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1. 发明申请

WO2013007598A1 RADIATION CURABLE AQUEOUS DISPERSIONS 审中-公开
标题翻译：辐射可固化水性分散体
公开(公告)号：WO2013007598A1
公开(公告)日：2013-01-17
申请号：PCT/EP2012/063141
申请日：2012-07-05
申请人： CYTEC SURFACE SPECIALTIES, S.A. , TIELEMANS, Michel , CAPPELLE, Steven , PEETERS, Stephan , DEPUYDT, Lieven
发明人： TIELEMANS, Michel , CAPPELLE, Steven , PEETERS, Stephan , DEPUYDT, Lieven
IPC分类号： C08L33/14 , C08G18/83
CPC分类号： C09D175/16 , C08G18/0823 , C08G18/12 , C08G18/348 , C08G18/4211 , C08G18/4238 , C08G18/672 , C08G18/758 , C08L33/14 , C08G18/6659 , C08G18/3876 , C08L75/04
摘要： An aqueous dispersion comprising a mixture of a first dispersion and a second dispersion, said first dispersion comprising at least one (meth)acrylated pre-polymer (A), and said second dispersion comprising at least one thiol-functional compound (B), said aqueous dispersion optionally comprising at least one ethylenically unsaturated compound (C).
摘要翻译：一种包含第一分散体和第二分散体的混合物的水分散体，所述第一分散体包含至少一种（甲基）丙烯酸酯化的预聚物（A），所述第二分散体包含至少一种硫醇官能化合物（B），所述含有至少一种烯属不饱和化合物（C）的水分散体。

2. 发明申请

WO2010003924A1 AQUEOUS RADIATION CURABLE POLYURETHANE COMPOSITIONS 审中-公开
标题翻译：水性可固化聚氨酯组合物
公开(公告)号：WO2010003924A1
公开(公告)日：2010-01-14
申请号：PCT/EP2009/058519
申请日：2009-07-06
申请人： CYTEC SURFACE SPECIALTIES, S.A. , VAN HOLEN, Jurgen , CAPPELLE, Steven , DERUYTTERE, Xavier , TIELEMANS, Michel
发明人： VAN HOLEN, Jurgen , CAPPELLE, Steven , DERUYTTERE, Xavier , TIELEMANS, Michel
IPC分类号： C08G18/67 , C08G18/08 , C09D175/16
CPC分类号： C08G18/673 , B05D3/06 , B05D2201/02 , B05D2203/20 , B05D2401/20 , B05D2503/00 , B32B27/40 , C08F283/006 , C08F283/008 , C08F290/067 , C08F290/147 , C08G18/0823 , C08G18/348 , C08G18/73 , C09D175/16
摘要： The present invention relates to an aqueous composition comprising from 5 to 90 % by weight of a polymerizable ethylenically unsaturated water dispersible polyurethane (A) and from 1 to 60 % by weight relative to the weight of polyurethane (A) of a least one polymerizable ethylenically unsaturated compound (B) having a water solubility at 25 °C of less than 50 g/l, and it use for making high gloss coatings as well as wood stains.
摘要翻译：本发明涉及一种水性组合物，其包含5至90重量％的可聚合烯属不饱和水分散性聚氨酯（A）和1至60重量％的相对于聚氨酯（A）重量的至少一种可聚合烯属在25℃下的水溶性低于50g / l的不饱和化合物（B），用于制造高光泽涂料以及木材污渍。

