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1. 发明申请

WO2009058861A2 HYDROPROCESSING BULK CATALYST AND USES THEREOF 审中-公开
标题翻译：氢化聚合物催化剂及其用途
公开(公告)号：WO2009058861A2
公开(公告)日：2009-05-07
申请号：PCT/US2008/081581
申请日：2008-10-29
申请人： CHEVRON U.S.A. INC. , BRAIT, Axel , KUPERMAN, Alexander E. , LOPEZ, Jaime , MIRONOV, Oleg , REYNOLDS, Bruce , CHEN, Kaidong
发明人： BRAIT, Axel , KUPERMAN, Alexander E. , LOPEZ, Jaime , MIRONOV, Oleg , REYNOLDS, Bruce , CHEN, Kaidong
IPC分类号： B01J23/16
CPC分类号： C10G47/04 , B01J23/24 , B01J23/28 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/8885 , B01J27/0515 , B01J35/002 , B01J35/023 , B01J35/1009 , B01J35/1014 , B01J35/1042 , B01J35/1047 , B01J37/0236 , B01J37/031 , B01J37/038 , B01J37/04 , B01J37/16 , B01J37/20 , B01J37/343 , C10G47/06 , C10G49/04 , C10G2300/107 , C10G2300/1077 , Y10S502/517
摘要： A hydroprocessing bulk catalyst is provided. A process to prepare hydroprocessing bulk catalysts is also provided. The use of the bulk catalyst in hydroprocessing oil feedstock is also provided. The hydroprocessing catalyst has the formula (M t ) a (L u ) b (S v ) d (C w ) e (H x ) f (O y ) g (N z ) h, , wherein M is at least one group VIB metal; promoter metal L is optional and if present, L is at least one Group VIII non-noble metal; t, u, v, w, x, y, z representing the total charge for each of the components (M, L, S, C, H, O and N, respectively); ta+ub+vd+we+xf+yg+zh=0; 0 =
摘要翻译：提供加氢处理体积催化剂。还提供了制备加氢处理大量催化剂的方法。还提供了在加氢处理油原料中使用本体催化剂。加氢处理催化剂具有式（Mt）a（Lu）b（Sv）d（Cw）e（Hx）f（Oy）g（Nz）h ,,其中M是至少一组VIB金属; 促进剂金属L是任选的，如果存在，L是至少一种第VIII族非贵金属; 表示各组分（M，L，S，C，H，O和N分别）的总电荷的t，u，v，w，x，y，z; TA + UB + VD +我们+ XF + YG + ZH = 0; 0 =

2. 发明申请

WO2010033487A8 SYSTEMS AND METHODS FOR PRODUCING A CRUDE PRODUCT 审中-公开
公开(公告)号：WO2010033487A8
公开(公告)日：2010-03-25
申请号：PCT/US2009/056932
申请日：2009-09-15
申请人： CHEVRON U.S.A. INC. , FARSHID, Darush , REYNOLDS, Bruce , CHABOT, Julie , KOU, Bo , BRENNAN, Vivion, Andrew , MARIS, Erin , YANG, Shuwu , BISWAS, Goutam , CHEN, Kaidong , NGUYEN, Joseph, V. , BRAIT, Axel , BHADURI, Rahul, S. , KUPERMAN, Alexander, E.
发明人： FARSHID, Darush , REYNOLDS, Bruce , CHABOT, Julie , KOU, Bo , BRENNAN, Vivion, Andrew , MARIS, Erin , YANG, Shuwu , BISWAS, Goutam , CHEN, Kaidong , NGUYEN, Joseph, V. , BRAIT, Axel , BHADURI, Rahul, S. , KUPERMAN, Alexander, E.
IPC分类号： C10G65/02 , C10G45/02
摘要： A flexible once-through process for hydroprocessing heavy oil feedstock is disclosed. The process employs a plurality of contacting zones and at least a separation zone to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst which comprises an active metal catalyst having an average particle size of at least 1 micron in a hydrocarbon oil diluent, at a concentration of greater than 500 wppm of active metal catalyst to heavy oil feedstock. The plurality of contacting zones and separation zones are configured in a permutable fashion allowing the once-through process to be flexible operating in various modes: a sequential mode; a parallel mode; a combination of parallel and sequential mode; all online; some online and some on stand-by; some online and some off-line; a parallel mode with the effluent stream from the contacting zone being sent to at least a separation zone in series with the contacting zone; a parallel mode with the effluent stream from the contacting zone being combined with an effluent stream from at least another contacting zone and sent to the separation zone; and combinations thereof. In one embodiment, the effluent from a contacting zone is sent to the next contacting zone in series for further upgrade, with the next contacting zone having a pressure drop of at most 100 psi, with the pressure drop is not due to a pressure reducing device as in the prior art. In one embodiment, at least an additive material selected from inhibitor additives, anti-foam agents, stabilizers, metal scavengers, metal contaminant removers, metal passivators, and sacrificial materials, in an amount of less than 1 wt. % of the heavy oil feedstock, is added to at least one of the contacting zones.

