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1. 发明申请

WO0149789A8 ORGANOSILOXANE COMPOSITIONS 审中-公开
标题翻译：有机硅氧烷组合物
公开(公告)号：WO0149789A8
公开(公告)日：2002-10-10
申请号：PCT/EP0100070
申请日：2001-01-04
申请人： DOW CORNING SA , DOW CORNING ASIA LTD , DOW CORNING TORAY SILICONE , TACHIKAWA MAMORU , SARUYAMA TOSHIO , OKABE KAZUTOSHI , ADACHI HIROSHI , DE BUYL FRANCOIS , SPRINGAEL SABINE , ZHANG LUO CHENG
发明人： TACHIKAWA MAMORU , SARUYAMA TOSHIO , OKABE KAZUTOSHI , ADACHI HIROSHI , DE BUYL FRANCOIS , SPRINGAEL SABINE , ZHANG LUO CHENG
IPC分类号： C08K5/00 , C08K5/07 , C08L83/04
CPC分类号： C08K5/0091 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/24 , C08G77/50 , C08G77/70 , C08G77/80 , C08K5/07 , C08L83/04 , C08L2666/52
摘要： A moisture curable composition capable of cure to an elastomeric body, comprising a polymeric material having not less than two hydroxyl or hydrolysable groups an alkoxysilane curative and a catalyst comprising: a mixture and/or reaction product of a compound (i) selected from M[OR]4 and M[OR']x[Z]z, wherein M represents a metal having a valency of 4 selected from Group IVB of the Periodic Table, preferably titanium or zirconium. Each R and R' may be a primary, secondary or tertiary aliphatic hydrocarbon or the group SiR 3; and a compound (ii) of the general formula A-C(=O)R -C(=O)-B wherein R is a methylene group or a substituted methylene radical, A is selected from -(CX2)nC(R )3 wherein n is from 0 to 5, and an adamantyl group or a derivative thereof; B is selected from the group of -(CX2)tC(R )3 wherein t is from 0 to 5; a monovalent alkyl group having from 1 to 6 carbon atoms; and OR , wherein R is selected from the group of -(CX2)tC(R )3 and a monovalent alkyl group having from 1 to 6 carbon atoms; wherein each X is the same or different and is selected from the group of a halogen radical and hydrogen, each R is the same or different and is selected from the group of a halogen radical and an alkyl radical having one to eight carbon atoms, and when n is greater than 0 at least one of X or R is a halogen radical.
摘要翻译：一种可固化成弹性体的可湿固化组合物，其包含具有不少于两个羟基或可水解基团的聚合物材料，烷氧基硅烷固化剂和催化剂，所述催化剂包含：选自以下的化合物（i）的混合物和/或反应产物： OR] 4和M [OR'] x [Z] z，其中M表示选自周期表第IVB族的4价金属，优选钛或锆。每个R和R'可以是伯，仲或叔脂族烃或SiR 9 3基团; 和通式AC（= O）R 1 -C（= O）-B的化合物（ii），其中R 1是亚甲基或取代的亚甲基，A选自 - （CX 2） nC（R 2）3，其中n为0-5，金刚烷基或其衍生物; B选自 - （CX 2）t C（R 2）3，其中t是0至5; 具有1至6个碳原子的一价烷基; 和OR 3，其中R 3选自 - （CX 2）t C（R 2）3和具有1至6个碳原子的一价烷基; 其中每个X是相同的或不同的并且选自卤素基团和氢的基团，每个R 2相同或不同并且选自卤素基团和具有1至8个碳的烷基原子，并且当n大于0时，X或R 2中的至少一个是卤素基团。