3. 发明申请

WO2011110495A1 RADIATION CURABLE AQUEOUS COATING COMPOSITIONS 审中-公开
标题翻译：辐射可固化水性涂料组合物
公开(公告)号：WO2011110495A1
公开(公告)日：2011-09-15
申请号：PCT/EP2011/053300
申请日：2011-03-04
申请人： CYTEC SURFACE SPECIALTIES, S.A. , PEETERS, Stephan , DE MICHELI, Philippe , URBANO, Edmund , TIELEMANS, Michel
发明人： PEETERS, Stephan , DE MICHELI, Philippe , URBANO, Edmund , TIELEMANS, Michel
IPC分类号： C09D4/06 , C09D11/00 , C09D133/00 , C09D167/00 , C09D175/00
CPC分类号： C09D4/06 , C08G18/683 , C08G18/8175 , C08G63/47 , C09D11/101 , C09D133/14 , C09D135/00 , C09D167/07 , C09D175/14 , C09J167/07 , C08L67/00
摘要： This invention relates to a radiation curable aqueous coating composition comprising: - from 1 to 99 % by weight, relative to the total weight of (1) and (2), of at least one radiation curable aqueously dispersed polyester resin composition (1) comprising an emulsifier D and the reaction product AC of a hydroxy functional polyester resin A and an olefinically unsaturated compound C which can be radically polymerised and which is attached to the polyester resin backbone by an ester linkage or a urethane linkage, and - from 1 to 99 % by weight, relative to the total weight of (1) and (2), of at least one other olefinically unsaturated compound (2) selected from the group of: water-dispersible compounds (21); water-soluble compounds (22); and/or water-compatible compounds (23) that have a weight average molecular weight of at least 450 Dalton and are different from the reaction product AC.
摘要翻译：本发明涉及一种可辐射固化水性涂料组合物，其包含： - 至少一种可辐射固化的高分散聚酯树脂组合物（1）的1-99重量％，相对于（1）和（2）的总重量，包括乳化剂D和羟基官能聚酯树脂A的反应产物AC和可自由基聚合的烯属不饱和化合物C，其通过酯键或氨基甲酸酯键连接到聚酯树脂主链上，和 - 1至99 相对于（1）和（2）的总重量的至少一种选自以下的其它烯属不饱和化合物（2）的重量％：水分散性化合物（21）; 水溶性化合物（22）; 和/或水相容化合物（23），其重均分子量至少为450道尔顿且不同于反应产物AC。

4. 发明申请

WO2012089575A1 RADIATION CURABLE COMPOSITIONS 审中-公开
标题翻译：辐射可固化组合物
公开(公告)号：WO2012089575A1
公开(公告)日：2012-07-05
申请号：PCT/EP2011/073524
申请日：2011-12-21
申请人： CYTEC SURFACE SPECIALTIES, S.A. , SALVIATO, Jean-Yves , VAN HOLEN, Jurgen , TIELEMANS, Michel , DECAUX, Marc
发明人： SALVIATO, Jean-Yves , VAN HOLEN, Jurgen , TIELEMANS, Michel , DECAUX, Marc
IPC分类号： C09D175/16 , C08G18/08 , C08G18/34 , C08G18/42 , C08G18/66 , C08G18/67 , C08G18/76 , C08F283/00
CPC分类号： C09D175/16 , C08F283/008 , C08G18/0823 , C08G18/348 , C08G18/4238 , C08G18/6659 , C08G18/6705 , C08G18/765 , C08L33/00 , C08L2666/04
摘要： The present invention relates to an ethylenically unsaturated hydroxyl-terminated polyurethane (I) obtained by reacting (i) at least one ethylenically unsaturated compound (A) containing at least two reactive groups capable of reacting with isocyanate groups and at least one ethylenically unsaturated group; with (ii) at least one saturated alcohol component (B) comprising: (iia) at least one saturated hydroxylated compound (B1) containing hydrophilic groups capable of rendering the polyurethane dispersible in aqueous medium either directly or after the reaction with a neutralizing agent to provide a salt, and, optionally, at least one compound (B2) that is selected from saturated polyester polyols (B21) and/or from saturated polycarbonate polyols (B22); and/or (iib) at least one compound (B3) that is selected from saturated polyester polyols (B31) containing compound (B1) moieties and/or from saturated polycarbonate polyols (B32) containing compound (B1) moieties; and, optionally, one or more of compounds (B1) and/or (B2); (iii) optionally, at least one ethylenically unsaturated compound (C) containing essentially one reactive group capable of reacting with isocyanate groups; with (iv) at least one polyisocyanate (D) selected from a tetramethylxylenediisocyanate. The present invention further relates to dispersions in water containing same, to their production and uses.
摘要翻译：本发明涉及通过使（i）至少一种含有至少两个能够与异氰酸酯基反应的反应性基团和至少一个烯属不饱和基团的烯属不饱和化合物（A）反应而获得的烯属不饱和羟基封端的聚氨酯（I）与（ii）至少一种饱和醇组分（B），其包含：（i）至少一种含有亲水基团的饱和羟基化合物（B1），所述亲水基团能够使聚氨酯在水性介质中直接或与中和剂反应后分散提供盐和任选的至少一种选自饱和聚酯多元醇（B21）和/或饱和聚碳酸酯多元醇（B22）的化合物（B2）; 和/或（iib）至少一种选自含有化合物（B1）部分的饱和聚酯多元醇（B31）和/或含有化合物（B1）部分的饱和聚碳酸酯多元醇（B32）的化合物（B3）和任选的一种或多种化合物（B1）和/或（B2）; （iii）任选的至少一种烯属不饱和化合物（C），其含有基本上能够与异氰酸酯基反应的一个反应性基团; 与（iv）至少一种选自四甲基亚甲基二异氰酸酯的多异氰酸酯（D）。本发明还涉及含有它们的水分散体及其生产和用途。

