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    • 2. 发明申请
    • PROCESS FOR DEACIDIFYING CRUDE OIL
    • 脱去原油的方法
    • WO02099013A8
    • 2003-03-20
    • PCT/GB0202485
    • 2002-05-28
    • BP EXPLORATION OPERATINGDUNCUM SIMON NEILOSBORNE CHRISTOPHER GEORGE
    • DUNCUM SIMON NEILOSBORNE CHRISTOPHER GEORGE
    • C10G21/16C10G21/28
    • C10G21/16C10G21/28
    • A process for deacidifying a crude oil and/or crude oil distillate containing organic acids the steps of (a) contacting the oil containing organic acids with a polar solvent comprising a C1 to C6 aliphatic alcohol in the presence of a Group IA and/or Group IIA metal salt selected from the group consisting of Group IA and/or Group IIA metal oxides, hydroxides and alkoxides such that at least a portion of the organic acids are converted into Group IA and/or Group IIA neutralization salts thereof and at least a portion of the neutralization salts are extracted into the polar solvent as an extract phase; (b) separating an oil phase which is reduced in acidity from the polar solvent extract phase; and (c) contacting the polar solvent extract phase with a heterogeneous esterification catalyst under condition effective to convert at least a portion of the Group IA and/or Group IIA neutralization salts to the corresponding esters of the organic acids and the C1 to C6 aliphatic alcohol.
    • 一种使含有有机酸的原油和/或原油馏出物脱酸的方法,包括以下步骤:(a)使含有油的有机酸与包含C1-C6脂族醇的极性溶剂在IA族和/或组的存在下接触 选自IA族和/或IIA族金属氧化物,氢氧化物和醇盐的IIA族金属盐,使得至少一部分有机酸转化为IA族和/或IIA族中和盐和至少一部分 的中和盐作为提取相被提取到极性溶剂中; (b)从极性溶剂萃取相中分离出酸度降低的油相; (c)使极性溶剂萃取相与非均相酯化催化剂在有效将至少一部分IA族和/或IIA族中和盐转化为相应的有机酸酯和C1-C6脂族醇的条件下接触 。