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1. 发明申请

WO2011115669A8 LOW TEMPERATURE CURING POLYURETDIONE COMPOSITIONS 审中-公开
标题翻译：低温固化聚脲组合物
公开(公告)号：WO2011115669A8
公开(公告)日：2012-10-18
申请号：PCT/US2011000473
申请日：2011-03-15
申请人： BAYER MATERIALSCIENCE LLC , BAYER MATERIALSCIENCE LLC , PPG IND OHIO INC , SHAFFER MYRON W , EKIN ABDULLAH , KINNEY CAROL L , GRESZTA-FRANZ DOROTA , MARTZ JONATHAN T , DENG JUN , HAYES DEBORAH E , THOMAS STEPHEN J
发明人： SHAFFER MYRON W , EKIN ABDULLAH , KINNEY CAROL L , GRESZTA-FRANZ DOROTA , MARTZ JONATHAN T , DENG JUN , HAYES DEBORAH E , THOMAS STEPHEN J
IPC分类号： C09D175/04 , C08G18/72 , C08J7/04 , C09D7/12
CPC分类号： C09D175/14 , C08G18/10 , C08G18/168 , C08G18/1883 , C08G18/2027 , C08G18/2063 , C08G18/244 , C08G18/42 , C08G18/44 , C08G18/6225 , C08G18/798
摘要： Composition and process for low temperature curing of polyuretdione-polyol compositions in which the polyuretdione is prepared from a polyisocyanate with isocyanate groups and a polyol containing primary hydroxyl groups. The catalyst for the composition and process is an amine catalyst containing the group -N=C-N-, being aprotic, having a pKa greater than 20 and upon addition to the liquid coating composition causing a phase-change of the coating composition from liquid to solid at 250C and 1atm. within one week.
摘要翻译：聚脲二酮 - 多元醇组合物的低温固化组合物和方法，其中聚脲二酮由具有异氰酸酯基团的多异氰酸酯和含有伯羟基的多元醇制备。用于组合物和方法的催化剂是含有基团-N = CN-的胺催化剂，它是非质子传递的，pKa大于20，并且在加入到液体涂料组合物中时导致涂料组合物从液体到固体的相变在25℃和1atm。在一周内。

2. 发明申请

WO2011115669A3 LOW TEMPERATURE CURING POLYURETDIONE COMPOSITIONS 审中-公开
标题翻译：低温固化聚氨酯组合物
公开(公告)号：WO2011115669A3
公开(公告)日：2012-01-05
申请号：PCT/US2011000473
申请日：2011-03-15
申请人： BAYER MATERIALSCIENCE LLC , BAYER MATERIALSCIENCE AG , PPG INDUSTRIES INC , SHAFFER MYRON W , EKIN ABDULLAH , KINNEY CAROL L , GRESZLA-FRANZ DOROTA , MARTZ JONATHAN T , DENG JUN , HAYES DEBORAH E , THOMAS STEPHEN J
发明人： SHAFFER MYRON W , EKIN ABDULLAH , KINNEY CAROL L , GRESZLA-FRANZ DOROTA , MARTZ JONATHAN T , DENG JUN , HAYES DEBORAH E , THOMAS STEPHEN J
IPC分类号： C09D175/04 , C08G18/72 , C08J7/04 , C09D7/12
CPC分类号： C09D175/14 , C08G18/10 , C08G18/168 , C08G18/1883 , C08G18/2027 , C08G18/2063 , C08G18/244 , C08G18/42 , C08G18/44 , C08G18/6225 , C08G18/798
摘要： Composition and process for low temperature curing of polyuretdione-polyol compositions in which the polyuretdione is prepared from a polyisocyanate with isocyanate groups and a polyol containing primary hydroxyl groups. The catalyst for the composition and process is an amine catalyst containing the group -N=C-N-, being aprotic, having a pKa greater than 20 and upon addition to the liquid coating composition causing a phase-change of the coating composition from liquid to solid at 250C and 1atm. within one week.
摘要翻译：聚脲二醇 - 多元醇组合物的低温固化的组合物和方法，其中聚脲二酮由具有异氰酸酯基团的多异氰酸酯和含有伯羟基的多元醇制备。用于组合物和方法的催化剂是含有非对质子基团-N = CN-的胺催化剂，其具有大于20的pKa，并且当添加到液体涂料组合物时导致涂料组合物从液体到固体的相变在25℃和1atm。一周内。