5. 发明申请

WO2012089538A1 RADIATION CURABLE COMPOSITIONS 审中-公开
标题翻译：辐射可固化组合物
公开(公告)号：WO2012089538A1
公开(公告)日：2012-07-05
申请号：PCT/EP2011/073087
申请日：2011-12-16
申请人： CYTEC SURFACE SPECIALTIES, S.A. , TIELEMANS, Michel , VAN HOLEN, Jurgen , DECAUX, Marc , SALVIATO, Jean-Yves
发明人： TIELEMANS, Michel , VAN HOLEN, Jurgen , DECAUX, Marc , SALVIATO, Jean-Yves
IPC分类号： C08G18/08 , C08G18/66 , C08G18/67 , C09D175/14 , C08F283/00 , C08F290/06
CPC分类号： C08G18/003 , C08F290/067 , C08G18/0823 , C08G18/0866 , C08G18/6659 , C08G18/675 , C09D4/00 , C09D175/14
摘要： The present invention provides for an ethylenically unsaturated hydroxyl- terminated polyurethane (I) obtained by reacting (i) at least one ethylenically unsaturated compound (A) containing at least two reactive groups capable of reacting with isocyanate groups and at least one ethylenically unsaturated group; with (ii) at least one saturated alcohol component (B) comprising: (iia) at least one saturated hydroxylated compound (B1) containing hydrophilic groups capable of rendering the polyurethane dispersible in aqueous medium either directly or after the reaction with a neutralizing agent to provide a salt, and at least one compound (B2) that is selected from saturated polyester polyols (B21) and/or from saturated polycarbonate polyols (B22); and/or (iib) at least one compound (B3) that is selected from saturated polyester polyols (B31) containing compound (B1) moieties and/or from saturated polycarbonate polyols (B32) containing compound (B1) moieties; and, optionally, one or more of compounds (B1) and/or (B2); (iii) optionally, at least one ethylenically unsaturated compound (C) containing essentially one reactive group capable of reacting with isocyanate groups; and with (iv) at least one polyisocyanate (D). The present invention further relates to radiation curable coating compositions comprising same, to their preparation process and their uses.
摘要翻译：本发明提供一种烯属不饱和羟基封端的聚氨酯（I），其通过使（i）至少一种含有至少两个能够与异氰酸酯基团反应的反应性基团和至少一个烯属不饱和基团的烯属不饱和化合物（A）反应而获得; 与（ii）至少一种饱和醇组分（B），其包含：（i）至少一种含有亲水基团的饱和羟基化合物（B1），所述亲水基团能够使所述聚氨酯在水性介质中直接或与中和剂反应，提供盐和至少一种选自饱和聚酯多元醇（B21）和/或饱和聚碳酸酯多元醇（B22）的化合物（B2）; 和/或（iib）选自含有化合物（B1）部分的饱和聚酯多元醇（B31）和/或含有化合物（B1）部分的饱和聚碳酸酯多元醇（B32）的至少一种化合物（B3）和任选的一种或多种化合物（B1）和/或（B2）; （iii）任选的至少一种含有能够与异氰酸酯基团反应的基本上一个反应性基团的烯键式不饱和化合物（C）; 和（iv）至少一种多异氰酸酯（D）。本发明还涉及包含它们的可辐射固化涂料组合物，其制备方法及其用途。

