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1. 发明申请

WO2022033918A1 SCREENING ASSEMBLY AND PROCESS FOR SCREENING POLYMER FROM AN EFFLUENT STREAM AT REDUCED LEVELS OF POLYMER ENTRAINMENT 审中-公开
公开(公告)号：WO2022033918A1
公开(公告)日：2022-02-17
申请号：PCT/EP2021/071622
申请日：2021-08-03
申请人： BOREALIS AG
发明人： SLEIJSTER, Henry , AL-HAJ ALI, Mohammad , SATTAR, Mubashar , AJELLAL, Noureddine , WEBER, Charlotta
IPC分类号： C08F2/00 , B01J8/00 , B01D47/05 , B01D47/06 , C08F10/00
摘要： A process for screening polymer from a polymer-lean vapor stream, whereby the process comprises the steps of separating an effluent stream comprising the polymer and a first mixture of hydrocarbons into a polymer-rich stream and the polymer-lean vapor stream; spraying a condensed vapor composition comprising a second mixture of hydrocarbons into the polymer-lean vapor stream via a condensed vapor composition stream; screening a screened condensed vapor composition stream comprising the polymer and the condensed vapor composition from the polymer-lean vapor stream.

2. 发明申请

WO2019110316A1 A METHOD OF RECOVERING OLEFINS IN A SOLUTION POLYMERISATION PROCESS 审中-公开
公开(公告)号：WO2019110316A1
公开(公告)日：2019-06-13
申请号：PCT/EP2018/082173
申请日：2018-11-22
申请人： BOREALIS AG
发明人： AL-HAJ ALI, Mohammad , ERIKSSON, Erik , MATHIVANAN, Guhan , RÄSÄNEN, Jukka , SLEIJSTER, Henry , VIJAY, Sameer , ZITTING, Samuli
IPC分类号： C08F2/06 , C08F6/00
摘要： The present invention relates to a process for removing hydrocarbons comprising the steps of: (A) passing a stream of a solution into a separator wherein a liquid phase comprising polymer and a vapour phase coexist; (B) withdrawing a vapour stream and a concentrated solution stream from the separator; (C) passing at least a part of the vapour stream into a first fractionator; (D) withdrawing a first overhead stream and a first bottom stream from the first fractionator; (E) passing the first overhead stream to a second fractionator; (F) withdrawing a second overhead stream and a second bottom stream from the second fractionator; (G) passing the second overhead stream to a third fractionator; (H) withdrawing a third overhead stream and a third bottom stream from the third fractionator; characterised in that at least a part of the third bottom stream is withdrawn as a purge stream.

3. 发明申请

WO2019110315A1 A METHOD OF RECOVERING OLEFINS IN A SOLUTION POLYMERISATION PROCESS 审中-公开
公开(公告)号：WO2019110315A1
公开(公告)日：2019-06-13
申请号：PCT/EP2018/082172
申请日：2018-11-22
申请人： BOREALIS AG
发明人： AL-HAJ ALI, Mohammad , ERIKSSON, Erik , MATHIVANAN, Guhan , RÄSÄNEN, Jukka , SLEIJSTER, Henry , VIJAY, Sameer , ZITTING, Samuli
IPC分类号： C08F2/06 , C08F6/00
摘要： The present invention relates to a process for removing hydrocarbons comprising the steps of: (A) passing a stream of a solution into a separator wherein a liquid phase comprising polymer and a vapour phase coexist; (B) withdrawing a vapour stream and a concentrated solution stream from the separator; (C) passing at least a part of the vapour stream into a first fractionator; (D) withdrawing a first overhead stream and a first bottom stream from the first fractionator; (E) passing the first bottom stream to a second fractionator; (F) withdrawing a second overhead stream and a second bottom stream from the second fractionator; characterised in that at least a part of the second overhead stream is withdrawn as a purge stream.

