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    • 5. 发明申请
    • A METHOD OF PRODUCING GLASS OF OPTICAL QUALITY
    • 生产光学玻璃的方法
    • WO2006094877A1
    • 2006-09-14
    • PCT/EP2006/050954
    • 2006-02-15
    • DEGUSSA AGOSWALD, MonikaMEYER, JürgenDELLER, Klaus
    • OSWALD, MonikaMEYER, JürgenDELLER, Klaus
    • C03B37/012C03B19/01C03B19/10C01B33/18
    • C03B37/01291C03B19/01C03B19/102C03B19/106C03B2201/07C03B2201/12
    • Glass is produced by depositing presintering composition on a preform set into move in front of a plasma torch which moves back and forth substantially parallel to a longitudinal direction of the preform, a first feed duct feeds the plasma with grains of the presintering composition while optionally a second feed duct feeds the plasma with a fluorine or chlorine compound, preferably a fluorine compound, mixed with a carrier gas, whereby the presintering composition consists of granules of metal oxides or metalloid oxides of a pyrogenic silicon dioxide powder with a BET surface area of 30 to 90 m2/g, a DBP index of 80 or less, a mean aggregate area of less than 25000 nm2 and a mean aggregate circumference of less than 1000 nm, wherein at least 70% of the aggregates have a circumference of less than 1300 nm or a high-purity pyrogenically prepared silicon dioxide having metal contents of less than 0.2 μg/g, which is prepared by reacting a silicon tetrachloride having a metal content of less than 30 ppb by means of flame hydrolysis.
    • 玻璃是通过将预烧结组合物沉积在等离子体焰炬之前移动的预成型体上制造的,所述等离子体焰炬基本上平行于预成型件的纵向方向前后移动,第一进料管将预烧结组合物的颗粒进料到等离子体, 第二进料管将等离子体与载体气体混合的氟或氯化合物,优选氟化合物进料,其中预烧结组合物由BET表面积为30的热解二氧化硅粉末的金属氧化物或准金属氧化物颗粒组成 至90m 2 / g,DBP指数为80以下,平均聚集面积小于25000nm 2,平均聚集体周长小于1000nm,其中至少70%的聚集体具有小于1300nm的圆周 或金属含量小于0.2μg/ g的高纯度热解法制备的二氧化硅,其通过使金属含量为1的四氯化硅 通过火焰水解30埃以上。
    • 7. 发明申请
    • METHOD FOR PRODUCING ULTRA-HIGH PURITY, OPTICAL QUALITY, GLASS ARTICLES
    • 生产超高纯度,光学品质,玻璃制品的方法
    • WO2006094878A1
    • 2006-09-14
    • PCT/EP2006/050971
    • 2006-02-15
    • DEGUSSA AGOSWALD, MonikaMEYER, JürgenDELLER, Klaus
    • OSWALD, MonikaMEYER, JürgenDELLER, Klaus
    • C03B19/06C03B32/00C01B33/18
    • C03B19/06C03B19/066C03B32/005
    • A method for producing ultra-high purity, optical quality, glass articles is disclosed which involves: 1. compacting metaloxide or metal loidoxide to granules having a mean particle size of less than about 1 millimeter; 2. optionally fully sintering the granules to produce high purity, artificial sand; 3. casting the granulesar artificial sand by conventional techniques, such as, slip casting, to form a high density, porous, green body; 4. optionally drying and partially sintering the green body; 5. optionally fully sintering the green body under vacuum,- and 6. optionally hot isostatic pressing the fully sintered green body whereby the metal oxide or metalloid oxides is a pyrogenic silicon dioxide powder with a BET surface area of 30 to 90 m2/g, a DBP index of 80 or less, a mean aggregate area of less than 25000 nm2 and a mean aggregate circumference of less than 1000 nm, wherein at least 70% of the aggregates have a circumference of less than 1300 nm or a high-purity pyrogenically prepared silicon dioxide having metal contents of less than 0.2 µg/g.