6. 发明申请

WO2009147092A1 AQUEOUS RADIATION CURABLE POLYURETHANE COMPOSITIONS 审中-公开
标题翻译：水性可固化聚氨酯组合物
公开(公告)号：WO2009147092A1
公开(公告)日：2009-12-10
申请号：PCT/EP2009/056615
申请日：2009-05-29
申请人： CYTEC SURFACE SPECIALTIES, S.A. , TIELEMANS, Michel
发明人： TIELEMANS, Michel
IPC分类号： C08G18/67 , C09D175/14
CPC分类号： C09D175/14 , C08G18/2825 , C08G18/348 , C08G18/675 , C08G18/683 , C08G18/758 , C08K3/20 , C08L75/14 , Y10S525/92 , C08G18/0823 , C08L2666/20
摘要： The invention relates to radiation-curable aqueous composition comprising a high molecular weight ethylenically unsaturated polyurethane obtained from the reaction of a polyisocyanate, at least one hydrophilic compound which is capable to render the polyurethane prepolymer dispersible in aqueous medium, an ethylenically unsaturated compound containing at least two reactive groups capable to react with isocyanate groups and an active hydrogen containing chain extender and a low molecular weight ethylenically unsaturated polyurethane end-capped with an ethylenically unsaturated compound containing essentially one reactive group capable to react with isocyanate groups.
摘要翻译：本发明涉及可辐射固化的水性组合物，其包含由多异氰酸酯反应获得的高分子量烯属不饱和聚氨酯，至少一种亲水性化合物，其能够使聚氨酯预聚物分散在水性介质中，至少含有至少含有两个能够与异氰酸酯基团反应的反应基团和含活性氢的扩链剂和低分子量烯键式不饱和聚氨酯封端，其中烯属不饱和化合物含有基本上可以与异氰酸酯基团反应的一个反应性基团。

7. 发明申请

WO2007118781A1 AQUEOUS RADIATION CURABLE POLYURETHANE COMPOSITIONS 审中-公开
标题翻译：水性可固化聚氨酯组合物
公开(公告)号：WO2007118781A1
公开(公告)日：2007-10-25
申请号：PCT/EP2007/053109
申请日：2007-03-30
申请人： CYTEC SURFACE SPECIALTIES, S.A. , TIELEMANS, Michel , BONTINCK, Dirk , VAN OVERVELT, Jean-Claude
发明人： TIELEMANS, Michel , BONTINCK, Dirk , VAN OVERVELT, Jean-Claude
IPC分类号： C09D175/16 , C08G18/67 , C08G18/75 , C08G18/08 , C08G18/12
CPC分类号： C09D175/16 , B29C64/124 , B29K2023/04 , B29K2023/10 , B29K2069/00 , B29K2075/00 , C08G18/0823 , C08G18/673 , C08G18/683 , C08J3/28 , C08J2375/16 , C08L75/16 , C09D175/14 , Y10T428/31551 , Y10T428/31554 , Y10T428/31591 , Y10T428/31598 , Y10T428/31601 , Y10T428/31605 , C08G18/6659 , C08L2666/20
摘要： The invention relates to radiation-curable aqueous composition comprising an (meth)acrylated polyurethane pre-polymer obtained from the reaction of a polyisocyanate, optionally a polyol, at least one hydrophilic compound containing at least one reactive group capable to react with isocyanate groups and which is capable to render the polyurethane pre-polymer dispersible in aqueous medium either directly or after the reaction with a neutralizing agent to provide a salt, an (meth)acrylated compound containing at least two reactive groups capable to react with isocyanate groups and an (meth)acrylated compound containing essentially one reactive group capable to react with isocyanate groups, said composition comprising an amount of (meth)acrylated and polymerizable ethylenically unsaturated groups of at least 3 meq per g.
摘要翻译：本发明涉及可辐射固化的水性组合物，其包含由多异氰酸酯，任选的多元醇反应获得的（甲基）丙烯酸酯化的聚氨酯预聚物，至少一种含至少一个能够与异氰酸酯基团反应的反应性基团的亲水性化合物，能够将聚氨酯预聚物直接或与中和剂反应后分散在水性介质中以提供盐，（甲基）丙烯酸酯化的化合物含有至少两个能够与异氰酸酯基团反应的反应性基团和（甲基））丙烯酸酯化的化合物，其基本上含有能够与异氰酸酯基团反应的一个反应性基团，所述组合物包含至少3meq / g的（甲基）丙烯酸酯化的和可聚合的烯键式不饱和基团。