2. 发明申请

WO0149789A3 ORGANOSILOXANE COMPOSITIONS 审中-公开
标题翻译：有机硅氧烷组合物
公开(公告)号：WO0149789A3
公开(公告)日：2002-03-21
申请号：PCT/EP0100070
申请日：2001-01-04
申请人： DOW CORNING SA , DOW CORNING ASIA LTD , DOW CORNING TORA SILICONE CO L , TACHIKAWA MAMORU , SARUYAMA TOSHIO , KAZUTOSHI OKABE , ADACHI HIROSHI , BUYL FRANCOIS DE , SPRINGAEL SABINE , ZHANG LUO CHENG
发明人： TACHIKAWA MAMORU , SARUYAMA TOSHIO , KAZUTOSHI OKABE , ADACHI HIROSHI , DE BUYL FRANCOIS , SPRINGAEL SABINE , ZHANG LUO CHENG
IPC分类号： C08K5/00 , C08K5/07 , C08L83/04
CPC分类号： C08K5/0091 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/24 , C08G77/50 , C08G77/70 , C08G77/80 , C08K5/07 , C08L83/04 , C08L2666/52
摘要： A moisture curable composition capable of cure to an elastomeric body, comprising a polymeric material having not less than two hydroxyl or hydrolysable groups an alkoxysilane curative and a catalyst comprising: a mixture and/or reaction product of a compound (i) selected from M[OR]4 and M[OR']x[Z]z, wherein M represents a metal having a valency of 4 selected from Group IVB of the Periodic Table, preferably titanium or zirconium. Each R and R' may be a primary, secondary or tertiary aliphatic hydrocarbon or the group SiR 3; and a compound (ii) of the general formula A-C(=O)R -C(=O)-B wherein R is a methylene group or a substituted methylene radical, A is selected from -(CX2)nC(R )3 wherein n is from 0 to 5, and an adamantyl group or a derivative thereof; B is selected from the group of -(CX2)tC(R )3 wherein t is from 0 to 5; a monovalent alkyl group having from 1 to 6 carbon atoms; and OR , wherein R is selected from the group of -(CX2)tC(R )3 and a monovalent alkyl group having from 1 to 6 carbon atoms; wherein each X is the same or different and is selected from the group of a halogen radical and hydrogen, each R is the same or different and is selected from the group of a halogen radical and an alkyl radical having one to eight carbon atoms, and when n is greater than 0 at least one of X or R is a halogen radical.
摘要翻译：包含具有不少于2个羟基或可水解基团的聚合物材料的可湿固化组合物，其中烷氧基硅烷固化剂和催化剂包含：选自M [ OR] 4和M [OR'] x [Z] z表示的化合物，其中M表示选自元素周期表IVB族的化合价为4的金属，优选为钛或锆。每个R和R'可以是伯，仲或叔脂族烃或SiR 9; 和通式AC（= O）R 1 -C（= O）-B的化合物（ii），其中R 1是亚甲基或取代的亚甲基，A选自 - （CX 2） nC（R 2）3，其中n为0至5，金刚烷基或其衍生物; B选自 - （CX2）tC（R 2）3，其中t为0至5; 具有1至6个碳原子的一价烷基; 和OR 3，其中R 3选自 - （CX 2）t C（R 2）3和具有1至6个碳原子的一价烷基; 其中每个X相同或不同，并且选自卤素基团和氢基团，每个R 2相同或不同，并且选自卤素基团和具有一至八个碳原子的烷基基团原子，并且当n大于0时，X或R 2中的至少一个是卤素基团。

3. 发明申请

WO2013117487A3 SUBSTRATE IN POWDER OR FIBRE FORM 审中-公开
标题翻译：粉末或纤维形式的基材
公开(公告)号：WO2013117487A3
公开(公告)日：2013-10-10
申请号：PCT/EP2013051965
申请日：2013-01-31
申请人： DOW CORNING , CHEVALIER PIERRE , DE BUYL FRANCOIS , MILLER SCOTT , PAULO CHRISTOPHE , RERAT VINCENT
发明人： CHEVALIER PIERRE , DE BUYL FRANCOIS , MILLER SCOTT , PAULO CHRISTOPHE , RERAT VINCENT
IPC分类号： C09C3/10 , C09C3/12
CPC分类号： C08J3/203 , C01P2006/22 , C08J7/047 , C08K9/06 , C08L23/12 , C08L27/18 , C08L63/00 , C08L83/04 , C08L2201/02 , C08L2205/03 , C09C3/10 , C09C3/12 , Y10T428/2962 , Y10T428/2995
摘要： The invention provides a substrate in powder or fibre form whose surface is treated with a silicone compound, characterised in that the surface has been treated with an emulsion containing the silicone compound, water and a ethylene oxide/propylene oxide block copolymer.
摘要翻译：本发明提供了一种粉末或纤维形式的基材，其表面用硅氧烷化合物处理，其特征在于表面已经用含有硅氧烷化合物，水和环氧乙烷/环氧丙烷嵌段共聚物的乳液处理。

