHI , ADACHI HIROSHI , DE BUYL FRANCOIS , SPRINGAEL SABINE , ZHANG LUO CHENG
发明人： TACHIKAWA MAMORU , SARUYAMA TOSHIO , OKABE KAZUTOSHI , ADACHI HIROSHI , DE BUYL FRANCOIS , SPRINGAEL SABINE , ZHANG LUO CHENG
IPC分类号： C08K5/00 , C08K5/07 , C08L83/04
CPC分类号： C08K5/0091 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/24 , C08G77/50 , C08G77/70 , C08G77/80 , C08K5/07 , C08L83/04 , C08L2666/52
摘要： A moisture curable composition capable of cure to an elastomeric body, comprising a polymeric material having not less than two hydroxyl or hydrolysable groups an alkoxysilane curative and a catalyst comprising: a mixture and/or reaction product of a compound (i) selected from M[OR]4 and M[OR']x[Z]z, wherein M represents a metal having a valency of 4 selected from Group IVB of the Periodic Table, preferably titanium or zirconium. Each R and R' may be a primary, secondary or tertiary aliphatic hydrocarbon or the group SiR 3; and a compound (ii) of the general formula A-C(=O)R -C(=O)-B wherein R is a methylene group or a substituted methylene radical, A is selected from -(CX2)nC(R )3 wherein n is from 0 to 5, and an adamantyl group or a derivative thereof; B is selected from the group of -(CX2)tC(R )3 wherein t is from 0 to 5; a monovalent alkyl group having from 1 to 6 carbon atoms; and OR , wherein R is selected from the group of -(CX2)tC(R )3 and a monovalent alkyl group having from 1 to 6 carbon atoms; wherein each X is the same or different and is selected from the group of a halogen radical and hydrogen, each R is the same or different and is selected from the group of a halogen radical and an alkyl radical having one to eight carbon atoms, and when n is greater than 0 at least one of X or R is a halogen radical.
摘要翻译：一种可固化成弹性体的可湿固化组合物，其包含具有不少于两个羟基或可水解基团的聚合物材料，烷氧基硅烷固化剂和催化剂，所述催化剂包含：选自以下的化合物（i）的混合物和/或反应产物： OR] 4和M [OR'] x [Z] z，其中M表示选自周期表第IVB族的4价金属，优选钛或锆。每个R和R'可以是伯，仲或叔脂族烃或SiR 9 3基团; 和通式AC（= O）R 1 -C（= O）-B的化合物（ii），其中R 1是亚甲基或取代的亚甲基，A选自 - （CX 2） nC（R 2）3，其中n为0-5，金刚烷基或其衍生物; B选自 - （CX 2）t C（R 2）3，其中t是0至5; 具有1至6个碳原子的一价烷基; 和OR 3，其中R 3选自 - （CX 2）t C（R 2）3和具有1至6个碳原子的一价烷基; 其中每个X是相同的或不同的并且选自卤素基团和氢的基团，每个R 2相同或不同并且选自卤素基团和具有1至8个碳的烷基原子，并且当n大于0时，X或R 2中的至少一个是卤素基团。

3. 发明申请

WO0149789A3 ORGANOSILOXANE COMPOSITIONS 审中-公开
标题翻译：有机硅氧烷组合物
公开(公告)号：WO0149789A3
公开(公告)日：2002-03-21
申请号：PCT/EP0100070
申请日：2001-01-04
申请人： DOW CORNING SA , DOW CORNING ASIA LTD , DOW CORNING TORA SILICONE CO L , TACHIKAWA MAMORU , SARUYAMA TOSHIO , KAZUTOSHI OKABE , ADACHI HIROSHI , BUYL FRANCOIS DE , SPRINGAEL SABINE , ZHANG LUO CHENG
发明人： TACHIKAWA MAMORU , SARUYAMA TOSHIO , KAZUTOSHI OKABE , ADACHI HIROSHI , DE BUYL FRANCOIS , SPRINGAEL SABINE , ZHANG LUO CHENG
IPC分类号： C08K5/00 , C08K5/07 , C08L83/04
CPC分类号： C08K5/0091 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/24 , C08G77/50 , C08G77/70 , C08G77/80 , C08K5/07 , C08L83/04 , C08L2666/52
摘要： A moisture curable composition capable of cure to an elastomeric body, comprising a polymeric material having not less than two hydroxyl or hydrolysable groups an alkoxysilane curative and a catalyst comprising: a mixture and/or reaction product of a compound (i) selected from M[OR]4 and M[OR']x[Z]z, wherein M represents a metal having a valency of 4 selected from Group IVB of the Periodic Table, preferably titanium or zirconium. Each R and R' may be a primary, secondary or tertiary aliphatic hydrocarbon or the group SiR 3; and a compound (ii) of the general formula A-C(=O)R -C(=O)-B wherein R is a methylene group or a substituted methylene radical, A is selected from -(CX2)nC(R )3 wherein n is from 0 to 5, and an adamantyl group or a derivative thereof; B is selected from the group of -(CX2)tC(R )3 wherein t is from 0 to 5; a monovalent alkyl group having from 1 to 6 carbon atoms; and OR , wherein R is selected from the group of -(CX2)tC(R )3 and a monovalent alkyl group having from 1 to 6 carbon atoms; wherein each X is the same or different and is selected from the group of a halogen radical and hydrogen, each R is the same or different and is selected from the group of a halogen radical and an alkyl radical having one to eight carbon atoms, and when n is greater than 0 at least one of X or R is a halogen radical.
摘要翻译：包含具有不少于2个羟基或可水解基团的聚合物材料的可湿固化组合物，其中烷氧基硅烷固化剂和催化剂包含：选自M [ OR] 4和M [OR'] x [Z] z表示的化合物，其中M表示选自元素周期表IVB族的化合价为4的金属，优选为钛或锆。每个R和R'可以是伯，仲或叔脂族烃或SiR 9; 和通式AC（= O）R 1 -C（= O）-B的化合物（ii），其中R 1是亚甲基或取代的亚甲基，A选自 - （CX 2） nC（R 2）3，其中n为0至5，金刚烷基或其衍生物; B选自 - （CX2）tC（R 2）3，其中t为0至5; 具有1至6个碳原子的一价烷基; 和OR 3，其中R 3选自 - （CX 2）t C（R 2）3和具有1至6个碳原子的一价烷基; 其中每个X相同或不同，并且选自卤素基团和氢基团，每个R 2相同或不同，并且选自卤素基团和具有一至八个碳原子的烷基基团原子，并且当n大于0时，X或R 2中的至少一个是卤素基团。

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