8. 发明申请

WO2012013488A1 RADIATION CURABLE AQUEOUS COMPOSITIONS 审中-公开
标题翻译：辐射可固化水性组合物
公开(公告)号：WO2012013488A1
公开(公告)日：2012-02-02
申请号：PCT/EP2011/061827
申请日：2011-07-12
申请人： CYTEC SURFACE SPECIALTIES, S.A. , TIELEMANS, Michel , BAURANT, Jean-Noël
发明人： TIELEMANS, Michel , BAURANT, Jean-Noël
IPC分类号： C08G18/67 , C09D175/16
CPC分类号： C08L33/14 , C08G18/6254 , C08G18/673 , C08G18/706 , C08G18/73 , C09D175/16 , Y10T428/31551
摘要： The present invention relates to a radiation curable aqueous composition comprising at least one ethylenically unsaturated polymer (1) which is the reaction product of - a water-dispersible (meth)acrylic polymer A containing pendant hydroxyl or isocyanate groups, and containing pendant groups capable to render the polymer dispersible in aqueous medium either directly or after reaction with a neutralizing agent; - at least one ethylenically unsaturated compound B which can be radically polymerized under irradiation and which attaches to the (meth)acrylic polymer A by an urethane linkage; - and, optionally, at least one neutralizing agent C. The present invention further relates to the making and use of such radiation curable aqueous compositions.
摘要翻译：本发明涉及可辐射固化的水性组合物，其包含至少一种烯属不饱和聚合物（1），其是 - 含有侧基羟基或异氰酸酯基团的水分散性（甲基）丙烯酸类聚合物A和含有侧链基团的反应产物使聚合物直接或与中和剂反应后在水性介质中分散; - 至少一种烯属不饱和化合物B，其可以在照射下自由基聚合，并通过氨基甲酸酯键连接到（甲基）丙烯酸类聚合物A上; - 和任选的至少一种中和剂C.本发明还涉及制备和使用这种可辐射固化水性组合物。

9. 发明申请

WO2002078835A2 SUBSTRATES, PREPARATION AND USE 审中-公开
标题翻译：基材，制备和使用
公开(公告)号：WO2002078835A2
公开(公告)日：2002-10-10
申请号：PCT/EP2002/003102
申请日：2002-03-20
申请人： UCB, S.A. , LINDEKENS, Luc , TIELEMANS, Michel , CAPPELLE, Steven , REMACLE, Jose , DE BECKER, Benoit
发明人： LINDEKENS, Luc , TIELEMANS, Michel , CAPPELLE, Steven , REMACLE, Jose , DE BECKER, Benoit
IPC分类号： B01J19/00
CPC分类号： G01N33/54366 , B01J19/0046 , B01J2219/00527 , B01J2219/00585 , B01J2219/00596 , B01J2219/00605 , B01J2219/00608 , B01J2219/0061 , B01J2219/00626 , B01J2219/00637 , B01J2219/00659 , B01J2219/00707 , B01J2219/0072 , B01J2219/00722 , C40B40/06 , G01N33/54386 , G01N33/54393 , Y10T428/31504
摘要： There is disclosed process for preparing a substrate 1. Process for preparing a substrate having thereon sites reactive with the reactive groups of a molecular probe, the process comprising the steps of applying to the substrate surface a material comprising one or more reactive sites having an activated ethylenically unsaturated double bond of the formula I: Wherein, if n= 0, m= 1, X 3 is carbon and X 1 is nitrogen, the bond between them being triple, and X 4 does not exist; if n= 1, m= 1, X 3 is carbon and X 1 is oxygen or sulphur, the bond between them being double, and X 2 is oxygen or sulphur or nitrogen substituted by an organo substituent; if n= 1, m= 1 or 2, X 3 is sulphur and X 1 is oxygen, the bond between them being double, and X 2 is nitrogen substituted by an organo substituent; R 1 , R 2 , each independently represent hydrogen, hydroxyl or organo group, R 3 and R 4 each independently represent hydrogen or organo group, eventually containing a silicon atom R 1 and R 2 being not linked to R 4 . and, in a further step, of covalently binding the reactive group of the molecular probe to the activated ethylenically unsaturated double bond of the reactive sites having formula I. Preferred activated unsaturated moiet(ies) comprises unsaturated ester moiet(ies) such as (meth)acrylate moiet(ies). Preferred probes comprise amino groups thereon. Preferred strong links are covalent bonds. Preferred linking reactions are Michael addition reactions. The substrate having probes deposed thereon may be used to interact with a target. Other aspects of the invention relate to substrates and multi-reactive systems (such as microarrays) so prepared; uses thereof; and products and information obtained therefrom.
摘要翻译：公开了制备基材的方法。1.制备在其上具有与分子探针的反应性基团反应的位点的基材的方法，所述方法包括以下步骤：将包含具有式I活化的烯属不饱和双键的一个或多个反应性位点：其中，如果n = 0，m = 1，X 3是碳并且X 1是氮，它们之间的键是三重的，并且X 4不存在; 如果n = 1，m = 1，X 3是碳并且X 1是氧或硫，它们之间的键是双键，并且X 2 = 是被有机取代基取代的氧或硫或氮; 如果n = 1，m = 1或2，X 3是硫而X 1是氧，它们之间的键是双键，并且X 2 = 是被有机取代基取代的氮; R 1，R 2各自独立地表示氢，羟基或有机基团，R 3和R 4分别为独立地表示氢或有机基团，最终含有硅原子R 1和R 2不连接到R 4上。并且在进一步的步骤中将分子探针的反应性基团共价结合到具有式I的反应活性部位的活化的烯键式不饱和双键上。优选的活化不饱和醇包括不饱和酯（例如（甲基）丙烯酸酯）丙烯酸酯（酯）。优选的探针在其上包含氨基。优选的强链接是共价键。优选的连接反应是迈克尔加成反应。具有置于其上的探针的衬底可以用于与目标相互作用。本发明的其他方面涉及如此制备的底物和多反应系统（如微阵列）其用途; 以及从中获得的产品和信息。