4. 发明申请

WO2017108909A1 PROCESS FOR WITHDRAWING POLYOLEFINS 审中-公开
标题翻译：撤消聚烯烃的方法
公开(公告)号：WO2017108909A1
公开(公告)日：2017-06-29
申请号：PCT/EP2016/082113
申请日：2016-12-21
申请人： BOREALIS AG
发明人： AL-HAJ ALI, Mohammad , ERIKSSON, Erik , VIJAY, Sameer , MATHIVANAN, Guhan , RÄSÄNEN, Jukka , SLEIJSTER, Henry , WURNITSCH, Christof , ZITTING, Samuli
IPC分类号： C08F6/00 , C08F6/12
CPC分类号： C08F6/003 , C08F6/12 , C08L23/02
摘要： A process for withdrawing polyolefins from a solution polymerization reactor comprising: providing - a low pressure separator 1, - a washing column 2, - a withdrawal line 3 connecting the upper part of the low pressure separator and the washing column - a condenser 4, - a condenser-line 5 connecting the top part of the washing column and the condenser - optionally a recycle solvent vessel 6 - optionally a solvent-vessel-line 7 connecting the condenser with the recycle solvent vessel - a reflux line 8 connecting the condenser and the upper part of the washing column or connecting the recycle solvent vessel and the upper part of the washing column - optionally a circulation line 9 fluidly connected to the middle part of the washing column and recycling line 10 - a recycling line 10 connecting the bottom of the washing column and the upper part of the low pressure separator, - optionally a wash recycle heater 11 embedded into the recycling line 10 - optionally a heater 12 embedded into the circulation line 9 (a) continuously withdrawing a liquid solution stream from the solution polymerization reactor and passing said liquid solution stream into the first low pressure separator 1; (b) withdrawing a first vapour stream and a first liquid stream from the low pressure separator and passing said first vapour stream via withdrawal line 3 into the washing column (c) withdrawing a second vapour stream from the washing column and feeding it via condenser line 5 to condenser 4 (d) cooling the second vapour stream in condenser 4 so that a part of the second vapour stream condenses thereby producing a condensed second vapour stream and an uncondensed second vapour stream (e) passing the condensed second vapour stream to the upper part of the washing column via reflux line 8 (f) withdrawing a second liquid stream from the washing column and passing at least a part of the second liquid stream to the low pressure separator via recycling line 10 (g) recovering heat from the condenser
摘要翻译：一种从溶液聚合反应器中取出聚烯烃的方法，其包括：提供 - 低压分离器1， - 洗涤塔2， - 连接低压分离器的上部部分和洗涤塔 - 冷凝器4 - 连接洗涤塔顶部和冷凝器的冷凝器管线5 - 任选的循环溶剂容器6 - 任选的连接冷凝器和循环溶剂容器的溶剂容器管线7 - 连接冷凝器和洗涤塔上部的回流管线8或连接再循环溶剂容器和洗涤塔上部的循环管线8 - 任选地循环管线9，其流体连接到洗涤塔的中间部分和循环管线10-a - 连接洗涤塔底部和低压分离器上部的再循环管线10， - 任选的嵌入再循环管线10中的洗涤再循环加热器11， - 可选地加热器12 em （a）连续地从溶液聚合反应器中排出液体溶液流并将所述液体溶液流输送到第一低压分离器1中; （b）从低压分离器中取出第一蒸气流和第一液体流，并将所述第一蒸气流经排出管线3送入洗涤塔（c）从洗涤塔中排出第二蒸气流，并通过冷凝器管线（d）冷却冷凝器4中的第二蒸气流，使得第二蒸气流的一部分冷凝，由此产生冷凝的第二蒸气流和未冷凝的第二蒸气流（e）将冷凝的第二蒸气流传送至上部（f）从洗涤塔抽出第二液体物流，并将至少一部分第二液体物流通过循环管线10输送到低压分离器（g），从冷凝器的部分回收热量 / p>