3. 发明申请

WO2010033480A2 SYSTEMS AND METHODS FOR PRODUCING A CRUDE PRODUCT 审中-公开
标题翻译：用于生产原料产品的系统和方法
公开(公告)号：WO2010033480A2
公开(公告)日：2010-03-25
申请号：PCT/US2009/056915
申请日：2009-09-15
申请人： CHEVRON U.S.A. INC. , CHABOT, Julie , KOU, Bo , BRENNAN, Vivion Andrew , MARIS, Erin , YANG, Shuwu , REYNOLDS, Bruce , BISWAS, Goutam , FARSHID, Darush , CHEN, Kaidong
发明人： CHABOT, Julie , KOU, Bo , BRENNAN, Vivion Andrew , MARIS, Erin , YANG, Shuwu , REYNOLDS, Bruce , BISWAS, Goutam , FARSHID, Darush , CHEN, Kaidong
IPC分类号： C10G69/04 , C10G69/06
CPC分类号： C10G65/12 , C10G47/26 , C10G2300/1044 , C10G2300/1074 , C10G2300/202 , C10G2300/203 , C10G2300/206 , C10G2300/208 , C10G2300/302 , C10G2300/308 , C10G2300/4081 , C10G2300/44 , C10G2300/805 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/28
摘要： Systems and methods for hydroprocessing a heavy oil feedstock with reduced heavy oil deposits, the system employs a plurality of contacting zones and separation zones zone under hydrocracking conditions to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products, wherein water and / or steam being optionally injected into first contacting zone in an amount of 1 to 25 weight % on the weight of the heavy oil feedstock. In one embodiment, the first contacting zone is operated at a temperature of at least 10°F. lower than a next contacting zone. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock, forming upgraded products of lower boiling hydrocarbons. In the separation zones, upgraded products are removed overhead and optionally, further treated in an in-line hydrotreater. At least a portion of the non-volatile fractions recovered from at least one of the separation zones is recycled back to the first contacting zone in the system, in an amount ranging between 3 to 50 wt. % of the heavy oil feedstock. In one embodiment, at least some of the heavy oil feedstock is supplied to at least a contacting zone other than the first contacting zone and / or at least some of the fresh slurry catalyst is supplied to at least a contacting zone other than the first contacting zone. In one embodiment, at least a portion of the non-volatile fractions recovered from at least one of the separation zones is sent to the interstage solvent deasphalting unit, for separating unconverted heavy oil feedstock into deasphalted oil and asphaltenes. The deasphalted oil stream is sent to one of the contacting zones for further upgrade.
摘要翻译：用于加氢处理具有减少的重油沉积物的重油原料的系统和方法，所述系统在加氢裂化条件下采用多个接触区和分离区，以将至少一部分重油原料转化为较低沸点的烃，形成升级产物，其中水和/或蒸汽任选以重油原料重量的1至25重量％的量注入第一接触区。在一个实施例中，第一接触区在至少10°F的温度下运行。低于下一个接触区域。接触区在加氢裂化条件下操作，使用浆料催化剂来升级重油原料，形成低沸点烃的升级产物。在分离区中，升级产物从顶部除去，并且任选地在联机加氢处理器中进一步处理。从至少一个分离区回收的至少一部分非挥发性馏分以3至50wt。％的量循环回到系统中的第一接触区。重油原料的％。在一个实施方案中，至少一部分重油给料被供应到除第一接触区以外的至少一个接触区和/或至少一些新鲜浆料催化剂被供应到除第一接触以外的至少一个接触区区。在一个实施方案中，从至少一个分离区回收的至少一部分非挥发性馏分被送至级间溶剂脱沥青装置，用于将未转化的重油原料分离成脱沥青油和沥青质。脱沥青油流被送到其中一个接触区进行进一步升级。

