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1. 发明申请

WO2004099302A1 PHOTO-CURED AND STABILIZED COATINGS 审中-公开
标题翻译：光固化和稳定涂料
公开(公告)号：WO2004099302A1
公开(公告)日：2004-11-18
申请号：PCT/EP2004/050603
申请日：2004-04-26
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SUHADOLNIK, Joseph , WOOD, Mervin Gale , RAVICHANDRAN, Ramanathan , RENZ, Walter L. , ROBERTS, Andrea R. , CLIFF, Nancy Nase , SITZMANN, Eugene Valentine , BRAMER, David
发明人： SUHADOLNIK, Joseph , WOOD, Mervin Gale , RAVICHANDRAN, Ramanathan , RENZ, Walter L. , ROBERTS, Andrea R. , CLIFF, Nancy Nase , SITZMANN, Eugene Valentine , BRAMER, David
IPC分类号： C08K5/07
CPC分类号： C09D4/06 , C09D4/00
摘要： Photo-curable coating formulations which comprise a durable and/or red-shifted reactable hydroxyphenylbenzotriazole ultraviolet light absorber (UVA) are effectively photocured employing a combination of α-hydroxy ketone and bisacylphosphine oxide photoinitiators. The reactable UVA's are reacted into the coating upon curing. The combination of the photoinitiators bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide and 1-hydroxycyclohexylphenylketone is especially effective for this purpose.
摘要翻译：使用α-羟基酮和双酰基氧化膦光引发剂的组合，有效地光固化包含耐久和/或红移反应性羟基苯基苯并三唑紫外光吸收剂（UVA）的光固化涂料制剂。固化后可反应的UVA反应成涂层。光引发剂双（2,4,6-三甲基苯甲酰基）苯基氧化膦和1-羟基环己基苯基酮的组合对于此目的是特别有效的。

2. 发明申请

WO2003046017A1 CURABLE MIXTURES COMPRISING UV-ABSORBER ACYLPHOSPHINOXIDE AND HYDROXY KETONE PHOTOINITIATOR 审中-公开
标题翻译：包含紫外线吸收剂的乙酰氧化膦和羟基酮酮光敏剂的可固化混合物
公开(公告)号：WO2003046017A1
公开(公告)日：2003-06-05
申请号：PCT/EP2002/013065
申请日：2002-11-21
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SUHADOLNIK, Joseph , WOOD, Mervin, Gale , RAVICHANDRAN, Ramanathan , RENZ, Walter, L. , SMITH, Andrea, R. , CLIFF, Nancy Nase , SITZMANN, Eugene Valentine , BRAMER, David
发明人： SUHADOLNIK, Joseph , WOOD, Mervin, Gale , RAVICHANDRAN, Ramanathan , RENZ, Walter, L. , SMITH, Andrea, R. , CLIFF, Nancy Nase , SITZMANN, Eugene Valentine , BRAMER, David
IPC分类号： C08F2/48
CPC分类号： C08F2/48 , C09D4/06 , C08F290/14
摘要： Photo-cureable coating formulations which comprise a durable and/or red-shifted hydroxyphenylbenzotriazole ultraviolet light absorber (UVA) are effectively photocured employing a combination of α-hydroxy ketone and bisacylphosphine oxide photoinitiators. The combination of the photoinitiators bis(2,4,6-trymethylbenzoyl)phenylphosphine oxide and 1-hydroxycyclohexylphenylketone is especially effective for this purpose.
摘要翻译：使用α-羟基酮和双酰基氧化膦光引发剂的组合，可有效地光固化包含持久和/或红移羟基苯基苯并三唑紫外线吸收剂（UVA）的可光固化涂料制剂。光引发剂双（2,4,6-三甲基苯甲酰基）苯基氧化膦和1-羟基环己基苯基酮的组合对于此目的是特别有效的。

3. 发明申请

WO2005070989A3 THERMALLY STABLE CATIONIC PHOTOCURABLE COMPOSITIONS 审中-公开
公开(公告)号：WO2005070989A3
公开(公告)日：2005-08-04
申请号：PCT/EP2005/050157
申请日：2005-01-17
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WOLF, Jean-Pierre , ILG, Stephan , BIRBAUM, Jean-Luc , SITZMANN, Eugene Valentine , BRAMER, David , LOSAPIO, Greg
发明人： WOLF, Jean-Pierre , ILG, Stephan , BIRBAUM, Jean-Luc , SITZMANN, Eugene Valentine , BRAMER, David , LOSAPIO, Greg
IPC分类号： C08G59/18
摘要： Disclosed are cationic photocurable compositions with improved shelf life stability. The thermally stable compositions comprise at least one cationically polymerizable compound, for example an epoxy compound, at least one onium salt photoinitiator and at least one compound selected from the group consisting of the organic phosphorus stabilizers and the hindered nitroxyl stabilizers. Also disclosed is a cationic photoinitiator composition comprising at least one onium salt photoinitiator and at least one compound selected from the group consisting of the organic phosphorus stabilizers and the hindered nitroxyl stabilizers.