4. 发明申请

WO2012099882A2 METHOD FOR PRODUCING SILYL-FUNCTIONALIZED POLYOLEFINS AND SILYL-FUNCTIONALIZED POLYOLEFINS WITH SILYL MONOMER INCORPORATION 审中-公开
标题翻译：用SILYL MONOMER INCORPORATION生产硅官能化聚烯烃和硅烷官能化聚烯烃的方法
公开(公告)号：WO2012099882A2
公开(公告)日：2012-07-26
申请号：PCT/US2012021558
申请日：2012-01-17
申请人： DOW CORNING , UNIV NORTHWESTERN , BURNS GARY , DE BUYL FRANCOIS , FU PENG-FEI , MARKS TOBIN J , SMITS VALERIE
发明人： BURNS GARY , DE BUYL FRANCOIS , FU PENG-FEI , MARKS TOBIN J , SMITS VALERIE
IPC分类号： C08F210/00 , C08L43/04
CPC分类号： C08F230/08 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F210/02 , C08F210/06 , C08J9/04 , C08J2323/08 , C08J2323/14 , C08J2343/04 , C08F2500/03 , C08F2230/085
摘要： Methods for producing a silyl-functionalized polyolefin with silyl monomer incorporation are provided. The method includes reacting a silicon-containing olefin with an a-olefin, in the presence of a catalytic amount of a group IV catalyst for a time sufficient to produce a silyl-functionalized polyolefin.
摘要翻译：提供了用甲硅烷基单体掺入制备甲硅烷基官能化聚烯烃的方法。该方法包括使含硅烯烃与α-烯烃在催化量的IV族催化剂存在下反应足以产生甲硅烷基官能化聚烯烃的时间。

5. 发明申请

WO2011083050A2 MODIFIED DIENE ELASTOMERS 审中-公开
标题翻译：改性的二烯弹性体
公开(公告)号：WO2011083050A2
公开(公告)日：2011-07-14
申请号：PCT/EP2010070489
申请日：2010-12-22
申请人： DOW CORNING , BACKER MICHAEL , CHAUSSEE THOMAS , DE BUYL FRANCOIS , DEHEUNYNCK DAMIEN , HABIMANA JEAN DE LA CROIX , SMITS VALERIE
发明人： BACKER MICHAEL , CHAUSSEE THOMAS , DE BUYL FRANCOIS , DEHEUNYNCK DAMIEN , HABIMANA JEAN DE LA CROIX , SMITS VALERIE
IPC分类号： C08F253/00
CPC分类号： C08K3/36 , B60C1/00 , C08C19/25 , C08F253/00 , C08F279/02 , C08F291/02 , C08G77/442 , C08K5/5425 , C08K5/544 , Y02T10/862 , C08F230/08 , C08L7/00 , C08L15/00
摘要： The invention is related to a process for grafting silane or silicone functionality onto a diene elastomer, comprising reacting the diene elastomer with an unsaturated monomer (A) containing an olefinic-C=C-bond or acetylenic -C=C- bond and a reactive functional group X with an organosilicon compound (B) having a functional group Y which is reactive with the functional group X of the unsaturated monomer (A). According to the invention, the unsaturated monomer (A) has the formula R"-CH=CH-Z (I) or R"-C=C-Z (II) in which Z represents an electron-withdrawing moiety containing the reactive functional group X and R" represents hydrogen or a group having an electron withdrawing effect or any other activation effect with respect to the -CH=CH-or -C=C- bond. According to a second aspect of the invention, the unsaturated monomer (A') contains at least two groups of the formula R"- CH=CH-Z'-(III) or R"-C=C-Z'-(IV) in which Z' represents a divalent linkage having an electron withdrawing effect with respect to the -CH=CH-or -C=C-bond, and R" represents hydrogen or a group having an electron withdrawing effect or any other activation effect with respect to the -CH=CH-or -C=C-bond, and the functional group Y of the organosilicon compound (B) is capable of reacting with the olefinic or acetylenic bond present in the group R"-CH=CH-Z'- (III) or R"-C=C-Z'- (IV). Such elastomer composition can be used to produce tires with good rolling resistance.
摘要翻译：本发明涉及将硅烷或硅氧烷官能团接枝到二烯弹性体上的方法，该方法包括使二烯弹性体与含有烯属-C = C-键或炔属-C = C-键的不饱和单体（A）官能团X与具有可与不饱和单体（A）的官能团X反应的官能团Y的有机硅化合物（B）。根据本发明，不饱和单体（A）具有式R“-CH = CH-Z（I）或R”-C = CZ（II）其中Z表示含有反应性官能团X的吸电子部分根据本发明的第二方面，所述不饱和单体（A'）与所述不饱和单体（A'）具有不同的吸电子效应或任何其它活化作用，）含有至少两个式R“-CH = CH-Z' - （III）或R”-C = C-Z' - （IV）的基团，其中Z'代表具有吸电子效应的二价连接基团关于-CH = CH-或-C = C-键，并且R“表示氢或对于-CH = CH-或-C = C-键具有吸电子效应或任何其它活化作用的基团并且有机硅化合物（B）的官能团Y能够与存在于基团R“-CH = CH-Z'-（III）或R”-C = C-Z'中的烯属或炔属键反应， - （IV）。这种弹性体组合物可用于生产具有良好滚动阻力的轮胎。