4. 发明申请

WO2007078620A3 PROCESS FOR UPGRADING HEAVY OIL USING A HIGHLY ACTIVE SLURRY CATALYST COMPOSITION 审中-公开
公开(公告)号：WO2007078620A3
公开(公告)日：2007-07-12
申请号：PCT/US2006/047005
申请日：2006-12-08
申请人： CHEVRON U.S.A. INC. , FARSHID, Darush , REYNOLDS, Bruce
发明人： FARSHID, Darush , REYNOLDS, Bruce
IPC分类号： C10G65/02
摘要： Applicants have developed a new residuum full hydroconversion slurry reactor system that allows the catalyst, unconverted oil and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is partially separated in between the reactors to remove only the products and hydrogen gas, while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor. A portion of the unconverted oil is then converted to lower boiling point hydrocarbons, once again creating a mixture of unconverted oil, products, hydrogen, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. Additional oil may be added at the interstage feed inlet, possibly in combination with slurry. The oil may alternately be partially converted, leaving a highly concentrated catalyst in unconverted oil which can be recycled directly to the first reactor.

5. 发明申请

WO2012170272A2 APPARATUS AND METHOD FOR HYDROCONVERSION 审中-公开
标题翻译：装置和方法
公开(公告)号：WO2012170272A2
公开(公告)日：2012-12-13
申请号：PCT/US2012/040132
申请日：2012-05-31
申请人： CHEVRON U.S.A. INC. , SONG, Steven X. , KUEHNE, Donald L. , KEMOUN, Abdenour , REYNOLDS, Bruce
发明人： SONG, Steven X. , KUEHNE, Donald L. , KEMOUN, Abdenour , REYNOLDS, Bruce
IPC分类号： C10G11/00 , B01J19/00
CPC分类号： B01J8/06 , B01J8/005 , B01J8/007 , B01J8/1827 , B01J8/22 , B01J8/226 , B01J8/44 , B01J2208/00176 , B01J2208/00929 , B01J2208/025 , B01J2208/026 , B01J2219/0004 , C10G45/02 , C10G45/16 , C10G45/22 , C10G47/26 , C10G49/12
摘要： An apparatus is disclosed for the hydroconversion of hydrocarbon feedstock with a hydrogen gas at elevated temperature and pressure with the use of a catalyst. The apparatus is a reactor vessel with a grid plate distributor for improved gas liquid distribution. The distributor comprises a grid plate and a bubble cap assembly with a plurality of tubular risers extending through the grid plate. Each tubular riser has an upper section above the grid plate and a lower section below the grid plate, the lower section terminated with an open bottom end for ingress of the hydrogen gas and hydrocarbon feedstock, the upper section having a closed top terminated with a housing cap. Each tubular riser has at least a vertical slot and at least a side hole sufficiently sized such that in operation, the liquid level in the zone below the grid plate is above the vertical slot and below the side hole opening.
摘要翻译：公开了一种使用催化剂在升高的温度和压力下用氢气加氢转化烃原料的装置。该装置是具有用于改善气体液体分布的格栅分配器的反应器容器。分配器包括格栅板和气泡盖组件，其具有延伸穿过格栅板的多个管状立管。每个管状提升管具有在格栅板上方的上部部分和在格栅板下方的下部分，下部部分终止于用于进入氢气和烃原料的开口底端，上部部分具有封闭的顶部，其与壳体帽。每个管状提升管至少具有垂直狭槽和至少一个足够大小的侧孔，使得在操作中，格栅板下方的区域中的液位高于垂直槽并且在侧孔开口下方。