3. 发明申请

WO2012100024A2 NON-AQUEOUS POLYURETHANE COATING COMPOSITIONS 审中-公开
标题翻译：非水性聚氨酯涂料组合物
公开(公告)号：WO2012100024A2
公开(公告)日：2012-07-26
申请号：PCT/US2012021832
申请日：2012-01-19
申请人： BAYER MATERIALSCIENCE LLC , BAYER MATERIALSCIENCE AG , SUBRAMANIAN RAMESH , EKIN ABDULLAH , KINNEY CAROL L , MEBANE CHRISTINE , FISCHER WOLFGANG , KUCZEWSKI HELMUT
发明人： SUBRAMANIAN RAMESH , EKIN ABDULLAH , KINNEY CAROL L , MEBANE CHRISTINE , FISCHER WOLFGANG , KUCZEWSKI HELMUT
IPC分类号： C09D175/04 , C03C17/32 , C09D4/02
CPC分类号： C03C17/322 , C03C17/005 , C08G18/672 , C09D4/06 , Y10T428/1321 , Y10T428/31601
摘要： The present invention relates to a non-aqueous coating composition comprising: 1) 75 to 99 wt.%, preferably 85 to 95 wt.% of a hard urethane (meth) acrylate polymer or oligomer; and 2) 1 to 25 wt.%, preferably 5 to 15 wt% of a soft unsaturated ucethane (meth) acrylai.e polymer or oligomer containing allophanate groups.
摘要翻译：本发明涉及一种非水性涂料组合物，其包含：1）75至99重量％，优选85至95重量％的硬氨基甲酸酯（甲基）丙烯酸酯聚合物或低聚物; 和2）1-25重量％，优选5-15重量％的含有脲基甲酸酯基团的软不饱和聚氨酯（甲基）丙烯酸酯聚合物或低聚物。

4. 发明申请

WO2009067185A3 AQUEOUS, STAIN-RESISTANT COATING COMPOSITIONS 审中-公开
标题翻译：水性，防污涂料组合物
公开(公告)号：WO2009067185A3
公开(公告)日：2009-07-09
申请号：PCT/US2008012858
申请日：2008-11-17
申请人： BAYER MATERIALSCIENCE LLC , WYLIE AMY S , KINNEY CAROL L , ROESLER RICHARD R , ERITANO RONALD G
发明人： WYLIE AMY S , KINNEY CAROL L , ROESLER RICHARD R , ERITANO RONALD G
IPC分类号： C09D175/04
CPC分类号： C08G18/2885 , C08G18/0823 , C08G18/12 , C08G18/283 , C08G18/6659 , C08G18/722 , C08G18/792 , C08G18/8087 , C09D175/04 , C08G18/3275
摘要： The present invention is directed to an aqueous coating composition comprising the reaction product of a hydrophobic, fluorine functional polyisocyanate and an aqueous hydroxy-functional polyisocyanate. The present invention is also directed to a process for the production of this aqueous coating composition.
摘要翻译：本发明涉及包含疏水氟官能多异氰酸酯和含水羟基官能多异氰酸酯的反应产物的含水涂料组合物。本发明还涉及生产这种水性涂料组合物的方法。

5. 发明申请

WO2007061663A8 LOW SURFACE ENERGY, ETHYLENICALLY UNSATURATED POLYISOCYANATE ADDITION COMPOUNDS AND THEIR USE IN COATING COMPOSITIONS 审中-公开
标题翻译：低表面能，乙烯基不饱和聚异氰酸酯添加剂及其在涂料组合物中的用途
公开(公告)号：WO2007061663A8
公开(公告)日：2008-08-21
申请号：PCT/US2006043977
申请日：2006-11-13
申请人： BAYER MATERIALSCIENCE LLC , ROESLER RICHARD R , GARRETT JAMES T , LOCKHART AARON , KINNEY CAROL L
发明人： ROESLER RICHARD R , GARRETT JAMES T , LOCKHART AARON , KINNEY CAROL L
IPC分类号： C08G18/28 , C08G18/78 , C09D175/04
CPC分类号： C08G18/289 , C08G18/6725 , C08G18/792 , C08G18/8175 , C09D175/16
摘要： The present invention is directed to polyisocyanate addition compounds which i) are substantially free from isocyanate groups and are prepared from one or more a) polyisocyanate adducts containing isocyanurate, uretdione, biuret, allophanate, iminooxadiazine dione carbodiimide and/or oxadiazinetrione groups and/or b) NCO prepolymers, ii) contain urethane groups, iii) contain siloxane groups (calculated as SiO, MW44) in an amount of 0.002 to 50% by weight, and iv) contain ethylenically unsaturated groups (calculated as C=C, MW 24) in an amount of 2 to 40% by weight, wherein the preceding percentages are based on the solids content of the polyisocyanate addition compounds and wherein the siloxane groups are incorporated by reacting an isocyanate group with a compound containing one or more hydroxyl groups directly attached to a carbon atom and one or more siloxane groups to form urethane groups and optionally aliophanate groups, provided that more than 50 mole % of the groups that chemically incorporate siloxane groups into the polyisocyanate addition compounds are urethane groups. The present invention also relates to the use of the polyisocyanate addition compounds in coating compositions curable by free radical polymerization.
摘要翻译：本发明涉及多异氰酸酯加成化合物，其i）基本上不含异氰酸酯基团，并且由一种或多种a）多异氰酸酯加合物制备，所述多异氰酸酯加合物含有异氰脲酸酯，脲二酮，缩二脲，脲基甲酸酯，亚氨基恶二嗪二酮碳二亚胺和/或恶二嗪二酮基团和/或b ）NCO预聚物，ii）含有氨基甲酸酯基团，iii）含有0.002至50重量％的硅氧烷基团（以SiO，MW44计），和iv）含有烯键式不饱和基团（按C = C，MW 24计算）其量为2至40重量％，其中前述百分比基于多异氰酸酯加成化合物的固体含量，并且其中硅氧烷基团通过使异氰酸酯基团与含有一个或多个羟基的化合物反应而引入，所述羟基直接连接到碳原子和一个或多个硅氧烷基团以形成氨基甲酸酯基团和任选的阿片剂基团，条件是超过50摩尔％的化学将硅氧烷基团结合到多异氰酸酯加成化合物中是氨基甲酸酯基团。本发明还涉及多异氰酸酯加成化合物在通过自由基聚合可固化的涂料组合物中的用途。