5. 发明申请

WO2014032794A1 REACTOR ASSEMBLY AND METHOD FOR POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：反应器组件和烯烃聚合方法
公开(公告)号：WO2014032794A1
公开(公告)日：2014-03-06
申请号：PCT/EP2013/002572
申请日：2013-08-26
申请人： BOREALIS AG
发明人： KANELLOPOULOS, Vasileios , AL-HAJ ALI, Mohammad
IPC分类号： B01J19/24 , B01J8/38 , B01J8/18 , B01J8/00
CPC分类号： C08F210/16 , B01J8/0055 , B01J8/006 , B01J8/1827 , B01J8/1872 , B01J8/24 , B01J8/388 , B01J19/2465 , B01J2208/00256 , B01J2208/00274 , B01J2208/00292 , B01J2208/00672 , B01J2208/00752 , B01J2208/00761 , B01J2208/00893 , B01J2208/00938 , B01J2219/00247 , B01J2219/00254
摘要： Reactor assembly for the production of polymers including a fluidized bed reactor and method for operating the reactor assembly. The reactor assembly comprises gas/solid separation means, a flow through device (29) in the solid recycling line (35) that varies the solid recycling stream that is recycled back to the fluidized bed reactor (1).
摘要翻译：用于生产包括流化床反应器的聚合物的反应器组件和用于操作反应器组件的方法。反应器组件包括气体/固体分离装置，固体再循环管线（35）中的流动装置（29），其改变再循环回到流化床反应器（1）的固体再循环流。

6. 发明申请

WO2022073805A1 High temperature solution process for the copolymerization of ethylene with one ore more α-Olefin comonomer(s) 审中-公开
公开(公告)号：WO2022073805A1
公开(公告)日：2022-04-14
申请号：PCT/EP2021/076667
申请日：2021-09-28
申请人： BOREALIS AG
发明人： AL-HAJ ALI, Mohammad , AJELLAL, Noureddine
IPC分类号： C08F2/06 , C08F210/16
摘要： A process for the polymerization of a polymer from an a-olefin monomer and one or more a-olefin comonomers in the presence of a catalyst, the process having a variation of reactor temperature and monomers concentrations (VTC) higher than 0, wherein the variation of reactor temperature and monomers concentrations (VTC) fulfils the criteria of equation (I): wherein Tf, Tb and Tt are the inlet feed temperature, the reactor temperature positioned 90° or more from the feeding point and the outlet temperature, respectively. (C8lC2)in and (C8lC2)out are the ratios of the concentrations of comonomer to monomer at the inlet and outlet, respectively.

7. 发明申请

WO2019243006A1 PROCESS FOR REDUCING THE VOC CONTENT OF PLASTOMERS 审中-公开
公开(公告)号：WO2019243006A1
公开(公告)日：2019-12-26
申请号：PCT/EP2019/063820
申请日：2019-05-28
申请人： BOREALIS AG
发明人： AL-HAJ ALI, Mohammad , BERGSTRA, Michiel , WEBER, Charlotta , STIJNEN, Gert
IPC分类号： C08F6/00
摘要： The present invention relates to a process for reducing the volatile organic compound (VOC) content of plastomers the process comprising the steps of subjecting the plastomer in granular form containing VOCs which is contained in an aeration vessel to a gasflow, and withdrawing granular plastomer from the aeration vessel which has a lower content of VOCs, wherein the average particle size of the granular plastomer is greater than 2.5 mm, preferably greater than 2.7 mm, more preferably greater than 3.0 mm, wherein the gas has a minimum temperature of at least 26°C measured at a gas inlet of the aeration vessel, and a maximum temperature of 4°C below the Vicat temperature (10N, ISO 306) of the granular plastomer or 35°C measured at the gas inlet of the aeration vessel, whatever value is lower, and wherein at least a part of the withdrawn granular plastomer is recirculated to the aeration vessel.