10. 发明申请

WO2013135621A1 ACTIVE ENERGY RAY CURABLE AQUEOUS EMULSIONS 审中-公开
标题翻译：活性能量可固化水性乳液
公开(公告)号：WO2013135621A1
公开(公告)日：2013-09-19
申请号：PCT/EP2013/054859
申请日：2013-03-11
申请人： ALLNEX BELGIUM, S.A. , TIELEMANS, Michel , BAURANT, Jean-Noel , LINDEKENS, Luc , PEETERS, Stephan
发明人： TIELEMANS, Michel , BAURANT, Jean-Noel , LINDEKENS, Luc , PEETERS, Stephan
IPC分类号： C09D5/02
CPC分类号： C09D5/022 , B05D3/007 , B05D3/067 , C08L63/10 , C08L2201/54 , C08L2312/06 , C09D5/027 , C09D7/65 , C09D11/101 , C09D133/14 , G03F7/027 , C08L71/02
摘要： The present invention relates to an aqueous radiation curable composition comprising: (I) at least one ethylenically unsaturated compound (A), and (II) at least one emulsifier (B) comprising alternating polyalkylene oxide segments, wherein said emulsifier optionally bears one or more groups selected from alkyl groups, aryl groups hydroxyl groups and/or ethylenically unsaturated groups, and wherein said emulsifier (B) has an HLB value of at least 4.5, preferably at least 7. The compositions of the invention are particularly suited for the manufacture of sprayable eco-friendly hardcoats, but they are also suitable for the making of inks, overprint varnishes and adhesives, alone or in combination with e.g. a water-borne polymer dispersion.
摘要翻译：本发明涉及一种水性可辐射固化组合物，其包含：（I）至少一种烯属不饱和化合物（A）和（II）至少一种包含交替聚环氧烷链段的乳化剂（B），其中所述乳化剂任选地具有一个或多个选自烷基，芳基羟基和/或烯键式不饱和基团的基团，其中所述乳化剂（B）的HLB值至少为4.5，优选至少为7.本发明的组合物特别适用于制备可喷涂的环保硬涂层，但它们也适用于油墨，套印清漆和粘合剂的制造，单独或与例如水性聚合物分散体。

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