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1. 发明申请

WO2007061663A2 LOW SURFACE ENERGY, ETHYLENICALLY UNSATURATED POLYISOCYANATE ADDITION COMPOUNDS AND THEIR USE IN COATING COMPOSITIONS 审中-公开
标题翻译：低表面能，乙烯基不饱和聚异氰酸酯添加剂及其在涂料组合物中的用途
公开(公告)号：WO2007061663A2
公开(公告)日：2007-05-31
申请号：PCT/US2006043977
申请日：2006-11-13
申请人： BAYER MATERIALSIENCE LLC , ROESLER RICHARD R , GARRETT JAMES T , LOCKHART AARON , KINNEY CAROL L
发明人： ROESLER RICHARD R , GARRETT JAMES T , LOCKHART AARON , KINNEY CAROL L
IPC分类号： C08G18/28 , C08G18/78 , C09D175/04
CPC分类号： C08G18/289 , C08G18/6725 , C08G18/792 , C08G18/8175 , C09D175/16
摘要： The present invention is directed to polyisocyanate addition compounds which i) are substantially free from isocyanate groups and are prepared from one or more a) polyisocyanate adducts containing isocyanurate, uretdione, biuret, allophanate, iminooxadiazine dione carbodiimide and/or oxadiazinetrione groups and/or b) NCO prepolymers, ii) contain urethane groups, iii) contain siloxane groups (calculated as SiO, MW44) in an amount of 0.002 to 50% by weight, and iv) contain ethylenically unsaturated groups (calculated as C=C, MW 24) in an amount of 2 to 40% by weight, wherein the preceding percentages are based on the solids content of the polyisocyanate addition compounds and wherein the siloxane groups are incorporated by reacting an isocyanate group with a compound containing one or more hydroxyl groups directly attached to a carbon atom and one or more siloxane groups to form urethane groups and optionally aliophanate groups, provided that more than 50 mole % of the groups that chemically incorporate siloxane groups into the polyisocyanate addition compounds are urethane groups. The present invention also relates to the use of the polyisocyanate addition compounds in coating compositions curable by free radical polymerization.
摘要翻译：本发明涉及多异氰酸酯加成化合物，其i）基本上不含异氰酸酯基团，并且由一种或多种a）多异氰酸酯加合物制备，所述多异氰酸酯加合物含有异氰脲酸酯，脲二酮，缩二脲，脲基甲酸酯，亚氨基恶二嗪二酮碳二亚胺和/或恶二嗪二酮基团和/或b ）NCO预聚物，ii）含有氨基甲酸酯基团，iii）含有0.002至50重量％的硅氧烷基团（以SiO，MW44计），和iv）含有烯键式不饱和基团（按C = C，MW 24计算）其量为2至40重量％，其中前述百分比基于多异氰酸酯加成化合物的固体含量，并且其中硅氧烷基团通过使异氰酸酯基团与含有一个或多个羟基的化合物反应而引入，所述羟基直接连接到碳原子和一个或多个硅氧烷基团以形成氨基甲酸酯基团和任选的阿片剂基团，条件是超过50摩尔％的化学将硅氧烷基团结合到多异氰酸酯加成化合物中是氨基甲酸酯基团。本发明还涉及多异氰酸酯加成化合物在通过自由基聚合可固化的涂料组合物中的用途。