6. 发明申请

WO2007092459A3 POLYURETHANE ELASTOMERS COMPRISING ALLOPHANATE MODIFIED ISOCYANATES 审中-公开
标题翻译：包含异丙醇改性异氰酸酯的聚氨酯弹性体
公开(公告)号：WO2007092459A3
公开(公告)日：2008-08-28
申请号：PCT/US2007003175
申请日：2007-02-05
申请人： BAYER MATERIALSCIENCE LLC , HARASIN STEPHEN J , ROESLER RICHARD R , STARCHER RICK V , KINNEY CAROL L , GARRETT JAMES
发明人： HARASIN STEPHEN J , ROESLER RICHARD R , STARCHER RICK V , KINNEY CAROL L , GARRETT JAMES
IPC分类号： C08G18/78 , C08G18/20 , C08G18/28 , C08G18/66 , C08G18/80
CPC分类号： C08G18/7837 , C08G18/165 , C08G18/2063 , C08G18/6674 , C08G18/8025 , C08G2120/00
摘要： This invention relates to polyurethane elastomers and to a process for their production. These elastomers comprise the reaction product of a polyisocyanate component comprising an allophanate modified (cyclo)aliphatic polyisocyanate which has an NCO group content of about 15 to about 35% or a prepolymer thereof, with an isocyanate-reactive component comprising one or more polyether polyols which is free of amine groups, and a low molecular weight organic compound containing two hydroxyl groups and which is free of amine groups, in the presence of one or more catalysts.
摘要翻译：本发明涉及聚氨酯弹性体及其生产方法。这些弹性体包含包含NCO基团含量为约15至约35％的脲基甲酸酯改性（环）脂族多异氰酸酯或其预聚物的多异氰酸酯组分与包含一种或多种聚醚多元醇的异氰酸酯反应性组分的多异氰酸酯组分的反应产物，在一种或多种催化剂的存在下，不含胺基团和含有两个羟基并且不含胺基团的低分子量有机化合物。

7. 发明申请

WO2007059011A8 LOW SURFACE ENERGY, ETHYLENICALLY UNSATURATED POLYISOCYANATE ADDITION COMPOUNDS AND THEIR USE IN COATING COMPOSITIONS 审中-公开
标题翻译：低表面能，乙烯基不饱和聚异氰酸酯添加剂及其在涂料组合物中的用途
公开(公告)号：WO2007059011A8
公开(公告)日：2008-07-31
申请号：PCT/US2006043939
申请日：2006-11-13
申请人： BAYER MATERIALSCIENCE LLC , KINNEY CAROL L , ROESLER RICHARD R , GARRETT JAMES T , LOCKHART AARON
发明人： KINNEY CAROL L , ROESLER RICHARD R , GARRETT JAMES T , LOCKHART AARON
IPC分类号： C08G18/28 , C08G18/67 , C08G18/79 , C09D175/16
CPC分类号： C08G18/2885 , C08G18/672 , C08G18/791 , C08G18/798 , C09D175/16
摘要： The present invention is directed to polyisocyanate addition compounds which i) are substantially free from isocyanate groups and are prepared from one or more a) polyisocyanate adducts containing uretdione, biuret, allophanate, carbodiimide and/or oxadiazinetrione groups and/or b) NCO prepolymers, ii) contain urethane groups, iii) . contain fluorine (calculated as F1 AW 19) in an amount of 0.01 to 50% by weight, and iv) contain ethylenically unsaturated groups (calculated as C=C, MW 24) in an amount of 2 to 40% by weight, wherein the preceding percentages are based on the solids content of the polyisocyanate addition compounds and wherein fluorine is incorporated by reacting an isocyanate group with a compound containing two or more carbon atoms, one or more hydroxyl groups and one or more fluorine atoms to form urethane groups and optionally allophanate groups, provided that more than 50 mole % of the groups that chemically incorporate fluorine into the polyisocyanate addition compounds are urethane groups. The present invention also relates to the use of the polyisocyanate addition compounds in coating compositions curable by free radical polymerization.
摘要翻译：本发明涉及i）基本上不含异氰酸酯基并且由一种或多种a）含有脲二酮，缩二脲，脲基甲酸酯，碳二亚胺和/或恶二嗪二酮基团的多异氰酸酯加合物和/或b）NCO预聚物制备的多异氰酸酯加成化合物， ii）含有氨基甲酸酯基团，iii）。含有0.01〜50重量％的氟（按F1 AW 19计算），和iv）含有2〜40重量％的烯键式不饱和基团（按C = C，MW 24计算），其中，前述百分比基于多异氰酸酯加成化合物的固体含量，其中通过使异氰酸酯基团与含有两个或更多个碳原子，一个或多个羟基和一个或多个氟原子的化合物反应形成氟以形成氨基甲酸酯基团和任选地脲基甲酸酯基团，只要将多于50摩尔％的将氟化学并入多异氰酸酯加成化合物的基团是氨基甲酸酯基团即可。本发明还涉及多异氰酸酯加成化合物在通过自由基聚合可固化的涂料组合物中的用途。