6. 发明申请

WO2007078621A2 PROCESS FOR UPGRADING HEAVY OIL USING A REACTOR WITH A NOVEL REACTOR SEPARATION SYSTEM 审中-公开
标题翻译：使用具有新型反应器分离系统的反应器升级重油的方法
公开(公告)号：WO2007078621A2
公开(公告)日：2007-07-12
申请号：PCT/US2006/047006
申请日：2006-12-08
申请人： CHEVRON U.S.A. INC. , FARSHID, Darush , MURPHY, James , REYNOLDS, Bruce
发明人： FARSHID, Darush , MURPHY, James , REYNOLDS, Bruce
IPC分类号： C10G45/00 , C10G65/02 , C10G69/02
CPC分类号： C10G65/02 , C10G49/12 , C10G2300/1022 , C10G2300/1033 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/1088 , C10G2300/4081 , C10G2300/703
摘要： Applicants have developed a new residuum full hydroconversion slurry reactor system that allows the catalyst, unconverted oil, hydrogen, and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is separated internally, within one of more of the reactors, to separate only the converted oil and hydrogen into a vapor product while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor as a liquid product. A portion of the unconverted oil is then converted to lower boiling point hydrocarbons in the next reactor, once again creating a mixture of unconverted oil, hydrogen, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a concentrated catalyst in unconverted oil which can be recycled directly to the first reactor.
摘要翻译：申请人已开发出一种新的渣油加氢转化淤浆反应器系统，其允许催化剂，未转化的油，氢气和转化的油在连续混合物中循环遍及整个反应器，而不限制混合物。混合物在内部在多个反应器中的一个反应器内分离，以仅将转化的油和氢气分离成蒸气产物，同时允许未转化的油和浆料催化剂作为液体产物继续进入下一个顺序反应器。一部分未转化的油然后在下一个反应器中转化为低沸点烃，再次产生未转化的油，氢气，转化油和浆料催化剂的混合物。在另外的反应器中可能发生进一步的加氢处理，从而完全转化油。油可以交替地部分转化，在未转化的油中留下浓缩的催化剂，其可以直接循环到第一反应器中。

7. 发明申请

WO2007078622A3 INTEGRATED HEAVY OIL UPGRADING PROCESS AND IN-LINE HYDROFINISHING PROCESS 审中-公开
公开(公告)号：WO2007078622A3
公开(公告)日：2007-07-12
申请号：PCT/US2006/047007
申请日：2006-12-08
申请人： CHEVRON U.S.A. INC. , FARSHID, Darush , REYNOLDS, Bruce
发明人： FARSHID, Darush , REYNOLDS, Bruce
IPC分类号： C10G45/00
摘要： A new residuum full hydroconversion slurry reactor system has been developed that allows the catalyst, unconverted oil and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is partially separated in between the reactors to remove only the converted oil while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor where a portion of the unconverted oil is converted to lower boiling point hydrocarbons, once again creating a mixture of unconverted oil, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a highly concentrated catalyst in unconverted oil which can be recycled directly to the first reactor. Fully converted oil can be subsequently hydrofinished for the nearly complete removal of hetoroatoms such as sulfur and nitrogen.

8. 发明申请

WO2007078619A2 REACTOR FOR USE IN UPGRADING HEAVY OIL ADMIXED WITH A HIGHLY ACTIVE CATALYST COMPOSITION IN A SLURRY 审中-公开
标题翻译：用于升级具有高活性催化剂组合物的重油中的反应物
公开(公告)号：WO2007078619A2
公开(公告)日：2007-07-12
申请号：PCT/US2006/047004
申请日：2006-12-08
申请人： CHEVRON U.S.A. INC. , REYNOLDS, Bruce
发明人： REYNOLDS, Bruce
IPC分类号： B01J8/22
CPC分类号： B01J8/22 , B01J8/1818 , B01J8/1827 , B01J8/226 , B01J2208/00548 , B01J2208/0084 , C10G9/005 , C10G2300/1022 , C10G2300/1033 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/1088 , C10G2300/703
摘要： The instant invention relates to a reactor useful in upgrading heavy oils admixed with a catalyst composition in a slurry. The liquid recirculating reactor of this invention employs a dispersed bubble flow regime, which requires a high liquid to gas ratio. A dispersed bubble flow regime results in more even flow patterns, increasing the amount of liquid that can be upgraded in a single reactor.
摘要翻译：本发明涉及一种用于升级与浆料中的催化剂组合物混合的重油的反应器。本发明的液体循环反应器采用分散的气泡流动状态，其需要高的液体/气体比。分散的气泡流动状态导致更均匀的流动模式，增加可以在单个反应器中升级的液体的量。

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