4. 发明申请

WO2005021457A2 OPTICAL FIBER COATINGS 审中-公开
标题翻译：光纤涂层
公开(公告)号：WO2005021457A2
公开(公告)日：2005-03-10
申请号：PCT/EP2004/051851
申请日：2004-08-20
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SITZMANN, Eugene Valentine , WOLF, Jean-Pierre , BRAMER, David , LOSAPIO, Greg
发明人： SITZMANN, Eugene Valentine , WOLF, Jean-Pierre , BRAMER, David , LOSAPIO, Greg
IPC分类号： C03C25/10
CPC分类号： C09D4/00 , C03C25/106 , C08F2/50 , C08F290/06 , C08F290/062 , C08F290/067
摘要： Optical fiber coating compositions which comprise at least one ethylenically unsaturated polymerizable compound and a photoinitiator blend, wherein the blend comprises (a) bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide and (b) 2,4,6,-trimethylbenzoyl ethoxyphenylphosphine oxide in an (a):(b) weight:weight ratio of between about 1:10 and about 1:8; or (c) bis(2,4,6-trimethylbenzoA)phenylphosphine oxide, (d) 2,4,6,-trimethylbenzoylethoxyphenylphosphine oxide and (e) 2-hydroxy-2-methyl-1-phenyl-1-propanone in a (c):(d):(e) weight:weight:weight ratio between about 3:11:14 and about 4:1:16; or (f) bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide and (g) 2-hydroxy-2-methyl-1-phenyl-1-propanone in a (f):(g) weight:weight ratio of between about 1:3 and about 1:5 exhibit fast photospeed, very low color and fast photobleaching. The photoinitiator blends have low volatility, high shelf life stability and high compatibility with resins and monomers. The photoinitiator blends are for example liquid and easy to use.
摘要翻译：包含至少一种烯键式不饱和可聚合化合物和光引发剂共混物的光学纤维涂料组合物，其中所述共混物包含（a）双（2,4,6-三甲基苯甲酰基）苯基氧化膦和（b）2 ，4,6-，-trimethylbenzoyl＆害羞; （a）：（b）重量比：约1:10至约1:8的重量比的乙氧基苯基氧化膦; 或（c）双（2,4,6-三甲基苯甲酰基）苯基氧化膦，（d）2,4,6-三甲基苯甲酰基乙氧基苯基氧化膦和（e）2-和2-羟基-2-甲基-1-苯基-1-丙酮在（c）：（d）:( e）重量：重量：约3:11:14和约4:1:16之间的重量比; 或（f）双（2,4,6-三甲基苯甲酰基）苯基氧化膦和（g）2-羟基-2-甲基-1-苯基-1-丙酮的（f）:( g）重量：约1：3和约1：5显示出快速的感光速度，非常低的颜色和快速的光漂白。光引发剂共混物具有低挥发性，高贮存期稳定性和与树脂和单体的高相容性。光引发剂混合物例如是液体并且易于使用。

5. 发明申请

WO2008017593A1 NOVEL POLYHEDRAL OLIGOMERIC SILSESQUIOXANE (POSS) BASED FLUORESCENT COLORANTS 审中-公开
标题翻译：新型聚乙烯（SILSESQUIOXANE（POSS））荧光颜料
公开(公告)号：WO2008017593A1
公开(公告)日：2008-02-14
申请号：PCT/EP2007/057740
申请日：2007-07-27
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , JEGANATHAN, Suruliappa Gowder , BRAMER, David , KOTE, Redina , MALADKAR, Gajanan J.
发明人： JEGANATHAN, Suruliappa Gowder , BRAMER, David , KOTE, Redina , MALADKAR, Gajanan J.
IPC分类号： C09B67/00 , C08K3/34 , C08K9/04 , C08L83/04
CPC分类号： C08G77/38 , C08G77/045 , C08L83/04 , C09B69/008 , C08L2666/54
摘要： Novel fluorescent polyhedral oligomeric silsesquioxane (POSS) colorants are provided. The colorants are strongly fluorescing and long lasting with excellent light stability. The novel colorants can be prepared from chromophores found in common pigments and provide a simple way to convert an insoluble pigment into a soluble fluorescent colorant.
摘要翻译：提供了新的荧光多面体低聚倍半硅氧烷（POSS）着色剂。着色剂具有强烈的荧光和持久性，具有出色的光稳定性。新型着色剂可以由常见颜料中发现的发色团制备，并提供将不溶性颜料转化为可溶性荧光着色剂的简单方法。

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