6. 发明申请

WO2008132236A2 POLYMER AND POLYMER COMPOSITIONS 审中-公开
标题翻译：聚合物和聚合物组合物
公开(公告)号：WO2008132236A2
公开(公告)日：2008-11-06
申请号：PCT/EP2008055369
申请日：2008-04-30
申请人： DOW CORNING , DE BUYL FRANCOIS , DURAND GERALDINE , MACKINNON IAIN A , O'HARE SARAH
发明人： DE BUYL FRANCOIS , DURAND GERALDINE , MACKINNON IAIN A , O'HARE SARAH
IPC分类号： C08G77/46
CPC分类号： C08G77/46 , C08K5/54 , C08L83/04 , C08L83/12 , C08L2666/44 , C08L83/00
摘要： A polyorganosiloxane polyoxyalkylene block copolymer having one or more polyorganosiloxane blocks and one or more polyoxyalkylene blocks linked to each other via divalent radicals which comprises at least two silicon-bonded alkoxy groups, preferably of the form PS (A PO) m (A PS) n , wherein PO is a polyoxyalkylene block, PS represents a polyorganosiloxane block, A is a divalent radical, m and n have independently a value of at least 1, comprising at least one alkoxy-substituted siloxane unit of the formula (R' ) q (OR)- SiO 3-q/2' wherein R represents an alkyl group having 1 to 4 carbon atoms and each R' represents an alkyl group having 1 to 6 carbon atoms, a phenyl group, or an alkoxy group of the formula -OR and q has a value of 0, 1 or 2, provided at least two silicon-bonded groups OR are present in the block copolymer. Also provided is a curable composition of the above which may comprise a condensation catalyst and a hydrophilic polymer network made from curing the composition in the presence of moisture, which exhibit interesting reversible hydrophilic properties.
摘要翻译：一种具有一个或多个聚有机硅氧烷嵌段和一个或多个聚氧化烯嵌段的聚有机硅氧烷聚氧化烯嵌段共聚物，其通过二价基团相互连接，所述二价基团包含至少两个与硅键合的烷氧基，优选形式为PS（A PO）其中PO是聚氧化烯嵌段，PS表示聚有机硅氧烷嵌段，A是二价基团，m和n独立地为至少为1的值，包括至少一个式（R'）q（OR） - SiO 3-q / 2'的烷氧基取代的硅氧烷单元其中R表示具有1至4个碳原子的烷基并且每个R'表示具有1至6个碳原子的烷基，苯基或式-OR的烷氧基，并且q具有0,1或2的值，条件是至少两个硅键合基团OR分别为存在于嵌段共聚物中。还提供了上述可固化组合物，其可以包含缩合催化剂和通过在水分存在下固化组合物而形成的亲水性聚合物网络，其显示出有趣的可逆亲水性质。

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