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    • 4. 发明申请
    • UNIVERSAL GRIGNARD METATHESIS POLYMERIZATION
    • 通用格氏硬脂酸聚合
    • WO2008028166A1
    • 2008-03-06
    • PCT/US2007/077461
    • 2007-08-31
    • CARNEGIE MELLON UNIVERSITYMCCULLOUGH, Richard, D.IOVU, Mihaela, C.OSAKA, Itaru
    • MCCULLOUGH, Richard, D.IOVU, Mihaela, C.OSAKA, Itaru
    • C08G61/00C07B49/00C07F3/02
    • C08G61/00C07B49/00
    • Universal Grignard Metathesis (GRIM) reactions which provide access to conjugated polymers by GRTM methods are disclosed. Furthermore revealed is a method comprising: providing an unsaturated ring compound comprising at least two halogen ring substituents, providing an organomagnesium reagent comprising an organomagnesium component and a metal activation agent, combining the unsaturated ring compound with the reagent to form a second compound by metal-halogen exchange, wherein the metal activation agent activates the metal-halogen exchange, coupling the second compound to itself in an oligomerization or polymerization reaction. Metal activation agent can be lithium chloride. The process is commercially attractive and can be executed in good yields. Polyfluorenes, polypyrroles, and polythiophenes can be prepared for use in OLED, PLED, photovoltaic, transistor, antistatic coatings, and sensor applications.
    • 公开了通过GRTM方法提供对共轭聚合物的通用格利雅复分解(GRIM)反应。 进一步揭示了一种方法,其包括:提供包含至少两个卤素环取代基的不饱和环化合物,提供包含有机镁组分和金属活化剂的有机镁试剂,将不饱和环化合物与试剂结合以通过金属 - 卤素交换,其中金属活化剂活化金属 - 卤素交换,在低聚或聚合反应中将第二化合物偶联到其自身。 金属活化剂可以是氯化锂。 该方法具有商业上的吸引力,可以以良好的产率进行。 聚芴,聚吡咯和聚噻吩可以制备用于OLED,PLED,光伏,晶体管,抗静电涂层和传感器应用。