2. 发明申请

WO2007061663A8 LOW SURFACE ENERGY, ETHYLENICALLY UNSATURATED POLYISOCYANATE ADDITION COMPOUNDS AND THEIR USE IN COATING COMPOSITIONS 审中-公开
标题翻译：低表面能，乙烯基不饱和聚异氰酸酯添加剂及其在涂料组合物中的用途
公开(公告)号：WO2007061663A8
公开(公告)日：2008-08-21
申请号：PCT/US2006043977
申请日：2006-11-13
申请人： BAYER MATERIALSCIENCE LLC , ROESLER RICHARD R , GARRETT JAMES T , LOCKHART AARON , KINNEY CAROL L
发明人： ROESLER RICHARD R , GARRETT JAMES T , LOCKHART AARON , KINNEY CAROL L
IPC分类号： C08G18/28 , C08G18/78 , C09D175/04
CPC分类号： C08G18/289 , C08G18/6725 , C08G18/792 , C08G18/8175 , C09D175/16
摘要： The present invention is directed to polyisocyanate addition compounds which i) are substantially free from isocyanate groups and are prepared from one or more a) polyisocyanate adducts containing isocyanurate, uretdione, biuret, allophanate, iminooxadiazine dione carbodiimide and/or oxadiazinetrione groups and/or b) NCO prepolymers, ii) contain urethane groups, iii) contain siloxane groups (calculated as SiO, MW44) in an amount of 0.002 to 50% by weight, and iv) contain ethylenically unsaturated groups (calculated as C=C, MW 24) in an amount of 2 to 40% by weight, wherein the preceding percentages are based on the solids content of the polyisocyanate addition compounds and wherein the siloxane groups are incorporated by reacting an isocyanate group with a compound containing one or more hydroxyl groups directly attached to a carbon atom and one or more siloxane groups to form urethane groups and optionally aliophanate groups, provided that more than 50 mole % of the groups that chemically incorporate siloxane groups into the polyisocyanate addition compounds are urethane groups. The present invention also relates to the use of the polyisocyanate addition compounds in coating compositions curable by free radical polymerization.
摘要翻译：本发明涉及多异氰酸酯加成化合物，其i）基本上不含异氰酸酯基团，并且由一种或多种a）多异氰酸酯加合物制备，所述多异氰酸酯加合物含有异氰脲酸酯，脲二酮，缩二脲，脲基甲酸酯，亚氨基恶二嗪二酮碳二亚胺和/或恶二嗪二酮基团和/或b ）NCO预聚物，ii）含有氨基甲酸酯基团，iii）含有0.002至50重量％的硅氧烷基团（以SiO，MW44计），和iv）含有烯键式不饱和基团（按C = C，MW 24计算）其量为2至40重量％，其中前述百分比基于多异氰酸酯加成化合物的固体含量，并且其中硅氧烷基团通过使异氰酸酯基团与含有一个或多个羟基的化合物反应而引入，所述羟基直接连接到碳原子和一个或多个硅氧烷基团以形成氨基甲酸酯基团和任选的阿片剂基团，条件是超过50摩尔％的化学将硅氧烷基团结合到多异氰酸酯加成化合物中是氨基甲酸酯基团。本发明还涉及多异氰酸酯加成化合物在通过自由基聚合可固化的涂料组合物中的用途。

3. 发明申请

WO2007059011A8 LOW SURFACE ENERGY, ETHYLENICALLY UNSATURATED POLYISOCYANATE ADDITION COMPOUNDS AND THEIR USE IN COATING COMPOSITIONS 审中-公开
标题翻译：低表面能，乙烯基不饱和聚异氰酸酯添加剂及其在涂料组合物中的用途
公开(公告)号：WO2007059011A8
公开(公告)日：2008-07-31
申请号：PCT/US2006043939
申请日：2006-11-13
申请人： BAYER MATERIALSCIENCE LLC , KINNEY CAROL L , ROESLER RICHARD R , GARRETT JAMES T , LOCKHART AARON
发明人： KINNEY CAROL L , ROESLER RICHARD R , GARRETT JAMES T , LOCKHART AARON
IPC分类号： C08G18/28 , C08G18/67 , C08G18/79 , C09D175/16
CPC分类号： C08G18/2885 , C08G18/672 , C08G18/791 , C08G18/798 , C09D175/16
摘要： The present invention is directed to polyisocyanate addition compounds which i) are substantially free from isocyanate groups and are prepared from one or more a) polyisocyanate adducts containing uretdione, biuret, allophanate, carbodiimide and/or oxadiazinetrione groups and/or b) NCO prepolymers, ii) contain urethane groups, iii) . contain fluorine (calculated as F1 AW 19) in an amount of 0.01 to 50% by weight, and iv) contain ethylenically unsaturated groups (calculated as C=C, MW 24) in an amount of 2 to 40% by weight, wherein the preceding percentages are based on the solids content of the polyisocyanate addition compounds and wherein fluorine is incorporated by reacting an isocyanate group with a compound containing two or more carbon atoms, one or more hydroxyl groups and one or more fluorine atoms to form urethane groups and optionally allophanate groups, provided that more than 50 mole % of the groups that chemically incorporate fluorine into the polyisocyanate addition compounds are urethane groups. The present invention also relates to the use of the polyisocyanate addition compounds in coating compositions curable by free radical polymerization.
摘要翻译：本发明涉及i）基本上不含异氰酸酯基并且由一种或多种a）含有脲二酮，缩二脲，脲基甲酸酯，碳二亚胺和/或恶二嗪二酮基团的多异氰酸酯加合物和/或b）NCO预聚物制备的多异氰酸酯加成化合物， ii）含有氨基甲酸酯基团，iii）。含有0.01〜50重量％的氟（按F1 AW 19计算），和iv）含有2〜40重量％的烯键式不饱和基团（按C = C，MW 24计算），其中，前述百分比基于多异氰酸酯加成化合物的固体含量，其中通过使异氰酸酯基团与含有两个或更多个碳原子，一个或多个羟基和一个或多个氟原子的化合物反应形成氟以形成氨基甲酸酯基团和任选地脲基甲酸酯基团，只要将多于50摩尔％的将氟化学并入多异氰酸酯加成化合物的基团是氨基甲酸酯基团即可。本发明还涉及多异氰酸酯加成化合物在通过自由基聚合可固化的涂料组合物中的用途。

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