8. 发明申请

WO2007061663A2 LOW SURFACE ENERGY, ETHYLENICALLY UNSATURATED POLYISOCYANATE ADDITION COMPOUNDS AND THEIR USE IN COATING COMPOSITIONS 审中-公开
标题翻译：低表面能，乙烯基不饱和聚异氰酸酯添加剂及其在涂料组合物中的用途
公开(公告)号：WO2007061663A2
公开(公告)日：2007-05-31
申请号：PCT/US2006043977
申请日：2006-11-13
申请人： BAYER MATERIALSIENCE LLC , ROESLER RICHARD R , GARRETT JAMES T , LOCKHART AARON , KINNEY CAROL L
发明人： ROESLER RICHARD R , GARRETT JAMES T , LOCKHART AARON , KINNEY CAROL L
IPC分类号： C08G18/28 , C08G18/78 , C09D175/04
CPC分类号： C08G18/289 , C08G18/6725 , C08G18/792 , C08G18/8175 , C09D175/16
摘要： The present invention is directed to polyisocyanate addition compounds which i) are substantially free from isocyanate groups and are prepared from one or more a) polyisocyanate adducts containing isocyanurate, uretdione, biuret, allophanate, iminooxadiazine dione carbodiimide and/or oxadiazinetrione groups and/or b) NCO prepolymers, ii) contain urethane groups, iii) contain siloxane groups (calculated as SiO, MW44) in an amount of 0.002 to 50% by weight, and iv) contain ethylenically unsaturated groups (calculated as C=C, MW 24) in an amount of 2 to 40% by weight, wherein the preceding percentages are based on the solids content of the polyisocyanate addition compounds and wherein the siloxane groups are incorporated by reacting an isocyanate group with a compound containing one or more hydroxyl groups directly attached to a carbon atom and one or more siloxane groups to form urethane groups and optionally aliophanate groups, provided that more than 50 mole % of the groups that chemically incorporate siloxane groups into the polyisocyanate addition compounds are urethane groups. The present invention also relates to the use of the polyisocyanate addition compounds in coating compositions curable by free radical polymerization.
摘要翻译：本发明涉及多异氰酸酯加成化合物，其i）基本上不含异氰酸酯基团，并且由一种或多种a）多异氰酸酯加合物制备，所述多异氰酸酯加合物含有异氰脲酸酯，脲二酮，缩二脲，脲基甲酸酯，亚氨基恶二嗪二酮碳二亚胺和/或恶二嗪二酮基团和/或b ）NCO预聚物，ii）含有氨基甲酸酯基团，iii）含有0.002至50重量％的硅氧烷基团（以SiO，MW44计），和iv）含有烯键式不饱和基团（按C = C，MW 24计算）其量为2至40重量％，其中前述百分比基于多异氰酸酯加成化合物的固体含量，并且其中硅氧烷基团通过使异氰酸酯基团与含有一个或多个羟基的化合物反应而引入，所述羟基直接连接到碳原子和一个或多个硅氧烷基团以形成氨基甲酸酯基团和任选的阿片剂基团，条件是超过50摩尔％的化学将硅氧烷基团结合到多异氰酸酯加成化合物中是氨基甲酸酯基团。本发明还涉及多异氰酸酯加成化合物在通过自由基聚合可固化的涂料组合物中的用途。

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