    • 公开了一种生产超高纯度,光学品质的玻璃制品的方法,其包括:1.将金属氧化物或金属氧化物压制成具有小于约1毫米的平均粒度的颗粒; 2.可选地完全烧结颗粒以产生高纯度人造砂; 3.通过常规技术如滑移浇注铸造颗粒状人造砂,形成高密度,多孔,生坯; 4.可选地干燥和部分烧结生坯; 5.可选地,在真空下完全烧结生坯体,以及6.可选地,对等离子体等温压制完全烧结的生坯,由此金属氧化物或准金属氧化物是BET表面积为30至90m 2 / g的致热二氧化硅粉末, DBP指数为80以下,平均聚集面积小于25000nm 2,平均聚集体周长小于1000nm,其中至少70%的聚集体具有小于1300nm的圆周或高纯度热解法 制备金属含量小于0.2μg/ g的二氧化硅。
    • 8. 发明申请
    • PROCESS FOR THE PRODUCTION OF GLASS-MONOLITHS BY MEANS OF THE SOL-GEL PROCESS
    • 通过溶胶凝胶法生产玻璃单体的方法
    • WO2006094875A1
    • 2006-09-14
    • PCT/EP2006/050919
    • 2006-02-14
    • DEGUSSA AGOSWALD, MonikaDELLER, Klaus
    • OSWALD, MonikaDELLER, Klaus
    • C03B19/12
    • C03B19/12Y02P40/57
    • Method for fabricating a glass -monolith by the sol-gel process, in which a pyrogenically produced silica (fumed silica) is used in the form of a powder and/or a dispersion, characterized in that as pyrogenically produced silica (fumed silica) a silica (fumed silica) deriving from the group highly pure, pyrogenically produced silica (fumed silica) with a metal content of lower than 9 ppm and/or a pyrogenically prepared silicon dioxide powder having - a BET surface area of 30 to 90 m2/g, - a DBP number of 80 or less, an average aggregate area of less than 25,000 nm2 , an average aggregate circumference of less than 1,000 nm, at least 70 % of the aggregates having a circumference of less than 1,300 nm is used.
    • 通过溶胶 - 凝胶法制造玻璃 - 单晶的方法,其中以粉末和/或分散体的形式使用热解法生产的二氧化硅(热解法二氧化硅),其特征在于,作为热解法生产的二氧化硅(热解二氧化硅)a 衍生自具有金属含量低于9ppm的高纯度,热解法生产的二氧化硅(热解法二氧化硅)和/或热解法制备的二氧化硅粉末(BET表面积为30至90m 2 / g)的二氧化硅(热解法二氧化硅) , - DBP值为80以下,平均聚集面积小于25000nm 2,平均聚集体周长小于1000nm,使用周长小于1300nm的聚集体的至少70%。
    • 10. 发明申请
    • SLIP CONTAINING ZIRCONIUM DIOXIDE AND ALUMINIUM OXIDE AND SHAPED BODY OBTAINABLE THEREFROM
    • 含有二氧化铅和氧化铝的滑动物和可获得的形状体
    • WO2006117318A1
    • 2006-11-09
    • PCT/EP2006/061864
    • 2006-04-27
    • DEGUSSA AGOSWALD, MonikaDELLER, Klaus
    • OSWALD, MonikaDELLER, Klaus
    • C04B35/119
    • C04B35/119
    • Slip containing at least one aluminium oxide powder and at least one unstabilized zirconium dioxide powder, wherein a) the zirconium dioxide powder i) has a mean particle diameter of less than 300 nm, ii) shows only the monoclinic phase and the tetragonal phase in the X-ray diffraction pattern, with the proportion of tetragonal phase at room temperature being from 20 to 70%, and iii) is present in a proportion of from 2 to 20% by weight, based on the total amount of the slip, b) the aluminium oxide powder i) has a mean particle diameter of more than 300 nm and ii) is present in a proportion of from 80 to 98% by weight, based on the total amount of the slip, and c) the solids content, as the sum of aluminium oxide and zirconium dioxide, is from 50 to 85% by weight, based on the total amount of the slip.
    • 含有至少一种氧化铝粉末和至少一种不稳定的二氧化锆粉末的滑动剂,其中a)二氧化锆粉末i)的平均粒径小于300nm,ii)仅显示单斜相和四方相 X射线衍射图,四方相在室温下的比例为20〜70%,和iii)以2〜20%(重量)的比例存在,基于滑动总量,b) 氧化铝粉末i)的平均粒径大于300nm,ii)以基于滑移总量的80至98重量%的比例存在,以及c)固体含量,如 氧化铝和二氧化锆的总量相对于滑移总量为50〜85重量%。