8. 发明申请

WO2019137634A1 PHASE-STABILIZED ETHYLENE ALPHA OLEFIN COPOLYMERIZATION PROCESS 审中-公开
公开(公告)号：WO2019137634A1
公开(公告)日：2019-07-18
申请号：PCT/EP2018/063384
申请日：2018-05-22
申请人： BOREALIS AG
发明人： AL-HAJ ALI, Mohammad , SLEIJSTER, Henry
IPC分类号： C08F2/04 , C08F210/02
摘要： A process for copolymerizing ethylene and at least one C3 to C8 alpha olefin to obtain an ethylene-C3 to C8 alpha olefin copolymer, the process comprising a) copolymerizing ethylene and at least one C3 to C8 alpha olefin in a solvent in a solution polymerization reactor to obtain an intermediate polymer solution, b) discharging an effluent stream from the intermediate polymer solution into a heat exchanger, c) setting the temperature of the effluent stream in the heat exchanger to obtain a heated effluent stream, d) feeding the heated effluent stream to a flash separation, e) separating at least a part of the ethylene-C3 to C8 alpha olefin copolymer in the flash separation, characterized by feeding an inert hydrocarbon fulfilling 90 °C

9. 发明申请

WO2018114071A1 PROCESS FOR OBTAINING LOW VOLATILE PLASTOMERS 审中-公开
公开(公告)号：WO2018114071A1
公开(公告)日：2018-06-28
申请号：PCT/EP2017/073871
申请日：2017-09-21
申请人： BOREALIS AG
发明人： AL-HAJ ALI, Mohammad , BERGSTRA, Michiel , HOCHRADL, Stefan , HRISTOV, Velichko , STANDLER, Alexander
IPC分类号： C08F210/14 , C08F6/00
摘要： A process for reducing the volatile organic compound content of granular plastomers having a density of equal to or lower than 883 kg/m 3 and a MFR 2 of 1 00.0 g/1 0 min or lower (ISO 1133 at 2.16 kg load and 190 °C), to below 65 ppm (VOC, VDA277), the process comprising the steps of providing a granular raw plastomer in a treatment vessel, the granular raw plastomer having a density of equal to or lower than 883 kg/m 3 , and a MFR 2 of 1 00.0 g/1 0 min or lower (ISO 1133 at 2.16 kg load and 190 °C), and a volatile organic compound content (VOC, VDA277) of above 150 ppm, subjecting said granular raw plastomer to a gasflow within the range of 30 m 3 /(h t) to 150 m 3 /(h t) for an aeration time of less than 96 hours, whereby the gas has a minimum temperature of at least 26 °C measured at a gas inlet of the treatment vessel and a maximum temperature of 4 °C below the Vicat temperature (10 N, ISO 306) of the granular raw plastomer or 35 °C measured at the gas inlet of the treatment vessel, whatever value is lower; and recovering the granular plastomer.

10. 发明申请

WO2017108586A1 A METHOD FOR WITHDRAWING AGGLOMERATES FROM A FLUIDISED BED REACTOR 审中-公开
标题翻译：一种从流化床反应器中除去聚集体的方法
公开(公告)号：WO2017108586A1
公开(公告)日：2017-06-29
申请号：PCT/EP2016/081280
申请日：2016-12-15
申请人： BOREALIS AG
发明人： AL-HAJ ALI, Mohammad , KANELLOPOULOS, Vasileios , KRALLIS, Apostolos , NYFORS, Klaus , AGUAYO ARELLANO, Pablo Ivan , WEICKERT, Gunter , PRINSEN, Eric-Jan
IPC分类号： B01J4/00
CPC分类号： B01J8/0035 , B01J2208/00761 , B01J2208/00769
摘要： The present invention relates to a process and apparatus for withdrawing polymer agglomerates from a fluidised bed polymerisation reactor, the polymerisation reactor comprising a bottom zone having a generally conical shape and no fluidisation grid. The agglomerates are withdrawn by using an agglomerate trap below the bottom zone. A value of a process variable indicative of the content of agglomerates in the agglomerate trap is measured and the opening time of the valves transferring polymer to and from the agglomerate trap is adjusted based on the measured value.
摘要翻译：本发明涉及一种用于从流化床聚合反应器中回收聚合物附聚物的方法和设备，该聚合反应器包括具有大致圆锥形状的底部区域和不具有流化网格。通过在底部区域下方使用团聚物收集器来收集团聚物。测量指示凝聚物收集器中凝聚物含量的过程变量的值，并且基于测量值来调节将聚合物转移到凝聚物收集器和从聚集物收集器转移聚合物的阀的打开时间。

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